EN 13656:2002

Characterization of waste - Microwave assisted digestion with hydrofluoric (HF), nitric (HNO3) and hydrochloric (HCl) acid mixture for subsequent determination of elements

This European Standard specifies methods of microwave assisted digestion with hydrofluoric (HF), nitric (HNO3)and hydrochloric (HCL) acid mixture. Solutions produced by the methods are suitable for analysis e.g.by atomic absorption spectometry (FLAAS,HGAAS,CVAAS,GFAAS), inductively coupled plasma emission spectometry(ICP-OES) and inductive coupled plasma mass spectometry(ICP-MS). The method is applicable to the microwave assisted acid digestion of waste for example for the following elements:Al,Sb,As,B,Ba,Be,Cd,Cr,Cu,Fe,Pb,Mg,Mn,Hg,Mo, Ni,P,K,Se,Ag,S,Na,Sr,Te,Ti,Tl,V,Zn.

Charakterisierung von Abfällen - Aufschluss mittels Mikrowellengerät mit einem Gemisch aus Fluorwasserstoffsäure (HF), Salpetersäure (HNO3) und Salzsäure (HCI) für die anschließende Bestimmung der Elemente im Abfall

Diese Norm legt Verfahren für den Aufschluß mittels Mikrowellengerät mit einem Gemisch aus Fluorwasserstoffsäure, Salpetersäure und Salzsäure fest. Die nach den Verfahren hergestellten Lösungen sind z.B. für Analysen mittels Flammen-Atomabsorptionsspektrometrie (FAAS), Hydrid-Atomabsorptions- spektrometrie (HGAAS), Kaltdampf-Atomabsorptionsspektrometrie (CVAAS), Graphitrohrofen-Atomabsorptionsspektrometrie (GFAAS), optischer Emissions- spektrometrie mit induktiv gekoppeltem Plasma (ICP-OES) und induktiv gekoppelterPlasma-Emission-Massenspektrometrie (ICP-MS) geeignet.

Caractérisation des déchets - Digestion assistée par micro-ondes avec un mélange d'acides fluorhydrique (HF), nitrique (HNO3) et chlorhydrique (HCI) pour la détermination ultérieure d'éléments contenus dans les déchets

La présente Norme européenne décrit des méthodes de digestion assistée par micro-ondes avec un mélange d'acides fluorhydrique (HF), nitrique (HNO3) et chlorhydrique (HCl). Les solutions produites par ces méthodes conviennent à l'analyse, par exemple par spectrométrie d'absorption atomique (FLAAS, HGAAS, CVAAS, GFAAS), spectrométrie d'émission par un plasma à couplage inductif (ICP-OES) et spectrométrie de masse par un plasma à couplage inductif (ICP-MS).
La méthode est applicable pour la digestion acide assistée par micro-ondes des déchets, par exemple pour les éléments suivants : Al, Sb, As, B, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Pb, Mg, Mn, Hg, Mo, Ni, P, K, Se, Ag, S, Na, Sr, Sn, Te, Ti, Tl, V, Zn.

Karakterizacija odpadkov - Mikrovalovni razklop z zmesjo fluorovodikove (HF), klorovodikove (HCl) in dušikove(V) kisline (HNO3) za določanje elementov

General Information

• Status: Withdrawn
• Publication Date: 15-Oct-2002
• Withdrawal Date: 03-Nov-2020
• ICS: 13.030.40 - Installations and equipment for waste disposal and treatment
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 3 - Inorganic analysis
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 04-Nov-2020
• Directive: 99/31/EC - Landfill of waste
• Mandate: M/326 - Standardization mandate to CEN for the development of standardized methods for the characterization of waste
• Ref Project: SIST EN 13656:2004 - Characterization of waste - Microwave assisted digestion with hydrofluoric (HF), nitric (HNO3) and hydrochloric (HCl) acid mixture for subsequent determination of elements

Relations

• Replaced By: EN 13656:2020 - Soil, treated biowaste, sludge and waste - Digestion with a hydrochloric (HCl), nitric (HNO3) and tetrafluoroboric (HBF4) or hydrofluoric (HF) acid mixture for subsequent determination of elements
• Effective Date: 11-Nov-2020

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN 13656:2004
01-januar-2004
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NORURYRGLNRYH+&OLQGXãLNRYH9NLVOLQH+12]DGRORþDQMHHOHPHQWRY
Characterization of waste - Microwave assisted digestion with hydrofluoric (HF), nitric
(HNO3) and hydrochloric (HCl) acid mixture for subsequent determination of elements
Charakterisierung von Abfällen - Aufschluss mittels Mikrowellengerät mit einem Gemisch
aus Fluorwasserstoffsäure (HF), Salpetersäure (HNO3) und Salzsäure (HCI) für die
anschließende Bestimmung der Elemente im Abfall
Caractérisation des déchets - Digestion assistée par micro-ondes avec un mélange
d'acides fluorhydrique (HF), nitrique (HNO3) et chlorhydrique (HCI) pour la détermination
ultérieure d'éléments contenus dans les déchets
Ta slovenski standard je istoveten z: EN 13656:2002
ICS:
13.030.40 Naprave in oprema za Installations and equipment
odstranjevanje in obdelavo for waste disposal and
odpadkov treatment
SIST EN 13656:2004 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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EUROPEAN STANDARD
EN 13656
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2002
ICS 13.030.40
English version
Characterization of waste - Microwave assisted digestion with
hydrofluoric (HF), nitric (HNO ) and hydrochloric (HCl) acid
3
mixture for subsequent determination of elements
Caractérisation des déchets - Digestion assistée par micro- Charakterisierung von Abfällen - Aufschluss mittels
ondes avec un mélange d'acides fluorhydrique (HF), Mikrowellengerät mit einem Gemisch aus
nitrique (HNO ) et chlorhydrique (HCI) pour la Fluorwasserstoffsäure (HF), Salpetersäure (HNO ) und
3 3
détermination ultérieure d'éléments contenus dans les Salzsäure (HCI) für die anschließende Bestimmung der
déchets Elemente im Abfall
This European Standard was approved by CEN on 19 August 2002.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,
Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2002 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 13656:2002 E
worldwide for CEN national Members.

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EN 13656:2002 (E)
Contents
page
Foreword . 3
1 Scope. 5
2 Normative references . 5
3 Terms and definitions. 5
4 Safety remarks . 6
5 Sample. 6
5.1 Sample pre-treatment. 6
5.2 Mass of test portion . 7
6 Equipment. 7
6.1 Closed vessel system . 7
6.1.1 Microwave unit.
...