Soil, treated biowaste and sludge - Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)

This European Standard specifies the quantitative determination of 16 polycyclic aromatic hydrocarbons (PAH) (see Table 2) in sludge, soil and treated biowaste using GC-MS and HPLC-UV-DAD/FLD covering a wide range of PAH contamination levels (see also Annex B).
When using fluorescence detection, acenaphthylene cannot be measured.
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Typically, a lower limit of application of 0,01 mg/kg (expressed as dry matter) can be ensured for each individual PAH. This depends on instrument and sample.
Sludge, soil and treated biowaste can differ in properties and also in the expected contamination levels of PAHs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used. Two general lines are followed, an agitation procedure (shaking) or use of soxhlet/pressurized liquid extraction.
NOTE   Other PAH compounds can also be analysed with this method, provided suitability has been proven.

Boden, behandelter Bioabfall und Schlamm - Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK) mittels Gaschromatographie (GC) und Hochleistungs-Flüssigkeitschromatographie (HPLC)

Diese Europäische Norm legt die quantitative Bestimmung von 16 polycyclischen aromatischen Kohlenwasserstoffen (PAK) (siehe Tabelle 2) in Schlamm und behandeltem Bioabfall unter Anwendung der GC MS und HPLC UV DAD/FLD fest, wobei ein breiter Bereich von PAK Kontaminationsniveaus (siehe auch Anhang B) abgedeckt wird.
Bei Anwendung der Fluoreszenzdetektion kann Acenaphthylen nicht gemessen werden.

Sols, biodéchets traités et boues - Dosage des hydrocarbures aromatiques polycycliques (HAP) par chromatographie en phase gazeuse et chromatographie liquide à haute performance

La présente Norme européenne spécifie le dosage de 16 hydrocarbures aromatiques polycycliques (HAP) (voir Tableau 2) dans les boues, les sols et les biodéchets traités, faisant appel à des méthodes CG-SM et HPLC-UV-DAD/FLD couvrant une large gamme de niveaux de contamination par les HAP (voir également l’Annexe B).
L’utilisation d’une méthode de détection fluorimétrique ne permet pas le mesurage de l’acénaphtylène.
(...)
La limite de détection dépend des composés à analyser, de l’équipement utilisé, de la qualité des réactifs chimiques utilisés pour l’extraction de l’échantillon et la purification de l’extrait.
En général, une limite inférieure d’application de 0,01 mg/kg (exprimée en matière sèche) peut être atteinte pour chacun des HAP. Cela dépend de l’instrument et de l’échantillon.
Les boues, les sols et les biodéchets traités peuvent présenter des propriétés, des niveaux de contamination par les HAP attendus et des substances interférentes différents. En raison de ces différences, il est impossible de décrire un mode opératoire général. La présente Norme européenne contient des tables de décision basées sur les propriétés de l'échantillon ainsi que sur le mode opératoire d'extraction et de purification à utiliser. Deux routes analytiques générales sont suivies : un mode opératoire par agitation ou l’utilisation d’une méthode d’extraction au Soxhlet/par liquide pressurisé.
NOTE   D’autres composés HAP peuvent être également analysés avec cette méthode, à condition que l’aptitude à l’emploi soit prouvée.

Tla, obdelani biološki odpadki in blato - Določevanje policikličnih aromatskih ogljikovodikov (PAH) s plinsko kromatografijo (GC) in s tekočinsko kromatografijo visoke ločljivosti (HPLC)

Ta evropski standard določa kvantitativno določevanje 16 policikličnih aromatskih ogljikovodikov (PAH) (glej preglednico 2) v blatu, tleh ter obdelanih bioloških odpadkih z metodama GC-MS in HPLC-UV-DAD/FLD, ki zajemata široko območje ravni onesnaženja PAH (glej tudi dodatek B).
S fluorescenčnim zaznavanjem ni mogoče izmeriti acenaftilena.
(...)
Meja detekcije je odvisna od determinant, uporabljene opreme, kakovosti kemikalij, uporabljenih za ekstrakcijo vzorca in očiščenje izvlečka.
Običajno je mogoče za vsak posamezen policiklični aromatski ogljikovodik zagotoviti spodnjo mejo uporabe 0,01 mg/kg (izraženo kot suha snov). To je odvisno od instrumenta in vzorca.
Blato, tla in obdelani biološki odpadki se lahko razlikujejo glede lastnosti, predvidenih ravni onesnaženja s policikličnimi aromatskimi ogljikovodiki ter prisotnosti motečih snovi. Zaradi teh razlik ni možen opis enotnega splošnega postopka. Ta evropski standard vključuje tabele odločanja, ki temeljijo na lastnostih vzorca, ter postopek za ekstrakcijo in očiščenje, ki ga je treba uporabiti. Upoštevata se dve splošni smernici, in sicer stresanje ali tekočinska ekstrakcija po Soxhletu/pod tlakom.
OPOMBA: S to metodo je mogoče analizirati tudi druge snovi PAH pod pogojem, da je bila dokazana primernost.

General Information

Status
Withdrawn
Publication Date
05-Jun-2018
Withdrawal Date
15-Feb-2022
Current Stage
9960 - Withdrawal effective - Withdrawal
Completion Date
16-Feb-2022

Relations

Buy Standard

Standard
EN 16181:2018
English language
47 pages
sale 10% off
Preview
sale 10% off
Preview
e-Library read for
1 day
Draft
prEN 16181:2017
English language
47 pages
sale 10% off
Preview
sale 10% off
Preview
e-Library read for
1 day

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Boden, behandelter Bioabfall und Schlamm - Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK) mittels Gaschromatographie (GC) und Hochleistungs-Flüssigkeitschromatographie (HPLC)Sols, biodéchets traités et boues - Dosage des hydrocarbures aromatiques polycycliques (HAP) par chromatographie en phase gazeuse et chromatographie liquide à haute performanceSoil, treated biowaste and sludge - Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)71.040.50Fizikalnokemijske analitske metodePhysicochemical methods of analysis13.080.10Chemical characteristics of soils13.030.20Liquid wastes. SludgeICS:Ta slovenski standard je istoveten z:EN 16181:2018SIST EN 16181:2018en,fr,de01-december-2018SIST EN 16181:2018SLOVENSKI
STANDARDSIST-TS CEN/TS 16181:20131DGRPHãþD



SIST EN 16181:2018



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16181
June
t r s z English Version
Soilá treated biowaste and sludge æ Determination of Solsá biodéchets traités et boues æ Dosage des chromatographie en phase gazeuse et chromatographie liquide à haute performance
Bodená behandelter Bioabfall und Schlamm æ Bestimmung von polycyclischen aromatischen This European Standard was approved by CEN on
v April
t r s zä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Serbiaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey and United Kingdomä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Rue de la Science 23,
B-1040 Brussels
9
t r s z CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s x s z sã t r s z ESIST EN 16181:2018



EN 16181:2018 (E) 2 Contents Page European foreword . 4 Introduction . 5 1 Scope . 6 2 Normative references . 7 3 Terms and definitions . 7 4 Principle . 8 5 Interferences . 9 5.1 Interference with sampling and extraction. 9 5.2 Interference with GC-MS . 9 5.3 Interferences with the HPLC . 9 6 Safety remarks . 10 7 Reagents . 10 8 Apparatus . 15 9 Sample storage and preservation . 17 9.1 Sample storage .
...

SLOVENSKI STANDARD
oSIST prEN 16181:2017
01-december-2017
%ODWRREGHODQLELRORãNLRGSDGNLLQWOD'RORþHYDQMHSROLFLNOLþQLKDURPDWVNLK
RJOMLNRYRGLNRY 3$+ VSOLQVNRNURPDWRJUDILMR *& LQVWHNRþLQVNRNURPDWRJUDILMR
YLVRNHORþOMLYRVWL +3/&
Soil, treated biowaste and sludge - Determination of polycyclic aromatic hydrocarbons
(PAH) by gas chromatography (GC) and high performance liquid chromatography
(HPLC)
Boden, behandelter Bioabfall und Schlamm - Bestimmung von polycyclischen
aromatischen Kohlenwasserstoffen (PAK) mittels Gaschromatographie (GC) und
Hochleistungs-Flüssigkeitschromatographie (HPLC)
Sols, biodéchets traités et boues - Dosage des hydrocarbures aromatiques polycycliques
(HAP) par chromatographie en phase gazeuse et chromatographie liquide à haute
performance
Ta slovenski standard je istoveten z: prEN 16181
ICS:
13.030.20 7HNRþLRGSDGNL%ODWR Liquid wastes. Sludge
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
oSIST prEN 16181:2017 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN 16181:2017

---------------------- Page: 2 ----------------------
oSIST prEN 16181:2017


DRAFT
EUROPEAN STANDARD
prEN 16181
NORME EUROPÉENNE

EUROPÄISCHE NORM

October 2017
ICS 13.030.01; 13.080.10 Will supersede CEN/TS 16181:2013
English Version

Soil, treated biowaste and sludge - Determination of
polycyclic aromatic hydrocarbons (PAH) by gas
chromatography (GC) and high performance liquid
chromatography (HPLC)
 Schlamm, behandelter Bioabfall und Boden -
Bestimmung von polycyclischen aromatischen
Kohlenwasserstoffen (PAK) mittels
Gaschromatographie (GC) und Hochleistungs-
Flüssigkeitschromatographie (HPLC)
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 444.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2017 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 16181:2017 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
oSIST prEN 16181:2017
prEN 16181:2017 (E)
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 7
3 Terms and definitions . 7
4 Principle . 8
5 Interferences . 9
5.1 Interference with sampling and extraction.
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.