EN 71-4:1990/A3:2007

Safety of toys - Part 4: Experimental sets for chemistry and related activities

Replacement of the carcinogenic and toxic-for-reproduction substances from table 1 with safer alternatives; updating of the classifications; addition of the environmental danger symbol for information; if applicable, the test method for borosilicate glassware of EN 71-1.

Sicherheit von Spielzeug - Teil 4: Experimentierkästen für chemische und ähnliche Versuche

Dieser Teil der Europäischen Norm EN 71 legt Anforderungen für die Höchstmengen bestimmter chemischer Stoffe und Zubereitungen in Experimentierkästen für chemische und ähnliche Versuche fest.
Bei diesen chemischen Stoffen und Zubereitungen handelt es sich um
   Chemikalien, die nach den Richtlinien zu gefährlichen Stoffen [1] als gefährlich eingestuft sind sowie gefährliche Zubereitungen [2] (einschließlich chemischer Stoffe mit Selbsteinstufung nach den Anfor¬derungen dieser Richtlinien);
   chemische Stoffe und Zubereitungen, die bei Verwendung in übermäßigen Mengen die Gesundheit der Kin¬der schädigen können, die jedoch nicht durch die vorstehend genannten Richtlinien als gefährlich einge¬stuft sind; sowie
   sonstige chemische Stoffe und Zubereitungen, die mit dem Spielzeug geliefert werden.
Diese Norm gilt für Chemieexperimentierkästen und Ergänzungskästen. Sie deckt weiterhin Spielzeug für Experimente auf dem Gebiet der Mineralogie, Biologie, Physik, Mikroskopie und der Umweltwissenschaften ab, sofern sie einen oder mehrere chemische Stoffe und/oder Zubereitungen enthalten.
Ferner legt diese Norm Anforderungen an die Kennzeichnung, die Inhaltsliste, die Gebrauchsanleitung und an die zur Ausführung der Experimente zu verwendende Ausrüstung fest.
Alle folgenden Abschnitte und Unterabschnitte sind neu zu benummern.
Abschnitt 3 Verweisungen ist durch 2 Normative Verweisungen zu ersetzen.
EN 71 1:1988, Richtlinie 67/548/EWG, 88/379/EWG sowie die Fußnoten 1 und 2 sind zu streichen.
EN 28317 sowie ihr Titel sind durch EN ISO 8317, Kindersichere Verpackung  Anforderungen und Prüfverfahren für wiederverschließbare Verpackungen (ISO 8317:2003) zu ersetzen.
Der erste Abschnitt in ehemals Abschnitt 5 ist durch Folgendes zu ersetzen:
Nur die chemischen Stoffe, Zubereitungen und Indikatoren, die in den Tabellen 1 und 2 aufgeführt sind
Im zweiten Absatz von ehemals Abschnitt 5, Chemische Stoffe, ist

Sécurité des jouets - Partie 4: Coffrets d'expériences chimiques et d'activités connexes

Varnost igrač - 4. del: Kompleti za kemijske poskuse in druge poskuse, pri katerih se uporabljajo kemikalije - Dopolnilo A3

General Information

• Status: Withdrawn
• Publication Date: 22-May-2007
• Withdrawal Date: 25-Aug-2009
• ICS: 97.200.50 - Toys
• Technical Committee: CEN/TC 52 - Safety of toys
• Drafting Committee: CEN/TC 52/WG 5 - Safety of toys - Chemical toys
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Start Date: 26-Aug-2009
• Completion Date: 26-Aug-2009
• Directive: 88/378/EEC - Safety of toys
• Mandate: M/BC/CEN/88/1 - Standardization request - Safety of toys - chemical toys
• Ref Project: SIST EN 71-4:1995/A3:2007 - Safety of toys - Part 4: Experimental sets for chemistry and related activities - Amendment A3

Relations

• Replaced By: EN 71-4:2009 - Safety of toys - Part 4: Experimental sets for chemistry and related activities
• Effective Date: 29-Aug-2009
• Amends: EN 71-4:1990 - Safety of toys - Part 4: Experimental sets for chemistry and related activities
• Effective Date: 08-Jun-2022

Standards Content (Sample)

SLOVENSKI STANDARD
01-oktober-2007
9DUQRVWLJUDþGHO.RPSOHWL]DNHPLMVNHSRVNXVHLQGUXJHSRVNXVHSULNDWHULK
VHXSRUDEOMDMRNHPLNDOLMH'RSROQLOR$
Safety of toys - Part 4: Experimental sets for chemistry and related activities -
Amendment A3
Sicherheit von Spielzeug - Teil 4: Experimentierkästen für chemische und ähnliche
Versuche
Sécurité des jouets - Partie 4: Coffrets d'expériences chimiques et d'activités connexes
Ta slovenski standard je istoveten z: EN 71-4:1990/A3:2007
ICS:
97.200.50 ,JUDþH Toys
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN 71-4:1990/A3
NORME EUROPÉENNE
EUROPÄISCHE NORM
May 2007
ICS 97.200.50
English Version
Safety of toys - Part 4: Experimental sets for chemistry and
related activities
Sécurité des jouets - Partie 4: Coffrets d'expériences Sicherheit von Spielzeug - Teil 4: Experimentierkästen für
chimiques et d'activités connexes chemische und ähnliche Versuche
This amendment A3 modifies the European Standard EN 71-4:1990; it was approved by CEN on 26 April 2007.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for inclusion of this
amendment into the relevant national standard without any alteration. Up-to-date lists and bibliographical references concerning such
national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This amendment exists in three official versions (English, French, German). A version in any other language made by translation under the
responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2007 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 71-4:1990/A3:2007: E
worldwide for CEN national Members.

Foreword
This document (EN 71-4:1990/A3:2007) has been prepared by Technical Committee CEN/TC 52 “Safety of
toys”, the secretariat of which is held by DS.
This Amendment to the European Standard EN 71-4:1990 shall be given the status of a national standard,
either by publication of an identical text or by endorsement, at the latest by November 2007, and conflicting
national standards shall be withdrawn at the latest by November 2007.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association, and supports essential requirements of EU Directive 88/378/EEC.
For relationship with EU Directive, see informative Annex ZA, which is an integral part of this document.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and United Kingdom.
Replace the heading "Brief history" by "Introduction".
Add to the "Introduction" after the last paragraph:
The following technical changes were introduced by EN 71-4:1990/A3:2007:
- deletion of dangerous substances which are suspected of having carcinogenic, mutagenic or toxic for
reproduction (CMR) properties;
- improvement in the classification of substances.
Replace Clause 1 "Object" and Clause 2 "Field of application" with the following:
1 Scope
"This part of the European Standard EN 71 specifies requirements for the maximum amount of certain
substances and preparations used in experimental sets for chemistry and related activities.
These substances and preparations are
 chemicals classified as dangerous by the Directives on dangerous substances [1] and dangerous
preparations [2] (including substances which have been self-classified according to the requirements of
these Directives);
 substances and preparations which in excessive amounts may harm the health of the children using them
but which are not classified as dangerous by the above mentioned Directives and
 other chemical substances and preparations delivered with the toy.
This standard applies to chemistry sets and supplementary sets. It also covers toys for experiments within the
fields of mineralogy, biology, physics, microscopy and environmental science whenever they contain one or
more chemical substances and/or preparations.
It also specifies requirements for marking, contents list, instructions for use and for equipment intended for
carrying out the experiments."

Renumber all the subsequent clauses and subclauses.
Replace Clause 3 "References" with Clause 2 “Normative references"
Delete "EN 71-1:1988, Directive 67/548/EEC, 88/379/EEC" and the" footnotes 1 and 2".
Replace "EN 28317"and its title with "EN ISO 8317, Child-resistant packaging - Requirements and
testing procedures for reclosable packages (ISO 8317:2003)".
st
In former Clause 5 change the 1 paragraph as follows:
"Only chemical substances, preparations and indicators given in Table 1 and Table 2…"
In the second paragraph of former Clause 5, Chemical substances, replace:
“….within the definitions contained in Directives 67/548/EEC (with subsequent amendments and adaptations)
and 88/379/EEC (with subsequent amendments and adaptations).”
with “(see [1] and [2])”
rd nd
In former Clause 5 put the 3 paragraph before the 2 paragraph and change "…referred to in
Table 2…" to "…referred to in Table 3…"
Replace Table 1 with the following:
Table 1 — Maximum amounts of chemical substances and preparations and labelling
b b
Chemical Max. amount per set Danger symbol(s)
CAS number EINECS number
substances / (see Figure 1 and
a
Figure 2)
preparation
Aluminium potassium 10 g − 10043-67-1 233-141-3
c
sulfate
Ammonium 5 g Xn 10361-29-2 233-786-0
g
carbonate
Ammonium chloride 30 g Xn 12125-02-9 235-186-4
Ammonium iron (III) 5 g Xi 10138-04-2 233-382-4
g
sulfate
Ammonium sodium 5 g − 13011-54-6 235-860-8
hydrogen phosphate
g
100 g Xi 471-34-1 207-439-9
Calcium carbonate
Calcium chloride 10 g Xi 10043-52-4 233-140-8
d, g
Calcium hydroxide 20 g Xi 1305-62-0 215-137-3
g
Calcium nitrate 5 g Xi, O 10124-37-5 233-332-1
d, g
10 g C 1305-78-8 215-138-9
Calcium oxide
Calcium sulfate 100 g − 7778-18-9 231-900-3
c
100 g − 7440-44-0 231-153-3
Charcoal
g
20 g Xi 77-92-9 201-069-1
Citric acid
c,g, i
10 ml Xn 84961-50-2 284-638-7
Clove oil
Copper sheet 100 g − 7440-50-8 231-159-6
g
10 g Xn 1317-38-0 215-269-1
Copper (II) oxide
Copper (II) sulfate 15 g Xn, N 7758-98-7 231-847-6
Disodium disulfite 10 g Xn 7681-57-4 231-548-0

Table 1 (continued)
b b
Chemical Max. amount per set Danger symbol(s)
CAS number EINECS number
substances / (see Figure 1 and
a
Figure 2)
preparation
Glycerol (containing at 25 g − 56-81-5 200-289-5
least 15 % water)
Hexamethylene- 10 g Xn, F 100-97-0 202-905-8
c
tetramine (solid fuel)
Iron fillings/iron 100 g F 7439-89-6 231-096-4
c, g
powder
g
10 g Xn 7705-08-0 231-729-4
Iron (III) chloride
g
10 g Xn 7720-78-7 231-753-5
Iron (II) sulfate
Lactose 100 g − 63-42-3 200-559-2
c
100 g − − −
Lead-free solder
g
3 g F 7439-95-4 231-104-6
Magnesium strip
Magnesium sulfate 25 g − 7487-88-9 231-298-2
Manganese (IV) 5 g Xn 1313-13-9 215-202-6
dioxide
Manganese (II) sulfate 15 g Xn, N 7785-87-7 232-089-9
g
1 g Xn 485-47-2 207-618-1
Ninhydrin
Pepsin A 10 g Xn 9001-75-6 232-629-3
g
15 g Xi 7758-02-3 231-830-3
Potassium bromide
Potassium 10 g − 13746-66-2 237-323-3
c
hexacyanoferrate (III)
Potassium 10 g − 13943-58-3 237-722-2
c
hexacyanoferrate (II)
Potassium iodide 10 g − 7681-11-0 231-659-4
Potassium 15 g Xn, O, N 7722-64-7 231-760-3
e
permanganate
Potassium 10 g Xn, O, N − −
permanganate:
sodium sulphate
mixture (1:2 m/m)
Silver nitrate (1 % m/V 10 ml Xi, N 7761-88-8 231-853-9
g
aqueous solution)
Sodium acetate 20 g − 127-09-3 204-823-8
Sodium carbonate 50 g Xi 497-19-8 207-838-8
Sodium chloride 100 g − 7647-14-5 231-598-3
Sodium hydrogen 50 g − 144-55-8 205-633-8
carbonate
Sodium hydrogen 30 g Xi 7681-38-1 231-665-7
sulphate
Table 1 (concluded)
b b
Chemical Max. amount per set Danger symbol(s)
CAS number EINECS number
substances / (see Figure 1 and
a
Figure 2)
preparation
Sodium silicate 100 ml C − −
solution
g
(SiO :Na O > 2)
2 2
Sodium sulfate 100 g − 7757-82-6 231-820-9
Sodium thiosulfate 50 g − 7772-98-7 231-867-5
g
15 g F 7704-34-9 231-722-6
Sulfur
c
15 g − 1401-55-4 215-753-2
Tannin
g
20 g Xi 87-69-4 201-766-0
Tartaric acid
g
15 g C 7772-99-8 231-868-0
Tin (II) chloride
c
f f
Tincture of iodine  10 ml − −
Xn , N , F
(2,5 % m/V ethanolic
h
solution)
c
10 g − 57-13-6 200-315-5
Urea
Zinc powder / zinc 20 g F, N 7440-66-6 231-175-3
pellets
Zinc sulfate 20 g Xn, N 7446-20-0 231-793-3
(heptahydrate)
a
The substances and preparations in Table 1 are listed in alphabetical order and may therefore be placed in different positions in the
national
translations.
b
Chemical Abstract Service (CAS) registry number and European Inventory of Existin
...