Cold reduced tinmill products - Electrolytic tinplate and electrolytic chromium/chromium oxide coated steel

This document specifies requirements for tinmill products in the form of sheets or coils. Tinmill products consist of single and double reduced low carbon mild steel electrolytically coated with either tin (tinplate) or chromium/chromium oxide (ECCS) or (ECCS-RC) (see 3.3).
Single reduced tinmill products are specified in nominal thicknesses that are multiples of 0,005 mm from 0,16 mm up to and including 0,49 mm. Double reduced tinmill products are specified in nominal thicknesses that are multiples of 0,005 mm from 0,12 mm up to and including 0,29 mm.
NOTE 1   Other thicknesses can be ordered upon agreement.
This document applies to coils and sheets cut from coils in nominal minimum widths of 600 mm.
NOTE 2   Standard width coils for specific uses, e.g. tabstock, can be slit into narrow strip for supply in coil form.

Kaltgewalzte Verpackungsblecherzeugnisse - Elektrolytisch verzinnter und spezialverchromter Stahl

Dieses Dokument legt die Anforderungen an Verpackungsblecherzeugnisse in Form von Tafeln oder von Coils fest. Verpackungsblecherzeugnisse sind einfach kaltgewalzte oder doppeltreduzierte weiche Stähle, die entweder elektrolytisch verzinnt (Weißblech) oder elektrolytisch spezialverchromt (ECCS) oder (ECCS-RC) (siehe 3.3).
Einfach kaltgewalzte Verpackungsblecherzeugnisse werden in Nenndicken von 0,16 mm bis 0,49 mm in Stufen von 0,005 mm geliefert. Doppeltreduzierte Verpackungsblecherzeugnisse werden in Nenndicken von 0,12 mm bis 0,29 mm in Stufen von 0,005 mm geliefert.
ANMERKUNG 1   Auf Anfrage können auch andere Dicken bestellt werden.
Dieses Dokument gilt für Band in Rollen und für aus Band geschnittene Tafeln in Nennbreiten von mindestens 600 mm.
ANMERKUNG 2   Für besondere Anwendungen, z. B. "Laschenband", darf das Band auch als durch Längsteilen hergestelltes schmaleres Band in Rollen geliefert werden.

Aciers pour emballage laminés à froid - Fer blanc électrolytique et acier revêtu de chrome/d'oxyde de chrome électrolytique

Le présent document spécifie les exigences relatives aux aciers pour emballage sous la forme de feuilles ou de bobines. Les aciers pour emballage sont constitués d’acier doux à faible teneur en carbone à simple et double laminage recouvert par électrolyse d’étain (fer blanc) ou de chrome ou d’oxyde de chrome (ECCS ou ECCS-RC) (voir 3.3).
Les aciers pour emballage à simple laminage sont spécifiés dans des épaisseurs nominales qui sont des multiples de 0,005 mm à partir de 0,16 mm jusqu’à 0,49 mm inclus. Les aciers pour emballage à double laminage sont spécifiés dans des épaisseurs nominales qui sont des multiples de 0,005 mm à partir de 0,12 mm jusqu’à 0,29 mm inclus.
NOTE 1   Après accord, il est possible de commander d’autres épaisseurs.
Le présent document s’applique aux bobines et aux feuilles découpées dans des bobines dont les largeurs nominales sont égales à 600 mm au minimum.
NOTE 2   Les bobines de largeurs normalisées pour usages spéciaux, tels que feuillard, peuvent être découpées en bandes refendues à longueur pour conditionnement en bobines.

Hladno valjani jekleni izdelki za embalažo - Elektrolizno pokositreni in pokromani izdelki

General Information

Status
Not Published
Current Stage
5060 - Closure of Vote - Formal Approval
Due Date
25-Nov-2021
Completion Date
25-Nov-2021

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SLOVENSKI STANDARD
oSIST prEN 10202:2021
01-april-2021

Hladno valjani jekleni izdelki za embalažo - Elektrolizno pokositreni in pokromani

izdelki

Cold reduced tinmill products - Electrolytic tinplate and electrolytic chromium/chromium

oxide coated steel
Kaltgewalzte Verpackungsblecherzeugnisse - Elektrolytisch verzinnter und
spezialverchromter Stahl
Aciers pour emballage laminés à froid - Fer blanc électrolytique et fer chromé
électrolytique
Ta slovenski standard je istoveten z: prEN 10202
ICS:
77.140.50 Ploščati jekleni izdelki in Flat steel products and semi-
polizdelki products
oSIST prEN 10202:2021 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN 10202:2021
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oSIST prEN 10202:2021
DRAFT
EUROPEAN STANDARD
prEN 10202
NORME EUROPÉENNE
EUROPÄISCHE NORM
February 2021
ICS 77.140.50 Will supersede EN 10202:2001
English Version
Cold reduced tinmill products - Electrolytic tinplate and
electrolytic chromium/chromium oxide coated steel

Aciers pour emballage laminés à froid - Fer blanc Kaltgewalzte Verpackungsblecherzeugnisse -

électrolytique et fer chromé électrolytique Elektrolytisch verzinnter und spezialverchromter Stahl

This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee

CEN/TC 459/SC 9.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations

which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other

language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC

Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are

aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without

notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 10202:2021 E

worldwide for CEN national Members.
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oSIST prEN 10202:2021
prEN 10202:2021 (E)
Contents Page

European foreword ............................................................................................................................................ 6

1 Scope .......................................................................................................................................................... 7

2 Normative references .......................................................................................................................... 7

3 Terms and definitions ......................................................................................................................... 7

4 Classification and designation ....................................................................................................... 11

4.1 Classification......................................................................................................................................... 11

4.2 Designation ........................................................................................................................................... 11

5 Information to be supplied by the purchaser ........................................................................... 11

5.1 Mandatory information .................................................................................................................... 11

5.2 Options .................................................................................................................................................... 12

5.3 Ordering examples ............................................................................................................................. 12

6 Manufacturing features .................................................................................................................... 12

6.1 Steelmaking process .......................................................................................................................... 12

6.2 Annealing ............................................................................................................................................... 13

6.3 Finish ....................................................................................................................................................... 13

6.4 Passivation ............................................................................................................................................ 14

6.4.1 General.................................................................................................................................................... 14

6.4.2 Titanium / Zirconium passivation ................................................................................................ 14

6.4.3 Chromium passivation ...................................................................................................................... 14

6.5 Oiling ....................................................................................................................................................... 15

6.6 Imperfections ....................................................................................................................................... 15

6.6.1 Coils .......................................................................................................................................................... 15

6.6.2 Sheets ...................................................................................................................................................... 15

7 Coatings .................................................................................................................................................. 16

7.1 Electrolytic tinplate ............................................................................................................................ 16

7.1.1 Properties .............................................................................................................................................. 16

7.1.2 Test method .......................................................................................................................................... 17

7.2 Electrolytic chromium coated steel .............................................................................................. 17

7.2.1 General.................................................................................................................................................... 17

7.2.2 Test method .......................................................................................................................................... 18

8 Mechanical properties ...................................................................................................................... 18

8.1 General.................................................................................................................................................... 18

8.2 Tensile test measurement ............................................................................................................... 19

8.2.1 General.................................................................................................................................................... 19

8.2.2 Location of test pieces ....................................................................................................................... 19

8.2.3 Aging ........................................................................................................................................................ 19

8.2.4 Thickness ............................................................................................................................................... 19

8.2.5 Testing conditions .............................................................................................................................. 19

8.2.6 Strength characteristics ................................................................................................................... 19

8.3 Mechanical properties of tinmill products ................................................................................ 23

9 Tolerances on dimensions and shape ......................................................................................... 25

9.1 General.................................................................................................................................................... 25

9.2 Thickness and feather edge ............................................................................................................ 25

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prEN 10202:2021 (E)

9.2.1 Thickness ............................................................................................................................................... 25

9.2.2 Test method for thickness ............................................................................................................... 25

9.2.3 Feather edge ......................................................................................................................................... 25

9.2.4 Test method for feather edge ......................................................................................................... 25

9.3 Linear dimensions .............................................................................................................................. 26

9.3.1 Width and length ................................................................................................................................ 26

9.3.2 Out-of-squareness of sheets............................................................................................................ 26

9.3.3 Short pitch camber (lateral weave) of coils .............................................................................. 27

9.3.4 Test method for short pitch camber ............................................................................................ 27

9.4 Shape ....................................................................................................................................................... 27

9.4.1 Edge wave .............................................................................................................................................. 27

9.4.2 Test method for edge wave ............................................................................................................. 28

9.4.3 Bow .......................................................................................................................................................... 28

9.4.4 Test method for bow.......................................................................................................................... 28

9.4.5 Centre fullness ..................................................................................................................................... 29

9.4.6 Test method for centre fullness..................................................................................................... 29

9.4.7 Burr .......................................................................................................................................................... 30

10 Welds within a coil ............................................................................................................................. 31

10.1 General ................................................................................................................................................... 31

10.2 Number of welds ................................................................................................................................. 31

10.3 Location of welds ................................................................................................................................ 31

10.4 Dimensions of welds .......................................................................................................................... 31

10.4.1 Thickness ............................................................................................................................................... 31

10.4.2 Overlap ................................................................................................................................................... 31

11 Marking of differentially coated cold reduced tinplate ........................................................ 31

12 Selection of samples .......................................................................................................................... 32

12.1 For quality control.............................................................................................................................. 32

12.2 In case of dispute ................................................................................................................................ 33

13 Retests .................................................................................................................................................... 33

14 Dispatch and packaging ................................................................................................................... 33

14.1 Coils ......................................................................................................................................................... 33

14.1.1 Coil dispatch ......................................................................................................................................... 33

14.1.2 Coil winding .......................................................................................................................................... 33

14.2 Sheets ...................................................................................................................................................... 34

Annex A (informative) De tinning .............................................................................................................. 35

A.1 Principle ................................................................................................................................................. 35

A.2 Clarke’s solution ................................................................................................................................. 35

A.3 Procedure .............................................................................................................................................. 35

Annex B (normative) Determination of chromium using the diphenylcarbazide method ... 36

B.1 General ................................................................................................................................................... 36

B.2 Principle ................................................................................................................................................. 36

B.3 Reagent ................................................................................................................................................... 36

B.4 Apparatus .............................................................................................................................................. 36

B.5 Procedure .............................................................................................................................................. 36

B.6 Calibration............................................................................................................................................. 37

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prEN 10202:2021 (E)

Annex C (normative) Determination of titanium content using the Inductively Coupled

Plasma (ICP) method ......................................................................................................................... 38

C.1 General.................................................................................................................................................... 38

C.2 Principle ................................................................................................................................................. 38

C.3 Reagent ................................................................................................................................................... 38

C.4 Apparatus .............................................................................................................................................. 39

C.5 Procedure .............................................................................................................................................. 39

Annex D (normative) Determination of tin oxides by galvanostatic potentiometry ............... 40

D.1 General.................................................................................................................................................... 40

D.2 Principle ................................................................................................................................................. 40

D.3 Reagents ................................................................................................................................................. 40

D.4 Apparatus .............................................................................................................................................. 40

D.5 Procedure .............................................................................................................................................. 40

Annex E (normative) Electromechanical method for determining tin coating mass .............. 42

E.1 Principle ................................................................................................................................................. 42

E.2 Reagents ................................................................................................................................................. 42

E.3 Apparatus .............................................................................................................................................. 42

E.3.1 Cell and electrodes ............................................................................................................................. 42

E.3.2 Power supply ........................................................................................................................................ 42

E.3.3 Voltmeter ............................................................................................................................................... 42

E.4 Procedure .............................................................................................................................................. 42

E.5 Calibration of the measuring system ........................................................................................... 42

E.6 Calculation ............................................................................................................................................. 43

Annex F (normative) Methods for determination of metallic chromium and chromium in the

oxide on the surface of electrolytic chromium coated steel (ECCS or ECCS-RC) .......... 46

F.1 Determination of chromium in the oxide .................................................................................. 46

F.1.1 Principle ................................................................................................................................................. 46

F.1.2 Reagents ................................................................................................................................................. 46

F.1.3 Apparatus .............................................................................................................................................. 46

F.1.4 Preparation of the chromium calibration curve ..................................................................... 47

F.1.5 Procedure .............................................................................................................................................. 47

F.1.6 Calculation ............................................................................................................................................. 47

F.2 Determination of metallic chromium .......................................................................................... 47

F.2.1 Principle ................................................................................................................................................. 47

F.2.2 Reagents ................................................................................................................................................. 48

F.2.3 Apparatus .............................................................................................................................................. 48

F.2.4 Preparation of the chromium calibration curve ..................................................................... 48

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prEN 10202:2021 (E)

F.2.5 Procedure .............................................................................................................................................. 49

F.2.5.1 General ................................................................................................................................................... 49

F.2.5.2 Removal of chromium oxide layer ............................................................................................... 49

F.2.5.3 Removal and determination of metallic chromium ............................................................... 49

F.2.6 Calculation ............................................................................................................................................ 49

Annex G (informative) The Rockwell Hardness test for routine determination of proof

strength for double reduced materials ....................................................................................... 53

G.1 General ................................................................................................................................................... 53

G.2 Test pieces ............................................................................................................................................. 53

G.3 Test method .......................................................................................................................................... 53

G.4 Hardness for tinmill products ........................................................................................................ 55

Annex H (informative) The springback test for routine determination of proof strength for

double reduced material.................................................................................................................. 56

H.1 General ................................................................................................................................................... 56

H.2 Principle ................................................................................................................................................. 56

H.3 Test pieces ............................................................................................................................................. 56

H.4 Test method .......................................................................................................................................... 56

Annex I (normative) Tensile testing conditions in case of dispute ............................................... 57

I.1 General ................................................................................................................................................... 57

I.2 Tensile test piece dimensions ........................................................................................................ 57

I.3 Elongation measurement................................................................................................................. 57

I.4 Testing velocity ................................................................................................................................... 57

I.4.1 General ................................................................................................................................................... 57

I.4.2 Material displaying no discontinuous yielding ........................................................................ 57

I.4.3 Discontinuous yielding material ................................................................................................... 58

Annex J (informative) Indicative tensile strength of tinmill products ......................................... 59

Annex K (informative) Alternative marking system for electrolytic tinplate — differentially

coated ...................................................................................................................................................... 60

Bibliography ....................................................................................................................................................... 62

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oSIST prEN 10202:2021
prEN 10202:2021 (E)
European foreword

This document (prEN 10202:2021) has been prepared by Technical Committee CEN/TC 459/SC 9

“Coated and uncoated flat products to be used for cold forming”, the secretariat of which is held by

AFNOR.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 10202:2001.

In comparison with the previous edition, the following technical modifications have been made:

— normative references have been updated;

— revision of the definition of electrolytic chromium coated steel with the addition of the symbol ECCS-

RC which allows the use of a trivalent process;

— rewording of Clause 5 with the split into mandatory information (5.1) and options (5.2);

— modification of Clause 6 with the rewording of 6.1 and the addition of 6.2 and 6.3 about annealing

and finish respectively;
— Table 1 has been updated;
— major modifications of 6.4 about passivation;

— addition of a new subclause 6.6 on imperfections that includes 6.6.1 and 6.6.2 for coils and sheets

respectively;

— major modifications of Clause 7 about coatings including changes of Table 2, Table 3 and Table 4;

— major modifications of Clause 8 about mechanical properties with the addition of stress-strain curves

for batch and continuous annealed material, curve showing the plateau height for continuous

annealed material and stress-strain curves for the determination of the yield strength of some

continuous annealed grades;

— removal of the tensile strength values from Table 5 and transfer into informative Annex J;

— modification of 9.4.6 about test method for centre fullness;
— modifications of the ordering of Annexes;
— new Annex I about tensile testing conditions in case of dispute;
— deletion of the Annex giving the previous designations.
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oSIST prEN 10202:2021
prEN 10202:2021 (E)
1 Scope

This document specifies requirements for tinmill products in the form of sheets or coils. Tinmill products

consist of single and double reduced low carbon mild steel electrolytically coated with either tin (tinplate)

or chromium/chromium oxide (ECCS) or (ECCS-RC) (see 3.3).

Single reduced tinmill products are specified in nominal thicknesses that are multiples of 0,005 mm from

0,16 mm up to and including 0,49 mm. Double reduced tinmill products are specified in nominal

thicknesses that are multiples of 0,005 mm from 0,12 mm up to and including 0,29 mm.

NOTE 1 Other thicknesses can be ordered upon agreement.

This document applies to coils and sheets cut from coils in nominal minimum widths of 600 mm.

NOTE 2 Standard width coils for specific uses, e.g. tabstock, can be slit into narrow strip for supply in coil form.

2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated refe
...

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