SIST EN 17351:2020
(Main)Bio-based products - Determination of the oxygen content using an elemental analyser
Bio-based products - Determination of the oxygen content using an elemental analyser
This document specifies a method for the determination of the oxygen content in bio-based products using an elemental analyser. The scope is limited to products containing elements C, H, O, N, Cl, Br and I without F, representing at least 95 % of the composition of the product to be analysed.
NOTE 1 Bio-based materials can contain inorganic components. Oxygen in these inorganic components is not bio-based but will nevertheless contribute to the amount of oxygen determined by the following prescribed methods and therefore influence the results in terms of oxygen content.
NOTE 2 Although this document has been drafted for the purpose of the determinations dealing with bio-based content, it can be also used as a standalone standard for determination of oxygen in organic compounds.
NOTE 3 For the purposes of this document, the term “% (m/m)” is used to represent the mass (μ) of a material.
Biobasierte Produkte - Sauerstoffgehalt - Bestimmung des Sauerstoffgehaltes unter Verwendung eines Elementaranalysators
Dieses Dokument legt ein Verfahren zur Bestimmung des Sauerstoffgehaltes in biobasierten Produkten unter Verwendung eines Elementaranalysators fest. Der Anwendungsbereich ist auf Produkte mit den Elementen C, H, O, N, Cl, Br und I ohne F begrenzt, die mindestens 95 % der Zusammensetzung des zu analysierenden Produkts ausmachen.
ANMERKUNG 1 Biobasierte Werkstoffe können anorganische Bestandteile enthalten. Sauerstoff in diesen anorganischen Bestandteilen ist nicht biobasiert, aber er trägt trotzdem zur durch die folgenden beschriebenen Verfahren bestimmten Sauerstoffmenge bei und beeinflusst deshalb die Ergebnisse in Bezug auf den Sauerstoffgehalt.
ANMERKUNG 2 Obwohl dieses Dokument zum Zweck der Bestimmungen in Bezug auf den biobasierten Gehalt erarbeitet wurde, kann es ebenso als eigenständige Norm zur Bestimmung von Sauerstoff in organischen Verbindungen verwendet werden.
ANMERKUNG 3 Für die Anwendung dieses Dokuments wird der Begriff „% (m/m)“ zur Darstellung der Masse (μ) eines Werkstoffs verwendet.
Produits biosourcés - Teneur en oxygène - Détermination de la teneur en oxygène à laide dun analyseur déléments
Le présent document spécifie une méthode directe de détermination de la teneur totale en oxygène dans les produits biosourcés à l’aide d’un analyseur élémentaire. Le domaine d’application se limite aux produits contenant les éléments carbone, hydrogène, oxygène, azote, chlorure, bromure et iodure sans fluorure, représentant au moins 95 % de la composition du produit à analyser.
NOTE 1 Les matériaux biosourcés peuvent contenir des composés organiques et inorganiques. La teneur en oxygène peut provenir des composés organiques et/ou inorganiques. Les composés inorganiques ne sont pas biosourcés mais contribueront néanmoins à la quantité d’oxygène déterminée par les méthodes prescrites suivantes et influenceront donc les résultats en termes de teneur en oxygène. Dans l'état actuel des connaissances, il est impossible de différencier, à l'aide de mesures isotopiques, l'oxygène issu de la biomasse de l'oxygène non issu de la biomasse.
NOTE 2 Bien que ce document ait été rédigé pour les déterminations ayant trait à la teneur biosourcée, il peut également être utilisé comme norme autonome pour déterminer la teneur en oxygène dans les composés organiques.
NOTE 3 Pour les besoins du présent document, l'unité « % (m/m) » est utilisée pour représenter la teneur en oxygène d’un matériau.
NOTE 4 La méthode spécifiée dans le présent document implique une méthode de mesure directe pour la détermination de la teneur en oxygène. Cette méthode présente de nombreuses similitudes avec la norme ASTM D5622 [1] sur l'essence et les combustibles au méthanol. La méthode spécifiée dans le présent document est spécialement élaborée et validée pour les produits biosourcés. En outre, cette méthode fournit des mesures pour l'oxygène plus précises et authentiques qu'avec les méthodes de mesure indirecte pour la détermination de la teneur en oxygène (par exemple, ASTM D3176 [2]).
Bioizdelki - Določevanje kisika z uporabo elementarnega analizatorja
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN 17351:2020
01-april-2020
Bioizdelki - Določevanje kisika z uporabo elementarnega analizatorja
Bio-based products - Determination of the oxygen content using an elemental analyser
Biobasierte Produkte - Sauerstoffgehalt - Bestimmung des Sauerstoffgehaltes unter
Verwendung eines Elementaranalysators
Produits biosourcés - Teneur en oxygène - Détermination de la teneur en oxygène à
laide dun analyseur déléments
Ta slovenski standard je istoveten z: EN 17351:2020
ICS:
13.020.55 Biološki izdelki Biobased products
SIST EN 17351:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
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SIST EN 17351:2020
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SIST EN 17351:2020
EN 17351
EUROPEAN STANDARD
NORME EUROPÉENNE
January 2020
EUROPÄISCHE NORM
ICS 13.020.55
English Version
Bio-based products - Determination of the oxygen content
using an elemental analyser
Produits biosourcés - Détermination de la teneur en Biobasierte Produkte - Bestimmung des
oxygène à l'aide d'un analyseur élémentaire Sauerstoffgehaltes unter Verwendung eines
Elementaranalysators
This European Standard was approved by CEN on 9 October 2019.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17351:2020 E
worldwide for CEN national Members.
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SIST EN 17351:2020
EN 17351:2020 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 6
5 General requirements for the determination of the oxygen content. 6
6 Reagents . 7
7 Apparatus . 7
8 Sampling . 8
9 Measurement procedure . 8
10 Calculation of the oxygen content . 9
11 Test report . 10
Annex A (normative) Performance characteristics . 11
Bibliography . 13
2
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SIST EN 17351:2020
EN 17351:2020 (E)
European foreword
This document (EN 17351:2020) has been prepared by Technical Committee CEN/TC 411 “Bio-based
products”, the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by July 2020, and conflicting national standards shall be
withdrawn at the latest by July 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United
Kingdom.
3
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SIST EN 17351:2020
EN 17351:2020 (E)
Introduction
Bio-based products from forestry and agriculture have a long history of application, such as paper, board
and various chemicals and materials. The last decades have seen the emergence of new bio-based
products in the market. Some of the reasons for the increased interest lie in the benefits of bio-based
products in relation to the depletion of fossil resources and climate change. Bio-based products may also
provide additional product functionalities. These developments have triggered a wave of innovation with
the development of knowledge and technologies allowing new transformation processes and product
development.
Acknowledging the need for common standards for bio-based products, the European Commission issued
)
1
Mandate M/492 , resulting in a series of standards developed by CEN/TC 411, with a focus on bio-based
products other than food, feed and biomass for energy applications.
The standards of CEN/TC 411 “Bio-based products” provide a common basis on the following aspects:
— common terminology;
— bio-based content determination;
— life Cycle Assessment (LCA);
— sustainability aspects;
— declaration tools.
It is important to understand what the term bio-based product covers and how it is being used. The term
‘bio-based’ means 'derived from biomass'. Bio-based products (bottles, insulation materials, wood and
wood products, paper, solvents, chemical intermediates, composite materials, etc.) are products which
are wholly or partly derived from biomass. It is essential to characterize the amount of biomass contained
in the product by, for instance, its bio-based content or bio-based carbon content.
The bio-based content of a product does not provide information on its environmental impact or
sustainability, which may be assessed through LCA and sustainability criteria. In addition, transparent
and unambiguous communication within bio-based value chains is facilitated by a harmonized
framework for certification and declaration.
This document has been developed with the aim to specify the method for the determination of oxygen
content in bio-based products using an elemental analyser. This document provides the reference test
methods for laboratories, producers, suppliers and purchasers of bio-based products. It may be also
useful for authorities and inspection organizations.
Part of the research leading to this document has been performed under the European Union Seventh
Framework Programme OpenBio (see https://www.biobasedeconomy.eu/).
1
) A mandate is a standardization task embedded in European trade laws. Mandate M/492 is addressed to the
European Standardization bodies, CEN, CENELEC and ETSI, for the development of horizontal European Standards
for bio-based products.
4
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SIST EN 17351:2020
EN 17351:2020 (E)
1 Scope
This document specifies a direct method for the determination of the total oxygen content in bio-based
products using an elemental analyser. The scope is limited to products containing elements carbon,
hydrogen, oxygen, nitrogen, chloride, bromide and iodide without fluoride, representing at least 95 % of
the composition of the product to be analysed.
NOTE 1 Bio-based materials can contain both organic and inorganic components. The oxygen content might
originate both from the organic and/or the inorganic components. The inorganic components are not bio-based but
will nevertheless contribute to the amount of oxygen determined by the following prescribed methods and
therefore influence the results in terms of oxygen content. According to the current state of the art, it is not possible
by isotopic measurements to establish a distinction between oxygen originating from biomass and oxygen
originating from non-biomass.
NOTE 2 Although this document has been drafted for the purpose of the determinations dealing with bio-based
content, it can be also used as a standalone standard for determination of oxygen in organic compounds.
NOTE 3 For the purposes of this document, the unit “% (m/m)” is used to represent the oxygen content of a
material.
NOTE 4 The method specified in this document involves a direct measurement method for the determination of
oxygen content. This method contains many similarities with the ASTM D5622 [1] standard for gasoline and
methanol fuels. The method specified in this document is specifically developed and validated for bio-based
products. In addition, this method provides more accurate and unadulterated measured values for oxygen in
contrast to indirect measurement methods for the determination of oxygen (e.g. ASTM D 3176 [2]).
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 16575, Bio-based products - Vocabulary
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 16575 and the following terms
and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
• IEC Electropedia: available at http://www.electropedia.org/
• ISO Online browsing platform: available at https://www.iso.org/obp/ui
3.1
laboratory sample
sub-quantity of a sample suitable for laboratory tests
3.2
sample
quantity of material, representative of a larger quantity for which the property is to be determined
3.3
sample preparation
action taken to obtain representative analysis samples or test portions from the original sample
5
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SIST EN 17351:2020
EN 17351:2020 (E)
4 Principle
One of the major components of bio-based products is oxygen. The amount of oxygen is determined using
an elemental analyser. The dried sample is pyrolyzed in an inert gas stream (e.g. Helium, Argon, Nitrogen)
in a reaction column at a suitable temperature. The gaseous pyrolysis products are exposed to nickel
activated carbon, carbon black or glassy carbon at typical temperatures as shown in Table 1. The oxygen
present in the pyrolysis gases is transformed to carbon monoxide. The formed water is removed using a
column filled with magnesium perchlorate. The carbon monoxide is then separated on a column and
measured using a thermal conductivity detector or a NDIR CO detector.
Table 1 — Reactant and pyrolysis temperatures
Reactant Pyrolysis temperatures
Nickel activated carbon 1 060 °C
Carbon black 1 100 °C
Glassy carbon 1 400 °C
NOTE There is a restriction to components containing fluorine. Fluorine is forbidden in oxygen analysis, it
attacks the glass according the following reaction: F+SiO → SiF +O . As a result of that reaction, the oxygen
2 2 2
concentration determined by the measurement will be higher than the actual value.
Some inorganic compounds containing oxygen will also contribute to the measured oxygen concentration
in the sample (e.g. carbonates). The
...
SLOVENSKI STANDARD
oSIST prEN 17351:2019
01-april-2019
Bioizdelki - Ugotavljanje deleža kisika z uporabo elementarnega analizatorja
Bio-based products - Determination of the oxygen content using an elemental analyser
Biobasierte Produkte - Sauerstoffgehalt - Bestimmung des Sauerstoffgehaltes unter
Verwendung eines Elementaranalysators
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Ta slovenski standard je istoveten z: prEN 17351
ICS:
13.020.55 Biološki izdelki Biobased products
oSIST prEN 17351:2019 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST prEN 17351:2019
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oSIST prEN 17351:2019
DRAFT
EUROPEAN STANDARD
prEN 17351
NORME EUROPÉENNE
EUROPÄISCHE NORM
January 2019
ICS 13.020.55
English Version
Bio-based products - Determination of the oxygen content
using an elemental analyser
Produits biosourcés - Teneur en oxygène - Biobasierte Produkte - Sauerstoffgehalt - Bestimmung
Détermination de la teneur en oxygène à l¿aide d¿un des Sauerstoffgehaltes unter Verwendung eines
analyseur d¿éléments Elementaranalysators
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 411.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17351:2019 E
worldwide for CEN national Members.
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oSIST prEN 17351:2019
prEN 17351:2019 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 General requirements for the determination of the oxygen content. 6
6 Reagents . 6
7 Apparatus . 7
8 Sampling . 7
9 Measurement procedure . 7
10 Calculation of the oxygen content . 9
11 Test report . 9
Annex A (normative) Performance characteristics . 11
Bibliography . 13
2
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oSIST prEN 17351:2019
prEN 17351:2019 (E)
European foreword
This document (prEN 17351:2019) has been prepared by Technical Committee CEN/TC 411 “Bio-based
products”, the secretariat of which is held by NEN.
This document is currently submitted to the CEN Enquiry.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
3
---------------------- Page: 5 ----------------------
oSIST prEN 17351:2019
prEN 17351:2019 (E)
Introduction
Bio-based products from forestry and agriculture have a long history of application, such as paper, board
and various chemicals and materials. The last decades have seen the emergence of new bio-based
products in the market. Some of the reasons for the increased interest lie in the bio-based products’
benefits in relation to the depletion of fossil resources and climate change. Bio-based products may also
provide additional product functionalities. This has triggered a wave of innovation with the development
of knowledge and technologies allowing new transformation processes and product development.
Acknowledging the need for common standards for bio-based products, the European Commission issued
)
1
Mandate M/492
, resulting in a series of standards developed by CEN/TC 411, with a focus on bio-based
products other than food, feed and biomass for energy applications.
The standards of CEN/TC 411 “Bio-based products” provide a common basis on the following aspects:
— common terminology;
— bio-based content determination;
— life Cycle Assessment (LCA);
— sustainability aspects;
— declaration tools.
It is important to understand what the term bio-based product covers and how it is being used. The term
‘bio-based’ means 'derived from biomass'. Bio-based products (bottles, insulation materials, wood and
wood products, paper solvents, chemical intermediates, composite materials, etc.) are products which
are wholly or partly derived from biomass. It is essential to characterize the amount of biomass contained
in the product by, for instance, its bio-based content or bio-based carbon content.
The bio-based content of a product does not provide information on its environmental impact or
sustainability, which may be assessed through LCA and sustainability criteria. In addition, transparent
and unambiguous communication within bio-based value chains is facilitated by a harmonized
framework for certification and declaration.
This document has been developed with the aim to specify the method for the determination of oxygen
content in bio-based products using an elemental analyser. This document provides the reference test
methods for laboratories, producers, suppliers and purchasers of bio-based product materials and
products. It may be also useful for authorities and inspection organizations.
Part of the research leading to this document has been performed under the European Union Seventh
Framework Programme OpenBio (see biobasedeconomy.eu).
1
) A mandate is a standardization task embedded in European trade laws. Mandate M/492 is addressed to the
European Standardization bodies, CEN, CENELEC and ETSI, for the development of horizontal European Standards
for bio-based products.
4
---------------------- Page: 6 ----------------------
oSIST prEN 17351:2019
prEN 17351:2019 (E)
1 Scope
This document specifies a method for the determination of the oxygen content in bio-based products
using an elemental analyser. The scope is limited to products containing elements C, H, O, N, Cl, Br and I
without F, representing at least 95 % of the composition of the product to be analysed.
NOTE 1 Bio-based materials can contain inorganic components. Oxygen in these inorganic components is not
bio-based but will nevertheless contribute to the amount of oxygen determined by the following prescribed
methods and therefore influence the results in terms of oxygen content.
NOTE 2 Although this document has been drafted for the purpose of the determinations dealing with bio-based
content, it can be also used as a standalone standard for determination of oxygen in organic compounds.
NOTE 3 For the purposes of this document, the term “% (m/m)” is used to represent the mass (µ) of a material.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 16575, Bio-based products — Vocabulary
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 16575 and the following terms
and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
• IEC Electropedia: available at http://www.electropedia.org/
• ISO Online browsing platform: available at http://www.iso.org/obp
3.1
laboratory sample
sub-quantity of a sample suitable for laboratory tests
3.2
sample
quantity of material, representative of a larger quantity for which the property is to be determined
3.3
sample preparation
all the actions taken to obtain representative analysis samples or test portions from the original sample
4 Principle
One of the major components of bio-based products is oxygen. The amount of oxygen is determined using
an elemental analyser. The dried sample is pyrolyzed in an inert gas stream (e.g. Helium, Argon, Nitrogen)
in a reaction column at a suitable temperature. The gaseous pyrolysis products are exposed to nickel
activated carbon, carbon black or glassy carbon at typical temperatures as shown in Table 1. The oxygen
present in the pyrolysis gases is transformed to carbon monoxide. The formed water is removed using a
column filled with magnesium perchlorate. The carbon monoxide is then separated on a column and
measured using a thermal conductivity detector or a NDIR CO detector.
5
---------------------- Page: 7 ----------------------
oSIST prEN 17351:2019
prEN 17351:2019 (E)
Table 1 — Reactant and pyrolysis temperatures
Reactant Pyrolysis temperatures
Nickel activated carbon 1 060 °C
Carbon black 1 100 °C
Glassy carbon 1 400 °C
NOTE 1 There is a restriction to components containing fluorine. Fluorine is forbidden in oxygen analysis, it
attacks the glass according the following reaction: F+SiO → SiF +O . As a result of that reaction, the oxygen
2 2 2
measurement is higher than the actual value
Some inorganic
...
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