ISO/TR 20118:2019

Plastics — Guidance on fire characteristics and fire performance of PVC materials used in building applications

This document provides information on the fire characteristics and performance in fire tests of PVC materials and products for use in building applications. It illustrates a number of suitable applications incorporating primarily PVC materials, including unplasticized PVC (PVC-U), plasticized (or flexible) PVC (PVC-P) and chlorinated PVC (PVC-C) based products. Except where otherwise stated, there is no restriction with reference to the content of PVC (in terms of quantity and composition) in the products mentioned in this document. This document draws attention to the limits of applicability or the unsuitability of some standard fire test methods for certain applications of PVC based products in buildings. This document applies to products during their use phase in the building and does not apply to the manufacturing phase of plastic products. It neither applies to general safety measures applicable to the installation phase nor to the dismantling or the demolition phase of the building.

Plastiques — Lignes directrices relatives aux caractéristiques et aux performances au feu des matériaux en PVC utilisés dans les applications de construction

General Information

• Status: Published
• Publication Date: 31-Mar-2019
• ICS: 13.220.50 - Fire-resistance of building materials and elements
• ICS: 83.080.01 - Plastics in general
• Technical Committee: ISO/TC 61/SC 4 - Burning behaviour
• Drafting Committee: ISO/TC 61/SC 4 - Burning behaviour
• Current Stage: 6060 - International Standard published
• Due Date: 16-Sep-2018
• Completion Date: 01-Apr-2019

Standards Content (Sample)

TECHNICAL ISO/TR
REPORT 20118
First edition
2019-04
Plastics — Guidance on fire
characteristics and fire performance
of PVC materials used in building
applications
Plastiques — Lignes directrices relatives aux caractéristiques et
aux performances au feu des matériaux en PVC utilisés dans les
applications de construction
Reference number
ISO/TR 20118:2019(E)
©
ISO 2019

---------------------- Page: 1 ----------------------
ISO/TR 20118:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: [phone]
Fax: [phone]
Email: [e-mail]
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

---------------------- Page: 2 ----------------------
ISO/TR 20118:2019(E)

Contents  Page
Foreword .v
Introduction .vi
1  Scope . 1
2  Normative references . 1
3  Terms and definitions . 1
4  PVC building materials and products . 3
4.1 Definition and description . 3
4.1.1 General. 3
4.1.2 PVC-U based products . 4
4.1.3 PVC-P based products . 4
4.1.4 PVC-C based products . 5
4.1.5 Flame retardants . . 5
4.2 Product standards . 6
5  Fire safety strategy . 8
5.1 Fire safety objectives . 8
5.1.1 General. 8
5.1.2 Safety of life . 9
5.1.3 Conservation of property . 9
5.1.4 Continuity of business or service operations .10
5.1.5 Protection of the environment .10
5.1.6 Preservation of heritage .11
5.2 Fire scenarios .11
6  Fire test methods — Description and relevance .13
6.1 General .13
6.1.1 Reaction to fire tests applicable to plastics construction products .13
6.1.2 Intermediate scale plastics reaction to fire tests .14
6.1.3 Fire stage and fire tests .14
6.1.4 Assessment of the fire threat to people .14
6.2 Relevance of results and studies comparisons .15
7  Material fire characteristics relevant for PVC construction products .16
7.1 Combustibility .16
7.2 Ignitability .18
7.2.1 Ignition temperature .18
7.2.2 Ignitability measured by the cone calorimeter test .19
7.3 Oxygen index.20
7.4 Heat release and heat release rate .21
7.4.1 General.21
7.4.2 Heat release data .22
7.5 Flame spread .24
7.5.1 General.24
7.5.2 Flame spread by flame propagation.26
7.5.3 Flame spread by flaming droplets .26
7.6 Smoke generation .27
7.6.1 Smoke obscuration.27
7.6.2 Smoke toxicity .28
7.6.3 Smoke corrosivity .31
7.6.4 HCl decay .32
7.7 Char formation and intumescence .33
Annex A (informative) Example of reaction to fire performance — PVC-U pipe .34
Annex B (informative) Example case history — Plastimet accident .35
© ISO 2019 – All rights reserved iii

---------------------- Page: 3 ----------------------
ISO/TR 20118:2019(E)

Bibliography .36
iv © ISO 2019 – All rights reserved

---------------------- Page: 4 ----------------------
ISO/TR 20118:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 4, Burning
behaviour.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
© ISO 2019 – All rights reserved v

---------------------- Page: 5 ----------------------
ISO/TR 20118:2019(E)

Introduction
Fire safety is an essential consideration in building design regardless of the type and nature of products
used. Effective measures should be taken to prevent or reduce the likelihood of fires that may result in
casualties, injuries or property damage.
National codes and regulations are the basis of such fire safety measures. Technical details are given
in standards and related documents, referred to as specific documents or incorporated in the said
codes or regulations. Such details are particularly important when performance-based behaviour
[77]
is concerned. A specific case is the European Construction Products Regulation , which specifies
that products need to be tested and classified regarding their fire performance according to the EU
harmonized classification systems for reaction to fire and for resistance to fire.
The construction industry makes significant efforts to protect society from the dramatic consequences
of fires. As a result, 1 % to 8 % of total construction costs are spent on fire safety measures. These costs
are directly dependent on the type of building and can increase considerably for sensitive buildings like
schools and theatres. In the case of shopping centres, fire safety measures can amount to 10 % of total
building costs.
Plastic products are increasingly specified by architects and used by builders. They contribute to
greater energy efficiency, cost savings and to a more comfortable and safer environment. The role
of plastics in fire safety should be addressed despite the fact that they are considered as a major
combustible contributor only in less than 15 % of fires.
Plastic materials or products can be tailored to meet specific needs and to reduce their contribution
to the propagation of a fire. Some families of plastics, such as halogen containing polymers like PVC,
inherently have superior fire performance. The same performance can be achieved or even improved
with other plastics by:
— adding flame retardants;
— covering them with less combustible layers.
Each type of building has its own specific potential fire hazards and fire risks linked to the permanent
elements of the building (i.e. construction products and overall design) as well as its content including
furniture, papers, clothes, domestic and leisure articles. Fire hazard and fire risk are also linked to the
proper use and installation of construction products in the building structure. This is also valid for PVC
and for plastic materials in general, which, like all other construction materials, should be used in the
correct applications and under appropriate conditions.
NOTE Data from various market surveys show that only 10 % to 15 % of all plastics contained in a private
house are in construction products. 85 % to 90 % of plastics are brought into the building by the occupants in, for
example, furniture (including, for example, wooden furniture containing minor plastics elements), decorations,
household and media appliances, clothes, toys and packaging. This means that although PVC is a significant
component of many construction products, other combustible materials often comprise a more important
potential source of fuel, in particular in private houses.
A fire usually involves a combination of different combustible and non-combustible materials. Organic
materials (including all plastics, wood and other carbon containing materials) produce a mixture of
gaseous substances (making fire smoke always hazardous) in addition to a certain degree of heat
release.
As fire is a complex phenomenon, the type and quantity of materials involved are only two of the various
parameters influencing the development and consequences of a fire. The other factors that come into
play include building design, location, potential ignition sources and other fire scenario parameters.
Fire tests results relate only to the behaviour of test specimens under the particular conditions of the test.
They are not intended to be the sole criterion of assessing the potential fire hazard of the product in use.
This document provides information on the fire characteristics and fire performance of PVC based
materials and products used in building applications. It is to be considered as a documentary and
vi © ISO 2019 – All rights reserved

---------------------- Page: 6 ----------------------
ISO/TR 20118:2019(E)

technical reference document for any entity interested in fire safety in building and construction, when
products containing PVC are concerned, including at the design or pre-building phase.
The intended audience for this document includes but is not necessarily limited to:
— materials and products manufacturers;
— building designers, specifiers and architects;
— building owners and managers;
— fire fighters and investigators;
— public health authorities;
— fire testing laboratories.
© ISO 2019 – All rights reserved vii

---------------------- Page: 7 ----------------------
TECHNICAL REPORT ISO/TR 20118:2019(E)
Plastics — Guidance on fire characteristics and
fire performance of PVC materials used in building
applications
1  Scope
This document provides information on the fire characteristics and performance in fire tests of PVC
materials and products for use in building applications.
It illustrates a number of suitable applications incorporating primarily PVC materials, including
unplasticized PVC (PVC-U), plasticized (or flexible) PVC (PVC-P) and chlorinated PVC (PVC-C) based
products. Except where otherwise stated, there is no restriction with reference to the content of PVC
(in terms of quantity and composition) in the products mentioned in this document.
This document draws attention to the limits of applicability or the unsuitability of some standard fire
test methods for certain applications of PVC based products in buildings.
This document applies to products during their use phase in the building and does not apply to the
manufacturing phase of plastic products. It neither applies to general safety measures applicable to the
installation phase nor to the dismantling or the demolition phase of the building.
2  Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 472, Plastics — Vocabulary
ISO 13943, Fire safety — Vocabulary
IEC 60695-4, Fire hazard testing — Part 4: Terminology concerning fire tests for electrotechnical products
3  Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 472, ISO 13943, IEC 60695-4
and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https: //www .iso .org/obp
— IEC Electropedia: available at http: //www .electropedia .org/
3.1
composite
solid product consisting of two or more distinct phases, including a binding material (matrix) and a
particulate or fibrous material
Note 1 to entry: Solid product consisting of two or more layers (often in a symmetrical assembly) of, for instance,
plastic film or sheet, normal or syntactic cellular plastic, metal, wood or a composite, with or without adhesive
interlayers.
[SOURCE: ISO 472:2013, 2.182.1 and 2.182.2, modified —2.182.1 and 2.182.2 have been merged into
one entry.]
© ISO 2019 – All rights reserved 1

---------------------- Page: 8 ----------------------
ISO/TR 20118:2019(E)

3.2
compound
intimate mixture of a polymer or polymers with other ingredients such as fillers, plasticizers catalysts
and colorants
Note 1 to entry: The terms “formulation” and “composition” are sometimes used as synonyms.
[SOURCE: ISO 472:2013, 2.184, modified — Note 1 to entry has been added.]
3.3
fire effluent
totality of gases and aerosols, including suspended particles, created by combustion or pyrolysis in a fire
Note 1 to entry: For the purpose of this document, fire effluent also includes run-off water generated during fire-
fighting activities.
3.4
fire safety engineering
application of engineering methods to the development or assessment of designs in the built
environment through the analysis of specific fire scenarios or through the quantification of risk for a
group of fire scenarios
[SOURCE: ISO 13943:2017, 3.149]
3.5
flash ignition temperature
minimum temperature at which, under specified test conditions, sufficient flammable gases are emitted
to ignite momentarily on application of a pilot flame
Note 1 to entry: Compare with the terms ignitability (3.7), minimum ignition temperature and spontaneous
ignition temperature (see ISO 13943].
Note 2 to entry: Flash ignition temperature refers to the ignition temperature determined for solid specimens
on application of a flame to the specimen, for example in a test method such as ISO 871. Flash point refers to the
temperature to which a flammable liquid must be heated for its vapours to ignite.
Note 3 to entry: The typical units are °C.
[SOURCE: ISO 871:2006, 3.1, modified — Notes to entry have been added.]
3.6
heat release
thermal energy produced by combustion
Note 1 to entry: The typical unit is J.
[SOURCE: ISO 13943:2017, 3.205]
3.7
ignitability
measure of the ease with which a test specimen can be ignited, under specified conditions
Note 1 to entry: Also known as ease of ignition.
[SOURCE: ISO 13943:2017, 3.212, modified — Notes to entry have been replaced.]
3.8
plastics products
articles or stock shapes of plastic materials for any type of application
[SOURCE: ISO 11469:2016, 3.2]
2 © ISO 2019 – All rights reserved

---------------------- Page: 9 ----------------------
ISO/TR 20118:2019(E)

3.9
plenum
compartment or chamber to which one or more air ducts are connected and that forms part of the air
distribution system
Note 1 to entry: Plenums are typically located above ceilings or below raised floors and they are the areas
that contain heating, ventilating or air conditioning ducts. Products such as data and communications cables,
associated cable management systems and sprinkler piping are also often contained in plenums.
[SOURCE: NFPA Glossary of terms (2013)]
3.10
profile
extruded plastic product, excluding film and sheet, having a characteristic constant cross-section along
the axis of the product
[SOURCE: ISO 472:2013, 2.839, modified — Note to entry has been omitted.]
3.11
chlorinated PVC
PVC-C
polyvinylchloride, which is a thermoplastic obtained by polymerization of vinyl chloride and to which
additional chloride is chemically bonded by substitution of hydrogen atoms
Note 1 to entry: It is also commonly referred to as CPVC.
3.12
plasticized PVC
PVC-P
polyvinylchloride, which is a thermoplastic obtained by polymerization of vinyl chloride and plasticized
by the addition of specific additives
Note 1 to entry: It is also commonly referred to as flexible PVC and soft PVC.
3.13
unplasticized PVC
PVC-U
polyvinylchloride, which is a thermoplastic obtained by polymerization of vinyl chloride
Note 1 to entry: It is also commonly referred to as rigid PVC.
3.14
spontaneous-ignition temperature
minimum temperature at which ignition is obtained by heating, under specified test conditions, in the
absence of any flame ignition source
Note 1 to entry: Spontaneous ignition temperature is typically used in fire tests while auto-ignition temperature
is often used as a material or product property.
4  PVC building materials and products
4.1  Definition and description
4.1.1  General
PVC is the most widely used polymer in building and construction applications and, for instance, up to
70 % of the World’s annual PVC production is used in this sector.
© ISO 2019 – All rights reserved 3

---------------------- Page: 10 ----------------------
ISO/TR 20118:2019(E)

PVC is a thermoplastic composed of 56,8 mass % of chlorine (typically derived from industrial grade
salt) and 43,2 mass % of carbon and hydrogen (derived predominantly from oil or gas via ethylene). The
chlorine content gives excellent intrinsic fire performance to PVC.
PVC resin is often supplied in powder form and long-term storage is possible since the material is
resistant to oxidation and degradation. Various additives such as processing agents, stabilizers, fillers,
plasticizers, flame retardants, and pigments are added to the PVC resin during the compounding stage,
depending on the desired properties of the final product. The compound is then converted into PVC
products.
According to ISO 1043-1, PVC belongs to Group A, homopolymers. PVC compounds are classified in
different categories:
— PVC-U: unplasticized PVC, commonly named rigid PVC
— PVC-P: plasticized PVC, also named soft or flexible PVC
— PVC-C: chlorinated PVC, also identified as CPVC
ISO 11469 specifies a system of uniform marking of products that have been fabricated from plastics
materials. It refers to ISO 1043-1 (basic polymers), ISO 1043-2 (fillers and reinforcing materials),
ISO 1043-3 (plasticizers) and ISO 1043-4 (flame retardants).
NOTE 1 ISO 11469 is not intended to supplant, replace or in any way interfere with the requirements for
labelling specified in products standards or legislation.
The same rules apply in the cases of PVC containing, for example, a plasticizer and/or a flame retardant
(see 4.1.2 to 4.1.5).
NOTE 2 When possible and appropriate, compounds containing plasticizers can be marked with the
abbreviated term for the polymer followed by a hyphen, then the symbol “P” followed by the abbreviated term
of the plasticizer in parentheses, as given in ISO 1043-3. The exact marking is generally specified in the product
standard. It can be compulsory in case it is specified, for example, in an applicable regulation.
While the marking system is intended to help identify plastics products for subsequent decisions
concerning handling, waste recovery or disposal, it is also very useful to identify a material to be
subjected to fire testing.
NOTE 3 For characteristics other than the chemical composition of the material or product, such as reaction
to fire properties, a complementary and specific marking can be used.
4.1.2  PVC-U based products
Unplasticized PVC products are intended for applications where rigidity is needed. Some common
applications for PVC-U products include pipes, window profiles, conduit, siding, fences, decks and
railings. The use of plasticizers differentiates flexible vinyl products from rigid ones. The rigidity of
PVC is maintained by not introducing plasticizers.
In reaction to fire tests, PVC-U displays a high resistance to ignition, a low rate of heat release, and
self-extinguishes when the external ignition source is removed. This is because of its high content of
chlorine.
4.1.3  PVC-P based products
PVC is plasticized for applications where the flexibility of the final product is essential such as wire
sheathing and insulation, floor and wall coverings and flexible sheets.
4 © ISO 2019 – All rights reserved

---------------------- Page: 11 ----------------------
ISO/TR 20118:2019(E)

The fire properties of PVC generally deteriorate to a certain extent when PVC is plasticized depending
on the amount and kind of plasticizer and other additives used. However, many of the plasticized PVC
products in use will not continue to burn once the flame source is removed, even if not additionally
fire-retarded. Moreover, technologies were developed in the 1980s and 1990s, using combinations of
plasticizers and other additives, which resulted in plasticized PVC materials with fire properties similar
or better than those of the corresponding native unplasticized PVC.
4.1.4  PVC-C based products
PVC-C is obtained from normal PVC resin to which additional chlorine is introduced in the polymer
chain, to reach a chlorine content in the range of 62 % to 68 % by mass, leading to a different family of
vinyl polymers. This addition leads to improved fire properties: further decrease in the flammability
(including heat release) of the polymer and significant decrease in intrinsic smoke generation. The reason
for this effect on smoke generation is likely to be a change in the mechanism of dehydrochlorination.
4.1.5  Flame retardants
The term “flame retardant” refers to a range of additives of various chemical compositions that can
be added to materials to improve their fire behaviour and reduce fire hazard. Various species of flame
retardants, including smoke suppressants, alone or in combination, can lead to consistent lowering of
heat release, flame spread, ignitability, (by increasing the time to ignition or the minimum heat flux for
ignition), or smoke release.
NOTE The presence of flam
...