ASTM D1239-22

Standard Test Method for Resistance of Plastic Films to Extraction by Chemicals

SIGNIFICANCE AND USE
4.1 This test method is intended to be a rapid empirical test to determine the loss of the plasticizer or other extractable components from the plastic film when immersed in liquids commonly used in households.
SCOPE
1.1 This test method for resistance of plastic films to chemicals covers the measurement of the weight loss of film after immersion in chemicals.  
Note 1: There is no known ISO equivalent to this standard.
Note 2: Film is defined as sheeting having nominal thickness not greater than 0.25 mm (0.010 in.), in accordance with Terminology D883.  
1.2 The values stated in SI units are to be regarded as standard. The values stated in other units are nominal values given for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

• Status: Historical
• Publication Date: 30-Apr-2022
• ICS: 83.140.10 - Films and sheets
• Technical Committee: D20 - Plastics
• Drafting Committee: D20.19 - Film, Sheeting, and Molded Products

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D1239 − 22
Standard Test Method for
1
Resistance of Plastic Films to Extraction by Chemicals
This standard is issued under the fixed designation D1239; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 3. Terminology
3.1 Definitions—For definitions of technical terms pertain-
1.1 This test method for resistance of plastic films to
ing to plastics used in this test method, refer to Terminology
chemicals covers the measurement of the weight loss of film
D883. For abbreviations used in this test method, refer to
after immersion in chemicals.
Terminology D1600.
NOTE 1—There is no known ISO equivalent to this standard.
4. Significance and Use
NOTE 2—Film is defined as sheeting having nominal thickness not
greater than 0.25 mm (0.010 in.), in accordance with Terminology D883.
4.1 This test method is intended to be a rapid empirical test
to determine the loss of the plasticizer or other extractable
1.2 The values stated in SI units are to be regarded as
standard. The values stated in other units are nominal values components from the plastic film when immersed in liquids
commonly used in households.
given for information only.
1.3 This standard does not purport to address all of the
5. Apparatus
safety concerns, if any, associated with its use. It is the
5.1 Balance—An analytical balance, capable of weighing to
responsibility of the user of this standard to establish appro-
0.0001 g.
priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use. NOTE 3—An analytical balance capable of weighing to 0.001 g can be
used when the specimen thickness is greater than 0.05 mm (0.002 in.) and
1.4 This international standard was developed in accor-
the extracted weight loss of the specimen exceeds 0.005 g.
dance with internationally recognized principles on standard-
5.2 Containers—Container with a diameter of at least 65
ization established in the Decision on Principles for the
mm (2.5 in.) and a minimum volume to hold one specimen.
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical
6. Materials
Barriers to Trade (TBT) Committee.
6.1 Distilled Water—Freshly prepared distilled or deionized
water.
2. Referenced Documents
2 6.2 Soap Solution (1 %)—Dissolve 12 g of dehydrated pure
2.1 ASTM Standards:
white soap flakes (dried for1hat 105°C) in 1200 mL of
D543 Practices for Evaluating the Resistance of Plastics to
distilled water. This is sufficient solution to test three speci-
Chemical Reagents
mens.
D882 Test Method for Tensile Properties of Thin Plastic
6.3 Cottonseed Oil—Household cooking grade.
Sheeting
D883 Terminology Relating to Plastics
6.4 Mineral Oil, USP—Heavy grade, sp gr 0.875 to 0.905.
D1600 Terminology forAbbreviatedTerms Relating to Plas-
6.5 Kerosine.
tics
6.6 Ethyl Alcohol (50 %), as described in Test Method
D543.
1
6.7 Any other standard or supplementary reagent listed in
This test method is under the jurisdiction ofASTM Committee D20 on Plastics
and is the direct responsibility of Subcommittee D20.19 on Film, Sheeting, and
Test Method D543.
Molded Products.
Current edition approved May 1, 2022. Published May 2022. Originally
7. Test Specimen
approved in 1952. Last previous edition approved in 2014 as D1239 – 14. DOI:
10.1520/D1239-22.
7.1 The test specimens for plastic films shall be in the form
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
of squares 50 6 0.25 mm (2 in.) on each side. At least three
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
specimens of each sample shall be tested with each chemical
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. reagent.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D1239 − 22
7.2 Nothing in this test method precludes the use of speci- 9.4 Remove the specimens from the liquids and gently wipe
mens of other dimensions or the making of other tests on the with a solvent-soaked lint-free soft cloth or absorbent tissue.
same specimens after they have been exposed to the chemicals.
Specimenstakenfromwaterorvolatilesolventslikeacetoneor
Another acceptable specimen is a disk 50 6 0.25 mm (2 in.) in gasoline require no rinsing, but simply wipe dry as directed;
2
diameter (total area 41.5 cm ), or a tension specimen at least
rinse spec
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D1239 − 14 D1239 − 22
Standard Test Method for
1
Resistance of Plastic Films to Extraction by Chemicals
This standard is issued under the fixed designation D1239; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This test method for resistance of plastic films to chemicals covers the measurement of the weight loss of film after immersion
in chemicals.
NOTE 1—There is no known ISO equivalent to this standard.
NOTE 2—Film is defined as sheeting having nominal thickness not greater than 0.25 mm (0.010 in.), in accordance with Terminology D883.
1.2 The values stated in SI units are to be regarded as standard. The values stated in other units are nominal values given for
information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D543 Practices for Evaluating the Resistance of Plastics to Chemical Reagents
D882 Test Method for Tensile Properties of Thin Plastic Sheeting
D883 Terminology Relating to Plastics
D6899D1600 Guide for Laboratory Cyclic Corrosion Testing of Automotive Painted SteelTerminology for Abbreviated Terms
Relating to Plastics (Withdrawn 2010)
3. Terminology
3.1 Definitions—For definitions of technical terms pertaining to plastics used in this test method, see refer to Terminology D883.
For abbreviations used in this test method, refer to Terminology D1600.
1
This test method is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.19 on Film, Sheeting, and Molded
Products.
Current edition approved May 15, 2014May 1, 2022. Published June 2014May 2022. Originally approved in 1952. Last previous edition approved in 20072014 as
D1239 – 07.D1239 – 14. DOI: 10.1520/D1239-14.10.1520/D1239-22.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D1239 − 22
4. Significance and Use
4.1 This test method is intended to be a rapid empirical test to determine the loss of the plasticizer or other extractable components
from the plastic film when immersed in liquids commonly used in households.
5. Apparatus
5.1 Balance—An analytical balance, capable of weighing to 0.0001 g.
NOTE 3—An analytical balance capable of weighing to 0.001 g can be used when the specimen thickness is greater than 0.05 mm (0.002 in.) and the
extracted weight loss of the specimen exceeds 0.005 g.
5.2 Containers—Pint jars or cans Container with a diameter of at least 65 mm (2.5 in.) (one container for each specimen). and
a minimum volume to hold one specimen.
6. Materials
6.1 Distilled Water—Freshly prepared distilled or deionized water.
6.2 Soap Solution (1 %)—Soap SolutionDissolve (1 %)—Dissolve 12 g of dehydrated pure white soap flakes (dried for 1 h at
105°C) in 1200 mL of distilled water. This is sufficient solution to test three specimens.
6.3 Cottonseed Oil—Household cooking grade.
6.4 Mineral Oil, USP—Heavy grade, sp gr 0.875 to 0.905.
6.5 Kerosine.Kerosine.
6.6 Ethyl Alcohol (50 %),Ethyl Alcohol (50 %) as described in Test Method D543.
6.7 Any other standard or supplementary reagent listed in Test Method D543.
7. Test Specimen
7.1 The test specimens for plastic films shall be in the form of squares 50 6 0.25 mm (2 in.) on each side. At least three specimens
of each sample shall be tested with each chemical reagent.
7.2
...