EN 15199-4:2015

Petroleum products - Determination of boiling range distribution by gas chromatography method - Part 4: Light fractions of crude oil

This European Standard describes a method for the determination of the boiling range distribution of petroleum products by capillary gas chromatography using flame ionization detection. The standard is applicable to stabilized crude oils and for the boiling range distribution and the recovery up to and including n-nonane. A stabilized crude oil is defined as having a Reid Vapour Pressure equivalent to or less than 82,7 kPa as determined by IP 481 [3].
NOTE   For the purposes of this European Standard, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction, ω, and the volume fraction, φ.
WARNING —The use of this European Standard may involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

Mineralölerzeugnisse - Gaschromatographische Bestimmung des Siedeverlaufes - Teil 4: Leichte Fraktionen des Rohöls

Diese Europäische Norm beschreibt ein Verfahren zur Bestimmung des Siedeverlaufes von Mineralöl-erzeugnissen mit Hilfe der Kapillar-Gaschromatographie unter Anwendung der Flammenionisationsdetektion. Die Norm ist anwendbar auf stabilisierte Rohöle und gilt für den Siedeverlauf und die Wiederfindung bis einschließlich n Nonan. Ein stabilisiertes Rohöl ist definiert als Öl mit einem Reid-Dampfdruck von höchstens 82,7 kPa.
ANMERKUNG   Für die Zwecke dieser Europäischen Norm wird zur Angabe des Massenanteils   einer Substanz der Ausdruck „% (m/m)“ und für den Volumenanteil   einer Substanz der Ausdruck „% (V/V)“ verwendet.
WARNUNG — Die Anwendung dieser Europäischen Norm kann den Einsatz gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Diese Europäische Norm gibt nicht vor, alle mit ihrer Anwendung verbundenen Sicherheitsprobleme anzusprechen. Der Anwender dieser Norm ist dafür verantwortlich, vorher angemessene Maßnahmen in Hinblick auf Sicherheit und Gesundheit zu ergreifen und die Anwendbarkeit einschränkender Vorschriften zu ermitteln.

Produits pétroliers - Détermination de la répartition dans l'intervalle de distillation par méthode de chromatographie en phase gazeuse - Partie 4 : Fractions légères du pétrole brut

Naftni proizvodi - Določevanje porazdelitve območja vrelišč z metodo plinske kromatografije - 4. del: Lahke frakcije surovega olja

Ta evropski standard opisuje metodo določevanja porazdelitve območja vrelišč v naftnih proizvodih, in sicer s kapilarno plinsko kromatografijo z zaznavanjem plamenske ionizacije. Standard se uporablja za k\lahke frakcije. Določi se lahko porazdelitev območja vrelišč in obnovitev na C100 ali C120.

General Information

• Status: Withdrawn
• Publication Date: 15-Sep-2015
• Withdrawal Date: 31-Aug-2021
• ICS: 75.080 - Petroleum products in general
• Technical Committee: CEN/TC 19 - Petroleum products, lubricants and related products
• Drafting Committee: CEN/TC 19/WG 9 - Chromatographic test methods
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 01-Sep-2021
• Ref Project: SIST EN 15199-4:2015 - Petroleum products - Determination of boiling range distribution by gas chromatography method - Part 4: Light fractions of crude oil

Relations

• Replaced By: EN 15199-4:2021 - Petroleum products - Determination of boiling range distribution by gas chromatography method - Part 4: Light fractions of crude oil
• Effective Date: 31-Jul-2019

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Mineralölerzeugnisse - Gaschromatographische Bestimmung des Siedeverlaufes - Teil 4: Leichte Fraktionen des RohölsProduits pétroliers - Détermination de la répartition dans l'intervalle de distillation par méthode de chromatographie en phase gazeuse - Partie 4 : Lumière fractions du pétrole brutPetroleum products - Determination of boiling range distribution by gas chromatography method - Part 4: Light fractions of crude oil75.080Naftni proizvodi na splošnoPetroleum products in general71.040.50Fizikalnokemijske analitske metodePhysicochemical methods of analysisICS:Ta slovenski standard je istoveten z:EN 15199-4:2015SIST EN 15199-4:2015en,fr,de01-december-2015SIST EN 15199-4:2015SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 15199-4
September
t r s w ICS
y wä r z r English Version
Petroleum products æ Determination of boiling range distribution by gas chromatography method æ Part
vã Light fractions of crude oil Produits pétroliers æ Détermination de la répartition dans l 5intervalle de distillation par méthode de chromatographie en phase gazeuse æ Partie
v ã Lumière fractions du pétrole brut
Mineralölerzeugnisse æ Gaschromatographische Bestimmung des Siedeverlaufes æ Teil
vã Leichte Fraktionen des Rohöls This European Standard was approved by CEN on
s August
t r s wä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
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t r s w CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s w s { {æ vã t r s w ESIST EN 15199-4:2015

page European foreword . 3 1 Scope . 4 2 Normative references . 4 3 Terms and definitions . 4 4 Principle . 4 5 Reagents and materials . 4 6 Apparatus . 5 6.1 Analytical balance . 5 6.2 Gas chromatograph . 5 6.3 Detector . 5 6.4 Pre-column configurations . 5 6.4.1 Heated valve switching box (see Figure B.1). 5 6.4.2 Injection port (see Figure B.2 and B.3) . 6 6.5 Analytical column . 6 6.5.1 General . 6 6.5.2 Resolution . 7 6.6 Skewness . 7 6.7 Data collection . 8 7 Sampling and sample handling . 8 8 Calculation of response factors . 8 9 Procedure. 9 9.1 Sample preparation . 9 9.2 Determination of backflush time. 9 9.2.1 Initial work . 9 9.2.2 Analytical column . 9 9.2.3 Accelerated analytical column . 9 9.3 Sample analysis . 10 9.3.1 Initial work . 10 9.3.2 Calculation of individual components results . 10 9.3.3 Boiling point distribution of fraction up to and including nonane . 11 10 Reporting . 11 11 Precision . 11 11.1 General . 11 11.2 Repeatability, r . 11 11.3 Reproducibility, R . 11 12 Test report . 12 Annex A (informative)
Analysis assistance . 13 Annex B (informative)
Apparatus configuration . 19 Bibliography . 21
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