ASTM D1007-00
(Specification)Standard Specification for sec-Butyl Alcohol
Standard Specification for <i>sec</i>-Butyl Alcohol
SCOPE
1.1 This specification covers sec -butyl alcohol for use in paint, varnish, lacquer, and related products.
1.2 For hazard information and guidance, see the supplier's Material Safety Data Sheet.
General Information
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Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 1007 – 00
Standard Specification for
,
1 2
sec-Butyl Alcohol
This standard is issued under the fixed designation D 1007; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope* 3. Properties
1.1 This specification covers sec-butyl alcohol for use in 3.1 sec-Butyl alcohol shall conform to the following re-
paint, varnish, lacquer, and related products. quirements:
1.2 For hazard information and guidance, see the supplier’s
Apparent specific gravity:
20/20°C 0.807 to 0.809
Material Safety Data Sheet.
25/25°C 0.804 to 0.806
Color, Pt-Co scale, max 10
2. Referenced Documents
Distillation range, 760 mmHg, °C as:
Initial boiling point, min 98.0
2.1 ASTM Standards:
Dry point, max 101.0
D 268 Guide for Sampling and Testing Volatile Solvents
Nonvolatile matter, max, mg/100 mL 5
and Chemical Intermediates for Use in Paint and Related
Water, max, weight % 0.5
A
Acidity, as acetic acid, max, weight % 0.002
Coatings and Materials
__________
D 1078 Test Method for Distillation Range of Volatile
A
Equivalent to 0.019 mg of KOH per gram of sample.
Organic Liquids
D 1209 Test Method for Color of Clear Liquids (Platinum-
4. Sampling
Cobalt Scale)
4.1 The material shall be sampled in accordance with
D 1353 Test Method for Nonvolatile Matter in Volatile
Practice E 300.
Solvents for Use in Paint, Varnish, Lacquer, and Related
Products
5. Test Methods
D 1364 Test Method for Water in Volatile Solvents (Karl
5.1 The properties enumerated in this specification shall be
Fischer Reagent Titration Method)
determined in accordance with the following ASTM methods:
D 1613 Test Method for Acidity in Volatile Solvents and
5.1.1 Apparent Specific Gravity—Determine the apparent
Chemical Intermediates Used in Paint, Varnish, Lacquer,
specific gravity at 20 or 25°C by a convenient method that is
and Related Products
accurate to the third decimal place. See Guide D 268 or Test
D 4052 Test Method for Density and Relative Density of
Method D 4052.
Liquids by Digital Density Meter
5.1.2 Color—Test Method D 1209.
E1 Specification for ASTM Thermometers
5.1.3 Distillation Range—Test Method D 1078 using an
E 300 Practice for Sampling Industrial Chemicals
ASTM Solvents DistillationThermometer 40C, having a range
2.2 U.S. Federal Specification:
from 72 to 126°C and conforming to the requirements in
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
SpecificationE1.
of
5.1.4 Nonvolatile Matter—Test Method D 1353.
5.1.5 Water—Test Methods D 1364 .
5.1.6 Acidity—Test Method D 1613.
Th
...
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SIGNIFICANCE AND USE
4.1 The kauri-butanol value is used as a measure of solvent power of hydrocarbon solvents. High kauri-butanol values indicate relatively strong solvency.
SCOPE
1.1 This test method covers the determination of the relative solvent power of hydrocarbon solvents used in paint and lacquer formulations. This test method is suitable for use with solvents having an initial boiling point over 40 °C and a dry point under 300 °C when determined in accordance with the procedures in Note 1.
Note 1: Test Method D86 is used to determine the initial boiling point and dry point for mineral spirits and similar petroleum solvents. Test Method D1078 is used for pure compounds and narrow boiling range cuts.
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification establishes the properties and requirements for sec-butyl alcohol for use in paint, varnish, lacquer, and related products. Specimens shall be sampled and tested as appropriate, and shall adhere to the following requirements: apparent specific gravity; color (Pt-Co scale); distillation range (initial boiling point and dry point); nonvolatile matter; water; and acidity as acetic acid.
SCOPE
1.1 This specification covers sec-butyl alcohol for use in paint, varnish, lacquer, and related products.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
4.1 The kauri-butanol value is used as a measure of solvent power of hydrocarbon solvents. High kauri-butanol values indicate relatively strong solvency.
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1.1 This test method covers the determination of the relative solvent power of hydrocarbon solvents used in paint and lacquer formulations. This test method is suitable for use with solvents having an initial boiling point over 40 °C and a dry point under 300 °C when determined in accordance with the procedures in Note 1.
Note 1: Test Method D86 is used to determine the initial boiling point and dry point for mineral spirits and similar petroleum solvents. Test Method D1078 is used for pure compounds and narrow boiling range cuts.
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification establishes the properties and requirements for sec-butyl alcohol for use in paint, varnish, lacquer, and related products. Specimens shall be sampled and tested as appropriate, and shall adhere to the following requirements: apparent specific gravity; color (Pt-Co scale); distillation range (initial boiling point and dry point); nonvolatile matter; water; and acidity as acetic acid.
SCOPE
1.1 This specification covers sec-butyl alcohol for use in paint, varnish, lacquer, and related products.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
5.1 This test method is useful in characterizing certain petroleum products, as one element in establishing uniformity of shipments and sources of supply.
5.2 See Guide D117 for applicability to mineral oils used as electrical insulating oils.
5.3 The Saybolt Furol viscosity is approximately one tenth the Saybolt Universal viscosity, and is recommended for characterization of petroleum products such as fuel oils and other residual materials having Saybolt Universal viscosities greater than 1000 s.
5.4 Determination of the Saybolt Furol viscosity of bituminous materials at higher temperatures is covered by Test Method E102/E102M.
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1.1 This test method covers the empirical procedures for determining the Saybolt Universal or Saybolt Furol viscosities of petroleum products at specified temperatures between 21 and 99 °C [70 and 210 °F]. A special procedure for waxy products is indicated.
Note 1: Test Methods D445 and D2170/D2170M are preferred for the determination of kinematic viscosity. They require smaller samples and less time, and provide greater accuracy. Kinematic viscosities may be converted to Saybolt viscosities by use of the tables in Practice D2161. It is recommended that viscosity indexes be calculated from kinematic rather than Saybolt viscosities.
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SIGNIFICANCE AND USE
5.1 Research O.N. correlates with commercial automotive spark-ignition engine antiknock performance under mild conditions of operation.
5.2 Research O.N. is used by engine manufacturers, petroleum refiners and marketers, and in commerce as a primary specification measurement related to the matching of fuels and engines.
5.2.1 Empirical correlations that permit calculation of automotive antiknock performance are based on the general equation:
Values of k1, k2, and k3 vary with vehicles and vehicle populations and are based on road-O.N. determinations.
5.2.2 Research O.N., in conjunction with Motor O.N., defines the antiknock index of automotive spark-ignition engine fuels, in accordance with Specification D4814. The antiknock index of a fuel approximates the Road octane ratings for many vehicles, is posted on retail dispensing pumps in the U.S., and is referred to in vehicle manuals.
This is more commonly presented as:
5.2.3 Research O.N. is also used either alone or in conjunction with other factors to define the Road O.N. capabilities of spark-ignition engine fuels for vehicles operating in areas of the world other than the United States.
5.3 Research O.N. is used for measuring the antiknock performance of spark-ignition engine fuels that contain oxygenates.
5.4 Research O.N. is important in relation to the specifications for spark-ignition engine fuels used in stationary and other nonautomotive engine applications.
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1.1 This laboratory test method covers the quantitative determination of the knock rating of liquid spark-ignition engine fuel in terms of Research O.N., including fuels that contain up to 25 % v/v of ethanol. However, this test method may not be applicable to fuel and fuel components that are primarily oxygenates.2 The sample fuel is tested using a standardized single cylinder, four-stroke cycle, variable compression ratio, carbureted, CFR engine run in accordance with a defined set of operating conditions. The O.N. scale is defined by the volumetric composition of PRF blends. The sample fuel knock intensity is compared to that of one or more PRF blends. The O.N. of the PRF blend that matches the K.I. of the sample fuel establishes the Research O.N.
1.2 The O.N. scale covers the range from 0 to 120 octane number but this test method has a working range from 40 to 120 Research O.N. Typical commercial fuels produced for spark-ignition engines rate in the 88 to 101 Research O.N. range. Testing of gasoline blend stocks or other process stream materials can produce ratings at various levels throughout the Research O.N. range.
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SIGNIFICANCE AND USE
5.1 Motor O.N. correlates with commercial automotive spark-ignition engine antiknock performance under severe conditions of operation.
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Values of k1, k2, and k3 vary with vehicles and vehicle populations and are based on road-octane number determinations.
5.2.2 Motor O.N., in conjunction with Research O.N., defines the antiknock index of automotive spark-ignition engine fuels, in accordance with Specification D4814. The antiknock index of a fuel approximates the road octane ratings for many vehicles, is posted on retail dispensing pumps in the United States, and is referred to in vehicle manuals.
This is more commonly presented as:
5.3 Motor O.N. is used for measuring the antiknock performance of spark-ignition engine fuels that contain oxygenates.
5.4 Motor O.N. is important in relation to the specifications for spark-ignition engine fuels used in stationary and other nonautomotive engine applications.
5.5 Motor O.N. is utilized to determine, by correlation equation, the Aviation method O.N. or performance number (lean-mixture aviation rating) of aviation spark-ignition engine fuel.7
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1.1 This laboratory test method covers the quantitative determination of the knock rating of liquid spark-ignition engine fuel in terms of Motor octane number, including fuels that contain up to 25 % v/v of ethanol. However, this test method may not be applicable to fuel and fuel components that are primarily oxygenates.2 The sample fuel is tested in a standardized single cylinder, four-stroke cycle, variable compression ratio, carbureted, CFR engine run in accordance with a defined set of operating conditions. The octane number scale is defined by the volumetric composition of primary reference fuel blends. The sample fuel knock intensity is compared to that of one or more primary reference fuel blends. The octane number of the primary reference fuel blend that matches the knock intensity of the sample fuel establishes the Motor octane number.
1.2 The octane number scale covers the range from 0 to 120 octane number, but this test method has a working range from 40 to 120 octane number. Typical commercial fuels produced for automotive spark-ignition engines rate in the 80 to 90 Motor octane number range. Typical commercial fuels produced for aviation spark-ignition engines rate in the 98 to 102 Motor octane number range. Testing of gasoline blend stocks or other process stream materials can produce ratings at various levels throughout the Motor octane number range.
1.3 The values of operating conditions are stated in SI units and are considered standard. The values in parentheses are the historical inch-pounds units. The standardized CFR engine measurements continue to be in inch-pound units only because of the extensive and expensive tooling that has been created for this equipment.
1.4 For purposes of determining conformance with all specified limits in this standard, an observed value or a calculated value shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specified limit, in accordance with the rounding method of Practice E29.
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SIGNIFICANCE AND USE
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1.5 SI units are the standard. No other units of measurement are included in this standard.
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