EN ISO 3233-1:2019

Paints and varnishes - Determination of percentage volume of non-volatile matter - Part 1: Method using a coated test panel to determine non-volatile matter and to determine dry-film density by the Archimedes principle (ISO 3233-1:2019)

This document specifies a method for determining the non-volatile matter by volume (NVV) of coating materials and related products by measuring the density of a dried coating for any specified temperature range and period of drying or curing. This method determines the non-volatile matter immediately after application.
Using the non-volatile matter by volume results obtained in accordance with this document, it is possible to calculate the spreading rate of coating materials.
The method specified in this document is the preferred method for air-drying materials. Its use for other materials has not yet been tested.
Annex B gives an overview of the existing methods for determination of non-volatile-matter content and volume of non-volatile matter.
This document is not applicable to coating materials in which the critical pigment volume concentration is exceeded.

Beschichtungsstoffe - Bestimmung des Volumens nichtflüchtiger Anteile - Teil 1: Verfahren mit einem beschichteten Probenträger zum Bestimmen des nichtflüchtigen Anteils und zum Bestimmen der Trockenfilmdichte nach dem Archimedes-Prinzip (ISO 3233-1:2019)

Dieses Dokument legt ein Verfahren zum Bestimmen des Volumens der nichtflüchtigen Anteile (VnfA) von Beschichtungsstoffen und ähnlichen Produkten durch Messung der Trockenfilmdichte (Dichte der trockenen Beschichtung) für einen beliebigen festgelegten Temperaturbereich und eine beliebige festgelegte Trocknungs  oder Härtungsdauer fest. Nach diesem Verfahren wird der nichtflüchtige Anteil direkt nach der Applikation bestimmt.
Mit Hilfe des nach diesem Dokument bestimmten Volumens nichtflüchtiger Anteile ist es möglich, die Ergiebigkeit eines Beschichtungsstoffes zu berechnen.
Das in diesem Dokument festgelegte Verfahren wird bevorzugt für lufttrocknende Stoffe eingesetzt. Seine Verwendung für andere Materialien wurde bisher nicht untersucht.
Anhang B gibt einen Überblick über die bestehenden Verfahren zum Bestimmen des Gehaltes an nicht-flüchtigen Anteilen und des Volumens nichtflüchtiger Anteile.
Dieses Dokument ist nicht anwendbar für Beschichtungsstoffe, die die kritische Pigmentvolumenkonzen-tration überschreiten.

Peintures et vernis - Détermination du pourcentage en volume de matière non volatile - Partie 1: Méthode utilisant un panneau d'essai revêtu pour déterminer la matière non volatile et pour déterminer la masse volumique du feuil sec par le principe d'Archimède (ISO 3233-1:2019)

Le présent document décrit une méthode de détermination de la teneur en volume de matière non volatile (NVV) dans les produits de peinture et produits assimilés, par mesure de la masse volumique d'un revêtement séché, quelles que soient la plage de température et la durée de séchage ou de réticulation spécifiées. La présente méthode détermine la matière non volatile immédiatement après application.
La teneur en volume de matière non volatile obtenue conformément au présent document permet de calculer le rendement superficiel spécifique des produits de peintures.
La méthode spécifiée dans le présent document est la méthode recommandée pour les revêtements séchant à l'air. Son utilisation pour d'autres produits n'a pas encore été soumise à l'essai.
L'Annexe B donne une vue d'ensemble des méthodes existantes pour la détermination de la teneur en matière non volatile et du volume de matière non volatile.
Le présent document n'est pas applicable aux produits de peinture qui dépassent la concentration pigmentaire volumique critique.

Barve in laki - Določevanje prostorninskega deleža nehlapnih snovi - 1. del: Metoda s premazano preskusno ploščo za določevanje nehlapnih snovi in gostote suhe plasti filma po Arhimedovem načelu (ISO 3233-1:2019)

Ta dokument določa metodo za določevanje nehlapnih snovi glede na prostornino (NVV) v premaznih sredstvih in povezanih izdelkih z merjenjem gostote posušenega premaza za katero koli določeno temperaturno območje ter obdobje sušenja ali strjevanja. Ta metoda določa nevnetljivo snov takoj po uporabi. Z rezultati nehlapnih snovi glede na prostornino, ki so pridobljeni v skladu s tem dokumentom, je mogoče izračunati hitrost nanašanja premaznih materialov. Metoda, ki je navedena v tem dokumentu, je prednostna metoda za vsa sredstva, ki se sušijo na zraku. Njena uporaba za druga sredstva ni bila preskušena. V dodatku B je na voljo pregled obstoječih metod za določevanje vsebnosti in prostornine nehlapnih snovi. Ta dokument se ne uporablja za premazna sredstva, v katerih je presežena kritična koncentracija prostornine pigmenta.

General Information

• Status: Published
• Publication Date: 03-Dec-2019
• Withdrawal Date: 29-Jun-2020
• ICS: 87.040 - Paints and varnishes
• Technical Committee: CEN/TC 139 - Paints and varnishes
• Drafting Committee: CEN/TC 139/WG 9 - Testing of coil coated metals
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 04-Dec-2019
• Completion Date: 04-Dec-2019
• Ref Project: SIST EN ISO 3233-1:2020 - Paints and varnishes - Determination of percentage volume of non-volatile matter - Part 1: Method using a coated test panel to determine non-volatile matter and to determine dry-film density by the Archimedes principle (ISO 3233-1:2019)

Relations

• Replaces: EN ISO 3233-1:2013 - Paints and varnishes - Determination of the percentage volume of non-volatile matter - Part 1: Method using a coated test panel to determine non-volatile matter and to determine dry film density by the Archimedes principle (ISO 3233-1:2013)
• Effective Date: 08-Jun-2022

Overview

EN ISO 3233-1:2019 (ISO 3233-1:2019) - Paints and varnishes: Determination of percentage volume of non-volatile matter - Part 1 - specifies a laboratory method using a coated test panel and the Archimedes principle to measure the dry-film density of a coating and to calculate the non-volatile matter by volume (NVV). The method determines NVV immediately after application and is the preferred technique for air-drying materials. Results can be used to calculate the spreading rate of coating materials. The standard is not applicable when the critical pigment volume concentration (CPVC) is exceeded.

Key topics and technical requirements

• Principle: Measure dry-film density by buoyancy (Archimedes principle) on a coated panel, then derive NVV.
• Scope constraints: Intended for air-drying systems; not suitable for porous films or coatings above CPVC.
• Temperature and time dependence: NVV results are dependent on specified drying/curing temperature and time - these must be documented.
• Minimum sample mass: The standard requires a practical minimum mass on the coated panel (minimum 25 mg for plate tests).
• Apparatus & reagents: Specifies equipment for coating, drying, buoyancy measurement, and density determination.
• Procedure elements:
  • Sampling and sample preparation
  • Choice of receptacle (discs or plates)
  • Determination of uncoated receptacle volume
  • Application and controlled drying/curing
  • Measurement of dry coating volume and liquid coating density
• Calculations: Methods for computing practical dry-film density, NVV and spreading rate.
• Precision: Includes repeatability and reproducibility information for laboratory use.
• Documentation: Test report requirements and informative annexes (examples of test conditions; overview of existing NVV methods).

Practical applications and users

This standard is primarily used by:

• Coating and paint manufacturers for product specification, quality control and formulation evaluation.
• Independent test laboratories performing NVV and spreading rate testing.
• R&D teams and paint formulators assessing coverage performance and comparing formulations.
• Procurement/specification engineers who require standardized NVV values for performance contracts. Practical uses include verifying declared NVV and spreading rate, optimizing formulations for coverage, and ensuring consistent lab-to-lab results.

Related standards

• ISO 1513 - Examination and preparation of test samples
• ISO 2811 (all parts) - Determination of density
• ISO 4618 - Terms and definitions for paints and varnishes
• ISO 15528 - Paints, varnishes and raw materials (referenced)

Keywords: EN ISO 3233-1:2019, ISO 3233-1, paints and varnishes, non-volatile matter by volume, NVV, dry-film density, Archimedes principle, coated test panel, spreading rate, CPVC.

Standards Content (Sample)

SLOVENSKI STANDARD
01-januar-2020
Nadomešča:
SIST EN ISO 3233-1:2013
Barve in laki - Določevanje prostorninskega deleža nehlapnih snovi - 1. del:
Metoda s premazano preskusno ploščo za določevanje nehlapnih snovi in gostote
suhe plasti filma po Arhimedovem načelu (ISO 3233-1:2019)
Paints and varnishes - Determination of percentage volume of non-volatile matter - Part
1: Method using a coated test panel to determine non-volatile matter and to determine
dry-film density by the Archimedes principle (ISO 3233-1:2019)
Beschichtungsstoffe - Bestimmung des Volumens nichtflüchtiger Anteile - Teil 1:
Verfahren mit einem beschichteten Probenträger zum Bestimmen des nichtflüchtigen
Anteils und zum Bestimmen der Trockenfilmdichte nach dem Archimedes-Prinzip (ISO
3233-1:2019)
Peintures et vernis - Détermination du pourcentage en volume de matière non volatile -
Partie 1: Méthode utilisant un panneau d'essai revêtu pour déterminer la matière non
volatile et pour déterminer la masse volumique du feuil sec par le principe d'Archimède
(ISO 3233-1:2019)
Ta slovenski standard je istoveten z: EN ISO 3233-1:2019
ICS:
87.040 Barve in laki Paints and varnishes
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 3233-1
EUROPEAN STANDARD
NORME EUROPÉENNE
December 2019
EUROPÄISCHE NORM
ICS 87.040 Supersedes EN ISO 3233-1:2013
English Version
Paints and varnishes - Determination of percentage
volume of non-volatile matter - Part 1: Method using a
coated test panel to determine non-volatile matter and to
determine dry-film density by the Archimedes principle
(ISO 3233-1:2019)
Peintures et vernis - Détermination du pourcentage en Beschichtungsstoffe - Bestimmung des Volumens
volume de matière non volatile - Partie 1: Méthode nichtflüchtiger Anteile - Teil 1: Verfahren mit einem
utilisant un panneau d'essai revêtu pour déterminer la beschichteten Probenträger zum Bestimmen des
matière non volatile et pour déterminer la masse nichtflüchtigen Anteils und zum Bestimmen der
volumique du feuil sec par le principe d'Archimède Trockenfilmdichte nach dem Archimedes-Prinzip (ISO
(ISO 3233-1:2019) 3233-1:2019)
This European Standard was approved by CEN on 4 November 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 3233-1:2019 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 3233-1:2019) has been prepared by Technical Committee ISO/TC 35 "Paints
and varnishes" in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the
secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by June 2020, and conflicting national standards shall be
withdrawn at the latest by June 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 3233-1:2013.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 3233-1:2019 has been approved by CEN as EN ISO 3233-1:2019 without any
modification.
INTERNATIONAL ISO
STANDARD 3233-1
Second edition
2019-11
Paints and varnishes — Determination
of percentage volume of non-volatile
matter —
Part 1:
Method using a coated test panel to
determine non-volatile matter and
to determine dry-film density by the
Archimedes' principle
Peintures et vernis — Détermination du pourcentage en volume de
matière non volatile —
Partie 1: Méthode utilisant un panneau d'essai revêtu pour
déterminer la matière non volatile et pour déterminer la masse
volumique du feuil sec par le principe d'Archimède
Reference number
ISO 3233-1:2019(E)
©
ISO 2019
ISO 3233-1:2019(E)
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: [phone]
Fax: [phone]
Email: [e-mail]
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

ISO 3233-1:2019(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and reagents . 2
6 Sampling . 5
7 Procedure. 5
7.1 Number of determinations and preparation . 5
7.2 Choice of receptacle . 5
7.3 Determination of volume of uncoated receptacle . 5
7.4 Application . 6
7.4.1 General. 6
7.4.2 Discs . 6
7.4.3 Plates . 6
7.4.4 Drying . 7
7.5 Determination of volume of dry coating . 7
7.6 Determination of density of the liquid coating material . 7
8 Calculation . 7
8.1 Calculation of the practical dry-film density, non-volatile-matter content and non-
volatile matter by volume . 7
8.2 Calculation of the spreading rate . 8
9 Precision . 9
9.1 Repeatability limit . 9
9.2 Reproducibility limit . 9
10 Test report . 9
Annex A (informative) Examples of test conditions .10
Annex B (informative) Overview of the existing methods for determination of non-volatile-
matter content and volume of non-volatile matter .11
Bibliography .13
ISO 3233-1:2019(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www .iso .org/
iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee
SC 9, General test methods for paints and varnishes.
This second edition cancels and replaces the first edition (ISO 3233-1:2013), which has been technically
revised.
The main changes compared to the previous edition are as follows:
— the definitions and sources have been updated in Clause 3;
— a minimum mass of 25 mg of the coating on the plate has been added in 7.4.1 because measurements
and simulation calculations demonstrate the need for a minimum mass for the coated panel;
— the text has been editorially revised.
A list of all parts in the ISO 3233 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
iv © ISO 2019 – All rights reserved

ISO 3233-1:2019(E)
Introduction
This method is used to measure the density and to determine the volume of a dry coating obtainable
from a given volume of liquid paint. This volume is considered to be the most meaningful measure of the
coverage (area of surface covered at a specified dry-film thickness per unit volume) of a paint, varnish
or related product. The value obtained by this method might not be the same as that calculated on the
basis of the addition of masses and volumes of the raw materials in a formulation. The volume occupied
by a combination of resin and solvent can be the same as, greater than or less than the combined volume
of the separate components, due to contraction or expansion of the resin and solvent. A second factor
affecting the volume of a dry coating formulation is the degree to which the spaces between pigment
particles are filled with binder. A third factor is the use of volatile components in reactive systems that,
by their reaction, change into non-volatile film-building materials, i.e. amines and reactive solvents in
high-build two-component coating materials.
Above and close to the critical pigment volume concentration, the volume of a dry paint film is greater
than the theoretical volume, due to an increase in unfilled voids between pigment particles. The
porosity of the film means that this method is unsuitable.
The values obtained for the non-volatile matter by volume are dependent on the temperature and time
of heating, and these conditions should be carefully considered for the material being tested.
INTERNATIONAL STANDARD ISO 3233-1:2019(E)
Paints and varnishes — Determination of percentage
volume of non-volatile matter —
Part 1:
Method using a coated test panel to determine non-
volatile matter and to determine dry-film density by the
Archimedes' principle
1 Scope
This document specifies a method for determining the non-volatile matter by volume (NV ) of
V
coating materials and related products by measuring the density of a dried coating for any specified
temperature range and period of drying or curing. This method determines the non-volatile matter
immediately after application.
Using the non-volatile matter by volume results obtained in accordance with this document, it is
possible to calculate the spreading rate of coating materials.
The method specified in this document is the preferred method for air-drying materials. Its use for
other materials has not yet been tested.
Annex B gives an overview of the existing methods for determination of non-volatile-matter content
and volume of non-volatile matter.
This document is not applicable to coating materials in which the critical pigment volume concentration
is exceeded.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 1513, Paints and varnishes — Examination and preparation of test samples
ISO 2811 (all parts), Paints and varnishes — Determination of density
ISO 4618, Paints and varnishes — Terms and definitions
ISO 15528, Paints, varnishes and raw materials for paints and varnishes — Sampling
3 Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 4618 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
ISO 3233-1:2019(E)
3.1
non-volatile matter
NV
residue by mass obtained by evaporation under specified conditions
Note 1 to entry: Instead of the term “non-volatile matter” different terms, such as solid, dry residue, dry matter,
...