EN 14602:2012
(Main)Footwear - Test methods for the assessment of ecological criteria
Footwear - Test methods for the assessment of ecological criteria
This European Standard has been designed to define certain test methods necessary to issue the footwear Ecolabel, Many of the criteria are defined in the core of the text. However, for some criteria, this European Standard provides important clarification or gives a test method to assess the ecological criteria.
NOTE The footwear Ecolabel has been published in the OJEC of July 28th, 2009.
This European Standard applies to any kind of footwear except those containing electrical or electronic components.
The chemical analysis of the metallic components is outside of the scope of this European Standard.
Schuhe - Prüfverfahren zur Beurteilung ökologischer Kriterien
Diese Europäische Norm legt bestimmte Prüfverfahren, die für die Erteilung des Eco-Labels für Schuhe erforderlich sind, fest. Für einige Kriterien liefert diese Europäische Norm wichtige Erläuterungen oder gibt ein Prüfverfahren zur Beurteilung der ökologischen Kriterien an.
ANMERKUNG Das Eco-Label für Schuhe wurde im Amtsblatt vom 28. Juli 2009 veröffentlicht.
Diese Europäische Norm gilt für jede Art von Schuhwerk, mit Ausnahme derer, die elektrische oder elektronische Bestandteile enthalten.
Die chemische Analyse von Bestandteilen aus Metall fällt nicht in den Anwendungsbereich dieser Europäischen Norm.
Chaussure - Méthodes d'essai pour l'évaluation de critères écologiques
La présente Norme européenne définit certaines méthodes d'essai requises pour l'attribution du label écologique communautaire Ecolabel. Pour certains critères, la présente Norme européenne fournit des éclaircissements importants ou indique une méthode d'essai permettant d'évaluer les critères écologiques.
NOTE Le label écologique communautaire Ecolabel destiné à être attribué aux articles chaussants a fait l'objet d'une décision publiée dans le Journal officiel du 28 juillet 2009.
La présente Norme européenne s'applique à tous les articles chaussants, à l'exception de ceux munis de composants électriques ou électroniques.
L'analyse chimique des composants métalliques ne relève pas du domaine d'application de la présente Norme européenne.
Obutev - Preskusna metoda za ocenjevanje ekoloških meril
Ta evropski standard določa nekatere preskusne metode, ki so potrebne za izdajo obutve z znakom Ecolabel. Ta evropski standard zagotavlja pomembna pojasnila nekaterih meril ali določa preskusno metodo za vrednotenje ekoloških meril.
General Information
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Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Obutev - Preskusna metoda za ocenjevanje ekoloških merilSchuhe - Prüfverfahren zur Beurteilung ökologischer KriterienChaussure - Méthodes d'essai pour l'évaluation de critères écologiquesFootwear - Test method for the assessment of ecological criteria61.060ObuvalaFootwearICS:Ta slovenski standard je istoveten z:EN 14602:2012SIST EN 14602:2012en,de01-oktober-2012SIST EN 14602:2012SLOVENSKI
STANDARDSIST EN 14602:20051DGRPHãþD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 14602
August 2012 ICS 61.060 Supersedes EN 14602:2004English Version
Footwear - Test methods for the assessment of ecological criteria
Chaussure - Méthodes d'essai pour l'évaluation de critères écologiques
Schuhe - Prüfverfahren zur Beurteilung ökologischer Kriterien This European Standard was approved by CEN on 13 July 2012.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14602:2012: ESIST EN 14602:2012
new reference test method the determination of phthalates; new test method for the determination of the electrical energy consumption. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
VOC organic compound that has, at 293,15 K, a vapour pressure of 0,01 KPa or more, or that has a corresponding volatility under the particular conditions of use 3.2 volatile organic compounds emissions
VOC emissions amount of volatile organic compounds emitted to the atmosphere to produce a pair of shoes SIST EN 14602:2012
PEC electricity used only by the process equipment used to manufacture the footwear 4 Test methods associated to the criteria NOTE The uncertainty of measurement for each test method described in this European Standard can be assessed according to the methods described ENV 13005 or ISO 5725-2. 4.1 Determination of total heavy metals content 4.1.1 General The total concentration of heavy metals in a product is considered as a relevant criterion regarding the end of life disposal. This test method identifies the main chemicals of potential hazard which may contaminate the environment after disposal or incineration. There shall be no Arsenic, Cadmium and Lead in the materials used for the product assembly or in the final product. Presence of heavy metals shall be established by either: testing the materials individually; or testing the upper and lower components of the shoe as composite groups of materials. NOTE The total concentration of other heavy metals (see Table 1) can be determined using this method. Table 1 Possible heavy metals determined Aluminium (Al)
Mercury (Hg)
Antimony (Sb)
Molybdenum (Mo) Barium (Ba)
Nickel (Ni) Boron (B) Potassium (K) Chromium (Cr)
Selenium (Se) Cobalt (Co)
Silicon (Si)
Copper (Cu)
Tin (Sn) Iron (Fe)
Titanium (Ti) Magnesium (Mg)
Zinc (Zn) Manganese (Mn)
Zirconium (Zr)
Fully grind each group of components separately according to EN ISO 4044 or a similar test method. NOTE Only a full grinding of the test specimen will ensure the reproducibility of the test results. 4.1.3 Reagents WARNING Violent reactions may be produced with perchloric acid (HClO4) on an organic matrix. 4.1.3.1 H2SO4, 96 % (mass fraction). 4.1.3.2 HNO3, 65 % (mass fraction). 4.1.3.3 HClO4, 65 % (mass fraction). 4.1.3.4 HCl, 36 % (mass fraction). 4.1.3.5 Demineralised water. 4.1.4 Apparatus and materials Standard laboratory apparatus and glassware, together with the following: 4.1.4.1 A suitable heating device (for the acid digestion only). 4.1.4.2 Volumetric flask, of 100 ml. 4.1.4.3 Filter paper of 0,45 µµµµm mesh size. 4.1.4.4 Microwave reactor (for the microwave digestion only), capable of working at maximum 100 bars (or 1 450 psi). 4.1.5 Digestion 4.1.5.1 Method A – acid digestion Prepare, according to 4.1.2, a test piece of (0,500 ± 0,005) g of ground sample. The digestion given in EN 1122:2001, 6.3.2, method B is to be used. 4.1.5.2 Method B – acid digestion Prepare, according to 4.1.2, a test piece of (1,000 ± 0,005) g of ground sample. The digestion given in EN ISO 17072-2:2011, 6.5.1 is to be used. SIST EN 14602:2012
When the cycles are completed, transfer the resulting solution, filtering it through a filter paper (4.1.4.3), to a volumetric flask (4.1.4.2) and adjust the volume to 100 ml with demineralised water (4.1.3.5).
One blank (acid solution) is treated at the same time and a validation with this reference solution is carried out. The digestion vessels shall be cleaned with special attention once the acid digestion is finished. 4.1.6 Determination of heavy metals content Table 3 defines the recommended options for the determination of heavy metals in footwear. Table 3 — Test method for heavy metals determination
Testing the materialsTesting the final productSoft material leather, textile Hard material polymers
Upper Lower components of the footwear
Method A possible Recommended (especially for PVC) possible Recommended (especially for PVC) Method B possible possible possible possible Method C possible possible possible possible
From the solution obtained in 4.1.5.1 or 4.1.5.2 or 4.1.5.3 determine, within 24 h, the Cd, As, Pb content by atomic absorption spectroscopy (AAS) as specified in ISO 8288, or by inductively coupled plasma atomic emission spectroscopy (ICP) as specified EN ISO 11885 or EN ISO 17294-2 (see EN ISO 17072-2). NOTE 1 The quantification limit for a 1 g sample is given in Table 4.
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