Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel

SCOPE
1.1 This specification covers nominally anhydrous denatured fuel ethanol intended to be blended with unleaded or leaded gasolines at 1 to 10 volume % for use as a spark-ignition automotive engine fuel. The significance of this specification is shown in .
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

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31-Oct-2006
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ASTM D4806-06c - Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
An American National Standard
Designation: D 4806 – 06c
Standard Specification for
Denatured Fuel Ethanol for Blending with Gasolines for Use
1
as Automotive Spark-Ignition Engine Fuel
This standard is issued under the fixed designation D 4806; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope* D 3505 Test Method for Density or Relative Density of
Pure Liquid Chemicals
1.1 This specification covers nominally anhydrous dena-
D 4052 Test Method for Density and Relative Density of
tured fuel ethanol intended to be blended with unleaded or
Liquids by Digital Density Meter
leaded gasolines at 1 to 10 volume % for use as a spark-
D 4057 Practice for Manual Sampling of Petroleum and
ignition automotive engine fuel. The significance of this
Petroleum Products
specification is shown in Appendix X2.
D 4177 Practice for Automatic Sampling of Petroleum and
1.2 The values stated in SI units are to be regarded as the
Petroleum Products
standard. The values given in parentheses are for information
D 4306 Practice for Aviation Fuel Sample Containers for
only.
Tests Affected by Trace Contamination
2. Referenced Documents
D 4814 SpecificationforAutomotiveSpark-IgnitionEngine
2
Fuel
2.1 ASTM Standards:
D 5453 Test Method for Determination of Total Sulfur in
D86 Test Method for Distillation of Petroleum Products at
Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel
Atmospheric Pressure
Engine Fuel, and Engine Oil by Ultraviolet Fluorescence
D 381 Test Method for Gum Content in Fuels by Jet
D 5501 Test Method for Determination of Ethanol Content
Evaporation
of Denatured Fuel Ethanol by Gas Chromatography
D 512 Test Methods for Chloride Ion In Water
D 5580 Test Method for Determination of Benzene, Tolu-
D 891 Test Methods for Specific Gravity, Apparent, of
ene, Ethylbenzene, p/m-Xylene, o-Xylene, C and Heavier
Liquid Industrial Chemicals 9
Aromatics, and Total Aromatics in Finished Gasoline by
D 1152 Specification for Methanol (Methyl Alcohol)
Gas Chromatography
D 1193 Specification for Reagent Water
D 5854 Practice for Mixing and Handling of Liquid
D 1613 Test Method for Acidity in Volatile Solvents and
Samples of Petroleum and Petroleum Products
Chemical Intermediates Used in Paint, Varnish, Lacquer,
D 6299 Practice for Applying Statistical Quality Assurance
and Related Products
Techniques to Evaluate Analytical Measurement System
D 1688 Test Methods for Copper in Water
Performance
D 2622 Test Method for Sulfur in Petroleum Products by
D 6423 Test Method for Determination of pHe of Ethanol,
Wavelength Dispersive X-ray Fluorescence Spectrometry
Denatured Fuel Ethanol, and Fuel Ethanol (Ed75-Ed85)
D 3120 Test Method for Trace Quantities of Sulfur in Light
D 6428 Test Method for Total Sulfur in Liquid Aromatic
Liquid Petroleum Hydrocarbons by Oxidative Microcou-
Hydrocarbons and Their Derivatives by Oxidative Com-
lometry
3
bustion and Electrochemical Detection
D 6550 Test Method for Determinationof OlefinContentof
1
Gasolines by Supercritical-Fluid Chromatography
This specification is under the jurisdiction of ASTM Committee D02 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
E 203 TestMethodforWaterUsingVolumetricKarlFischer
D02.A0.01 on Gasoline and Gasoline-Oxygenate Blends.
Titration
Current edition approved Nov. 1, 2006. Published December 2006. Originally
E 300 Practice for Sampling Industrial Chemicals
approved in 1988. Last previous edition approved in 2006 as D 4806–06b.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
3
the ASTM website. Withdrawn.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

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D 4806 – 06c
E 1064 Test Method for Water in Organic Liquids by
Ethanol, volume %, min 92.1
Methanol, volume %, max 0.5
Coulometric Karl Fischer Titration
Solvent-washed gum, 5.0
2.2 Other Standards:
mg/100 mL, max
Water content, volume %, max 1.0 (Note 1)
United States Code of Federal Regulations, Title 27, Parts
Denaturant content, volume %, min 1.96
4
20 and 21
volume %, max 5.0
Inorganic Chloride content, mass 40 (32)
United States Federal Specification O-E-760b Ethyl Alco-
ppm (mg/L), max
hol (Ethanol): Denatured Alcohol: and Proprietary Sol-
Copper content, mg/kg, max 0.1
5
Acidity (as acetic acid CH COOH),
...

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