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ASTM D5702-18(2022)

(Practice)

Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals

SIGNIFICANCE AND USE
3.1 Prior to beginning a project that involves the removal, cutting, grinding, or burning of paint, it is necessary to determine if the coating contains hazardous metals, such as lead. If it does, certain requirements for worker and environmental protection may need to be imposed. The presence and quantity of hazardous metals in a paint can be determined through laboratory analysis. Proper sampling protocol is needed to assure the laboratory results represent the actual amount of heavy metal in the coating. The number and location of samples to be removed must also be determined to characterize properly the extent of the presence of hazardous materials, if any, on a structure.
SCOPE
1.1 This practice covers a method to control the removal of samples of coating films from substrates for subsequent laboratory analysis for heavy metal content on a mass basis. This technique can be used in the field, the fabricating shop, or laboratory.  
1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard information, see Section 5, Note 1, and Note 3.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
30-Nov-2022
ICS
13.040.01 - Air quality in general
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.46 - Industrial Protective Coatings
Current Stage
Ref Project

Relations

Refers
ASTM D6132-13 - Standard Test Method for Nondestructive Measurement of Dry Film Thickness of Applied Organic Coatings Using an Ultrasonic Coating Thickness Gage
Effective Date
01-Nov-2013
Refers
ASTM D7091-12 - Standard Practice for Nondestructive Measurement of Dry Film Thickness of Nonmagnetic Coatings Applied to Ferrous Metals and Nonmagnetic, Nonconductive Coatings Applied to Non-Ferrous Metals
Effective Date
01-Apr-2012
Refers
ASTM D6132-08 - Standard Test Method for Nondestructive Measurement of Dry Film Thickness of Applied Organic Coatings Using an Ultrasonic Gage
Effective Date
01-Jul-2008
Refers
ASTM D4138-07a - Standard Practices for Measurement of Dry Film Thickness of Protective Coating Systems by Destructive, Cross-Sectioning Means
Effective Date
01-Jul-2007
Refers
ASTM D4138-07 - Standard Practices for Measurement of Dry Film Thickness of Protective Coating Systems by Destructive, Cross-Sectioning Means
Effective Date
01-Feb-2007
Refers
ASTM D7091-05 - Standard Practice for Nondestructive Measurement of Dry Film Thickness of Nonmagnetic Coatings Applied to Ferrous Metals and Nonmagnetic, Nonconductive Coatings Applied to Non-Ferrous Metals
Effective Date
01-Aug-2005
Refers
ASTM D6132-04 - Standard Test Method for Nondestructive Measurement of Dry Film Thickness of Applied Organic Coatings Using an Ultrasonic Gage
Effective Date
01-Jun-2004
Refers
ASTM D4138-94(1999) - Standard Test Methods for Measurement of Dry Film Thickness of Protective Coating Systems by Destructive Means
Effective Date
01-Jan-2001
Refers
ASTM D4138-94(2001)e1 - Standard Test Methods for Measurement of Dry Film Thickness of Protective Coating Systems by Destructive Means
Effective Date
01-Jan-2001
Refers
ASTM D6132-97 - Standard Test Method for Nondestructive Measurement of Dry Film Thickness of Applied Organic Coatings Over Concrete Using an Ultrasonic Gage
Effective Date
10-Jul-1997

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ASTM D5702-18(2022) - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy MetalsASTM D5702-18(2022) - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
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ASTM D5702-18(2022) - Standard Practice for Field Sampling of Coating Films for Analysis for Heavy Metals
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5702 − 18 (Reapproved 2022)
Standard Practice for
Field Sampling of Coating Films for Analysis for Heavy
Metals
This standard is issued under the fixed designation D5702; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Ferrous Metals and Nonmagnetic, Nonconductive Coat-
ings Applied to Non-Ferrous Metals
1.1 This practice covers a method to control the removal of
samples of coating films from substrates for subsequent labo-
3. Significance and Use
ratory analysis for heavy metal content on a mass basis. This
3.1 Prior to beginning a project that involves the removal,
technique can be used in the field, the fabricating shop, or
cutting, grinding, or burning of paint, it is necessary to
laboratory.
determine if the coating contains hazardous metals, such as
1.2 The values stated in SI units are to be regarded as the
lead. If it does, certain requirements for worker and environ-
standard. The values in parentheses are for information only.
mental protection may need to be imposed. The presence and
1.3 This standard does not purport to address all of the
quantity of hazardous metals in a paint can be determined
safety concerns, if any, associated with its use. It is the
through laboratory analysis. Proper sampling protocol is
responsibility of the user of this standard to establish appro-
needed to assure the laboratory results represent the actual
priate safety, health, and environmental practices and deter-
amount of heavy metal in the coating.The number and location
mine the applicability of regulatory limitations prior to use.
of samples to be removed must also be determined to charac-
For specific hazard information, see Section 5, Note 1, and
terize properly the extent of the presence of hazardous
Note 3.
materials, if any, on a structure.
1.4 This international standard was developed in accor-
4. Materials and Equipment
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
4.1 Sample Collection Container—A clean plastic bag or
Development of International Standards, Guides and Recom-
rigid container comprised of a material such as polyethylene
mendations issued by the World Trade Organization Technical
that will not contaminate the sample.
Barriers to Trade (TBT) Committee.
4.2 Straight Edge or Ruler.
2. Referenced Documents 4.3 Knife or Chisel, cleaned and sharpened, for removing
2 paint samples.
2.1 ASTM Standards:
D4138 Practices for Measurement of Dry Film Thickness of 4.4 Dry Film Thickness Gage, for measuring total coating
Protective Coating Systems by Destructive, Cross- thickness.
Sectioning Means
5. Procedure
D6132 Test Method for Nondestructive Measurement of Dry
Film Thickness of Applied Organic Coatings Using an
5.1 Select a sufficient number of areas for coating removal
Ultrasonic Coating Thickness Gage that properly characterize the coatings on the structure.
D7091 Practice for Nondestructive Measurement of Dry
5.1.1 Selection may be based on painting history, knowl-
Film Thickness of Nonmagnetic Coatings Applied to edge of previously applied coatings, prior touch-up and re-
painting programs, and other such factors.
5.1.2 Select areas that properly characterize the range of
This practice is under the jurisdiction of ASTM Committee D01 on Paint and
thickness found. Dry film thickness can be measured in
Related Coatings, Materials, and Applications and is the direct responsibility of
accordance with Test Methods D4138, D6132, or Practice
Subcommittee D01.46 on Industrial Protective Coatings.
Current edition approved Dec. 1, 2022. Published December 2022. Originally D7091.
approved in 1995. Last previous edition approved in 2018 as D5702 – 18. DOI:
5.1.3 Remove a minimum of three samples.
10.1520/D5702-18R22.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or 5.2 At each sample site, clean the surface of dirt, dust, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
debris.
Standard
...

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6.1 Manufacturers increasingly are being asked or required to demonstrate that vapor-phase emissions of chemicals of concern from their products under normal use conditions comply with various voluntary or regulatory acceptance criteria. This process typically requires manufacturers to have their products periodically tested for VOC emissions by independent laboratories using designated reference test methods (for example, Test Method D6007, ISO 16000-9, and ISO 16000-10). To ensure continuing compliance, manufacturers may opt to, or be required to, implement screening tests at the production level.  
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5.1 Effects of Air Change—Air change often accounts for a significant portion of the heating or air-conditioning load of a building. It also affects the moisture and contaminant balances in the building. Moisture-laden air passing through the building envelope can permit condensation and cause material degradation. An appropriate level of ventilation is required in all buildings; one should consult ASHRAE Standard 62 to determine the ventilation requirements of a building.  
5.2 Prediction of Air Change—Air change depends on the size and distribution of air leakage sites, pressure differences induced by wind and temperature, mechanical system operation, and occupant behavior. Air change may be calculated from this information, however, many of the needed parameters are difficult to determine. Tracer gas testing permits direct measurement of air change.  
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5.5 Applicability of Results—The values for air change obtained by the techniques used in this test method apply to the specific conditions prevailing at the time of the measurement. Air change values for the same building will differ if the prevailing wind and temperature conditions have changed, if the operation of the building is different, or if the envelope changes between m...
SCOPE
1.1 This test method covers techniques using tracer gas dilution for determining a single zone's air change with the outdoors, as induced by weather conditions and by mechanical ventilation. These techniques are: (1) concentration decay, (2) constant injection, and (3) constant concentration.  
1.2 This test method is restricted to a single tracer gas.  
1.3 The associated data analysis assumes that one can characterize the tracer gas concentration within the zone with a single value. The zone shall be a building, vehicle, test cell, or any conforming enclosure.  
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5.6.3 Ability to ship and store samples, if necessary,  
5.6.4 Unattended sample collection,  
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SCOPE
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1.2 This test method describes the collection of integrated whole air samples in silanized or other passivated stainless steel canisters, and their subsequent laboratory analysis.  
1.2.1 This test method describes a procedure for sampling in canisters at final pressures above atmospheric pressure (pressurized sampling).  
1.3 This test method employs a cryogenic trapping procedure for concentration of the NMOC prior to analysis.  
1.4 This test method describes the determination of the NMOC by the flame ionization detection (FID), without the use of gas chromatographic columns and other procedures necessary for species separation.  
1.5 The range of this test method is from 20 ppb C to 10 000 ppb C (1, 2).3  
1.6 This test method has a larger uncertainty for some halogenated or oxygenated hydrocarbons than for simple hydrocarbons or aromatic compounds. This is especially true if there are high concentrations of chlorocarbons or chlorofluorocarbons present.  
1.7 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Techn...

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ASTM
ASTM D8141-22(Guide)
Standard Guide for Selecting Volatile Organic Compounds (VOCs) and Semi-Volatile Organic Compounds (SVOCs) Emission Testing Methods to Determine Emission Parameters for Modeling of Indoor Environments

SIGNIFICANCE AND USE
4.1 Emissions of VOCs are typically controlled by internal mass-transfer limitations (for example, diffusion through the material), while emissions of SVOCs are typically controlled by external mass-transfer limitations (migration through the air immediately above the material). The emission of some chemicals may be controlled by both internal and external mass-transfer limitations. In addition, due to their lower vapor pressure, SVOCs generally adsorb to different media (chamber walls, building materials, particles, and other surfaces) at greater rates than VOCs. This sorption can increase the amount of time required to reach steady-state SVOC concentrations using conventional VOC emission test methods to months for a single test (2).  
4.2 Thus, existing methods for characterizing emissions of VOCs may not be appropriate or practical to properly characterize emission rates of SVOCs for use in modeling SVOC concentrations in indoor environments. A mass-transfer framework is needed to accurately assess emission rates of SVOCs when predicting the SVOC indoor air concentrations in indoor environments. The SVOC mass-transfer framework includes SVOC emission characteristics and its partition to multimedia including sorption to indoor surfaces, airborne particles, and settled dust. Once the SVOC emission parameters and partitioning coefficients have been determined, these values can be used to modeling SVOC indoor concentrations.
SCOPE
1.1 This guide is intended to serve as a foundation for understanding when to use emission testing methods designed for volatile organic compounds (VOCs) to determine area-specific emission rates that are typically used in modeling indoor air VOC concentrations and when to use emission testing methods designed for semi-volatile organic compounds (SVOCs) to determine mass transfer emission parameters that are typically used to model indoor air, dust, and surface SVOC concentrations.  
1.2 This guide discusses how organic chemicals are conventionally categorized with respect to volatility.  
1.3 This guide presents a simplified mass-transfer model describing organic chemical emissions from a material to bulk air. The values of the model parameters are shown to be specific to material/chemical/chamber combinations.  
1.4 This guide shows how to use a mass-transfer model to estimate whether diffusion of the chemical within the material or convective mass transfer of the chemical from the surface of the material to the overlying air limits chemical emissions from the material surface.  
1.5 This guide describes the range of different chambers that are available for emission testing. The chambers are classified as either dynamic or static and either conventional or sandwich. The chambers are categorized as being optimal to determine either the area-specific emission rate or mass-transfer emission parameters.  
1.6 This guide discusses the roles sorption and convective mass-transfer coefficients play in selecting the appropriate emission chamber and analysis method to accurately and efficiently characterize emissions from indoor materials for use in modeling indoor chemical concentrations.  
1.7 This guide recommends when to choose an emission test method that is optimized to determine either the area-specific emission rate or mass-transfer emission parameters. For chemicals where the controlling mass-transfer process is unknown, the guide outlines a procedure to determine if the chemical emission is controlled by convective mass transfer of the chemical from the material.  
1.8 This guide does not provide specific guidance for measuring emission parameters or conducting indoor exposure modeling.  
1.9 Mechanisms controlling emissions from wet and dry materials and products are different. This guide considers the emission of chemicals from dry materials and products. Examples of functional uses of VOCs and SVOCs that this guide applies to include blowing agents, ...

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ASTM
ASTM D5954-22a(Test Method)
Standard Test Method for Mercury Sampling and Measurement in Gaseous Fuels by Atomic Absorption Spectroscopy

SIGNIFICANCE AND USE
5.1 This test method can be used to measure the level of mercury in any gaseous fuel (as defined by Terminology D4150) for purposes such as determining compliance with regulations, studying the effect of various abatement procedures on mercury emissions, checking the validity of direct instrumental measurements, and verifying that mercury concentrations are below those required for gaseous fuel processing and operations.  
5.2 Adsorption of the mercury on gold-coated sorbent can remove interferences associated with the direct measurement of mercury in the presence of high concentrations of organic compounds. It preconcentrates the mercury before analysis, thereby offering measurement of ultra-low average concentrations in a gas stream over a long time span. It avoids the cumbersome use of liquid spargers with on-site sampling and eliminates contamination problems associated with the use of potassium permanganate solutions.5,6,7
SCOPE
1.1 This test method covers the determination of total mercury in gaseous fuels at concentrations down to 0.5 ng/m3. It includes separate procedures for both sampling and atomic absorption spectrophotometric determination of mercury. This procedure detects both inorganic and organic forms of mercury.  
1.2 Units—The values stated in SI units are to be regarded as the standard.  
1.3 Warning—Mercury has been designated by many regulatory agencies as a hazardous material that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Safety Data Sheet (SDS) for additional information. Users should be aware that selling mercury or mercury containing products, or both, into your state or country may be prohibited by law.  
1.4 This standard does not purport to address all of the safety concerns associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D5110-22a(Practice)
Standard Practice for Calibration of Ozone Monitors and Certification of Ozone Transfer Standards Using Ultraviolet Photometry

SIGNIFICANCE AND USE
5.1 The reactivity and instability of O3 preclude the storage of O3 concentration standards for any practical length of time, and precludes direct certification of O3 concentrations as Standard Reference Materials (SRMs). Moreover, there is no available SRM that can be readily and directly adapted to the generation of O3 standards analogous to permeation devices and standard gas cylinders for sulfur dioxide and nitrogen oxides. Dynamic generation of O3 concentrations is relatively easy with a source of ultraviolet (UV) radiation. However, accurately certifying an O3 concentration as a primary standard requires assay of the concentration by a comprehensively specified analytical procedure, which must be performed every time a standard is needed (10).  
5.2 This practice is not designed for the routine calibration of O3 monitors at remote locations (see Practices D5011).
SCOPE
1.1 This practice covers a means for calibrating ambient, workplace, or indoor ozone monitors, and for certifying transfer standards to be used for that purpose.  
1.2 This practice describes means by which dynamic streams of ozone in air can be designated as primary ozone standards.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 8 for specific precautionary statements.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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