EN 17332:2023
(Main)Construction products: Assessment of release of dangerous substances - Analysis of organic substances in eluates
Construction products: Assessment of release of dangerous substances - Analysis of organic substances in eluates
This document specifies methods for the determination of specific organic substances in aqueous eluates from leaching of construction products.
The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP, phenols and phthalates.
NOTE 1 Methods still under development or available at national level only are listed in Annex B (informative) for certain amines, AOX, and biocidal and plant protection products.
NOTE 2 Methods that have not been validated for aqueous eluates from leaching of construction products, because no suitable material was available at the time of the robustness validation, only are listed in Annex B (informative). This applies to organotin compounds.
The methods in this document come from different fields, mainly the analysis of water, and are applicable for the eluates from construction products. They are validated for eluates of the product types listed in Annex A (informative).
NOTE 3 Construction products include, e.g. mineral-based products (S), bituminous products (B), wood-based products (W), plastic and rubbers (P), sealants and adhesives (A), paints and coatings (C) and metals (M) (see also CEN/TR 16045). This document includes analytical methods for all matrices except metals.
The selection of the method to be applied is based on the product matrix and the required sensitivity.
Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von organischen Stoffen in Eluaten
Dieses Dokument legt Verfahren zur Bestimmung spezifischer organischer Stoffe in wässrigen Eluaten fest, die durch die Auslaugung von Bauprodukten gewonnen wurden.
Die folgenden Parameter sind abgedeckt: pH, elektrische Leitfähigkeit, Biozide, Bisphenol A, BTEX, Dioxine und Furane, DOC, Epichlorhydrin, Mineralöl, Nonylphenole, PAK, PBDE, PCB, dioxinähnliche PCB, PCP, Phenole und Phthalate.
ANMERKUNG 1 Noch in der Entwicklung befindliche Verfahren oder solche, die ausschließlich auf nationaler Ebene vorhanden sind, sind für bestimmte Amine, AOX und Biozid- und Pflanzenschutzmittel in Anhang B (informativ) aufgeführt.
ANMERKUNG 2 Verfahren, die für durch Auslaugung aus Bauprodukten gewonnene wässrige Eluate nicht validiert wurden, da zum Zeitpunkt der Robustheitsvalidierung kein geeignetes Material verfügbar war, sind lediglich in Anhang B (informativ) aufgeführt. Dies betrifft Organozinnverbindungen.
Die Verfahren in diesem Dokument stammen aus unterschiedlichen Bereichen, hauptsächlich der Wasseranalyse, und sind für Eluate aus Bauprodukten anwendbar. Sie sind für die Eluate der in Anhang A (informativ) aufgeführten Produkttypen validiert.
ANMERKUNG 3 Bauprodukte umfassen z. B. mineralische Produkte (S), bituminöse Produkte (B), Holzprodukte (W), Kunststoffe und Gummi (P), Dichtstoffe und Kleber (A), Farben und Beschichtungen (C) und Metalle (M) (siehe auch CEN/TR 16045). Dieses Dokument enthält analytische Verfahren für alle Matrizes mit Ausnahme von Metallen.
Die Auswahl des anzuwendenden Verfahrens basiert auf der Produktmatrix und der erforderlichen Empfindlichkeit.
Produits de construction : Évaluation de l'émission de substances dangereuses - Analyse des substances organiques dans les éluats
Le présent document spécifie les méthodes pour la détermination de substances organiques spécifiques dans les éluats aqueux provenant de la lixiviation de produits de construction.
Les paramètres suivants sont couverts : pH, conductivité électrique, biocides, bisphénol A, BTEX, dioxines et furanes, COD, épichlorhydrine, huile minérale, nonylphénols, HAP, PBDE, PCB, PCB de type dioxine, PCP, phénols et phtalates.
NOTE 1 Les méthodes encore en cours d'élaboration ou disponibles uniquement au niveau national sont énumérées à l'Annexe B (informative) pour certaines amines, les AOX, les biocides et les produits phytosanitaires.
NOTE 2 Les méthodes qui n'ont pas été validées pour les éluats aqueux provenant de la lixiviation de produits de construction, parce qu'aucun matériau approprié n'était disponible au moment de la validation de la robustesse, sont uniquement énumérées à l'Annexe B (informative). Cela s'applique aux composés organostanniques.
Les méthodes présentées dans le présent document proviennent de différents domaines, principalement l'analyse de l'eau, et sont applicables aux éluats des produits de construction. Elles sont validées pour les éluats des types de produits énumérés à l'Annexe A (informative).
NOTE 3 Les produits de construction comprennent par exemple les produits à base de minéraux (S) ; les produits bitumineux (B) ; les produits à base de bois (W) ; les plastiques et les caoutchoucs (P) ; les produits d'étanchéité et les adhésifs (A) ; les peintures et les revêtements (C) et les métaux (M) (voir également la CEN/TR 16045). Le présent document comprend des méthodes d'analyse pour toutes les matrices, à l'exception des métaux.
Le choix de la méthode à appliquer est fondé sur la matrice du produit et la sensibilité requise.
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih snovi v izlužkih
Ta dokument vsebuje obstoječe metode za določanje specifičnih organskih snovi v vodnih izlužkih pri izluževanju gradbenih proizvodov.
Zajema naslednje parametre: vrednost pH, električna prevodnost, bisfenol A, BTEX, dioksini in furani, DOC, epiklorohidrin, mineralno olje, nonilfenoli, PAH, PBDE, PCB, dioksinom podobni PCB, PCP, fenoli in ftalati.
Metode, navedene v tem dokumentu, prihajajo iz različnih področij, predvsem iz analize vode, in so primerne za izlužke iz gradbenih proizvodov. Potrjene so za izlužke vrst proizvodov, navedenih v dodatku A.
OPOMBA: Gradbeni proizvodi vključujejo na primer mineralne proizvode; bitumenske proizvode, lesne proizvode, polimerne proizvode in kovine. Ta dokument vsebuje analitične metode za vse matrice, razen kovin.
Izbira uporabljene metode temelji na matrici izdelka in zahtevani občutljivosti.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-april-2024
Nadomešča:
SIST-TS CEN/TS 17332:2019
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih
snovi v izlužkih
Construction products - Assessment of release of dangerous substances - Analysis of
organic substances in eluates
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
organischen Stoffen in Eluaten
Produits de construction - Évaluation de l'émission de substances dangereuses -
Analyse des substances organiques dans les éluats
Ta slovenski standard je istoveten z: EN 17332:2023
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17332
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2023
EUROPÄISCHE NORM
ICS 91.100.01 Supersedes CEN/TS 17332:2019
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of organic substances in
eluates
Produits de construction : Évaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von organischen Stoffen
organiques dans les éluats in Eluaten
This European Standard was approved by CEN on 14 August 2023.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17332:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Abbreviations . 8
5 Sample preparation . 8
6 Blank determination . 9
7 Interferences . 9
8 Selection of the suitable test method . 9
9 Expression of results .11
10 Test performance .11
11 Test report .12
Annex A (informative) Validation results for analysis of organic substances in eluates
from construction products .14
A.1 General.14
A.2 Precision data for eluates from construction products .14
Annex B (informative) Overview of alternative methods and of methods for biocidal and
plant protection products .20
Bibliography .22
European foreword
This document (EN 17332:2023) has been prepared by Technical Committee CEN/TC 351
“Construction products: Assessment of release of dangerous substances”, the secretariat of which is held
by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2024, and conflicting national standards shall be
withdrawn at the latest by May 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN/TS 17332:2019.
In comparison with the previous edition, the following technical modifications have been made:
— the addition of performance data and data from intercomparison validation;
— alignment of terms and definitions within the working groups of CEN/TC 351, i.e. through the
revised version of EN 16687.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the United
Kingdom.
Introduction
This document deals with the determination of organic substances in eluates which have been obtained
by leaching of construction products.
Following an extended evaluation of available methods for content and eluate analysis in construction
products (CEN/TR 16045) it was concluded that eluate analysis methods are very similar to analytical
methods used to determine organic substances in water. The present document is similar in structure
to EN 16192.
This document is part of a modular horizontal approach and belongs to the analytical step. An overview
of all modules which belong to a chain of measurement and the manner how modules are selected is
given in CEN/TR 16220.
In the growing amount of product and sector-oriented test methods it was recognized that many steps
in test procedures are or could be used in test procedures for many products, materials and sectors. It
was supposed that, by careful determination of these steps and selection of specific questions within
these steps, elements of the test procedure could be described in a way that can be used for all materials
and products or for all materials and products with certain specifications.
In this context a horizontal modular approach is adopted in CEN/TC 351. “Horizontal” means that the
methods can be used for a wide range of materials and products with certain properties. “Modular”
means that a test standard developed in this approach concerns a specific step in assessing a property
and not the whole “chain of measurement” (from sampling to analyses). A beneficial feature of this
approach is that “modules” can be replaced by better ones without jeopardizing the standard “chain”.
The use of modular horizontal standards implies the drawing of test schemes as well. Before executing
a test on a certain material or product to determine certain characteristics, it is recommended to draw
up a protocol in which the adequate modules are selected and together form the basis for the entire test
procedure.
This module relates to EN 16637-1, EN 16637-2, and EN 16637-3.
1 Scope
This document specifies methods for the determination of specific organic substances in aqueous
eluates from leaching of construction products.
The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins
and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP,
phenols and phthalates.
NOTE 1 Methods still under development or available at national level only are listed in Annex B (informative)
for certain amines, AOX, and biocidal and plant protection products.
NOTE 2 Methods that have not been validated for aqueous eluates from leaching of construction products,
because no suitable material was available at the time of the robustness validation, only are listed in Annex B
(informative). This applies to organotin compounds.
The methods in this document come from different fields, mainly the analysis of water, and are
applicable for the eluates from construction products. They are validated for eluates of the product types
listed in Annex A (informative).
NOTE 3 Construction products include, e.g. mineral-based products (S), bituminous products (B), wood-based
products (W), plastic and rubbers (P), sealants and adhesives (A), paints and coatings (C) and metals (M) (see also
CEN/TR 16045). This document includes analytical methods for all matrices except metals.
The selection of the method to be applied is based on the product matrix and the required sensitivity.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1484, Water analysis — Guidelines for the determination of total organic carbon (TOC) and dissolved
organic carbon (DOC)
EN 12673, Water quality — Gas chromatographic determination of some selected chlorophenols in water
EN 14207, Water quality — Determination of epichlorohydrin
EN 16687:2023, Construction products: Assessment of release of dangerous substances — Terminology
EN 16694, Water quality — Determination of selected polybrominated diphenyl ether (PBDE) in whole
water samples — Method using solid phase extraction (SPE) with SPE-disks combined with gas
chromatography — Mass spectrometry (GC-MS)
EN 17845, Construction products: Assessment of release of dangerous substances — Determination of
biocide residues using liquid chromatography with mass spectrometric detection (LC-MS/MS)
EN 27888, Water quality — Determination of electrical conductivity (ISO 7888)
EN ISO 5667-3, Water quality — Sampling — Part 3: Preservation and handling of water samples (ISO
5667-3)
EN ISO 9377-2:2000, Water quality — Determination of hydrocarbon oil index — Part 2: Method using
solvent extraction and gas chromatography (ISO 9377-2:2000)
EN ISO 10523, Water quality — Determination of pH (ISO 10523)
EN ISO 14402, Water quality — Determination of phenol index by flow analysis (FIA and CFA)(ISO 14402)
EN ISO 15680, Water quality — Gas-chromatographic determination of a number of monocyclic aromatic
hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and thermal
desorption (ISO 15680)
EN ISO 18856:2005, Water quality — Determination of selected phthalates using gas
chromatography/mass spectrometry (ISO 18856:2004)
EN ISO 18857-2, Water quality — Determination of selected alkylphenols — Part 2: Gas chromatographic-
mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered
samples following solid-phase extraction and derivatisation (ISO 18857-2)
ISO 17858, Water quality — Determination of dioxin-like polychlorinated biphenyls — Method using gas
chromatography/mass spectrometry
ISO 18073, Water quality — Determination of tetra- to octa-chlorinated dioxins and furans — Method
using isotope dilution HRGC/HRMS
ISO 20595, Water quality — Determination of selected highly volatile organic compounds in water —
Method using gas chromatography and mass spectrometry by static headspace technique (HS-GC-MS)
ISO 28540, Water quality — Determination of 16 polycyclic aromatic hydrocarbons (PAH) in water —
Method using gas chromatography with mass spectrometric detection (GC-MS)
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 16687:2023 and the following
apply.
ISO and IEC maintain terminology databases for use in stand
...
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