EN 13466-1:2001

Fertilizers - Determination of water content (Karl Fischer methods) - Part 1: Methanol as extracting medium

This European Standard specifies a Karl Fischer titrimetric method for the determination of the water content of fertilizers based on the use of methanol as extracting medium.
The method is applicable to all solid mineral fertilizers. The result (KFM water) includes "free" water and extracted water of crystallization from the following components of fertilizers: calcium nitrate tetrahydrate (Ca(NO3)2·4H2O); calcium hydrogen phosphate dihydrate (CaHPO4·2H2O); calcium sulfate dihydrate (gypsum, CaSO4·2H2O), calcium sulfate hemihydrate (CaSO4·0,5H2O); magnesium sulfate heptahydrate (MgSO4·7H2O) ; potassium chloride magnesium sulfate water (1/1/2,75, Kainite, KCl·MgSO4·2,75H2O); potassium magnesium sulfate hexahydrate (Schoenite, K2SO4·MgSO4·6H2O); potassium magnesium sulfate tetrahydrate (Leonite, K2SO4·MgSO4·4H2O); potassium sulfate calcium sulfate monohydrate (Syngenite, K2SO4·CaSO4·H2O); potassium chloride magnesium chloride hexahydrate (Carnallite, KCl·MgCl2·6H2O); magnesium nitrate hexahydrate (Mg(NO3)2·6H2O).
Metal oxides and hydroxides soluble in methanol and pyridine will have an effect which can be corrected for, if their content is known.

Düngemittel - Bestimmung des Wassergehaltes (Karl-Fischer-Verfahren) - Teil 1: Methanol als Extraktionsmittel

Diese Europäische Norm legt ein titrimetrisches Karl-Fischer-Verfahren für die maßanalytische Bestimmung des Wasser-gehaltes von Düngemitteln fest, das auf der Verwendung von Methanol als Extraktionsmittel basiert.
Das Verfahren gilt für alle festen mineralischen Düngemittel. Das Ergebnis (KFM-Wasser) umfasst ¿freies" Wasser sowie extrahiertes Kristallwasser der folgenden Düngemittelbestandteile: Calciumnitrattetrahydrat (Ca(NO3)2 · 4H2O); Calciumhydrogenphosphatdihydrat (CaHPO4 · 2H2O); Calciumsulfatdihydrat (Gips, CaSO4 · 2H2O), Calciumsulfa-themihy-drat (CaSO4 · 0,5H2O); Magnesiumsulfatheptahydrat (MgSO4 · 7H2O); Kaliumchlorid-Magnesiumsulfathydrat-wasser (1/1/2,75, Kainit, KCl · MgSO4 · 2,75H2O); Kalium-Magnesium-sulfat-hexahydrat (Schoenit, K2SO4 · MgSO4 · 6H-2O); Kalium-Magnesiumsulfattetrahydrat (Leonit, K2SO4 · MgSO4 · 4H2O); Kaliumsulfat-Calciumsulf-atmonohydrat (Syngenit, K2SO4 · CaSO4 · H2O); Kaliumchlorid-Magnesiumchloridhexahydrat (Carnallit, KCl · MgCl2 · 6H2O); Magnesiumnitrathexahy-drat (Mg(NO3)2 · 6H2O).
In Methanol und Pyridin lösliche Metalloxide und Hydroxide haben Auswirkungen, die jedoch korrigiert werden können, falls deren Anteil bekannt ist.

Engrais - Détermination de la teneur en eau (Méthodes Karl Fischer) - Partie 1: Le méthanol comme milieu d'extraction

La présente norme spécifie une méthode Karl Fischer de titrage de la teneur en eau des engrais, reposant sur l'utilisation de méthanol comme milieu d'extraction.
La méthode est applicable à toutes les engrais solides. Le résultat (eau KFM) englobe l'eau "libre" et l'eau de cristallisation des éléments suivants des matières fertilisantes : nitrate de calcium tétrahydraté (Ca(NO3)2.4H2O), hydrogénophosphate de calcium dihydraté (CaHPO4).2H2O), sulfate de calcium dihydraté (gypse, (CaSO4.2H2O), sulfate de calcium hémihydraté (CaSO4.0,5 H2O), sulfate de magnésium heptahydraté (MgSO4.7H2O), eau au sulfate de magnésium/chlorure de potassium (1°1/2,75, Kainite, KCl MgSO4.2,75H2O), sulfate de magnésium-potassium hexahydraté (Schoenite, K2SO4 MgSO4.6H2O), sulfate de magnésium-potassium tétrahydraté (Léonite, K2SO4 MgSO4 . 4H2O), sulfate de potassium - sulfate de calcium monohydraté (Syngénite, K2SO4 CaSO4.H2O), chlorure de potassium - chlorure de magnésium hexahydraté (carnallite, KCl MgCl2.6H2O), nitrate de magnésium hexahydraté (Mg(NO3)2.6H2O).
Les oxydes et les hydroxydes de métaux solubles dans le méthanol et la pyridine ont un effet qui peut être corrigé si leur teneur est connue.

Gnojila - Določevanje količine vode (Karl Fischerjeve metode) - 1. del: Ekstrakcija z metanolom

General Information

• Status: Published
• Publication Date: 09-Oct-2001
• Withdrawal Date: 29-Apr-2002
• ICS: 65.080 - Fertilizers
• Technical Committee: CEN/TC 260 - Fertilizers and liming materials
• Drafting Committee: CEN/TC 260/WG 2 - Physical properties of fertilizers
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Completion Date: 08-Jul-2022
• Ref Project: SIST EN 13466-1:2002 - Fertilizers - Determination of water content (Karl Fischer methods) - Part 1: Methanol as extracting medium

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.PHWDQRORPDüngemittel - Bestimmung des Wassergehaltes (Karl-Fischer-Verfahren) - Teil 1: Methanol als ExtraktionsmittelEngrais - Détermination de la teneur en eau (Méthodes Karl Fischer) - Partie 1: Le méthanol comme milieu d'extractionFertilizers - Determination of water content (Karl Fischer methods) - Part 1: Methanol as extracting medium65.080GnojilaFertilizersICS:Ta slovenski standard je istoveten z:EN 13466-1:2001SIST EN 13466-1:2002en01-november-2002SIST EN 13466-1:2002SLOVENSKI
STANDARD
EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 13466-1October 2001ICS 65.080English versionFertilizers - Determination of water content - (Karl Fischermethods) - Part 1: Methanol as extracting mediumEngrais - Détermination de la teneur en eau (Méthodes KarlFischer) - Partie 1: Le méthanol comme milieu d'extractionDüngemittel - Bestimmung des Wassergehaltes (Karl-Fischer-Verfahren) - Teil 1: Methanol als ExtraktionsmittelThis European Standard was approved by CEN on 18 August 2001.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2001 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 13466-1:2001 ESIST EN 13466-1:2002

calcium sulfate hemihydrate (CaSO4·0,5H2O); magnesium sulfateheptahydrate (MgSO4·7H2O); potassium chloride magnesium sulfate water (1/1/2,75, Kainite,KCl·MgSO4·2,75H2O); potassium magnesium sulfate hexahydrate (Schoenite, K2SO4·MgSO4·6H2O); potassiummagnesium sulfate tetrahydrate (Leonite, K2SO4·MgSO4·4H2O); potassium sulfate calcium sulfate monohydrate(Syngenite, K2SO4·CaSO4·H2O); potassium chloride magnesium chloride hexahydrate (Carnallite, KCl·MgCl2·6H2O); magnesium nitrate hexahydrate (Mg(NO3)2·6H2O).Extraction with 2-propanol gives a result which is a combination of free water and extracted water of crystallizationfrom the following components of fertilizers: calcium nitrate tetrahydrate (Ca(NO3)2·4H2O); magnesium sulfateheptahydrate (MgSO4·7H2O); potassium chloride magnesium chloride hexahydrate (Carnallite, KCl·MgCl2·6H2O);magnesium nitrate hexahydrate (Mg(NO3)2·6H2O).SIST EN 13466-1:2002
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