ASTM E1775-07(2016)

Standard Guide for Evaluating Performance of On-Site Extraction and Field-Portable Electrochemical or Spectrophotometric Analysis for Lead

SIGNIFICANCE AND USE
4.1 This guide is intended for use in evaluating the performance of field-portable electroanalytical or spectrophotometric devices for lead determination, or both.  
4.2 Desired performance criteria for field-based extraction procedures are provided.  
4.3 Performance parameters of concern may be determined using protocols that are referenced in this guide.  
4.4 Example reference materials to be used in assessing the performance of field-portable lead analyzers are listed.  
4.5 Exhaustive details regarding quality assurance issues are outside the scope of this guide. Applicable quality assurance aspects are dealt with extensively in references that are cited in this guide.
SCOPE
1.1 This guide provides guidelines for determining the performance of field-portable quantitative lead analysis instruments.  
1.2 This guide applies to field-portable electroanalytical and spectrophotometric (including reflectance and colorimetric) analyzers.  
1.3 Sample matrices of concern herein include paint, dust, soil, and airborne particles.  
1.4 This guide addresses the desired performance characteristics of field-based sample extraction procedures for lead, as well as on-site extraction followed by field-portable analysis.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 31-Dec-2015
• ICS: 71.040.50 - Physicochemical methods of analysis
• Technical Committee: E06 - Performance of Buildings

Relations

• Replaces: ASTM E1775-07 - Standard Guide for Evaluating Performance of On-Site Extraction and Field-Portable Electrochemical or Spectrophotometric Analysis for Lead
• Effective Date: 01-Jan-2016
• Referred By: ASTM E1979-21 - Standard Practice for Ultrasonic Extraction of Paint, Dust, Soil, and Air Samples for Subsequent Determination of Lead
• Effective Date: 01-Jan-2016
• Referred By: ASTM E631-15 - Standard Terminology of Building Constructions
• Effective Date: 01-Jan-2016

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E1775 − 07(Reapproved 2016)
Standard Guide for
Evaluating Performance of On-Site Extraction and Field-
Portable Electrochemical or Spectrophotometric Analysis
for Lead
This standard is issued under the fixed designation E1775; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Coupled Plasma Atomic Emission Spectrometry (ICP-
AES)
1.1 This guide provides guidelines for determining the
D7144 Practice for Collection of Surface Dust by Micro-
performance of field-portable quantitative lead analysis instru-
vacuum Sampling for Subsequent Metals Determination
ments.
E1605 Terminology Relating to Lead in Buildings
1.2 This guide applies to field-portable electroanalytical and
E1613 Test Method for Determination of Lead by Induc-
spectrophotometric (including reflectance and colorimetric)
tively Coupled Plasma Atomic Emission Spectrometry
analyzers.
(ICP-AES), Flame Atomic Absorption Spectrometry
1.3 Sample matrices of concern herein include paint, dust, (FAAS), or Graphite Furnace Atomic Absorption Spec-
trometry (GFAAS) Techniques
soil, and airborne particles.
E1644 Practice for Hot Plate Digestion of Dust Wipe
1.4 This guide addresses the desired performance character-
Samples for the Determination of Lead
istics of field-based sample extraction procedures for lead, as
E1645 Practice for Preparation of Dried Paint Samples by
well as on-site extraction followed by field-portable analysis.
Hotplate or Microwave Digestion for Subsequent Lead
1.5 This standard does not purport to address all of the
Analysis
safety concerns, if any, associated with its use. It is the
E1726 Practice for Preparation of Soil Samples by Hotplate
responsibility of the user of this standard to establish appro-
Digestion for Subsequent Lead Analysis
priate safety and health practices and determine the applica-
E1727 Practice for Field Collection of Soil Samples for
bility of regulatory limitations prior to use.
Subsequent Lead Determination (Withdrawn 2014)
E1729 Practice for Field Collection of Dried Paint Samples
2. Referenced Documents
for Subsequent Lead Determination (Withdrawn 2014)
2.1 ASTM Standards:
E1792 Specification for Wipe Sampling Materials for Lead
D5438 Practice for Collection of Floor Dust for Chemical
in Surface Dust
Analysis
E1864 Practice for Evaluating Quality Systems of Organi-
D6785 TestMethodforDeterminationofLeadinWorkplace
zations Conducting Facility and Hazard Assessments for
Air Using Flame or Graphite Furnace Atomic Absorption
Lead in Paint, Dust, Airborne Particulate, and Soil in and
Spectrometry
around Buildings and Related Structures (Withdrawn
D6966 Practice for Collection of Settled Dust Samples
2011)
Using Wipe Sampling Methods for Subsequent Determi-
2.2 U.S. EPA Documents:
nation of Metals
EPA 600/R-93/200 Standard Operating Procedure for the
D7035 Test Method for Determination of Metals and Met-
Field Analysis of Lead in Paint, Bulk Dust, and Soil by
alloids in Airborne Particulate Matter by Inductively
Ultrasonic,AcidDigestionandColorimetricMeasurement
(1993)
1 EPA 747-R-92-001 Laboratory Accreditation Guidelines:
This guide is under the jurisdiction of ASTM Committee E06 on Performance
of Buildings and is the direct responsibility of Subcommittee E06.23 on Lead Measurement of Lead in Paint, Dust, and Soil (1992)
Hazards Associated with Buildings.
Current edition approved Jan. 1, 2016. Published January 2016. Originally
approved in 1996. Last previous edition approved in 2007 as E1775 – 07. DOI:
10.1520/E1775-07R16. The last approved version of this historical standard is referenced on
For referenced ASTM standards, visit the ASTM website, www.astm.org, or www.astm.org.
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM AvailablefromUnitedStatesEnvironmentalProtectionAgency(EPA),William
Standards volume information, refer to the standard’s Document Summary page on Jefferson Clinton Bldg., 1200 Pennsylvania Ave., NW, Washington, DC 20460,
the ASTM website. http://www.epa.gov.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
E1775 − 07 (2016)
3. Terminology 5.1.1 Paint—Examples are NIST paint SRMs, for example,
NIST SRMs 2582, 2583, and numerous other CRMs.
3.1 For definitions of terms not listed here, seeTerminology
5.1.2 Dust—Examples are NIST 1648 (urban particulate
E1605.
matter), other NIST dust SRMs, and other CRMs.
3.2 anodic stripping voltammetry—an electroanalytical
5.1.3 Soil—Examples are NIST 2704 (river sediment) and
technique in which the concentration of analyte metal species
NIST soil standards: SRMs 2709, 2710, and 2711 and numer-
dissolved in solution is determined in the following manner:
ous other CRMs.
The analyte is first deposited (preconcentrated) electrochemi-
5.1.4 Airborne Particulate Matter—An example is NIST
cally by reducing the dissolved ion in solution to immobilized
SRM 2783, which is available for airborne particulate matter
metal species at an electrode surface (such as mercury or
collected on filters. Other CRMs are also available.
bismuth). The metal is deposited at an applied potential
5.2 Real-World Materials:
(voltage) which is negative of the standard oxidation potential
5.2.1 Paint, collected using Practice E1729 (or equivalent).
for the metal/ion redox couple. After deposition, the precon-
To obtain reference values, determine lead concentration using
centrated metal species is then stripped from the electrode by
Test Method E1613 and Practice E1645 (or equivalent).
applying a positive potential sweep, which causes anodic
5.2.2 Dust Wipes, collected using Practice D6966, with
oxidation of the analyte metal species to dissolved ion. The
wipes meeting the requirements of Specification E1792.To
current associated with this reoxidation is measured. The peak
obtain reference values, determine lead concentration using
current is proportional to the original concentration of dis-
Test Method E1613 and Practice E1644 (or equivalent).
solved analyte species over a wide range of concentrations.
5.2.3 Vacuumed Dust, collected using Practices D7144 or
3.3 colorimetry—an analytical technique that is similar to D5438. To obtain reference values, determine lead concentra-
spectrophotometry (see 3.5), except that ultraviolet-visible
tion using Test Method E1613 and Practice E1726 (or equiva-
light of a single, narrow wav
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E1775 − 07 E1775 − 07 (Reapproved 2016)
Standard Guide for
Evaluating Performance of On-Site Extraction and Field-
Portable Electrochemical or Spectrophotometric Analysis
for Lead
This standard is issued under the fixed designation E1775; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This standardguide provides guidelines for determining the performance of field-portable quantitative lead analysis
instruments.
1.2 This guide applies to field-portable electroanalytical and spectrophotometric (including reflectance and colorimetric)
analyzers.
1.3 Sample matrices of concern herein include paint, dust, soil, and airborne particles.
1.4 This guide addresses the desired performance characteristics of field-based sample extraction procedures for lead, as well
as on-site extraction followed by field-portable analysis.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
D5438 Practice for Collection of Floor Dust for Chemical Analysis
D6785 Test Method for Determination of Lead in Workplace Air Using Flame or Graphite Furnace Atomic Absorption
Spectrometry
D6966 Practice for Collection of Settled Dust Samples Using Wipe Sampling Methods for Subsequent Determination of Metals
D7035 Test Method for Determination of Metals and Metalloids in Airborne Particulate Matter by Inductively Coupled Plasma
Atomic Emission Spectrometry (ICP-AES)
D7144 Practice for Collection of Surface Dust by Micro-vacuum Sampling for Subsequent Metals Determination
E1605 Terminology Relating to Lead in Buildings
E1613 Test Method for Determination of Lead by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES),
Flame Atomic Absorption Spectrometry (FAAS), or Graphite Furnace Atomic Absorption Spectrometry (GFAAS) Techniques
E1644 Practice for Hot Plate Digestion of Dust Wipe Samples for the Determination of Lead
E1645 Practice for Preparation of Dried Paint Samples by Hotplate or Microwave Digestion for Subsequent Lead Analysis
E1726 Practice for Preparation of Soil Samples by Hotplate Digestion for Subsequent Lead Analysis
E1727 Practice for Field Collection of Soil Samples for Subsequent Lead Determination (Withdrawn 2014)
E1729 Practice for Field Collection of Dried Paint Samples for Subsequent Lead Determination (Withdrawn 2014)
E1792 Specification for Wipe Sampling Materials for Lead in Surface Dust
E1864 Practice for Evaluating Quality Systems of Organizations Conducting Facility and Hazard Assessments for Lead in Paint,
Dust, Airborne Particulate, and Soil in and around Buildings and Related Structures (Withdrawn 2011)
This guide is under the jurisdiction of ASTM Committee E06 on Performance of Buildings and is the direct responsibility of Subcommittee E06.23 on Lead Hazards
Associated with Buildings.
Current edition approved Aug. 1, 2007Jan. 1, 2016. Published August 2007January 2016. Originally approved in 1996. Last previous edition approved in 20012007 as
E1775 – 01.E1775 – 07. DOI: 10.1520/E1775-07.10.1520/E1775-07R16.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
The last approved version of this historical standard is referenced on www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
E1775 − 07 (2016)
2.2 U.S. EPA Documents:
EPA 600/R-93/200 Standard Operating Procedure for the Field Analysis of Lead in Paint, Bulk Dust, and Soil by Ultrasonic,
Acid Digestion and Colorimetric Measurement (1993)
EPA 747-R-92-001 Laboratory Accreditation Guidelines: Measurement of Lead in Paint, Dust, and Soil (1992)
3. Terminology
3.1 For definitions of terms not listed here, see Terminology E1605.
3.2 anodic stripping voltammetry—an electroanalytical technique in which the concentration of analyte metal species dissolved
in solution is determined in the following manner: The analyte is first deposited (preconcentrated) electrochemically by reducing
the dissolved ion in solution to immobilized metal species at an electrode surface (such as mercury or bismuth). The metal is
deposited at an applied potential (voltage) which is negative of the standard oxidation potential for the metal/ion redox couple.
After deposition, the preconcentrated metal species is then stripped from the electrode by applying a positive potential sweep,
which causes anodic oxidation of the analyte metal species to dissolved ion. The current associated with this reoxidation is
measured. The peak current is proportional to the original concentration of dissolved analyte species over a wide range of
concentrations.
3.3 colorimetry—an analytical technique that is similar to spectrophotometry (see 3.5), except that ultraviolet-visible light of a
single, narrow wavelength range is passed through a sample cell containing dissolved analyte, and the absorption measured.
3.4 reflectance—a measurement technique (subset of spectrophotometry; see 3.5) in which light is reflected off of a reflecting
surface and measured by a detector. The amount of reflected light may be a function of analyte concentration.
3.5 spectrophotometry—an analytical technique in which a spectrum of analyte species is obtained and used to determine the
analyte concentration in the following manner. Light is directed onto or through analyte species, and the absorption of this light
across a range of wavelengths is measured by a detector. The amount of absorbed light is a function of the concentration of analyte
species.
4. Significance and Use
4.1 This guide is intended for use in evaluating the performance of field-portable electroanalytical or spectrophotometric
devices for lead determination, or both.
4.2 Desired performance criteria for field-based extraction procedures are provided.
4.3 Performance parameters of concern may be determined using protocols that are referenced in this guide.
4.4 Example reference materials to be used in assessing the performance of field-portable lead analyzers are listed.
4.5 Exhaustive details regarding quality assurance issues are outside the scope of this guide. Applicable q
...