CEN/TR 10261:2018
(Main)Iron and steel - European standards for the determination of chemical composition
Iron and steel - European standards for the determination of chemical composition
This document lists, under Clause 4, the European Standards which are currently available for the determination of the chemical composition of steels and cast irons.
In Clause 5, this document provides details on the range of application and gives the principle of the method described in each standard.
Items which are under preparation as European Standards or as CEN Technical Reports by ECISS/TC 102 are available on the webpage of CEN, through the link https://standards.cen.eu/dyn/www/f?p=204:22:0::::FSP_ORG_ID:733643&cs=123E58BF77E3DE921F548B80C5FF2E5D4.
Annex A gives a list of other European Standards and CEN Technical Reports applicable for the determination of the chemical composition of steels and cast irons.
Annex B gives a list of withdrawn Euronorms, together with the corresponding replacement European Standards, if any.
Annex C shows graphical representations of the content ranges of the methods listed in this document. Figure C.1 gives the content ranges of the referee methods, Figure C.2 gives the content ranges of the routine methods and Figure C.3 represents the fields of application of all the methods described.
Annex D provides a trilingual key of the abbreviations used in the Figures given in Annex C.
NOTE Three methods applicable for the analysis of some ferro-alloys are listed in Annex A.
Eisen und Stahl - Europäische Normen für die Bestimmung der chemischen Zusammensetzung
Aciers et fontes - Normes européennes pour la détermination de la composition chimique
Le présent Rapport technique énumère, à l'Article 3, les Normes européennes actuellement disponibles pour la détermination de la composition chimique des aciers et des fontes. Dans l'Article 4, ce Rapport Technique détaille le domaine d'application et donne le principe de la méthode pour chaque norme.
Les projets de Normes européennes ou de Rapports techniques du CEN, en cours de préparation par l'ECISS/TC 102 sont disponibles sur la page internet du CEN, par le lien https://standards.cen.eu/dyn/www/f?p=204:22:0::::FSP_ORG_ID:733643&cs=123E58BF77E3DE921F548B80C5FF2E5D4.
L'Annexe A donne une liste d’autres Normes européennes et Rapports techniques du CEN applicables pour la détermination de la composition chimique des aciers et des fontes.
L'Annexe B donne une liste des Euronorm annulées, ainsi que les Normes européennes correspondantes qui les remplacent, le cas échéant.
L'Annexe C présente les représentations graphiques des intervalles de teneurs des méthodes présentées dans le présent Rapport technique. La Figure C.1 donne les intervalles de teneurs des méthodes de référence, la Figure C.2 donne les intervalles de teneurs des méthodes de routine et la Figure C.3 représente les domaines d’application de toutes les méthodes disponibles.
L’Annexe D fournit une correspondance trilingue des abréviations utilisées dans les figures de l’Annexe C.
NOTE Trois méthodes applicables à l'analyse de certains ferro-alliages sont énumérées dans l'annexe A.
Železo in jeklo - Evropski standardi za določevanje kemijske sestave
V tem dokumentu so v točki 3 navedeni evropski standardi, ki so trenutno na voljo za določevanje kemijske sestave jekel in železovih litin.
V točki 4 tega tehničnega poročila so navedene podrobnosti glede območja uporabe in načela metod za posamezne standarde.
V dodatku A je seznam drugih evropskih standardov in tehničnih poročil CEN, ki se uporabljajo za določevanje kemijske sestave jekel in železovih litin.
V dodatku B je seznam preklicanih normativov EURONORM z ustrezno nadomestitvijo morebitnih evropskih standardov.
V dodatku C so grafični prikazi razponov vsebnosti metod, ki so na voljo v tem tehničnem poročilu. S slike C.1 so razvidni razponi vsebnosti referenčnih metod, s slike C.2 razponi vsebnosti rutinskih metod, s slike C.3 pa področja uporabe vseh razpoložljivih metod.
V dodatku D je trijezična legenda kratic, ki so uporabljene na slikah v dodatku C.
OPOMBA: Tri metode, ki se uporabljajo za analizo nekaterih železovih litin, so navedene v dodatku A.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-december-2018
1DGRPHãþD
SIST-TP CEN/TR 10261:2013
äHOH]RLQMHNOR(YURSVNLVWDQGDUGL]DGRORþHYDQMHNHPLMVNHVHVWDYH
Iron and steel - European standards for the determination of chemical composition
Eisen und Stahl - Europäische Normen für die Bestimmung der chemischen
Zusammensetzung
Aciers et fontes - Normes européennes pour la détermination de la composition chimique
Ta slovenski standard je istoveten z: CEN/TR 10261:2018
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
77.080.01 Železne kovine na splošno Ferrous metals in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TR 10261
TECHNICAL REPORT
RAPPORT TECHNIQUE
October 2018
TECHNISCHER BERICHT
ICS 77.040.30 Supersedes CEN/TR 10261:2013
English Version
Iron and steel - European standards for the determination
of chemical composition
Aciers et fontes - Normes européennes pour la Eisen und Stahl - Europäische Normen für die
détermination de la composition chimique Bestimmung der chemischen Zusammensetzung
This Technical Report was approved by CEN on 13 August 2018. It has been drawn up by the Technical Committee ECISS/TC 102.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 10261:2018 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 European Standards for the determination of the chemical composition of steels and
irons . 5
4.1 Mono-elemental methods . 5
4.2 Multi-elemental methods . 7
5 Range of application and principle of the methods . 8
5.1 Mono-elemental methods . 8
5.2 Multi-elemental methods . 21
Annex A (informative) List of other European Standards and CEN Technical Reports
applicable for the determination of the chemical composition of ferrous materials . 26
Annex B (informative) List of withdrawn Euronorms and of the corresponding replacement
European standards . 27
Annex C (normative) Graphical representation of the scope of methods described in this
technical report . 30
Annex D (informative) Trilingual key of the abbreviations used in the figures given in
Annex C . 34
European foreword
This document (CEN/TR 10261:2018) has been prepared by Technical Committee ECISS/TC 102
“Methods of chemical analysis for iron and steel”, the secretariat of which is held by SIS.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN/TR 10261:2013.
In comparison with the previous edition of CEN/TR 10261:2013, the following significant technical
changes were made:
— Clause 1: updating the link to the webpage of CEN;
— in 4.1, for carbon, withdrawal of EN 10036;
— in 4.1, for calcium, reference updated;
— in 4.1, for chromium, addition of prCEN/TR 10367;
— in 4.1, for copper, replacement of EN 24946:1990 and EN 24946:1990/AC:1991 with EN ISO 4946;
— in 4.1, for lead, reference updated;
— in 4.1, for manganese, EN 24159:1989 moved to Annex A;
— in 4.1, addition of EN 10361, for nickel;
— in 4.1, for nickel, replacement of EN 24938:1990 and EN 24938:1990/AC:1991 with EN ISO 4938;
— in 4.1, for nickel, reference updated;
— in 4.1, for selenium, addition of CEN/TR 10364;
— in 4.1, for silicon, replacement of EN 24829-2:1990 and EN 24829-2:1990/AC:1991 with
EN ISO 4829-2;
— in 4.1, for titanium, updating the date of publication of EN 10211;
— in 4.2, addition of EN 10355.
1 Scope
This document lists, under Clause 4, the European Standards which are currently available for the
determination of the chemical composition of steels and cast irons.
In Clause 5, this document provides details on the range of application and gives the principle of the
method described in each standard.
Items which are under preparation as European Standards or as CEN Technical Reports by ECISS/TC 102
are available on the webpage of CEN, through the link
https://standards.cen.eu/dyn/www/f?p=204:22:0::::FSP_ORG_ID:733643&cs=123E58BF77E3DE921F
548B80C5FF2E5D4.
Annex A gives a list of other European Standards and CEN Technical Reports applicable for the
determination of the chemical composition of steels and cast irons.
Annex B gives a list of withdrawn Euronorms, together with the corresponding replacement European
Standards, if any.
Annex C shows graphical representations of the content ranges of the methods listed in this document.
Figure C.1 gives the content ranges of the referee methods, Figure C.2 gives the content ranges of the
routine methods and Figure C.3 represents the fields of application of all the methods described.
Annex D provides a trilingual key of the abbreviations used in the Figures given in Annex C.
NOTE Three methods applicable for the analysis of some ferro-alloys are listed in Annex A.
2 Normative references
There are no normative references in this document.
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
referee method
stoichiometric method or a method calibrated against pure metals or stoichiometric compounds, which
is to be used for certification analysis or in case of arbitration
3.2
routine method
method calibrated against reference materials or certified reference materials, or against standard
solutions commercially available, which is widely used for control purposes (day to day analysis)
4 European Standards for the determination of the chemical composition of
steels and irons
4.1 Mono-elemental methods
— Aluminium, Al
EN 29658:1991, Steel — Determination of aluminium content — Flame atomic absorption spectrometric
method (ISO 9658:1990)
— Arsenic, As
EN 10212:1995, Chemical analysis of ferrous materials — Determination of arsenic in steel and iron —
Spectrophotometric method
— Boron, B
EN 10200:2012, Chemical analysis of ferrous materials — Determination of boron in steels —
Spectrophotometric method
EN ISO 13900:2002, Steel — Determination of boron content — Curcumin spectrophotometric method
after distillation (ISO 13900:1997)
— Calcium, Ca
prEN 10177:2018, Steels — Determination of calcium content — Flame atomic absorption spectrometric
method (FAAS)
— Carbon, C
EN ISO 15349-2:2003, Unalloyed steel — Determination of low carbon content — Part 2: Infrared
absorption method after combustion in an induction furnace (with preheating) (ISO 15349-2:1999)
EN ISO 9556:2001, Steel and iron — Determination of total carbon content — Infrared absorption method
after combustion in an induction furnace (ISO 9556:1989)
— Chromium, Cr
prCEN/TR 10367, Alloyed steels — Determination of chromium content — Inductively coupled plasma
optical emission spectrometric method
EN 10188:1989, Chemical analysis of ferrous materials — Determination of chromium in steels and irons
— Flame atomic absorption spectrometric method
EN 24937:1990, Steel and iron — Determination of chromium content — Potentiometric or visual method
(ISO 4937:1986)
EN 24937:1990/AC:1991 (Editorial correction), Steel and iron — Determination of chromium content —
Potentiometric or visual method (ISO 4937:1986)
— Copper, Cu
EN 24943:1990, Chemical analysis of ferrous metal — Determination of copper content — Flame atomic
absorption spectrometric method (ISO 4943:1985)
EN 24943:1990/AC:1991 (Editorial correction), Steel and cast iron — Determination of copper content —
Flame atomic absorption spectrometric method (ISO 4943:1985)
EN ISO 4946:2016, Steel and cast iron — Determination of copper — 2,2’-Biquinoline spectrophotometric
method (ISO 4946:2016)
— Lead, Pb
prEN 10181:2018, Steels — Determination of lead content — Flame atomic absorption spectrometric
method (FAAS)
— Manganese, Mn
EN 10071:2012, Chemical analysis of ferrous materials — Determination of manganese in steels and
irons — Electrometric titration method
EN ISO 10700:1995, Steel and iron — Determination of manganese content — Flame atomic spectrometric
method (ISO 10700:1994)
— Nickel, Ni
prEN 10136:2018, Steels and cast irons — Determination of nickel content — Flame atomic absorption
spectrometric method (FAAS)
EN 10361:2015, Alloyed steels - Determination of nickel content - Inductively coupled plasma optical
emission spectrometric method
EN ISO 4938:2016, Steel and iron — Determination of nickel content — Gravimetric or titrimetric method
(ISO 4938:2016)
— Niobium, Nb
EN 10178:1989, Chemical analysis of ferrous materials — Determination of niobium in steels —
Spectrophotometric method
— Nitrogen, N
EN 10179:1989, Chemical analysis of ferrous materials — Determination of nitrogen (trace amounts) in
steels — Spectrophotometric method
EN ISO 10720:2007, Steel and iron — Determination of nitrogen content — Thermal conductimetric
method after fusion in a current of inert gas (ISO 10720:1997)
EN ISO 15351:2010, Steel and iron — Determination of nitrogen content — Thermal conductimetric
method after fusion in a current of inert gas (Routine method) (ISO 15351:1999)
EN ISO 4945:2009, Steel — Determination of nitrogen content — Spectrophotometric method (ISO
4945:1977)
— Oxygen, O
EN 10276-1:2000, Chemical analysis of ferrous materials — Determination of oxygen in steel and iron —
Part 1: Sampling and preparation of steel samples for oxygen determination
EN 10276-2:2003, Chemical analysis of ferrous materials — Determination of oxygen content in steel and
iron — Part 2: Infrared method after fusion under inert gas
— Phosphorus, P
EN 10184:2006, Chemical analysis of ferrous materials — Determination of phosphorus in non-alloyed
steels and irons — Molybdenum blue spectrophotometric method
EN ISO 10714:2002, Steel and iron — Determination of phosphorus content — Phosphovanadomolybdate
spectrophotometric method (ISO 10714:1992)
— Selenium, Se
CEN/TR 10362:2014, Chemical analysis of ferrous materials - Determination of selenium in steels -
Electrothermal atomic absorption spectrometric method
— Silicon, Si
EN ISO 4829-1:2018, Steel and cast iron — Determination of total silicon contents — Reduced
molybdosilicate spectrophotometric method — Part 1: Silicon contents between 0,05 % and 1,0 % (ISO
4829-1:2018)
EN ISO 4829-2:2016, Steels — Determination of total silicon contents - Reduced molybdosilicate
spectrophotometric method — Part 2: Silicon contents between 0,01 % and 0,05 % (ISO 4829-2:2016)
EN ISO 439:2010, Steel and iron — Determination of total silicon content — Gravimetric method
(ISO 439:1994)
— Sulphur, S
EN 24935:1991, Steel and iron — Determination of sulphur content — Infrared absorption method after
combustion in an induction furnace (ISO 4935:1989)
EN ISO 4934:2003, Steel and iron — Determination of sulfur content — Gravimetric method
(ISO 4934:2003)
— Titanium, Ti
EN 10211:2013, Chemical analysis of ferrous materials — Determination of titanium in steels and cast irons
— Flame atomic absorption spectrometric method
EN ISO 10280:1995, Steel and iron — Determination of titanium content — Diantipyrylmethane
spectrophotometric method (ISO 10280:1991)
— Vanadium, V
EN 24947:1991, Steel and cast iron — Determination of vanadium content — Potentiometric titration
method (ISO 4947:1986)
4.2 Multi-elemental methods
— Aluminium, Al; Chromium, Cr; Cobalt, Co; Copper, Cu; Mang
...
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