EN 14110:2003

Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of methanol content

This European Standard specifies a method for the determination of methanol content in fatty acid methyl esters (FAME) for use as diesel fuel and domestic heating fuel. The method is applicable for a concentration range from 0,01 % to 0,5 % (m/m) methanol. The method is not applicable to mixtures of FAME which contain other low boiling components.

Erzeugnisse aus pflanzlichen und tierischen Fetten und Ölen - Fettsäure-Methylester (FAME) - Bestimmung des Methanolgehaltes

Diese Europäische Norm legt ein Verfahren zur Bestimmung von Methanol in Fettsäure-Methylestern (FAME) für deren Gebrauch als Dieselkraftstoff oder als Heizöl fest. Dieses Verfahren ist anwendbar auf einen Konzentrationsbereich von 0,01 % (m/m) bis 0,5 % (m/m) Methanol. Dieses Verfahren ist nicht anwendbar auf FAME-Mischungen, die andere niedrig siedende Komponenten enthalten.

Produits dérivés des corps gras - Esters méthyliques d'acides gras (EMAG) - Détermination de la teneur en méthanol

La présente Norme européenne décrit une méthode de dosage du méthanol dans les esters méthyliques d'acides gras (EMAG) utilisable pour le gazole et le combustible de chauffage domestique. Cette méthode est applicable sur une plage de concentrations en méthanol comprise entre 0,01 % et 0,5 % (m/m). Elle n'est pas applicable aux mélanges d'EMAG qui contiennent des composants à faible point d'ébullition.

Derivati maščob in olj - Metil estri maščobnih kislin (FAME) - Določevanje metanola

General Information

• Status: Withdrawn
• Publication Date: 29-Apr-2003
• Withdrawal Date: 09-Apr-2019
• ICS: 67.200.10 - Animal and vegetable fats and oils
• Technical Committee: CEN/TC 307 - Oilseeds, vegetables and animal fats and oils and their by-products - Methods of sampling and analys
• Drafting Committee: CEN/TC 307/WG 1 - Test methods on fatty acid methylester
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 10-Apr-2019
• Mandate: M/245 - Mandate to CEN for the elaboration and adoption of standards concerning minimum requirement specifications including test methods for Fatty Acid MethylEster (FAME) as fuel for diesel engines and for space heating
• Ref Project: SIST EN 14110:2003 - Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of methanol content

Relations

• Replaced By: EN 14110:2019 - Fat and oil derivatives - Fatty Acid Methyl Esters - Determination of methanol content
• Effective Date: 18-Jan-2017

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.ORþHYDQMHPHWDQRODErzeugnisse aus pflanzlichen und tierischen Fetten und Ölen - Fettsäure-Methylester (FAME) - Bestimmung des MethanolgehaltesProduits dérivés des corps gras - Esters méthyliques d'acides gras (EMAG) - Détermination de la teneur en méthanolFat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of methanol content67.200.10Animal and vegetable fats and oilsICS:Ta slovenski standard je istoveten z:EN 14110:2003SIST EN 14110:2003en01-november-2003SIST EN 14110:2003SLOVENSKI
STANDARD



SIST EN 14110:2003



EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 14110April 2003ICS 67.200.10English versionFat and oil derivatives - Fatty Acid Methyl Esters (FAME) -Determination of methanol contentProduits dérivés des corps gras - Esters méthyliquesd'acides gras (EMAG) - Détermination de la teneur enméthanolErzeugnisse aus pflanzlichen und tierischen Fetten undÖlen - Fettsäure-Methylester (FAME) - Bestimmung desMethanolgehaltesThis European Standard was approved by CEN on 2 January 2003.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Slovakia, Spain, Sweden, Switzerland and UnitedKingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2003 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 14110:2003 ESIST EN 14110:2003



EN 14110:2003 (E)2ForewordThis document (EN 14110:2003) has been prepared by Technical Committee CEN/TC 307 "Oilseeds, vegetableand animal fats and oils and their by-products - Methods of sampling and analysis", the secretariat of which is heldby AFNOR.This European Standard shall be given the status of a national standard, either by publication of an identical text orby endorsement, at the latest by October 2003, and conflicting national standards shall be withdrawn at the latestby October 2003.This document has been prepared under Mandate M/245 on Fatty Acid Methylester (FAME) given to CEN by theEuropean Commission and the European Free Trade Association, and supports essential requirements of EUDirective(s).Annexes A and B are informative.According to the CEN/CENELEC Internal Regulations, the national standards organizations of the followingcountries are bound to implement this European Standard: Austria, Belgium, Czech Republic, Denmark, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal,Slovakia, Spain, Sweden, Switzerland and the United Kingdom.SIST EN 14110:2003



EN 14110:2003 (E)31 ScopeThis European Standard specifies a method for the determination of methanol content in fatty acid methyl esters(FAME) for use as diesel fuel and domestic heating fuel. The method is applicable for a concentration range from0,01 % (m/m) to 0,5 % (m/m) methanol. The method is not applicable to mixtures of FAME which contain other lowboiling components.2 PrincipleThe sample is heated at 80 °C in a hermetically sealed vial to allow desorption of contained methanol into the gasphase. When equilibrium is reached, a defined part of the gas phase is injected into a gas chromatograph, wheremethanol is detected with a flame ionisation detector. Normally methanol is the only peak in the chromatogram.The amount of methanol is calculated by reference to an external calibration. Methanol can also be determinedafter addition of an internal standard to the sample before heating, followed by calculation with the use of aninternal calibration factor.NOTEIf only manual equipment is available then only internal standard calibration should be used.3 ReagentsUse only reagents of recognized analytical grade, unless otherwise specified.3.1Methanol, of known purity greater than 99,5 %.3.22-propanol, of known purity, greater than 99,5 % (for procedure A, internal calibration).3.3Reference FAME, with a methanol content less than 0,001 % (m/m).NOTEReference FAME can either be obtained from commercial sources or by washing by three or five times with distilledwater in a separator fun
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