EN ISO 15009:2016

Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2016)

ISO 15009:2016 specifies a method for quantitative gas-chromatographic determination of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons in soil.
This International Standard is applicable to all types of soil.
NOTE          In the case of unsaturated peaty soils, absorption of the extraction solution may occur.
The lower limit of quantification is dependent on the equipment used and the quality of the methanol grade used for the extraction of the soil sample.
Under the conditions specified in this International Standard the following limits of quantification apply (expressed on basis of dry matter):
Typical limit of quantification when using GC-FID:
-      Volatile aromatic hydrocarbons: 0,1 mg/kg
Typical limit of quantification when using GC-ECD:
-      Volatile halogenated hydrocarbons: 0,01 mg/kg
Lower limits of quantification for some compounds can be achieved by using mass spectrometry (MS) with selected ion detection.

Bodenbeschaffenheit - Gaschromatographische Bestimmung des Anteils an flüchtigen aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen Halogenkohlenwasserstoffen - Purge-und-Trap-Anreicherung mit thermischer Desorption (ISO 15009:2016)

Diese Internationale Norm legt ein quantitatives gaschromatographisches Verfahren zur Bestimmung von flüchtigen aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen Halogenkohlenwasserstoffen im Boden fest.
Diese Internationale Norm ist auf alle Bodenarten anwendbar.
ANMERKUNG   Im Fall von ungesättigten Torfböden kann es zur Absorption des Lösungsmittels kommen.
Die untere Bestimmungsgrenze ist abhängig von der verwendeten Prüfeinrichtung und der Qualität des Methanols, mit dem die Bodenprobe extrahiert wird.
Unter den in dieser Internationalen Norm festgelegten Bedingungen gelten folgende Bestimmungsgrenzen (bezogen auf Trockensubstanz):
Bei Anwendung eines Gaschromatographen mit Flammenionisationsdetektor (GC-FID) liegt die typische Bestimmungsgrenze:
—   für flüchtige aromatische Kohlenwasserstoffe: 0,1 mg/kg.
Bei Anwendung eines Gaschromatographen mit Elektronen-Einfang-Detektor (GC-ECD) liegt die typische Bestimmungsgrenze:
—   für flüchtige Halogenkohlenwasserstoffe: 0,01 mg/kg.
Niedrigere Bestimmungsgrenzen für einige Verbindungen können durch Anwendung der Massenspektrometrie (MS) mit selektiver Ionendetektion erreicht werden.

Qualité du sol - Détermination par chromatographie en phase gazeuse des teneurs en hydrocarbures aromatiques volatils, en naphtalène et en hydrocarbures halogénés volatils - Méthode par purge et piégeage avec désorption thermique (ISO 15009:2016)

ISO 15009:2016 spécifie une méthode pour la détermination quantitative par chromatographie en phase gazeuse des hydrocarbures aromatiques volatils, du naphtalène et des hydrocarbures halogénés volatils contenus dans les sols.
La présente Norme internationale est applicable à tous les types de sols.
NOTE          En cas de sols tourbeux insaturés, une absorption de la solution d'extraction peut avoir lieu.
La limite inférieure de détermination quantitative dépend du matériel utilisé et de la qualité du méthanol utilisé pour l'extraction de l'échantillon de sol.
Dans les conditions spécifiées dans la présente Norme internationale, les limites de détermination quantitative suivantes (exprimées par rapport à la matière sèche) s'appliquent:
Limite de détermination quantitative type lorsque le couplage CG-FID est utilisé:
-      Hydrocarbures aromatiques volatils: 0,1 mg/kg
Limite de détermination quantitative type lorsque le couplage CG-ECD est utilisé:
-      Hydrocarbures halogénés volatils: 0,01 mg/kg
Des limites de détermination quantitative plus faibles peuvent être atteintes pour certains composés si l'on utilise la spectrométrie de masse (SM) avec détection sélective des ions.

Kakovost tal - Določevanje hlapnih aromatskih ogljikovodikov, naftalena in hlapnih halogeniranih ogljikovodikov s plinsko kromatografijo - Metoda "purge-and-trap" s toplotno desorpcijo (ISO 15009:2016)

Ta mednarodni standard določa metodo za določevanje
hlapnih aromatskih ogljikovodikov, naftalena in hlapnih halogeniranih ogljikovodikov v tleh s kvantitativno plinsko kromatografijo.
Ta mednarodni standard se uporablja za vse vrste tal.
OPOMBA: V primeru nenasičenih šotnih tal lahko pride do absorpcije ekstrakcijske raztopine.
Nižja mejna vrednost kvantifikacije je odvisna od uporabljene opreme in kakovosti stopnje metanola,
ki se uporablja za ekstrakcijo vzorca tal.
Pod pogoji, določenimi v tem mednarodnem standardu, se uporabljajo naslednje mejne vrednosti kvantifikacije
(izraženo na podlagi suhe snovi):
Običajna mejna vrednost kvantifikacije pri uporabi plinske kromatografije/plamenske ionizacijske detekcije:
– hlapni aromatski ogljikovodiki: 0,1 mg/kg
Običajna mejna vrednost kvantifikacije pri uporabi plinske kromatografije/detektorja na zajetje elektronov:
– hlapni halogenirani ogljikovodiki: 0,01 mg/kg
Nižje mejne vrednosti kvantifikacije za nekatere zmesi se lahko dosežejo z masno spektrometrijo (MS)
z izbrano detekcijo iona.

General Information

• Status: Published
• Publication Date: 15-Mar-2016
• ICS: 13.080.10 - Chemical characteristics of soils
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 2 - Organic analysis
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 16-Mar-2016
• Completion Date: 16-Mar-2016
• Ref Project: SIST EN ISO 15009:2016 - Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2016)

Relations

• Replaces: EN ISO 15009:2013 - Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2012)
• Effective Date: 23-Mar-2016

Standards Content (Sample)

SLOVENSKI STANDARD
01-december-2016
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SIST EN ISO 15009:2013
.DNRYRVWWDO'RORþHYDQMHKODSQLKDURPDWVNLKRJOMLNRYRGLNRYQDIWDOHQDLQKODSQLK
KDORJHQLUDQLKRJOMLNRYRGLNRYVSOLQVNRNURPDWRJUDILMR0HWRGDSXUJHDQGWUDSV
WRSORWQRGHVRUSFLMR,62
Soil quality - Gas chromatographic determination of the content of volatile aromatic
hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap
method with thermal desorption (ISO 15009:2016)
Bodenbeschaffenheit - Gaschromatographische Bestimmung des Anteils an flüchtigen
aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen
Halogenkohlenwasserstoffen - Purge-und-Trap-Anreicherung mit thermischer Desorption
(ISO 15009:2016)
Qualité du sol - Détermination par chromatographie en phase gazeuse des teneurs en
hydrocarbures aromatiques volatils, en naphtalène et en hydrocarbures halogénés
volatils - Méthode par purge et piégeage avec désorption thermique (ISO 15009:2016)
Ta slovenski standard je istoveten z: EN ISO 15009:2016
ICS:
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 15009
EUROPEAN STANDARD
NORME EUROPÉENNE
March 2016
EUROPÄISCHE NORM
ICS 13.080.10 Supersedes EN ISO 15009:2013
English Version
Soil quality - Gas chromatographic determination of the
content of volatile aromatic hydrocarbons, naphthalene
and volatile halogenated hydrocarbons - Purge-and-trap
method with thermal desorption (ISO 15009:2016)
Qualité du sol - Détermination par chromatographie en Bodenbeschaffenheit - Gaschromatographische
phase gazeuse des teneurs en hydrocarbures Bestimmung des Anteils an flüchtigen aromatischen
aromatiques volatils, en naphtalène et en Kohlenwasserstoffen, Naphthalin und flüchtigen
hydrocarbures halogénés volatils - Méthode par purge Halogenkohlenwasserstoffen - Purge-und-Trap-
et piégeage avec désorption thermique (ISO Anreicherung mit thermischer Desorption (ISO
15009:2016) 15009:2016)
This European Standard was approved by CEN on 23 January 2016.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2016 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 15009:2016 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
European foreword
This document (EN ISO 15009:2016) has been prepared by Technical Committee ISO/TC 190 “Soil
quality” in collaboration with Technical Committee CEN/TC 345 “Characterization of soils” the
secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by September 2016, and conflicting national standards
shall be withdrawn at the latest by September 2016.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document supersedes EN ISO 15009:2013.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands,
Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 15009:2016 has been approved by CEN as EN ISO 15009:2016 without any modification.
INTERNATIONAL ISO
STANDARD 15009
Third edition
2016-02-15
Soil quality — Gas chromatographic
determination of the content of
volatile aromatic hydrocarbons,
naphthalene and volatile halogenated
hydrocarbons — Purge-and-trap
method with thermal desorption
Qualité du sol — Détermination par chromatographie en phase
gazeuse des teneurs en hydrocarbures aromatiques volatils, en
naphtalène et en hydrocarbures halogénés volatils — Méthode par
purge et piégeage avec désorption thermique
Reference number
ISO 15009:2016(E)
©
ISO 2016
ISO 15009:2016(E)
© ISO 2016, Published in Switzerland
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
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ii © ISO 2016 – All rights reserved

ISO 15009:2016(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Principle . 2
4 Reagents . 2
4.1 Water, free of volatile aromatic and volatile halogenated hydrocarbons . 2
4.2 Internal standards . 2
4.3 Standard compounds . . 3
4.3.1 Volatile aromatic hydrocarbons . 3
4.3.2 Volatile halogenated hydrocarbons . 3
4.4 Methanol . 4
4.5 Adsorbing agent . 4
4.6 Cooling water for purge and trap . 4
4.7 Inert gas for the gas chromatograph . 5
4.8 Nitrogen or helium as inert gas for the purge equipment . 5
4.9 Standard solutions . 5
4.9.1 Standard stock solutions for volatile aromatic and halogenated
compounds in methanol, 4 g/l . 5
4.9.2 Internal standard solutions in methanol, 4 g/l . 5
4.9.3 Calibration solutions . 5
4.10 Methanol containing internal standards . 6
5 Apparatus . 6
6 Sampling, preservation and sample pretreatment . 7
6.1 General . 7
6.2 Sampling using vials pre-filled with methanol . 8
6.3 Sampling using coring tube method . 8
7 Procedure. 8
7.1 Blank determination . 8
7.2 Extraction . 9
7.3 Purge and trap . 9
7.4 Gas chromatographic analysis . 9
7.4.1 Gas chromatographic conditions . 9
7.4.2 Calibration .10
7.4.3 Measurement .11
8 Calculation .12
8.1 Calculation of the concentration of a volatile compound in the water sample .12
8.2 Calculation of the concentration of a volatile compound in the soil sample .12
9 Expression of results .13
10 Precision .13
11 Test report .13
Annex A (informative) Relative retention time with respect to ethylbenzene-D10 of volatile
aromatic hydrocarbons and volatile halogenated hydrocarbons on following
columns: CP-Sil 5 CB and CP-Sil 13 CB .
...