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ASTM E2046-03

(Test Method)

Standard Test Method for Reaction Induction Time by Thermal Analysis

Standard Test Method for Reaction Induction Time by Thermal Analysis

SIGNIFICANCE AND USE
This test method measures the time to extrapolated onset of an exothermic reaction under constant temperature (isothermal) conditions for reactions which have an induction period, for example, those which are catalytic or autocatalytic in nature or which contain reaction inhibitors.
The RIT determined by this test method is to be considered an index measurement that is useful for comparing one material to another at the test temperature of interest and in the same apparatus type only.
This test method is a useful adjunct to dynamic thermal tests, such as Test Method E 537, which are performed under conditions in which the sample temperature is increased continuously at constant rate. Results obtained under dynamic test conditions may result in higher estimates of temperature at which an exothermic reaction initiates because the detected onset temperature is dependent upon the heating rate and because dynamic methods allow insufficient time for autocatalytic reactions to measurably affect the onset temperature.
RIT values determined under a series of isothermal test conditions may be plotted as their logarithm versus the reciprocal of the absolute temperature to produce a plot, the slope of which is proportional to the activation energy of the reaction as described in Test Method E 2070.
This test method may be used in research and development, manufacturing, process and quality control, and regulatory compliance.
This test method is similar to that for Oxidation Induction Time (OIT) (for example, Specification D 3350 and Test Methods D 3895, D 4565, D 5483, D 6186, and E 1858) where the time to the oxidation reaction under isothermal test conditions is measured. The OIT test method measures the presence of antioxidant packages and is a relative measurement of a material’resistance to oxidation.
SCOPE
1.1 This test method describes the measurement of Reaction Induction Time (RIT) of chemical materials that undergo exothermic reactions with an induction period. The techniques and apparatus described may be used for solids, liquids, or slurries of chemical substances. The temperature range covered by this test method is typically from ambient to 400C. This range may be extended depending upon the apparatus used.
1.2 The RIT is a relative index value, not an absolute thermodynamic property. As an index value, the RIT value may change depending upon experimental conditions. A comparison of RIT values may be made only for materials tested under similar conditions of apparatus, specimen size, and so forth. Furthermore, the RIT value may not predict behavior of large quantities of material.
1.3 The RIT shall not be used by itself to establish a safe operating temperature. It may be used in conjunction with other test methods (for example, E 487, E 537, and E 1981 as part of a hazard analysis of a particular operation.
1.4 This test method may be used for RIT values greater than 15 min (as relative imprecision increases at shorter periods).
1.5 This test method is used to study catalytic and autocatalytic reactions. These reactions depend upon time as well as temperature. Such reactions are often studied by fixing one experimental parameter (that is, time or temperature) and then measuring the other parameter (that is, temperature or time). This test method measures time to reaction onset detection under isothermal conditions. It is related to Test Method E 487 that measures detected reaction onset temperature under constant time conditions
1.6 SI units are the standard.
1.7 There is no ISO standard equivalent to this test method.
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Jul-2003
ICS
17.200.20 - Temperature-measuring instruments
Technical Committee
E27 - Hazard Potential of Chemicals
Drafting Committee
E27.02 - Thermal Stability and Condensed Phases
Current Stage
Ref Project

Relations

Replaces
ASTM E2046-99 - Standard Test Method for Reaction Induction Time by Thermal Analysis
Effective Date
10-Jul-2003
Replaced By
ASTM E2046-08 - Standard Test Method for Reaction Induction Time by Thermal Analysis
Effective Date
01-Apr-2008
Referred By
ASTM E1445-08(2015) - Standard Terminology Relating to Hazard Potential of Chemicals
Effective Date
10-Jul-2003
Referred By
ASTM E2070-13(2018) - Standard Test Methods for Kinetic Parameters by Differential Scanning Calorimetry Using Isothermal Methods
Effective Date
10-Jul-2003

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ASTM E2046-03 - Standard Test Method for Reaction Induction Time by Thermal Analysis
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:E2046–03
Standard Test Method for
1
Reaction Induction Time by Thermal Analysis
This standard is issued under the fixed designation E 2046; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
1.1 This test method describes the measurement of Reaction 2.1 ASTM Standards:
Induction Time (RIT) of chemical materials that undergo D 3350 Specification for Polyethylene Plastics Pipe and
2
exothermic reactions with an induction period. The techniques Fittings Materials
and apparatus described may be used for solids, liquids, or D 3895 Test Method for Oxidative-Induction Time of Poly-
2
slurriesofchemicalsubstances.Thetemperaturerangecovered olefins by Differential Scanning Calorimetry
by this test method is typically from ambient to 400°C. This D 4565 Test Methods for Physical and Environmental Per-
range may be extended depending upon the apparatus used. formance Properties of Insulations and Jackets for Tele-
3
1.2 The RIT is a relative index value, not an absolute communications Wire and Cable
thermodynamicproperty.Asanindexvalue,theRITvaluemay D 5483 Test Method for Oxidation Induction Time of Lu-
change depending upon experimental conditions. A compari- bricating Greases by Pressure Differential Scanning Calo-
4
son of RITvalues may be made only for materials tested under rimetry
similar conditions of apparatus, specimen size, and so forth. D 6186 Test Method for Oxidation Induction Time of Lu-
Furthermore, the RIT value may not predict behavior of large bricating Oils by Pressure Differential Scanning Calorim-
quantities of material. etry
5
1.3 The RIT shall not be used by itself to establish a safe E 473 Terminology Relating to Thermal Analysis
operating temperature. It may be used in conjunction with E 487 Test Method for Constant-Temperature Stability of
5
other test methods (for example, E 487, E 537, and E 1981 as Chemical Materials
part of a hazard analysis of a particular operation. E 537 Test Method for Assessing the Thermal Stability of
5
1.4 This test method may be used for RIT values greater Chemicals by Methods of Differential Thermal Analysis
than 15 min (as relative imprecision increases at shorter E 967 Practice for Temperature Calibration of Differential
periods). Scanning Calorimeters and Differential Thermal Analyz-
5
1.5 This test method is used to study catalytic and autocata- ers
lytic reactions. These reactions depend upon time as well as E 968 Practice for Heat Flow Calibration of Differential
5
temperature. Such reactions are often studied by fixing one Scanning Calorimeters
experimental parameter (that is, time or temperature) and then E 1445 Terminology Relating to Hazardous Potential of
5
measuring the other parameter (that is, temperature or time). Chemicals
This test method measures time to reaction onset detection E 1858 Test Method for Determining Oxidative Induction
under isothermal conditions. It is related to Test Method E 487 Time of Hydrocarbons by Differential Scanning Calorim-
5
that measures detected reaction onset temperature under con- etry
stant time conditions E 1860 Test Method for Elapsed Time Calibration of Ther-
5
1.6 SI units are the standard. mal Analyzers
1.7 There is no ISO standard equivalent to this test method. E 1981 Guide for Assessing the Thermal Stability of Mate-
5
1.8 This standard does not purport to address all of the rials by Method of Accelerating Rate Calorimetry
safety concerns, if any, associated with its use. It is the E 2070 Test Method for Kinetic Parameters by Differential
5
responsibility of the user of this standard to consult and Scanning Calorimetry Using Isothermal Methods
establish appropriate safety and health practices and deter-
3. Terminology
mine the applicability of regulatory limitations prior to use.
3.1 The specialized terms used in this test method are
described in Terminologies E 473 and E 1445.
1
This test method is under the jurisdiction ofASTM Committee E27 on Hazard
2
Potential of Chemicals and is the direct responsibility of Subcommittee E27.02 on Annual Book of ASTM Standards, Vol 08.02.
3
Thermal Stability and Condensed Phases. Annual Book of ASTM Standards, Vol 10.02.
4
Current edition approved July 10, 2003. Published September 2003. Originally Annual Book of ASTM Standards, Vol 05.03.
5
approved in 1999. Last previous edition approved in 1999 as E 2046 – 99. Annual Book of ASTM Standards, Vol 14.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

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ASTM E2046-19(Test Method)
Standard Test Method for Reaction Induction Time by Thermal Analysis

SIGNIFICANCE AND USE
5.1 This test method measures the time to extrapolated onset of an exothermic reaction under constant temperature (isothermal) conditions for reactions which have an induction period, for example, those which are catalytic, autocatalytic, or accelerating in nature or which contain reaction inhibitors.  
5.2 The RIT determined by this test method is an index measurement that is useful for comparing one material to another at the test temperature of interest and in the same apparatus type only.  
5.3 This test method is a useful adjunct to dynamic thermal tests, such as Test Method E537, which are performed under conditions in which the sample temperature is increased continuously at constant rate. Results obtained under dynamic test conditions may result in higher estimates of temperature at which an exothermic reaction initiates because the detected onset temperature is dependent upon the heating rate and because dynamic methods allow insufficient time for autocatalytic reactions to measurably affect the onset temperature.  
5.4 RIT values determined under a series of isothermal test conditions may be plotted as their logarithm versus the reciprocal of the absolute temperature to produce a plot, the slope of which is proportional to the activation energy of the reaction as described in Test Methods E2070.  
5.5 This test method may be used in research and development, manufacturing, process and quality control, and regulatory compliance.  
5.6 This test method is similar to that for oxidation induction time (OIT) (for example, Specification D3350 and Test Methods D3895, D4565, D5483, D6186, and E1858) where the time to the oxidation reaction under isothermal test conditions is measured. The OIT test method measures the presence of antioxidant packages and is a relative measurement of a material’s resistance to oxidation.
SCOPE
1.1 This test method describes the measurement of reaction induction time (RIT) of chemical materials that undergo exothermic reactions with an induction period. The techniques and apparatus described may be used for solids, liquids, or slurries of chemical substances. The temperature range covered by this test method is typically from ambient to 400 °C. This range may be extended depending upon the apparatus used.  
1.2 The RIT is a relative index value, not an absolute thermodynamic property. As an index value, the RIT value may change depending upon experimental conditions. A comparison of RIT values may be made only for materials tested under similar conditions of apparatus, specimen size, and so forth. Furthermore, the RIT value may not predict behavior of large quantities of material.  
1.3 The RIT shall not be used by itself to establish a safe operating temperature. It may be used in conjunction with other test methods (for example, Test Methods E487 and E537, and Guide E1981) as part of a hazard analysis of a particular operation.  
1.4 This test method may be used for RIT values greater than 15 min (as relative imprecision increases at shorter periods).  
1.5 This test method is used to study catalytic, autocatalytic, and accelerating reactions. These reactions depend upon time as well as temperature. Such reactions are often studied by fixing one experimental parameter (that is, time or temperature) and then measuring the other parameter (that is, temperature or time). This test method measures time to reaction onset detection under isothermal conditions. It is related to Test Method E487 that measures detected reaction onset temperature under constant time conditions  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this test method.  
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ASTM E2067-23(Practice)
Standard Practice for Full-Scale Oxygen Consumption Calorimetry Fire Tests

SIGNIFICANCE AND USE
4.1 The oxygen consumption principle, used for the measurements described here, is based on the observation that, generally, the net heat of combustion is directly related to the amount of oxygen required for combustion (1).7 Approximately 13.1 MJ of heat are released per 1 kg of oxygen consumed. Test specimens in the test are burned in ambient air conditions, while being subjected to a prescribed external heating source.  
4.1.1 This technique is not appropriate for use on its own when the combustible fuel is an oxidizer or an explosive agent, which release oxygen. Further analysis is required in such cases (see Appendix X2).  
4.2 The heat release is determined by the measurement of the oxygen consumption, as determined by the oxygen concentration and the flow rate in the combustion product stream, in a full scale environment.  
4.3 The primary measurements are oxygen concentration and exhaust gas flow rate. Additional measurements include the specimen ignitability, the smoke obscuration generated, the specimen mass loss rate, the effective heat of combustion and the yields of combustion products from the test specimen.  
4.4 The oxygen consumption technique is used in different types of test methods. Intermediate scale (Test Method E1623, UL 1975) and full scale (Test Method D5424, Test Method D5537, Test Method E1537, Test Method E1590, Test Method E1822, ISO 9705, NFPA 265, NFPA 266, NFPA 267, NFPA 286, UL 1685) test methods, as well as unstandardized room scale experiments following Guide E603, using this technique involve a large instrumented exhaust hood, where oxygen concentration is measured, either standing alone or positioned outside a doorway. A large test specimen is placed either under the hood or inside the room. This practice is intended to address issues associated with equipment requiring a large instrumented hood and not stand-alone test apparatuses with small test specimens.  
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1.1 This practice deals with methods to construct, calibrate, and use full scale oxygen consumption calorimeters to help minimize testing result discrepancies between laboratories.  
1.2 The methodology described herein is used in a number of ASTM test methods, in a variety of unstandardized test methods, and for research purposes. This practice will facilitate coordination of generic requirements, which are not specific to the item under test.  
1.3 The principal fire-test-response characteristics obtained from the test methods using this technique are those associated with heat release from the specimens tested, as a function of time. Other fire-test-response characteristics also are determined.  
1.4 This practice is intended to apply to the conduction of different types of tests, including both some in which the objective is to assess the comparative fire performance of products releasing low amounts of heat or smoke and some in which the objective is to assess whether flashover will occur.  
1.5 This practice does not provide pass/fail criteria that can be used as a regulatory tool, nor does it describe a test method for any material or product.  
1.6 For use of the SI system of units in referee decisions, see IEEE/ASTM SI-10. The units given in parentheses are provided for information only.  
1.7 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.
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SIGNIFICANCE AND USE
5.1 This standard provides a description of test methods used in other ASTM specifications to establish certain acceptable methods for characterizing thermocouple assemblies and thermocouple cable. These test methods define how those characteristics shall be determined.  
5.2 The usefulness and purpose of the included tests are given for the category of tests.  
5.3 Warning—Users should be aware that certain characteristics of thermocouples might change with time and use. If a thermocouple’s designed shipping, storage, installation, or operating temperature has been exceeded, that thermocouple’s moisture seal may have been compromised and may no longer adequately prevent the deleterious intrusion of water vapor. Consequently, the thermocouple’s condition established by test at the time of manufacture may not apply later. In addition, inhomogeneities can develop in thermoelements because of exposure to higher temperatures, even in cases where maximum exposure temperatures have been lower than the suggested upper use temperature limits specified in Table 1 of Specification E608/E608M. For this reason, calibration of thermocouples destined for delivery to a customer is not recommended. Because the emf indication of any thermocouple depends upon the condition of the thermoelements along their entire length, as well as the temperature profile pattern in the region of any inhomogeneity, the emf output of a used thermocouple will be unique to its installation. Because temperature profiles in calibration equipment are unlikely to duplicate those of the installation, removal of a used thermocouple to a separate apparatus for calibration is not recommended. Instead, in situ calibration by comparison to a similar thermocouple known to be good is often recommended.
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1.1 This document lists methods for testing Mineral-Insulated, Metal-Sheathed (MIMS) thermocouple assemblies and thermocouple cable, but does not require that any of these tests be performed nor does it state criteria for acceptance. The acceptance criteria are given in other ASTM standard specifications that impose this testing for those thermocouples and cable. Examples from ASTM thermocouple specifications for acceptance criteria are given for many of the tests. These tabulated values are not necessarily those that would be required to meet these tests, but are included as examples only.  
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1.3.3.5 Thermoelement spacing.
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5.1 This test method is intended to be used by wire producers and thermocouple manufacturers for certification of refractory metal thermocouples. It is intended to provide a consistent method for calibration of refractory metal thermocouples referenced to a calibrated radiation thermometer. Uncertainty in calibration and operation of the radiation thermometer, and proper construction and use of the test furnace are of primary importance.  
5.2 Calibration establishes the temperature-emf relationship for a particular thermocouple under a specific temperature and chemical environment. However, during high temperature calibration or application at elevated temperatures in vacuum, oxidizing, reducing or contaminating environments, and depending on temperature distribution, local irreversible changes may occur in the Seebeck Coefficient of one or both thermoelements. If the introduced inhomogeneities are significant, the emf from the thermocouple will depend on the distribution of temperature between the measuring and reference junctions.  
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SCOPE
1.1 This test method covers the calibration of refractory metal thermocouples using a radiation thermometer as the standard instrument. This test method is intended for use with types of thermocouples that cannot be exposed to an oxidizing atmosphere. These procedures are appropriate for thermocouple calibrations at temperatures above 800 °C (1472 °F).  
1.2 The calibration method is applicable to the following thermocouple assemblies:  
1.2.1 Type 1—Bare-wire thermocouple assemblies in which vacuum or an inert or reducing gas is the only electrical insulating medium between the thermoelements.  
1.2.2 Type 2—Assemblies in which loose fitting ceramic insulating pieces, such as single-bore or double-bore tubes, are placed over the thermoelements.  
1.2.3 Type 2A—Assemblies in which loose fitting ceramic insulating pieces, such as single-bore or double-bore tubes, are placed over the thermoelements, permanently enclosed and sealed in a loose fitting metal or ceramic tube.  
1.2.4 Type 3—Swaged assemblies in which a refractory insulating powder is compressed around the thermoelements and encased in a thin-walled tube or sheath made of a high melting point metal or alloy.  
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5.1 Most thermal analysis experiments are carried out under increasing temperature conditions where temperature is the independent parameter. Some experiments, however, are carried out under isothermal temperature conditions where the elapsed time to an event is measured as the independent parameter. Isothermal Kinetics (Test Methods E2070), Thermal Stability (Test Method E487), Oxidative Induction Time (OIT) (Test Methods D3895, D4565, D5483, E1858, and Specification D3350) and Loss-on-Drying (Test Methods E1868) are common examples of these kinds of experiments.  
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SCOPE
1.1 This test method describes the calibration or performance confirmation of the elapsed-time signal from thermal analyzers.  
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5.1 Thermomechanical analyzers are employed in their various modes of operation (penetration, expansion, flexure, etc.) to characterize a wide range of materials. In most cases, the value to be assigned in thermomechanical measurements is the temperature of the transition (or event) under study. Therefore, the temperature axis (abscissa) of all TMA thermal curves must be accurately calibrated either by direct reading of a temperature sensor or by adjusting the programmer temperature to match the actual temperature over the temperature range of interest.
SCOPE
1.1 This test method describes the temperature calibration of thermomechanical analyzers from −50 °C to 1500 °C. (See Note 1.)  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.  
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Standard Test Method for Performance Validation of Thermomechanical Analyzers

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5.1 This test method may be used to determine and validate the performance of a particular thermomechanical analyzer apparatus.  
5.2 This test method may be used to determine and validate the performance of a particular method based upon thermomechanical analyzer temperature or length change measurements.  
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5.4 This test method may be used for specification and regulatory compliance purposes.
SCOPE
1.1 This test method provides procedures for validating temperature and length change measurements of thermomechanical analyzers (TMA) and analytical methods based upon the measurement of temperature and length change. Performance parameters include temperature repeatability, linearity, and bias; and dimension change repeatability, detection limit, quantitation limit, linearity, and bias.  
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ASTM E235/E235M-23(Specification)
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ABSTRACT
This specification covers the requirements for sheathed, Type K and N thermocouples for nuclear service. This specification can be used for sheathed thermocouples which are required for laboratory or general commercial applications where the environmental conditions exceed normal service requirements. The measuring junction styles for thermocouples are as follows: Style G2 (grounded) in which measuring junction is electrically connected to conductive sheaths and Style U2 (ungrounded) in which measuring junctions are electrically isolated from conductive sheaths and from reference ground. Different properties of the sheath such as integrity, cracks, voids, inclusions, surface finish, surface defect, and metallurgical structure shall be determined by performing different tests. Insulation resistance between thermoelements and the sheath shall be measured as well.
SCOPE
1.1 This specification covers the requirements for simplex, compacted mineral-insulated, metal-sheathed (MIMS), Type K and N thermocouples for nuclear or other high reliability service. Depending on size, these thermocouples are normally suitable for operating temperatures to 1652 °F [900 °C]; special conditions of environment and life expectancy may permit their use at temperatures in excess of 2012 °F [1100 °C]. This specification was prepared to detail requirements for this type of MIMS thermocouple for use in nuclear environments, but they can also be used for laboratory or general commercial applications where the environmental conditions exceed normal service requirements. The intended use of a MIMS thermocouple in a specific nuclear application will require evaluation of the compatibility of the thermocouple, including the effect of the temperature, atmosphere, and integrated neutron flux on the materials and accuracy of the thermoelements in the proposed application by the purchaser.  
1.2 This specification does not attempt to include all possible specifications, standards, etc., for materials that may be used as sheathing, insulation, and thermocouple wires for sheathed-type construction. The requirements of this specification include only the austenitic stainless steels and other alloys as allowed by Specification E585/E585M for sheathing, magnesium oxide or aluminum oxide as insulation, and Type K and N thermocouple wires for thermoelements (see Note 1).  
1.3 General Design—Nominal sizes of the finished thermocouples shall be 0.0400 in., 0.0625 in., 0.125 in., 0.1875 in., or 0.250 in. [1.000 mm, 1.500 mm, 3.000 mm, 4.500 mm, or 6.000 mm]. Sheath dimensions and tolerances for each nominal size shall be in accordance with Table 1 and Figs. 1 and 2. The measuring junction styles for thermocouples covered by this specification are as follows:  
FIG. 1 Grounded Measuring Junction, Style G  
FIG. 2 Ungrounded Measuring Junction, Style U  
1.3.1 Style G2  (grounded)—The measuring junction is electrically connected to its conductive sheath, and  
1.3.2 Style U2 (ungrounded)—The measuring junction is electrically isolated from its conductive sheath and from reference ground.  
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not exact equivalents or conversions; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recomm...

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ASTM
ASTM E1350-18(2023)(Guide)
Standard Guide for Testing Sheathed Thermocouples, Thermocouple Assemblies, and Connecting Wires Prior to, and After Installation or Service

SIGNIFICANCE AND USE
5.1 These test procedures confirm and document that the thermocouple assembly was not damaged prior to or during the installation process and that the extension wires are properly connected.  
5.2 The test procedures should be used when thermocouple assemblies are first installed in their working environment.  
5.3 In the event of subsequent thermocouple failure, these procedures will provide benchmark data to verify failure and may help to identify the cause of failure.  
5.4 The usefulness and purpose of the applicable tests will be found within each category.  
5.5 These tests are not meant to ensure that the thermocouple assembly will measure temperatures accurately. Such assurance is derived from proper thermocouple and instrumentation selection and proper placement in the location at which the temperature is to be measured. For further information, the reader is directed to MNL 12, Manual on the Use of the Thermocouples in Temperature Measurement2 which is an excellent reference document on metal sheathed thermocouple uses.
SCOPE
1.1 This guide covers methods for users to test metal sheathed thermocouple assemblies, including the extension wires just prior to and after installation or some period of service.  
1.2 The tests are intended to ensure that the thermocouple assemblies have not been damaged during storage or installation, to ensure that the extension wires have been attached to connectors and terminals with the correct polarity, and to provide benchmark data for later reference when testing to assess possible damage of the thermocouple assembly after operation. Some of these tests may not be appropriate for thermocouples that have been exposed to temperatures higher than the recommended limits for the particular type.  
1.3 The tests described herein include methods to measure the following characteristics of installed sheathed thermocouple assemblies and to provide benchmark data for determining if the thermocouple assembly has been subsequently damaged in operation:  
1.3.1 Loop Resistance:  
1.3.1.1 Thermoelements,
1.3.1.2 Combined extension wires and thermoelements.  
1.3.2 Insulation Resistance:  
1.3.2.1 Insulation, thermocouple assembly,
1.3.2.2 Insulation, thermocouple assembly and extension wires.  
1.3.3 Seebeck Voltage:  
1.3.3.1 Thermoelements,
1.3.3.2 Combined extension wires and thermocouple assembly.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM E585/E585M-23(Specification)
Standard Specification for Compacted Mineral-Insulated, Metal-Sheathed, Base Metal Thermocouple Cable

ABSTRACT
This specification establishes the required material, processing and testing requirements, and also the optional supplementary testing and quality assurance and verification choices for compacted, mineral-insulated, metal-sheathed, base metal thermocouple cables with at least two thermoelements. The material of construction includes standard base metal thermoelements, austenitic stainless steel or other corrosion resistant sheath material, and either magnesia (MgO) or alumina (Al2O3) insulation. The required tests to which the thermocouple cables shall undergo for quality verification are dimensions, insulation resistance at room temperature, calibration, electrical continuity, insulation density, sheath integrity, and EMF versus temperature values.
SCOPE
1.1 This specification establishes requirements for compacted, mineral-insulated, metal-sheathed (MIMS), base metal thermocouple cable,2 with at least two thermoelements.3  
1.2 This specification describes the required material, processing and testing requirements, optional supplementary testing, quality assurance, and verification choices.  
1.3 The material of construction includes standard base metal thermoelements, austenitic stainless steel or other corrosion resistant sheath material, and either magnesia (MgO) or alumina (Al2O3) insulation.  
1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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  • Technical specification
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