Standard Specification for Synthetic Brown Iron Oxide Pigment

ABSTRACT
This specification establishes the properties and requirements for the pigments commercially known as synthetic pure brown iron oxides and its blends, suitable for use in paints and coatings. The pigment, which shall be soft, dry, and finely pulverized, may be manufactured by either of the following methods: precipitation of iron salts; calcination of precipitated iron oxides; blends of synthetic red, yellow, and black iron oxides; and blends of synthetic red, yellow, and black iron oxides plus the addition of carbon black. Specimens shall be suitably sampled and tested, and shall adhere to specified requirements as to total iron oxide, ferrous iron, carbon black, moisture and other volatile matter, organic coloring matter, total sulfates, coarse particles (total residue retained on No. 325 sieve), and water-soluble matter.
SCOPE
1.1 This specification covers the pigments commercially known as synthetic pure brown iron oxides and blends. These pigments are suitable for use in paints and coatings. Methods of manufacture are:  
1.1.1 Precipitation of iron salts.  
1.1.2 Calcination of precipitated iron oxides.  
1.1.3 Blends of synthetic red, yellow, and black iron oxides.  
1.1.4 Blends of synthetic red, yellow, and black iron oxides plus the addition of carbon black to a maximum of 5.0 %. Small amounts of carbon black are added to obtain tinting colors not obtainable when synthetic brown iron oxide or carbon black are used singly.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Publication Date
30-Sep-2019
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ASTM D3724-01(2019) - Standard Specification for Synthetic Brown Iron Oxide Pigment
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D3724 −01 (Reapproved 2019)
Standard Specification for
Synthetic Brown Iron Oxide Pigment
This standard is issued under the fixed designation D3724; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D1208 Test Methods for Common Properties of Certain
Pigments
1.1 This specification covers the pigments commercially
D3872 Test Method for Ferrous Iron in Iron Oxides
known as synthetic pure brown iron oxides and blends. These
E350 Test Methods for Chemical Analysis of Carbon Steel,
pigments are suitable for use in paints and coatings. Methods
Low-Alloy Steel, Silicon Electrical Steel, Ingot Iron, and
of manufacture are:
Wrought Iron
1.1.1 Precipitation of iron salts.
E351 Test Methods for ChemicalAnalysis of Cast Iron—All
1.1.2 Calcination of precipitated iron oxides.
Types
1.1.3 Blends of synthetic red, yellow, and black iron oxides.
1.1.4 Blends of synthetic red, yellow, and black iron oxides
3. Composition and Properties
plus the addition of carbon black to a maximum of 5.0 %.
3.1 The pigment shall be a manufactured iron oxide or a
Small amounts of carbon black are added to obtain tinting
blend. It shall be a soft dry finely pulverized pigment and shall
colors not obtainable when synthetic brown iron oxide or
conform to the following requirements:
carbon black are used singly.
FeO 0to10%
1.2 The values stated in SI units are to be regarded as the
Fe O 83 to 98 %
2 3
Carbon black, max, % 5.0 %
standard. The values given in parentheses are for information
Moisture and other volatile matter, max, % 1.0 %
only.
Organic coloring matter none
Total sulfates expressed as SO , max, % 2.0 %
1.3 This international standard was developed in accor-
Coarse particles (total residue retained on No. 1.0 %
dance with internationally recognized principles on standard-
325 (45-µm) mesh sieve, max, %
ization established in the Decision on Principles for the
Matter soluble in water, max, % 0.5 %
Development of International Standards, Guides and Recom-
3.2 Inasmuchassyntheticbrownironoxidesareavailablein
mendations issued by the World Trade Organization Technical
awiderangeofshades.Themasscolorandcharacterofthetint
Barriers to Trade (TBT) Committee.
and the tinting strength formed by a mixture with a white
pigment shall be within mutually agreed upon limits of a
2. Referenced Documents
standard acceptable to both the purchaser and the seller when
2.1 ASTM Standards:
tested by Test Method D387.
D50 Test Methods for ChemicalAnalysis ofYellow, Orange,
4. Sampling
Red, and Brown Pigments Containing Iron and Manga-
nese
4.1 Two samples shall be taken at random from different
D185 Test Methods for Coarse Particles in Pigments
packages from each lot, batch, day’s pack, or other unit of
D280 Test Methods for Hygroscopic Moisture (and Other
production in a shipment. When no markings distinguishing
Matter Volatile Under the Test Conditions) in Pigments
between units of production appear, samples shall be taken
D387 Test Met
...

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