ASTM D3645-02

Standard Test Methods for Beryllium in Water

SCOPE
1.1 These test methods cover the determination of dissolved and total recoverable beryllium in most waters and wastewaters:ConcentrationRange SectionsTest Method A-Atomic Absorption, Direct10 to 500 μg/L7 to 16Test Method B-Atomic Absorption, Graphite Furnace10 to 50 μg/L17 to 25
1.2 The analyst should direct attention to the precision and bias statements for each test method. It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 12 and 23.4.

General Information

• Status: Historical
• Publication Date: 09-Jul-2002
• ICS: 13.060.50 - Examination of water for chemical substances
• Technical Committee: D19 - Water
• Drafting Committee: D19.05 - Inorganic Constituents in Water

Relations

• Replaces: ASTM D3645-97 - Standard Test Methods for Beryllium in Water
• Effective Date: 10-Jul-2002
• Replaced By: ASTM D3645-03 - Standard Test Methods for Beryllium in Water
• Effective Date: 10-Jan-2003
• Referred By: ASTM D1971-16(2021)e1 - Standard Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite Furnace Atomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass Spectrometry
• Effective Date: 10-Jul-2002

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 3645 – 02
Standard Test Methods for
1
Beryllium in Water
This standard is issued under the fixed designation D 3645; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope * D 3919 Practice for Measuring Trace Elements in Water by
2
Graphite Furnace Atomic Absorption Spectrophotometry
1.1 These test methods cover the determination of dissolved
D 4841 Practice for Estimation of Holding Time for Water
and total recoverable beryllium in most waters and wastewa-
2
Samples Containing Organic and Inorganic Constituents
ters:
2
D 5810 Guide for Spiking into Aqueous Samples
Concentration
D 5847 Practice for Writing Quality Control Specifications
Range Sections
3
for Standard Test Methods for Water Analysis
Test Method A–Atomic Absorption, 10 to 500 μg/L 7 to 16
Direct
3. Terminology
Test Method B–Atomic Absorption, 10 to 50 μg/L 17 to 25
Graphite Furnace
3.1 Definitions—For definitions of terms used in these test
methods, refer to Terminology D 1129.
1.2 The analyst should direct attention to the precision and
3.2 Definitions of Terms Specific to This Standard:
bias statements for each test method. It is the user’s responsi-
3.2.1 total recoverable beryllium—total recoverable beryl-
bility to ensure the validity of these test methods for waters of
lium relates only to the recoverable forms of beryllium by these
untested matrices.
test methods.
1.3 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
4. Significance and Use
responsibility of the user of this standard to establish appro-
4.1 These test methods are significant because the concen-
priate safety and health practices and determine the applica-
tration of beryllium in water must be measured accurately in
bility of regulatory limitations prior to use. For specific hazard
order to evaluate potential health and environmental effects.
statements, see Section 12 and 23.4.
5. Purity of Reagents
2. Referenced Documents
5.1 Reagent grade chemicals shall be used in all tests.
2.1 ASTM Standards:
2
Unless otherwise indicated, it is intended that all reagents shall
D 858 Test Methods for Manganese in Water
2
conform to the specifications of the Committee on Analytical
D 1068 Test Methods for Iron in Water
2
Reagents of the American Chemical Society, where such
D 1129 Terminology Relating to Water
4
2
specifications are available. Other grades may be used, pro-
D 1193 Specification for Reagent Water
2
vided it is first ascertained that the reagent is sufficiently high
D 1687 Test Methods for Chromium in Water
2 in purity to permit its use without lessening the accuracy of the
D 1688 Test Methods for Copper in Water
2
determination.
D 1691 Test Methods for Zinc in Water
2 5.2 Unless otherwise indicated, reference to water shall be
D 1886 Test Methods for Nickel in Water
understood to mean reagent water conforming to Specification
D 2777 Practice for Determination of Precision and Bias of
2 D 1193, Type I. Other reagent water types may be used
Applicable Test Methods of Committee D19 on Water
provided it is first ascertained that the water is of sufficiently
D 3370 Practices for Sampling Water from Closed Con-
2 high purity to permit its use without adversely affecting the
duits
2
bias and precision of the test method. Type II water was
D 3557 Test Methods for Cadmium in Water
2 specified at the time of round robin testing of this test method.
D 3558 Test Methods for Cobalt in Water
2
D 3559 Test Methods for Lead in Water
3
Annual Book of ASTM Standards, Vol 11.02.
1 4
These test methods are under the jurisdiction of ASTM Committee D19 on Reagent Chemicals, American Chemical Society Specifications, American
Water and are the direct responsibility of Subcommittee D19.05 on Inorganic Chemical Society, Washington, DC. For suggestions on the testing of reagents not
Constituents in Water. listed by the American Chemical Society, see Analar Standards for Laboratory
Current edition approved July 10, 2002. Published August 2002. Originally Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
published as D 3645 – 78. Last previous edition D 3645 – 97. and National Formulary, U.S. Pharmaceutical Convention, Inc. (USPC), Rockville,
2
Annual Book of ASTM Standards, Vol 11.01. MD.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
NOTICE: This standard has either been superseded and replaced by
...