ASTM D2989-97e1

Standard Test Method for Acidity-Alkalinity of Halogenated Organic Solvents and Their Admixtures

SCOPE
1.1 This test method covers the determination of acidity in halogenated organic solvents and admixtures thereof. The alkalinity may be determined utilizing Test Method D2106, by substituting the end point measured at pH7 by bromothymol blue or pH meter.  
1.2 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 7.

General Information

• Status: Historical
• Publication Date: 09-Dec-2001
• Technical Committee: D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
• Drafting Committee: D26.04 - Test Methods

Relations

• Replaces: ASTM D2989-97 - Standard Test Method for Acidity-Alkalinity of Halogenated Organic Solvents and Their Admixtures
• Effective Date: 10-Dec-2001
• Replaced By: ASTM D2989-01 - Standard Test Method for Acidity-Alkalinity of Halogenated Organic Solvents and Their Admixtures
• Effective Date: 10-Dec-2001
• Referred By: ASTM D5616-04(2022) - Standard Specification for Reclaimed Trichloroethylene
• Effective Date: 10-Dec-2001
• Referred By: ASTM D5960-03(2023) - Standard Specification for Technical Grade Ethylene Dichloride
• Effective Date: 10-Dec-2001
• Referred By: ASTM D4079-00(2022) - Standard Specification for Vapor-Degreasing Grade Methylene Chloride
• Effective Date: 10-Dec-2001
• Referred By: ASTM D5988-18 - Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials in Soil
• Effective Date: 10-Dec-2001
• Referred By: ASTM D7509-09(2021) - Standard Specification for Fluorocarbon Feedstock Grade Chloroform
• Effective Date: 10-Dec-2001
• Referred By: ASTM D4701-00(2020) - Standard Specification for Technical Grade Methylene Chloride
• Effective Date: 10-Dec-2001
• Referred By: ASTM D5395-03(2023) - Standard Specification for Reclaimed Methylene Chloride
• Effective Date: 10-Dec-2001
• Referred By: ASTM D4080-15(2020) - Standard Specification for Trichloroethylene, Technical and Vapor-Degreasing Grade
• Effective Date: 10-Dec-2001
• Referred By: ASTM D6368-06(2023) - Standard Specification for Vapor-Degreasing Solvents Based on <emph type="bdit">normal</emph >-Propyl Bromide and Technical Grade <emph type="bdit">normal</emph >-Propyl Bromide
• Effective Date: 10-Dec-2001
• Referred By: ASTM D5396-04(2020) - Standard Specification for Reclaimed Perchloroethylene
• Effective Date: 10-Dec-2001
• Referred By: ASTM D4376-15(2020) - Standard Specification for Vapor-Degreasing Grade Perchloroethylene
• Effective Date: 10-Dec-2001

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
An American National Standard
e1
Designation: D 2989 – 97
Standard Test Method for
Acidity-Alkalinity of Halogenated Organic Solvents and
1
Their Admixtures
This standard is issued under the fixed designation D 2989; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1
e NOTE—A research report footnote was added in November 2001.
1. Scope 4. Significance and Use
1.1 This test method covers the determination of acidity in 4.1 This test method can be used to establish manufacturing
halogenated organic solvents and admixtures thereof. The and purchasing specifications. It can also be used to determine
alkalinity may be determined utilizing Test Method D 2106, by the condition of solvents in use.
substituting the end point measured at pH7 by bromothymol
5. Apparatus
blue or pH meter.
1.2 This standard does not purport to address all of the 5.1 Separatory Funnel, 250-mL.
5.2 Graduated Cylinder, 100 mL.
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro- 5.3 Volumetric Pipets, 1 mL, 10 mL, 25 mL, 50 mL.
5.4 Beaker, 100 mL.
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. Specific precau- 5.5 Borosilicate or Stainless Steel Beaker,2L.
5.6 Erlenmeyer Flask, 100 mL.
tionary statements are given in Section 7.
5.7 pH Meter with pH Electrodes.
2. Referenced Documents
5.8 Buret,10mL.
2.1 ASTM Standards: 5.9 Volumetric Flask, 100 mL, 1 L.
D 2106 Test Method for the Determination of Amine Acid
2 6. Reagents
Acceptance (Alkalinity) of Halogenated Organic Solvents
D 2110 Test Method for pH of Water Extractions of Halo- 6.1 Purity of Reagents—Reagent grade chemicals shall be
2
used in all tests. Unless otherwise indicated, it is intended that
genated Organic Solvents and Their Admixtures
all reagents shall conform to the specifications of the Commit-
3. Summary of Test Method
tee on Analytical Reagents of the American Chemical Society,
3
Other grades may be
3.1 A sample of halogenated solvent or admixture is mea- where such specifications are available.
sured for pH using Test Method D 2110. If the pH of the used, provided it is first ascertained that the reagent is of
sample is above 7.0, the alkalinity is determined using Test sufficiently high purity to permit its use without lessening the
Method D 2106 (to an end point of pH 7). If the pH is below accuracy of the determination.
7.0, the free acid content of the halogenated organic solvent or 6.2 Water—Prepare neutral distilled water as follows: Boil 1
admixture is determined after water extraction using Procedure L of distilled water for 5 min in a borosilicate glass or stainless
A or B, or can be determined directly using Procedure C. steel container, then cover and cool to room temperature.
3.1.1 Procedure A, using glass electrode pH meter, or Titrate a 50-mL aliquot to a pH of 7.0 to 7.3 with either 0.01
3.1.2 Procedure B, using indicator. N sodium hydroxide (NaOH) solution or 0.01 N hydrochloric
3.2 Procedure C, anhydrous methanolic sodium hydroxide acid (HCl), depending upon whether the initial pH is above or
titration. below 7. From this titer, calculate the volume of 0.01 N NaOH
solution or 0.01 N HCl required to adjust the pH of the
1 3
This test method is under the jurisdiction of ASTM Committee D-26 on Reagent Chemicals, American Chemical Society Specifications, American
Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct Chemical Society, Washington, DC. For suggestions on the testing of reagents not
responsibility of Subcommittee D26.04 on Test Methods. listed by the American Chemical Society, see Analar Standards for Laboratory
Current edition approved Dec. 10, 1997. Published May 1998. Originally Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
published as D 2989 – 71 T. Last previous edition D 2989 – 93. and National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,
2
Annual Book of ASTM Standards, Vol 15.05. MD.
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D 2989
remaining 950 mL of boiled distilled water to a pH of 7.0 to ing 50 mL of freshly boiled, neutral, distilled water adjusted to
7.3. Add the calculated volume of 0.01 N NaOH solution or a bromothymol blue end point (see Note 1). Shake the mixture
0.01 N HCl together with the titrated 50
...