EN 15605:2010

Copper and copper alloys - Inductively coupled plasma optical emission spectrometry

This European Standard specifies six inductively coupled plasma emission spectrometry methods (A to F) for the determination of alloying elements and impurities in copper and copper alloys in the form of unwrought, wrought and cast products.
A complementary method, for the analysis of Copper-tin-lead alloys, is described in Annex B (informative). The precision criteria concerning this method do not reach the suitable level, for all the elements specified (zinc and phosphorus, namely).
These methods are applicable to the elements listed in Tables 1 to 6 within the composition ranges shown: (...)
NOTE 1   The ranges specified for each method can be extended or adapted, for the determination of lower mass fractions.
NOTE 2   Other elements may be included. However such elements and their mass fractions should be carefully checked, taking into account interference, sensitivity, resolution and linearity criteria for each instrument and each wavelength.

Kupfer und Kupferlegierungen - Optische Emissionsspektrometrie mit induktiv gekoppelter Plasmaanregung

Diese Europäische Norm legt sechs Verfahren (A bis F) zur optischen Emissionsspektrometrie mit induktiv gekoppelter Plasmaanregung für die Analyse von Legierungselementen und Verunreinigungen in Kupfer und Kupferlegierungen fest, die als Gussstücke oder als plastisch oder nicht plastisch geformte Produkte vorliegen.
Ein zusätzliches Verfahren für die Analyse von Kupfer-Zinn-Blei-Legierungen ist in Anhang B (informativ) beschrieben. Die ermittelten Daten zur Präzision für dieses Verfahren waren nicht für alle Elemente ausreichend gut (Zink und Phosphor).

Cuivre et alliages de cuivre - Analyse par spectrométrie d'émission optique avec source à plasma induit par haute fréquence

La présente Norme européenne spécifie six méthodes par spectrométrie d'émission avec plasma induit par
haute fréquence (A à F) pour la détermination des éléments d'alliage et des impuretés dans le cuivre et les
alliages de cuivre sous la forme de produits non corroyés, corroyés et moulés.
Une méthode complémentaire, pour analyser les alliages cuivre-étain-plomb est décrite dans l’Annexe B
(informative). Les critères de fidélité de cette méthode n’atteignent pas le niveau requis pour tous les
éléments spécifiés (zinc et phosphore notamment).
Ces méthodes sont applicables aux éléments listés dans les Tableaux 1 à 6 dans les domaines de
composition indiqués :

Baker in bakrove zlitine - Optična emisijska spektrometrija z induktivno sklopljeno plazmo

Ta evropski standard določa šest metod emisijske spektrometrije z induktivno sklopljeno plazmo (od A do F) za določevanje legirnih elementov  in nečistoč v bakru in bakrovih zlitinah v obliki negnetenih, gnetenih in ulitih polizdelkov. Komplementarna metoda za analizo kositrovih svinčenih zlitin je opisana v Dodatku B (informativni). Merila natančnosti, ki zadevajo to metodo, niso na primerni ravni za vse navedene elemente (in sicer cink in fosfor).

General Information

• Status: Published
• Publication Date: 20-Jul-2010
• ICS: 77.120.30 - Copper and copper alloys
• Technical Committee: CEN/TC 133 - Copper and copper alloys
• Drafting Committee: CEN/TC 133/WG 10 - Methods of analysis
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Completion Date: 19-Nov-2020
• Ref Project: SIST EN 15605:2010 - Copper and copper alloys - Inductively coupled plasma optical emission spectrometry

Relations

• Replaces: CEN/TS 15605:2007 - Copper and copper alloys - Inductively coupled plasma optical emission spectrometry
• Effective Date: 24-Jul-2010

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.SOD]PRKupfer und Kupferlegierungen - Optische Emissionsspektrometrie mit induktiv gekoppelter PlasmaanregungCuivre et alliages de cuivre - Analyse par spectrométrie d'émission optique avec source à plasma induit par haute fréquenceCopper and copper alloys - Inductively coupled plasma optical emission spectrometry77.120.30Baker in bakrove zlitineCopper and copper alloysICS:Ta slovenski standard je istoveten z:EN 15605:2010SIST EN 15605:2010en,de01-oktober-2010SIST EN 15605:2010SLOVENSKI
STANDARDSIST-TS CEN/TS 15605:20081DGRPHãþD

EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 15605
July 2010 ICS 77.120.30 Supersedes CEN/TS 15605:2007English Version
Copper and copper alloys - Inductively coupled plasma optical emission spectrometry
Cuivre et alliages de cuivre - Analyse par spectrométrie d'émission optique avec source à plasma induit par haute fréquence
Kupfer und Kupferlegierungen - Optische Emissionsspektrometrie mit induktiv gekoppelter Plasmaanregung This European Standard was approved by CEN on 12 June 2010.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15605:2010: ESIST EN 15605:2010

Optical emission spectrometer (OES) — Suggested performance criteria to be checked . 41Annex B (informative)
Inductively coupled plasma emission spectrometry method for the analysis of Copper-tin-lead alloys . 43Bibliography . 49 SIST EN 15605:2010

CEN/TS 15605, Copper and copper alloys — Inductively coupled plasma optical emission spectrometry In comparison with the first edition of CEN/TS 15605:2007, the following significant technical changes were made:  Revision from a Technical Specification to a European Standard;  Method G (specifying the analysis of Copper-tin-lead alloys) is edited under an informative basis (see An-nex B), taking into account the mediocrity of the precision criteria related to this method;  Precision criteria for methods A and E were added;  Precision criteria for methods B, C, D and F were improved and up-dated. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. SIST EN 15605:2010

% min. max. Sn 0,02 0,60 Pb 0,02 0,60 Zn 0,02 0,60 Fe 0,01 0,60 Ni 0,01 0,60 Mn 0,01 0,60 Al 0,02 0,60 P 0,01 0,40 Be 0,01 0,60 Co 0,01 0,60 Cd 0,01 0,60
Table 2 — Copper-zinc alloys Element Mass fraction
% min. max. Sn
0,05
2,00 Pb
0,03
4,00 Zn 10,00 42,00 Fe
0,01
5,00 Ni
0,02
4,00 Mn
0,01
6,00 P
0,01
0,40 Al
0,02
9,00 As
0,01
0,20
% min. max. Sn 3,00 16,00 Pb 0,01
9,00 Zn 0,03
6,00 Fe 0,01
1,00 Ni 0,05
7,00 Mn 0,01
0,40 P 0,01
0,60 Al 0,01
0,50 Sb 0,02
1,60 As 0,02
0,25
Table 4 — Copper-aluminium alloys Element Mass fraction
% min. max. Sn 0,02
0,50 Pb 0,03
0,50 Zn 0,03
1,00 Fe 0,05
7,00 Ni 0,10
8,00 Mn 0,01
5,00 Al 6,00 14,00 Cd 0,01
0,50 Mg 0,002
0,15
Table 5 — Copper-beryllium alloys Element Mass fraction
% min. max. Sn 0,02 0,20 Pb 0,01 0,20 Zn 0,03 0,20 Fe 0,03 0,30 Ni 0,04 2,50 Mn 0,006 0,15 Al 0,03 0,20 Be 0,08 4,00 Co 0,03 4,00 SIST EN 15605:2010

% min. max. Sn 0,10
0,50 Pb 0,03
0,50 Zn 0,04
2,00 Fe 0,10
4,00 Ni 7,00 35,00 Mn 0,02
3,00 Al 0,02
0,50 NOTE 1 The ranges specified for each method can be extended or adapted, for the determination of lower mass frac-tions. NOTE 2 Other elements may be included. However such elements and their mass fractions should be carefully checked, taking into account interference, sensitivity, resolution and linearity criteria for each instrument and each wave-length. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated refer-ences, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 1811-1, Copper and copper alloys — Selection and preparation of samples for chemical analysis — Part 1: Sampling of cast unwrought products ISO 1811-2, Copper and copper alloys — Selection and preparation of samples for chemical analysis — Part 2: Sampling of wrought products and castings 3 Principle Dissolution of a test portion with hydrochloric and nitric acids. After suitable dilution and addition of an internal reference element, nebulization of the solution into an inductively coupled plasma emission spectrometer and measurement of the intensity of the emitted light, including that of the internal reference element. 4 Reagents During the analysis, use only reagents of recognised analytical grade and only distilled water or water of equivalent purity. The same reagents should be used for the preparation of calibration solutions and of sample solutions. 4.1 Hydrochloric acid, HCl (ρ = 1,19 g/ml) SIST EN 15605:2010
...