CEN/TS 16182:2012

Sludge treated biowaste and soil - Determination of nonylphenols (NP) and nonylphenol-mono- and diethoxylates using gas chromatography with mass selective detection (GC-MS)

This Technical Specification specifies a method for the determination of nonylphenols (NP), nonylphenol-monoethoxylates (NP1EO) and nonylphenol-diethoxylates (NP2EO) in sludge using GC-MS.
For sludge a limit of detection of 0,1 mg/kg and for soil and treated bio-waste 0,02 mg/kg (expressed as dry matter) may be achieved.
Lower limits of detection may be achieved by concentrating the extract by solvent evaporation.
NOTE   4-tert-octylphenol can also be analysed with this method.

Schlamm, behandelter Bioabfall und Boden - Bestimmung von Nonylphenolen (NP) und Nonylphenol-Mono- und Diethoxylaten mittels Gaschromatographie mit massenselektiver Detektion (GC-MS)

Diese Technische Spezifikation legt ein Verfahren fest zur Bestimmung von Nonylphenolen (NP), Nonylphenol monoethoxylaten (NP1EO) und Nonylphenol diethoxylaten (NP2EO) in Schlamm, behandeltem Bioabfall und Boden, mit Hilfe der GC-MS.
Für Schlamm kann eine Nachweisgrenze von 0,1 mg/kg und für Boden und behandelten Bioabfall eine Nachweisgrenze von 0,02 mg/kg (angegeben als Trockenmasse) erreicht werden.
Niedrigere Nachweisgrenzen können erreicht werden, wenn der Extrakt durch Verdampfen des Lösemittels konzentriert wird.
ANMERKUNG   Nach diesem Verfahren kann auch 4 tert Octylphenol analysiert werden.

Boues, biodéchets traités et sols - Détermination des nonylphénols et nonylphénol-mono- et di-éthoxylates par chromatographie en phase gazeuse avec détection sélective de masse (GC-MS)

La présente Spécification technique définit une méthode pour le dosage des nonylphénols (NP), des nonylphénol monoéthoxylates (NP1EO) et des nonylphénol diéthoxylates (NP2EO) dans les boues, les biodéchets traités et les sols par chromatographie en phase gazeuse avec détection par spectrométrie de masse (CG-SM).
Il est possible d'atteindre une limite de détection de 0,1 mg/kg pour les boues et de 0,02 mg/kg (exprimée en teneur en matière sèche) pour les sols et les biodéchets traités.
Il est possible d'atteindre des limites de détection inférieures en augmentant la concentration de l'extrait par évaporation de solvant.
NOTE   Il est également possible d'analyser le 4-tert-octylphénol par cette méthode.

Blato, obdelani biološki odpadki in tla - Določevanje nonilfenolov (NP) ter nonilfenol-monoetoksilatov in dietoksilatov z uporabo plinske kromatografije z masno selektivno detekcijo (GC/MS)

Ta tehnična specifikacija opredeljuje metodo za določevanje nonilfenolov (NP), nonilfenol-monoetoksilatov (NP1EO) in nonilfenol-dietoksilatov (NP2EO) v blatu, obdelanih bioloških odpadkih in tleh z uporabo plinske kromatografije z masno selektivno detekcijo (GC/MS). Za blato se lahko doseže meja detekcije 0,1 mg/kg, za tla in obdelane biološke odpadke pa 0,02 mg/kg (izraženo kot suha snov). Nižje meje detekcije se lahko dosežejo s koncentracijo izvlečka z izhlapevanjem raztopine.

General Information

• Status: Published
• Publication Date: 21-Feb-2012
• ICS: 13.030.01 - Wastes in general
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 2 - Organic analysis
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Completion Date: 09-Oct-2023
• Directive: 86/278/EEC - Protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture
• Mandate: M/330 - Mandate given to CEN for the development of horizontal standards in the fields of sludge, biowaste and soil.
• Ref Project: SIST-TS CEN/TS 16182:2012 - Sludge treated biowaste and soil - Determination of nonylphenols (NP) and nonylphenol-mono- and diethoxylates using gas chromatography with mass selective detection (GC-MS)

Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TS CEN/TS 16182:2012
01-junij-2012
%ODWRREGHODQLELRORãNLRGSDGNLLQWOD'RORþHYDQMHQRQLOIHQRORY13WHU
QRQLOIHQROPRQRHWRNVLODWRYLQGLHWRNVLODWRY]XSRUDERSOLQVNHNURPDWRJUDILMH]
PDVQRVHOHNWLYQRGHWHNFLMR*&06
Sludge treated biowaste and soil - Determination of nonylphenols (NP) and nonylphenol-
mono- and diethoxylates using gas chromatography with mass selective detection (GC-
MS)
Schlamm, behandelter Bioabfall und Boden - Bestimmung von Nonylphenolen (NP) und
Nonylphenol-Mono- und Diethoxylaten mittels Gaschromatographie mit massenselektiver
Detektion (GC-MS)
Boues, bio-déchets traités et sols - Détermination des nonylphénols et nonylphénol-
mono- et di-éthoxylates par chromatographie en phase gazeuse avec détection sélective
de masse (GC-MS)
Ta slovenski standard je istoveten z: CEN/TS 16182:2012
ICS:
13.030.20 7HNRþLRGSDGNL%ODWR Liquid wastes. Sludge
SIST-TS CEN/TS 16182:2012 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TS CEN/TS 16182:2012

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SIST-TS CEN/TS 16182:2012


TECHNICAL SPECIFICATION
CEN/TS 16182

SPÉCIFICATION TECHNIQUE

TECHNISCHE SPEZIFIKATION
February 2012
ICS 13.030.01
English Version
Sludge treated biowaste and soil - Determination of
nonylphenols (NP) and nonylphenol-mono- and diethoxylates
using gas chromatography with mass selective detection (GC-
MS)
Boues, biodéchets traités et sols - Détermination des Schlamm, behandelter Bioabfall und Boden - Bestimmung
nonylphénols et nonylphénol-mono- et di-éthoxylates par von Nonylphenolen (NP) und Nonylphenol-Mono- und
chromatographie en phase gazeuse avec détection Diethoxylaten mittels Gaschromatographie mit
sélective de masse (GC-MS) massenselektiver Detektion (GC-MS)
This Technical Specification (CEN/TS) was approved by CEN on 24 April 2011 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2012 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 16182:2012: E
worldwide for CEN national Members.

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SIST-TS CEN/TS 16182:2012
CEN/TS 16182:2012 (E)
Contents Page
Foreword .3
Introduction .4
1 Scope .5
2 Normative references .5
3 Principle .5
4 Interferences .5
4.1 Interferences from sampling .5
4.2 Interferences by GC-MS .6
5 Reagents .6
6 Apparatus .
...