ASTM D5200-03(2021)

• Abstract:

  SIGNIFICANCE AND USE; 4.1 This test method is the procedure of choice for determining the volatile content in aerosol coatings under specified test conditions modeled after Method 35.4 The inverse value, nonvolatile, is used to determine the weight percent solids content. This information is useful to the paint producer, user, and to environmental interests for determining the grams of volatile organic compounds per gram of solids emitted from aerosol cans.; SCOPE; 1.1 This test method is for the determination of the weight percent volatile organic compounds of solvent-borne paints in aerosol cans. It offers a unique way to obtain paint specimens from aerosol cans. ; 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. ; 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. A specific hazard statement is given in 6.7. ; 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

• Status: Published
• Publication Date: 31-Jan-2021
• ICS: 87.040 - Paints and varnishes
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.21 - Chemical Analysis of Paints and Paint Materials

• Refers: ASTM E145-19 - Standard Specification for Gravity-Convection and Forced-Ventilation Ovens
• Effective Date: 01-Mar-2019
• Refers: ASTM E145-94(2011) - Standard Specification for Gravity-Convection and Forced-Ventilation Ovens
• Effective Date: 01-Dec-2011
• Refers: ASTM E145-94(2006) - Standard Specification for Gravity-Convection And Forced-Ventilation Ovens
• Effective Date: 01-Nov-2006
• Refers: ASTM E145-94e1 - Standard Specification for Gravity-Convection And Forced-Ventilation Ovens
• Effective Date: 15-Aug-1994
• Refers: ASTM E145-94(2001) - Standard Specification for Gravity-Convection And Forced-Ventilation Ovens
• Effective Date: 15-Aug-1994

Overview

ASTM D5200-03(2021) is the internationally recognized standard test method for determining the weight percent volatile content in solvent-borne paints packaged in aerosol cans. Developed by ASTM International, this method provides precise procedures for quantifying the amount of volatile organic compounds (VOC) present in aerosol coatings. The results obtained from this method are critical for paint manufacturers, users, and regulatory authorities to assess product content, manage environmental impact, and ensure compliance with regulations regarding VOC emissions from aerosol paints.

Key Topics

• Volatile Content Determination: This standard outlines a laboratory procedure for accurately measuring the weight percent of volatile organic compounds in solvent-borne aerosol paints. The method requires specialized equipment such as a glass tube assembly, oven, and precise balance, ensuring reliability and repeatability.
• Solids and Nonvolatile Calculation: The inverse of the volatile content provides the weight percent solids (nonvolatile matter) in the paint, essential for formulation quality and regulatory reporting.
• Environmental Significance: Quantification of VOC emissions from aerosol cans is vital for understanding environmental impacts and complying with air quality regulations.
• Safety and Compliance: The standard emphasizes the importance of safety precautions when handling aerosol paints, solvents, and related laboratory equipment, and directs users to establish proper health and environmental practices.

Applications

• Paint Manufacturing: Paint producers utilize ASTM D5200-03(2021) to determine the volatile content of aerosol coatings during product development, formulation adjustment, and quality control.
• Regulatory Compliance: This method supports environmental compliance by providing accurate VOC measurements, which are used to calculate emissions per gram of solids and to satisfy reporting requirements for air quality standards.
• Product Labeling and User Information: Clear documentation of VOC and solids content aids in accurate product labeling, enhancing transparency for end users.
• Laboratory Testing: Research and development laboratories use this standard to compare formulations, ensure batch consistency, and validate product performance through repeatable test results.

Related Standards

• ASTM Method 35: The procedure in ASTM D5200-03(2021) is modeled after Method 35, focusing on the determination of percent volatile organic compounds in solvent-based aerosol paints.
• ASTM E145: Specification for gravity-convection and forced-ventilation ovens, referenced for the temperature and equipment requirements.
• ASTM E180: Practice for determining the precision of ASTM methods for analysis and testing of industrial and specialty chemicals, providing guidance on data analysis and test method validation.

Practical Value

Implementing ASTM D5200-03(2021) ensures consistent and precise determination of volatile content in solvent-borne aerosol paints, supporting:

• Enhanced quality control processes
• Effective VOC management and regulatory reporting
• Safer laboratory practices
• Environmental stewardship in paint manufacturing

By adhering to this standard, organizations can accurately monitor and control the VOC emissions of their aerosol paint products, contributing to both product excellence and environmental responsibility.

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5200 − 03 (Reapproved 2021)
Standard Test Method for
Determination of Weight Percent Volatile Content of Solvent-
Borne Paints in Aerosol Cans
This standard is issued under the fixed designation D5200; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2.2 Other Standard:
Method 35 Determination of PercentVolatile Organic Com-
1.1 This test method is for the determination of the weight
pounds (VOC) in Solvent Based Aerosol Paints
percent volatile organic compounds of solvent-borne paints in
aerosol cans. It offers a unique way to obtain paint specimens
3. Summary of Test Method
from aerosol cans.
3.1 Adesignatedquantityfromanaerosolcoatingissprayed
1.2 The values stated in SI units are to be regarded as into an adapter glass tube assembly and heated in an oven at
110 6 5°C for 60 min. The percent volatile is calculated from
standard. No other units of measurement are included in this
the loss in weight.
standard.
1.3 This standard does not purport to address all of the
4. Significance and Use
safety concerns, if any, associated with its use. It is the
4.1 This test method is the procedure of choice for deter-
responsibility of the user of this standard to establish appro-
mining the volatile content in aerosol coatings under specified
priate safety, health, and environmental practices and deter-
test conditions modeled after Method 35. The inverse value,
mine the applicability of regulatory limitations prior to use. A
nonvolatile, is used to determine the weight percent solids
specific hazard statement is given in 6.7.
content. This information is useful to the paint producer, user,
1.4 This international standard was developed in accor-
and to environmental interests for determining the grams of
dance with internationally recognized principles on standard-
volatile organic compounds per gram of solids emitted from
ization established in the Decision on Principles for the
aerosol cans.
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical
5. Apparatus
Barriers to Trade (TBT) Committee.
5.1 Adapter Glass Tube Assembly, (Fig. 1).
5.1.1 Sample Adapter Tube, straight connecting with 35/25
2. Referenced Documents
spherical joints. Loosely fill with glass wool and precondition
for 30 min in an oven at 110 6 5°C and store in a dessicator
2.1 ASTM Standards:
5,6
prior to use.
E145 Specification for Gravity-Convection and Forced-
5.1.2 Charcoal Adapter Tube, straight connecting with
Ventilation Ovens
35/25 spherical joints. Fill with activated charcoal and plug
E180 Practice for Determining the Precision of ASTM
both ends with glass wool. This tube is used to prevent the
Methods for Analysis and Testing of Industrial and Spe-
6,7
3 solvent vapors from contaminating the vacuum pump.
cialty Chemicals (Withdrawn 2009)
6,8
5.1.3 Adapters, connecting hose with 35/25 socket joints.
1 4
This test method is under the jurisdiction of ASTM Committee D01 on Paint Bay Area Air Quality Management District, (BAAQMD) Manual of
and Related Coatings, Materials, andApplications and is the direct responsibility of Procedures, Vol III, 939 Ellis St., San Francisco, CA 94109.
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials. The sole source of supply of the adapter tube, No. 5035-35 known to the
Current edition approved Feb. 1, 2021. Published February 2021. Originally committee at this time is Ace Glass Inc., P.O. Box 688, 1430 Northwest Blvd.,
approved in 1991. Last previous edition approved in 2014 as D5200 – 03 (2014). Vineland, NJ 08360.
DOI: 10.1520/D5200-03R21. If you are aware of alternative suppliers, please provide this information to
For referenced ASTM standards, visit the ASTM website, www.astm.org, or ASTM International Headquarters. Your comments will receive careful consider-
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM ation at a meeting of the responsible technical committee, which you may attend.
Standards volume information, refer to the standard’s Document Summary page on The sole source of supply of the charcoal adapter tube, No. 5035-3 known to
the ASTM website. the committee at this time is Ace Glass Inc.
3 8
The last approved version of this historical standard is referenced on The sole source of supply of the adapters (socket joints) No. 5217-35 known to
www.astm.org. the committee at this time is Ace Glass Inc.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D5200 − 03 (2021)
5.6 Shaker, similar to the Eberbach shaker in Fig. 2.
6. Procedure
6.1 Mix the aerosol can thoroughly using a shaker, similar
to the Eberbach shaker in Fig. 2, for 15 min at the low-speed
setting. It is essential that the samples be well mixe
...