Binders for magnesite screeds - Caustic magnesia and magnesium chloride - Part 1: Definitions, requirements

This European Standard specifies requirements for caustic magnesia and magnesium chloride, which will be used for magnesite screed material and magnesite screeds as specified in EN 13813.

Bindemittel für Magnesiaestriche - Kaustische Magnesia und Magnesiumchlorid - Teil 1: Begriffe und Anforderungen

Diese Europäische Norm legt Anforderungen an kaustische Magnesia und Magnesiumchlorid, die zur Herstellung von Magnesiaestrichmörteln und Magnesiaestrichen nach EN 13813 verwendet werden, fest.

Liants pour chapes a base de magnésie - Magnésie caustique et chlorure de magnésium - Partie 1: Définitions, exigences

La présente Norme européenne spécifie les exigences relatives a la magnésie caustique et au chlorure de magnésium, utilisés comme matériaux pour chapes et chapes a base de magnésie tels que spécifiés dans l'EN 13813.

Veziva za magnezitne estrihe – Kaustični magnezit in magnezijev klorid - 1. del. Definicije in zahteve

General Information

Status
Published
Publication Date
31-Mar-2004
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
01-Apr-2004
Due Date
01-Apr-2004
Completion Date
01-Apr-2004

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EN 14016-1:2004
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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Binders for magnesite screeds - Caustic magnesia and magnesium chloride - Part 1: Definitions, requirementsLiants pour chapes a base de magnésie - Magnésie caustique et chlorure de magnésium - Partie 1: Définitions, exigencesBindemittel für Magnesiaestriche - Kaustische Magnesia und Magnesiumchlorid - Teil 1: Begriffe und AnforderungenTa slovenski standard je istoveten z:EN 14016-1:2004SIST EN 14016-1:2004en91.100.5001.040.91ICS:SLOVENSKI
STANDARDSIST EN 14016-1:200401-april-2004







EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 14016-1January 2004ICS 01.040.91; 91.100.50English versionBinders for magnesite screeds - Caustic magnesia andmagnesium chloride - Part 1: Definitions, requirementsLiants pour chapes à base de magnésie - Magnésiecaustique et chlorure de magnésium - Partie 1: Définitions,exigencesBindemittel für Magnesiaestriche - Kaustische Magnesiaund Magnesiumchlorid - Teil 1: Begriffe und AnforderungenThis European Standard was approved by CEN on 15 September 2003.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2004 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 14016-1:2004: E



EN 14016-1:2004 (E)2ContentspageForeword.31Scope.42Normative references.43Terms and definitions.44Requirements.54.1Magnesium chloride.54.2Caustic magnesia.54.2.1Homogeneity.54.2.2Chemical composition.54.2.3Loose density.54.2.4Fineness of grind.54.2.5Setting time.64.2.6Flexural and compressive strength.64.3Reaction to fire.65Testing.66Evaluation of conformity.66.1General.66.2Initial type testing (ITT).76.3Factory production control (FPC).76.4Technical specifications for binders for magnesite screed.77Designation.78Marking and labelling.89Conformity criteria and assessment procedure.89.1General.89.2Statistical conformity criteria.89.2.1General.89.2.2Check by variables.89.2.3Check by attributes.99.3Minimum testing frequencies.10Annex ZA (informative)
Clauses of this European Standard addressing essential requirements or otherprovisions of EU Directives.11ZA.1Scope and relevant characteristics.11ZA.2Procedure(s) for attestation of conformity of binders for magnesite screed materials.12ZA.2.1System(s) of attestation of conformity.12ZA.2.2EC Declaration of conformity.13ZA.3CE marking and labelling.14Bibliography.16



EN 14016-1:2004 (E)3ForewordThis document (EN 14016-1:2004) has been prepared by Technical Committee CEN/TC 303, “Floor screeds andin-situ floorings in buildings”, the secretariat of which is held by BSI.This European Standard shall be given the status of a national standard, either by publication of an identical text orby endorsement, at the latest by July 2004, and conflicting national standards shall be withdrawn at the latest byOctober 2005.This document belongs to a series of standards for screed material and floor screeds within building constructions.No existing European Standard is superseded.This document has been prepared under Mandate M 132 "Floorings” given to CEN by the European Commissionand the European Free Trade Association, and supports essential requirements of EU Directive(s).For relationship with EU Directive(s), see informative annex ZA, which is an integral part of this document.According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following coun-tries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Esto-nia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.



EN 14016-1:2004 (E)41 ScopeThis European Standard specifies requirements for caustic magnesia and magnesium chloride, which will be usedfor magnesite screed material and magnesite screeds as specified in EN 13813.2 Normative referencesThis European Standard incorporates by dated or undated reference, provisions from other publications. Thesenormative references are cited at the appropriate places in the text and the publications are listed hereafter. Fordated references, subsequent amendments to or revisions of any of these publications apply to this EuropeanStandard only when incorporated in it by amendment or revision. For undated references the latest edition of thepublication referred to applies (including amendments).EN 196-1, Methods of testing cement
— Part 1: Determination of strength.EN 13318:2000, Screed materials and floor screeds — Definitions.EN 14016-2, Binders for magnesite screeds — Caustic magnesia and magnesium chloride — Part 2: Test meth-ods.EN 13501-1, Fire classification of construction products and building elements - Part 1: Classification using testdata from reaction to fire tests.EN ISO 9001, Quality management systems - Requirements (ISO 9001:2000).3 Terms and definitionsFor the purposes of this European Standard, the terms and definitions given in EN 13318:2000 and the followingapply.3.1magnesium chloridecompound (magnesium chloride (MgCl2)) which may contain water insoluble substances, e.g. ferrous oxide (Fe2O3)and magnesium oxide (MgO), as well as water-soluble substances, e.g. sodium chloride (NaCl), potassium chloride(KCl), calcium chloride (CaCl2) and magnesium sulfate (MgSO4); it is traded as solid salt or aqueous solution3.2caustic magnesiaa finely ground binder, which is burned out of naturally occurring magnesium carbonate MgCO3 or other magne-sium compounds; the main constituent of the caustic magnesia is magnesium oxide (MgO); sub-constituents maybe carbonate (CO3), silicic oxide (SiO2), aluminium oxide (Al2O3), ferric oxide (Fe2O3), calcium oxide (CaO) andsulfate (SO4)



EN 14016-1:2004 (E)54 Requirements4.1 Magnesium chlorideMagnesium chloride shall conform to the requirements by composition given in Table 1:Table 1 — Requirements for magnesium chlorideSub ingredientsMainconstituentWater insolublesubstancesWater-solublesubstancesTradeformmass MgCl2(%)mass(%)NaCl + KClmass(%)MgSO4mass(%)CaCl2mass(%)pH-valueAqueoussolution³ 20£ 0,05£ 1£ 0,5£ 0,5Solid salt³ 46£ 0,1£ 2£ 1£ 1³ 64.2 Caustic magnesia4.2.1 HomogeneityCharges shall be homogenous and show the same colour by visual inspection.4.2.2 Chemical compositionThe chemical composition shall fulfil the following requirements:a) magnesium oxide MgO³ 80 % by massb) hydrochloric-acid-insoluble residues + sesquioxides£ 14 % by massc) calcium oxide CaO1) £ 4 % by massd) ignition loss£ 8 % by mass4.2.3 Loose densityThe loose density shall not be more than 1 000 kg/m3.4.2.4 Fineness of grindBy testing the fineness of the grind the residues in the sieves shall not exceed the value in Table 2.
1)A higher total amount of CaO is allowed, if the free CaO content is lower then 1 % by mass.



EN 14016-1:2004 (E)6Table 2 — Fineness of grindSieve mesh width(mm)Mass of residues(%)0,09304.2.5 Setting timeThe setting process of the magnesia paste shall begin 30 minutes after mixing at the earliest and end 5 h aftermixing at the latest.4.2.6 Flexural and compressive strengthThe magnesia test mortar, consisting of caustic magnesia, magnesium chloride and CEN-standard sand accordingto EN 196-1 (see EN 14016-2) shall have at least the strength characteristics given in Table 3.Table 3 — Flexural and compressive strengthAgedaysFlexural strengthN/mm2Compressive strengthN/mm228³ 9³ 60NOTEWhen tested at the age of 3 days, a flexural strength of about 8 N/mm2 and a compressive strength of approxi-mately 50 N/mm2 should be obtained.4.3 Reaction to fireBinders for magnesite screed materials which do not contain more than 1 % of organic material by mass or volume(whichever is the more onerous) are classified A1fl without the need for testing2). All other materials shall be testedand classified in accordance with EN 13501-1.5 TestingTesting, except for reaction to fire, shall be carried out as specified in EN 14016-2.6 Evaluation of conformity6.1 GeneralEvaluation of conformity is carried out by declaring conformity of binders for magnesite screeds, caustic magnesiaand magnesium chloride, with the requirements of this standard on the basis of:¾ Initial type testing (ITT);¾ Factory production control (FPC).The conformity criteria and assessment procedure are given in clause 9.
2)See Commission Decision 96/603/EC, as amended.



EN 14016-1:2004 (E)76.2 Initial type testing (ITT)An initial type testing shall be carried out to show conformity of the product to this standard. Additionally, an initialtype testing shall be carried out at the beginning of production of a new product type. Before starting productionand introduction of the product into the market, suitable initial type testing shall be carried out to confirm that thepredicted product properties conform to the requirements in this standard and correspond to the declared values.Initial type tests shall also be carried out if the specification for the binders or the manufacturing method have beenchanged.Tests previously performed in accordance with the provisions of this standard may be taken into account providedthat product characteristic(s), test method, sampling procedure and system of attestation of conformity are identi-cal.6.3 Factory production control (FPC)Factory production control means the permanent internal control of production exercised by the manufacturer or hisagent under the responsibility of the manufacturer himself.The purpose of the factory production control is to ensure that binders for magnesite screeds placed on the marketconform to their technical specifications given in clause 4. Sampling and tests shall be carried out as described inEN 14016-2, except as provided for in 6.4.The manufacturer shall record the results of production control (manufacturer’s record). These records shall includeat least the following:¾ identification of the product tested;¾ date of sampling;¾ test methods used;¾ test and inspection results;¾ date of tests;¾ identification of the person responsible for the tests;¾ calibration records.An FPC system conforming to the requirements in EN ISO 9001 and corresponding to the requirements in thisstandard is considered as a system
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