ASTM D564-87(2014)
(Test Method)Standard Test Methods for Liquid Paint Driers
Standard Test Methods for Liquid Paint Driers
SIGNIFICANCE AND USE
3.1 Driers accelerate the drying of oil, paint, printing ink, and varnish.
3.2 These test methods are applicable to liquid driers manufactured for use in paints and related coatings.
3.3 The tests for metallic content using ethylenediaminetetraacetic acid dihydrate (EDTA) are intended for concentrated solutions of single metals; two or more metals may cause interference.
SCOPE
1.1 These test methods cover the test procedures to be applied to liquid paint driers used in paints and related coatings. Typical paint driers, listed in Specification D600, are carboxylates of lead, cobalt, manganese, zinc, iron, calcium, and zirconium.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
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Designation: D564 − 87 (Reapproved 2014)
Standard Test Methods for
Liquid Paint Driers
This standard is issued under the fixed designation D564; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope D2374Test Method for Lead in Paint Driers by EDTA
Method
1.1 These test methods cover the test procedures to be
D2375TestMethodforManganeseinPaintDriersbyEDTA
applied to liquid paint driers used in paints and related
Method
coatings. Typical paint driers, listed in Specification D600, are
D2613Test Method for Calcium or Zinc in Paint Driers by
carboxylates of lead, cobalt, manganese, zinc, iron, calcium,
EDTA Method
and zirconium.
D3804Test Method for Iron in Paint Driers by EDTA
1.2 The values stated in SI units are to be regarded as
Method
standard. No other units of measurement are included in this
D3924Specification for Environment for Conditioning and
standard.
Testing Paint, Varnish, Lacquer, and Related Materials
1.3 This standard does not purport to address all of the
D3969Test Method for Zirconium in Paint Driers by EDTA
safety concerns, if any, associated with its use. It is the Method
responsibility of the user of this standard to establish appro-
D3970Test Method for Cerium in Paint Driers by Oxidime-
priate safety and health practices and determine the applica- tric Determination
bility of regulatory limitations prior to use.
D3980Practice for Interlaboratory Testing of Paint and
Related Materials (Withdrawn 1998)
2. Referenced Documents
D3988Test Method for Vanadium in Paint Driers by EDTA
Method
2.1 ASTM Standards:
D234Specification for Raw Linseed Oil (Withdrawn 2007) D3989Test Method for Total Rare Earth Metals in Paint
Driers by EDTA Method
D235Specification for Mineral Spirits (Petroleum Spirits)
(Hydrocarbon Dry Cleaning Solvent)
3. Significance and Use
D600Specification for Liquid Paint Driers
D1544TestMethodforColorofTransparentLiquids(Gard-
3.1 Driers accelerate the drying of oil, paint, printing ink,
ner Color Scale)
and varnish.
D1640Test Methods for Drying, Curing, or Film Formation
3.2 These test methods are applicable to liquid driers
of Organic Coatings at Room Temperature
D1644Test Methods for Nonvolatile Content of Varnishes manufactured for use in paints and related coatings.
D2090Test Method for Clarity and Cleanness of Paint and
3.3 The tests for metallic content using ethylenediaminetet-
Ink Liquids (Withdrawn 2007)
raacetic acid dihydrate (EDTA) are intended for concentrated
D2373Test Method for Determination of Cobalt in Paint
solutions of single metals; two or more metals may cause
Driers by EDTA Method
interference.
4. Physical Tests
These test methods are under the jurisdiction of ASTM Committee D01 on
Paint and Related Coatings, Materials, and Applications and are the direct
4.1 Sampling—Sample in accordance with Practice D3980.
responsibility of Subcommittee D01.21 on Chemical Analysis of Paints and Paint
Materials.
4.2 Conditioning—Follow Specification D3924 except
CurrenteditionapprovedJuly1,2014.PublishedJuly2014.Originallyapproved
in 1940. Last previous edition approved in 2008 as D564–87(2008). DOI: where other temperatures are specified.
10.1520/D0564-87R14.
4.3 Appearance—Afterconditioningovernightatroomtem-
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
perature (see Specification D3924) examine the drier without
Standards volume information, refer to the standard’s Document Summary page on
aid of magnification for clarity and cleanness and for presence
the ASTM website.
of foreign matter, sediment, skins, turbidity or haziness, in
The last approved version of this historical standard is referenced on
www.astm.org. accordance with Test Method D2090.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D564 − 87 (2014)
4.4 Sediment or Suspended Matter—If sediment or sus- 4.9 Drying Power—Determine the drying power in accor-
pended matter is observed, proceed as follows: dancewithTestMethodsD1640.Itisusefultotestapreviously
4.4.1 Weigh to 1 mg, by difference, 1 to5gof drier into a evaluated standard of known drying power for comparative
tared 10 to 15-µm fritted-glass crucible.After most of the drier purposes.
has passed through wash with mineral spirits conforming to
NOTE 4—The drying powers or efficiencies of individual metal driers
SpecificationD235anddryat50°Cuntiltheweightisconstant
may be a function of: (1) the class of carboxylic acids, for example,
to 1 mg. Calculate the difference in weight and report as
octoate versus naphthenate, etc., (2) additives in drier solutions, for
example,
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D564 − 87 (Reapproved 2008) D564 − 87 (Reapproved 2014)
Standard Test Methods for
Liquid Paint Driers
This standard is issued under the fixed designation D564; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope
1.1 These test methods cover the test procedures to be applied to liquid paint driers used in paints and related coatings. Typical
paint driers, listed in Specification D600, are carboxylates of lead, cobalt, manganese, zinc, iron, calcium, and zirconium.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
D234 Specification for Raw Linseed Oil (Withdrawn 2007)
D235 Specification for Mineral Spirits (Petroleum Spirits) (Hydrocarbon Dry Cleaning Solvent)
D600 Specification for Liquid Paint Driers
D1544 Test Method for Color of Transparent Liquids (Gardner Color Scale)
D1640 Test Methods for Drying, Curing, or Film Formation of Organic Coatings at Room Temperature
D1644 Test Methods for Nonvolatile Content of Varnishes
D2090 Test Method for Clarity and Cleanness of Paint and Ink Liquids (Withdrawn 2007)
D2373 Test Method for Determination of Cobalt in Paint Driers by EDTA Method
D2374 Test Method for Lead in Paint Driers by EDTA Method
D2375 Test Method for Manganese in Paint Driers by EDTA Method
D2613 Test Method for Calcium or Zinc in Paint Driers by EDTA Method
D3804 Test Method for Iron in Paint Driers by EDTA Method
D3924 Specification for Environment for Conditioning and Testing Paint, Varnish, Lacquer, and Related Materials
D3969 Test Method for Zirconium in Paint Driers by EDTA Method
D3970 Test Method for Cerium in Paint Driers by Oxidimetric Determination
D3980 Practice for Interlaboratory Testing of Paint and Related Materials (Withdrawn 1998)
D3988 Test Method for Vanadium in Paint Driers by EDTA Method
D3989 Test Method for Total Rare Earth Metals in Paint Driers by EDTA Method
3. Significance and Use
3.1 Driers accelerate the drying of oil, paint, printing ink, and varnish.
3.2 These test methods are applicable to liquid driers manufactured for use in paints and related coatings.
3.3 The tests for metallic content using ethylenediaminetetraacetic acid dihydrate (EDTA) are intended for concentrated
solutions of single metals; two or more metals may cause interference.
These test methods are under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and are the direct responsibility of
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.
Current edition approved Feb. 1, 2008July 1, 2014. Published February 2008July 2014. Originally approved in 1940. Last previous edition approved in 20022008 as
D564 – 87 (2002).(2008). DOI: 10.1520/D0564-87R08.10.1520/D0564-87R14.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
The last approved version of this historical standard is referenced on www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D564 − 87 (2014)
4. Physical Tests
4.1 Sampling—Sample in accordance with Practice D3980.
4.2 Conditioning—Follow Specification D3924 except where other temperatures are specified.
4.3 Appearance—After conditioning overnight at room temperature (see Specification D3924) examine the drier without aid of
magnification for clarity and cleanness and for presence of foreign matter, sediment, skins, turbidity or haziness, in accordance with
Test Method D2090.
4.4 Sediment or Suspended Matter—If sediment or suspended matter is observed, proceed as follows:
4.4.1 Weigh to 1 mg, by difference, 1 to 5 g of drier into a tared 10 to 15-μm fritted-glass crucible. After most of the drier has
passed through wash with mineral spirits conforming to Specification D235 and dry at 50°C until the weight is constant to 1 mg.
Calculate the difference in weight and report as percent sediment in the drier.
4.5 Color—Determine color in accordance with Test Method D1544.
NOTE 1—This scale is useful for yellow and brown organic chromophores, but not with the reds or purple of cobalt and certain other metal compounds.
4.6 Nonvolatile Matter—De
...
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