Standard Specification for Phosphorized Coppers—Refinery Shapes

ABSTRACT
This specification establishes the requirements for phosphorized copper in refinery shapes such as wire bars, billets, and cakes. The product furnished shall be produced from one of the following copper UNS Nos.: C10300, C10800, C12000, C12200, and C14200. Billets shall be supplied sheared on one end with the other end flat or with both ends flat depending on the specified diameter. The product shall conform to the chemical composition requirements prescribed for copper and silver, phosphorus, and arsenic. The electrical mass resistivity for phosphorized copper in annealed condition is specified. The requirements for chemical analysis, reverse bend test (hydrogen embrittlement susceptibility), and microscopical examination are detailed including sampling and specimen preparation.
SCOPE
1.1 This specification establishes the requirements for phosphorized copper wire bars, billets, and cakes.  
Note 1—Wire bars furnished under this specification do not conform in dimensions with that furnished under Specification B5.  
1.2 Units—Values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units, which are provided for information only and are not considered standard.
1.3 The following safety hazard caveat pertains only to the test method in sections 14.2 and 14.3 in this specification.
1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-Mar-2011
Technical Committee
Drafting Committee
Current Stage
Ref Project

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:B379 −11
Standard Specification for
1
Phosphorized Coppers—Refinery Shapes
This standard is issued under the fixed designation B379; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* E62Test Methods for Chemical Analysis of Copper and
3
CopperAlloys(PhotometricMethods)(Withdrawn2010)
1.1 Thisspecificationestablishestherequirementsforphos-
E255Practice for Sampling Copper and Copper Alloys for
phorized copper wire bars, billets, and cakes.
the Determination of Chemical Composition
NOTE1—Wirebarsfurnishedunderthisspecificationdonotconformin
dimensions with that furnished under Specification B5.
3. Terminology
1.2 Units—Values stated in inch-pound units are to be
3.1 For definitions of terms related to copper and copper
regarded as standard. The values given in parentheses are
alloys, refer to Terminology B846.
mathematical conversions to SI units, which are provided for
3.2 Definitions of Terms Specific to This Standard:
information only and are not considered standard.
3.2.1 copper, oxygen-free—electrolytic copper produced
1.3 The following safety hazard caveat pertains only to the
without the use of metallic or metalloidal deoxidizers, free of
test method in sections 14.2 and 14.3 in this specification.
cuprousoxideasdeterminedbymetallographicexaminationat
1.3.1 This standard does not purport to address all of the
75× under polarized light.
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
4. Ordering Information
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
4.1 Contracts or purchase orders for product under this
specification should include the following information:
2. Referenced Documents
4.1.1 ASTM designation and year of issue (for example,
2
2.1 ASTM Standards: B379–XX),
B5Specification for High ConductivityTough-Pitch Copper
4.1.2 Copper UNS Number (for example, C10800),
Refinery Shapes
4.1.3 Shape required: wire bar, billet or cake,
B193Test Method for Resistivity of Electrical Conductor
4.1.3.1 Billet end type,
Materials
4.1.4 Dimensions and tolerances (Section 10), and
B224Classification of Coppers
4.1.5 Quantity; total weight or number of pieces for each
B577TestMethodsforDetectionofCuprousOxide(Hydro-
shape, size,
gen Embrittlement Susceptibility) in Copper
4.2 The following are optional and should be specified in
B846Terminology for Copper and Copper Alloys
the contract or purchase order when required:
E3Guide for Preparation of Metallographic Specimens
E8Test Methods for Tension Testing of Metallic Materials 4.2.1 Hydrogen embrittlement test (Section 8),
E29Practice for Using Significant Digits in Test Data to
4.2.2 Certification (Section 19), and
Determine Conformance with Specifications
4.2.3 Test report (Section 20).
E53Test Method for Determination of Copper in Unalloyed
Copper by Gravimetry
5. Materials and Manufacture
5.1 Material:
1
5.1.1 The product furnished shall be produced from one of
ThisspecificationisunderthejurisdictionofASTMCommitteeB05onCopper
and Copper Alloys and is the direct responsibility of Subcommittee B05.07 on
the following coppers as specified in the contract or purchase
Refined Copper.
order:
Current edition approved April 1, 2011. Published May 2011. Originally
approved in 1962. Last previous edition approved in 2004 as B379–04. DOI:
10.1520/B0379-11.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on The last approved version of this historical standard is referenced on
the ASTM website. www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
B379−11
TABLE 1 Chemical Requirements
Composition, %
Copper UNS No. Type Phosphorus Arsenic
Copper (Including
Silver), min
min max min max
A
C10300 OFXLP 99.95 0.001 0.005 . . . . . .
A
C10800 OFLP 99.95 0.005 0.012 . . . . . .
C12000 DLP 99.90 0.004 0.012 . . . . . .
C12200 DHP 99.9 0.015 0.040 . . . . . .
B
C14200 DPA 99.4 0.015 0.040 0.15 0.50
A
Includes phosphorus.
B
Copper (including phosphorus and arsenic) = 99.9 % min.
TABLE 2 Electrical Resistivity Requirements for UNS nos.
C10300. C 10800, and C12000
4
UNS Nos. Former Description A
Alloy Electrical Resistivity Conductivity % IACS
C10300 OFXLP Oxygen-free
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:B379–04 Designation: B379 – 11
Standard Specification for
1
Phosphorized Coppers—Refinery Shapes
This standard is issued under the fixed designation B379; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification establishes the requirements for phosphorized copper wire bars, billets, and cakes.
NOTE 1—Wire bars furnished under this specification do not conform in dimensions with that furnished under Specification B5.
1.2The values in inch-pound units are the standard. SI values given in parentheses are for information only.
1.3The following hazard caveat applies to 14.2 and 14.3 of this specification: This standard does not purport to address all of
the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety
and health practices and determine the applicability of regulatory limitations prior to use.
1.2 Units—Values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical
conversions to SI units, which are provided for information only and are not considered standard.
1.3 The following safety hazard caveat pertains only to the test method in sections 14.2 and 14.3 in this specification.
1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
B5 Specification for High Conductivity Tough-Pitch Copper Refinery Shapes
B193 Test Method for Resistivity of Electrical Conductor Materials
B224 Classification of Coppers
B577 Test Methods for Detection of Cuprous Oxide (Hydrogen Embrittlement Susceptibility) in Copper
B846 Terminology for Copper and Copper Alloys
E83 Guide for Preparation of Metallographic Specimens
E8 Test Methods for Tension Testing of Metallic Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E53 Test Method for Determination of Copper in Unalloyed Copper by Gravimetry
E62 Test Methods for Chemical Analysis of Copper and Copper Alloys (Photometric Methods)
E255 Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition
3. Terminology
3.1 For definitions of terms related to copper and copper alloys, refer to Terminology B846.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 billet—refinery shape used for piercing or extrusion into tubular products or for extrusion into rod, bars, and shapes.
Circular in cross section, usually 3 to 16 in. (76 to 406 mm) in diameter, normally ranging in weight from 100 to 4200 lb (45 to
1905 kg).
3.2.2cake—refinery shape used for rolling into plate, sheet, strip, or shape. Rectangular in cross section and of various sizes,
normally ranging in weight from 140 to 62000 lb (64 to 28123 kg).
3.2.3capable of—possessing the required properties or characteristics, or both, necessary to conform to specification
requirements when subjected to specified test(s).
3.2.4copper, electrolytic—copper of any origin refined by electrolytic deposition including electrowinning. When used alone,
1
This specification is under the jurisdiction ofASTM Committee B05 on Copper and CopperAlloys and is the direct responsibility of Subcommittee B05.07 on Refined
Copper.
Current edition approved MayApril 1, 2004.2011. Published June 2004.May 2011. Originally approved in 1962. Last previous edition approved in 19992004 as
B379–99.B379–04. DOI: 10.1520/B0379-04.10.1520/B0379-11.
2
ForreferencedASTMstandards,visittheASTMwebsite,www.astm.org,orcontactASTMCustomerServiceatservice@astm.org.For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
B379 – 11
this term usually refers to electrolytic tough pitch copper.
3.2.5copper, fire-refined—copper of any origin or type finished by furnace refining without having
...

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