EN ISO 12010:2014
(Main)Water quality - Determination of short-chain polychlorinated alkanes (SCCPs) in water - Method using gas chromatography-mass spectrometry (GC-MS) and negative-ion chemical ionization (NCI) (ISO 12010:2012)
Water quality - Determination of short-chain polychlorinated alkanes (SCCPs) in water - Method using gas chromatography-mass spectrometry (GC-MS) and negative-ion chemical ionization (NCI) (ISO 12010:2012)
ISO 12010:2012 specifies a method for the quantitative determination of the sum of short-chain polychlorinated n‑alkanes, also known as short-chain polychlorinated paraffins (SCCPs), in the carbon bond range n-C10 to n-C13 inclusive, in mixtures with chlorine mass fractions ("contents") between 49 % and 67 %, including approximately 6 300 of approximately 8 000 congeners.
This method is applicable to the determination of the sum of SCCPs in unfiltered surface water, ground water, drinking water and waste water using gas chromatography-mass spectrometry with electron capture negative ionization (GC-ECNI-MS).
The method can be applied to samples containing 0,1 µg/l to 10 µg/l. Depending on the waste water matrix, the lowest detectable concentration is estimated to be >0,1 µg/l.
Wasserbeschaffenheit - Bestimmung von kurzkettigen Chloralkanen (SCCP) in Wasser - Verfahren mittels Gaschromatographie-Massenspektrometrie (GC-MS) und negativer chemischer Ionisation (NCI) (ISO 12010:2012)
Diese Internationale Norm legt ein Verfahren zur quantitativen Bestimmung der Summe kurzkettiger polychlorierter n-Alkane (oder kurzkettiger polychlorierter Paraffine, Abk.: SCCP) mit einer Kohlenstoff-Kettenlänge zwischen n-C10 bis einschließlich n-C13 in Gemischen mit Chlorgehalten zwischen 49 % und 67 % fest, die ungefähr 6 300 der etwa 8 000 Kongenere umfassen.
Dieses Verfahren ist zur Bestimmung der Summe von SCCP in ungefiltertem Oberflächenwasser, Grund-wasser, Trinkwasser und Abwasser unter Verwendung der Gaschromatographie-Massenspektrometrie mit Elektroneneinfang nach negativer chemischer Ionisierung (GC-ECNI-MS) geeignet.
Das Verfahren kann für Proben mit einem Gehalt von 0,1 µg/l bis 10 µg/l angewendet werden. In Abhängigkeit von der Abwasser-Matrix ist die niedrigste nachweisbare Konzentration > 0,1 µg/l.
Qualité de l'eau - Détermination des alcanes polychlorés à chaîne courte (SCCP) dans l'eau - Méthode par chromatographie gazeuse-spectrométrie de masse (CG-SM) avec ionisation chimique négative (ICN) (ISO 12010:2012)
Kakovost vode - Določevanje polikloriranih alkanov s kratko verigo (SCCP) v vodi - Metoda s plinsko kromatografijo/masno spektrometrijo (GC/MS) in negativno kemijsko ionizacijo (NCI) (ISO 12010:2012)
EN ISO 12010 podaja metodo za kvantitativno določevanje vsote polikloriranih alkanov s kratko verigo (SCCP), znanih tudi kot poliklorirani parafini s kratko verigo, v razponu ogljikovih vezi n-C10 do vključno n-C13, v zmeseh z masnimi deleži klora („vsebnost“) med 49 in 67 %, vključno s približno 6300 od približno 8000 analogov. Ta metoda se uporablja za določevanje vsote polikloriranih alkanov s kratko verigo v nefiltrirani površinski vodi, podtalnici, pitni vodi in odpadni vodi, z uporabo plinske kromatografije/masne spektrometrije (GC/MS) in negativno kemijsko ionizacijo z zajetjem elektronov (GC-ECNI-MS). Ta metoda se uporablja za vzorce, ki vsebujejo od 0,1 do 10 μg/l. Najnižja koncentracija, ki jo je še mogoče zaznati, je ocenjena na višjo od 0,1 μg/l, odvisno od matriksa odpadne vode.
General Information
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Standards Content (Sample)
SLOVENSKI STANDARD
01-julij-2014
.DNRYRVWYRGH'RORþHYDQMHSROLNORULUDQLKDONDQRYVNUDWNRYHULJR 6&&3 YYRGL
0HWRGDVSOLQVNRNURPDWRJUDILMRPDVQRVSHNWURPHWULMR *&06 LQQHJDWLYQR
NHPLMVNRLRQL]DFLMR 1&, ,62
Water quality - Determination of short-chain polychlorinated alkanes (SCCPs) in water -
Method using gas chromatography-mass spectrometry (GC-MS) and negative-ion
chemical ionization (NCI) (ISO 12010:2012)
Wasserbeschaffenheit - Bestimmung von kurzkettigen Chloralkanen (SCCP) in Wasser -
Verfahren mittels Gaschromatographie-Massenspektrometrie (GC-MS) und negativer
chemischer Ionisation (NCI) (ISO 12010:2012)
Qualité de l'eau - Détermination des alcanes polychlorés à chaîne courte (SCCP) dans
l'eau - Méthode par chromatographie gazeuse-spectrométrie de masse (CG-SM) avec
ionisation chimique négative (ICN) (ISO 12010:2012)
Ta slovenski standard je istoveten z: EN ISO 12010:2014
ICS:
13.060.50 3UHLVNDYDYRGHQDNHPLþQH Examination of water for
VQRYL chemical substances
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EUROPEAN STANDARD
EN ISO 12010
NORME EUROPÉENNE
EUROPÄISCHE NORM
April 2014
ICS 13.060.50
English Version
Water quality - Determination of short-chain polychlorinated
alkanes (SCCPs) in water - Method using gas chromatography-
mass spectrometry (GC-MS) and negative-ion chemical
ionization (NCI) (ISO 12010:2012)
Qualité de l'eau - Détermination des alcanes polychlorés à Wasserbeschaffenheit - Bestimmung von kurzkettigen
chaîne courte (SCCP) dans l'eau - Méthode par Chloralkanen (SCCP) in Wasser - Verfahren mittels
chromatographie gazeuse-spectrométrie de masse (CG- Gaschromatographie-Massenspektrometrie (GC-MS) und
SM) avec ionisation chimique négative (ICN) (ISO negativer chemischer Ionisation (NCI) (ISO 12010:2012)
12010:2012)
This European Standard was approved by CEN on 11 April 2014.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 12010:2014 E
worldwide for CEN national Members.
Contents Page
Foreword .3
Foreword
The text of ISO 12010:2012 has been prepared by Technical Committee ISO/TC 147 “Water quality” of the
International Organization for Standardization (ISO) and has been taken over as EN ISO 12010:2014 by
Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by October 2014, and conflicting national standards shall be withdrawn at
the latest by October 2014.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece,
Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO 12010:2012 has been approved by CEN as EN ISO 12010:2014 without any modification.
INTERNATIONAL ISO
STANDARD 12010
First edition
2012-03-15
Water quality — Determination of
short-chain polychlorinated alkanes
(SCCPs) in water — Method using gas
chromatography-mass spectrometry
(GC-MS) and negative-ion chemical
ionization (NCI)
Qualité de l’eau — Détermination des alcanes polychlorés à chaîne
courte (SCCP) dans l’eau — Méthode par chromatographie gazeuse-
spectrométrie de masse (CG-SM) avec ionisation chimique négative (ICN)
Reference number
ISO 12010:2012(E)
©
ISO 2012
ISO 12010:2012(E)
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means,
electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISO’s
member body in the country of the requester.
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Published in Switzerland
ii © ISO 2012 – All rights reserved
ISO 12010:2012(E)
Contents Page
Foreword .iv
Introduction . v
1 Scope . 1
2 Normative references . 1
3 Principle . 1
4 Interferences . 2
5 Reagents and standards . 2
6 Apparatus . 6
7 Sampling and sample pretreatment . 7
8 Procedure . 7
8.1 Extraction with liquid-liquid extraction method . 7
8.2 Extraction of samples with higher content of suspended matter . 7
8.3 Extract clean-up . 8
8.4 Measurement and integration of the chromatogram . 9
8.5 Calibration . 9
9 Expression of results .12
10 Test report .12
Annex A (informative) Additional quality control check solutions .13
Annex B (informative) Explanation of the calibration of the sum of SCCPs with multiple
linear regression .14
Annex C (informative) Typical GC-MS conditions .19
Annex D (informative) Typical chromatograms of standard solutions 1 µg/ml .22
Annex E (informative) Presentation of goodness of fit .23
Annex F (informative) Example for recoveries of quality assurance solutions .24
Annex G (informative) Chromatogram of a real water sample with a sum of SCCPs concentration of
2,59 µg/l .25
Annex H (informative) Precision data.27
Bibliography .28
ISO 12010:2012(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International
Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 12010 was prepared by Technical Committee ISO/TC 147, Water quality, Subcommittee SC 2, Physical,
chemical and biochemical methods.
iv © ISO 2012 – All rights reserved
ISO 12010:2012(E)
Introduction
The user should be aware that particular problems might require the specifications of additional marginal conditions.
INTERNATIONAL STANDARD ISO 12010:2012(E)
Water quality — Determination of short-chain polychlorinated
alkanes (SCCPs) in water — Method using gas
chromatography-mass spectrometry (GC-MS) and negative-ion
chemical ionization (NCI)
WARNING — Persons using this International Standard should be familiar with normal laboratory
practice. This International Standard does not purport to address all of the safety problems, if any,
associated with its use. It is the responsibility of the user to establish appropriate safety and health
practices and to ensure compliance with any national regulatory conditions.
IMPORTANT — It is absolutely essential that tests conducted in accordance to this International
Standard be carried out by suitably qualified staff.
1 Scope
This International Standard specifies a method for the quantitative determination of the sum of short-chain
polychlorinated n-alkanes, also known as short-chain polychlorinated paraffins (SCCPs), in the carbon bond
range n-C to n-C inclusive, in mixtures with chlorine mass fractions (“contents”) between 49 % and 67 %,
10 13
including approximately 6 300 of approximately 8 000 congeners.
This method is applicable to the determination of the sum of SCCPs in unfiltered surface water, ground water,
drinking water and waste water using gas chromatography-mass spectrometry with electron capture negative
ionization (GC-ECNI-MS).
The method can be applied to samples containing 0,1 µg/l to 10 µg/l. Depending on the waste water matrix, the
lowest detectable concentration is estimated to be >0,1 µg/l.
2 N
...
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