EN 62321-8:2017
(Main)Determination of certain substances in electrotechnical products - Part 8: Phthalates in polymers by gas chromatography-mass spectrometry (GC-MS), gas chromatography-mass spectrometry using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS)
Determination of certain substances in electrotechnical products - Part 8: Phthalates in polymers by gas chromatography-mass spectrometry (GC-MS), gas chromatography-mass spectrometry using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS)
IEC 62321-8:2017 specifies two normative and two informative techniques for the determination of di-isobutyl phthalate (DIBP), di-n-butyl phthalate (DBP), benzylbutyl phthalate (BBP), di-(2-ethylhexyl) phthalate (DEHP), di-n-octyl phthalate (DNOP), di-isononyl phthalate (DINP) and di-iso-decyl phthalate (DIDP) in polymers of electrotechnical products.
Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik - Teil 8: Phthalate in Polymeren mittels Gaschromatographie-Massenspektrometrie (GC-MS), Gaschromatographie-Massenspektrometrie mit Nutzung des Zusatzes der Pyrolyse/thermischen Desorption (Py/TD-GC-MS)
Détermination de certaines substances dans les produits électrotechniques - Partie 8: Analyse des phtalates dans les polymères par chromatographie en phase gazeuse-spectrométrie de masse (GC-MS), chromatographie en phase gazeuse-spectrométrie de masse par pyrolyse/thermodésorption (Py/TD-GC-MS)
L'IEC 62321-8:2017 spécifie deux techniques normatives et deux techniques informatives de détermination de la présence de phtalate de diisobutyle (DIBP - di-isobutyl phthalate), de phtalate de dibutyle (DBP - di-n-butyl phthalate), de phtalate de benzyle et de butyle (BBP - benzylbutyl phthalate), de phtalate de bis(2-éthylhexyle) (DEHP - di-(2-ethylhexyl) phthalate), de phtalate de di-n-octyle (DNOP - di-n-octyl phthalate), de phtalate de di-isononyle (DINP - di-isononyl phthalate) et de phtalate de di-isodécyle (DIDP - di-iso-decyl phthalate) dans les polymères qui sont utilisés dans des produits électrotechniques.
Določevanje posameznih substanc v elektrotehniških izdelkih - 8. del: Ftalati v polimerih s plinsko kromatografijo-masno spektrometrijo (GC-MS), plinsko kromatografijo-masno spektrometrijo z uporabo pirolize/toplotne desorpcije (Py/TD-GC-MS)
Ta del standarda IEC 62321 določa dve normativni in dve informativni tehniki za določanje di-izobutil ftalata (DIBP), di-n-butil ftalata (DBP), butil benzil ftalata (BBP), di-2-etilheksil ftalata (DEHP), di-n-oktil ftalata (DNOP), di-izononil ftalata (DINP) in di-izo-decil ftalata (DIDP) v polimerih v elektrotehniških izdelkih.
V normativnem delu tega dokumenta sta opisani plinska kromatografija-masna spektrometrija (GC-MS) in plinska kromatografija-masna spektrometrija z uporabo pirolize/toplotne desorpcije (Py/TD-GC-MS).
Metoda GC-MS je glavna tehnika za kvantitativno določanje DIBP, DBP, BBP, DEHP, DNOP, DINP in DIDP v razponu 50–2000 mg/kg.
Metoda GC-MS z uporabo pirolize/toplotne desorpcije (TD) je primerna za presejalne preskuse in polkvantitativno analizo DIBP, DBP, BBP, DEHP, DNOP, DINP in DIDP v polimerih, ki se uporabljajo kot deli elektrotehniških izdelkov v razponu 100–2000 mg/kg.
Tehnika masne spektrometrije s pripenjanjem iona (IAMS) je primerna za presejalne preskuse in polkvantitativno analizo DIBP, DBP, BBP, DEHP, DNOP, DINP in DIDP. DBP in DIBP ter DEHP in DNOP niso določeni z masno spektrometrijo s pripenjanjem iona (IAMS) zaradi omejitev pri določanju vrhov in omejitev ločljivosti masnega spektra.
Tehnika LC-MS je omejena na določanje BBP, DEHP, DNOP, DINP in DIDP. DBP in DIBP nista določena z metodo LC-MS zaradi omejitev pri določanju vrhov in omejitev ločljivosti masnega spektra.
Diagram poteka, ki prikazuje, kako je mogoče uporabiti normativni metodi Py/TD-GC-MS in GC-MS ter informativne metode z masno spektrometrijo s pripenjanjem iona (IAMS) skupaj s sondo za neposredno injiciranje (DIP) in tekočinsko kromatografijo – masno spektrometrijo (LC-MS), je na voljo v dodatkih tega dokumenta.
Te štiri preskusne metode so bile ocenjene s preskusom PE (polietilenskih) in PVC (polivinilkloridnih) materialov, ki vsebujejo posamezne ftalate ~450–30.000 mg/kg, kot je prikazano v normativnem in informativnem delu tega dokumenta. Uporaba teh štirih metod, ki so opisane v tem dokumentu, za druge vrste polimerov, ftalatov ali razpone koncentracij, ki niso določene zgoraj, ni bila posebej ocenjena.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-september-2017
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Determination of certain substances in electrotechnical products - Part 8: Phthalates in
polymers by gas chromatography-mass spectrometry (GC-MS), gas chromatography-
mass spectrometry using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS)
Ta slovenski standard je istoveten z: EN 62321-8:2017
ICS:
29.020 Elektrotehnika na splošno Electrical engineering in
general
31.020 Elektronske komponente na Electronic components in
splošno general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EUROPEAN STANDARD EN 62321-8
NORME EUROPÉENNE
EUROPÄISCHE NORM
June 2017
ICS 31.020; 71.040.50
English Version
Determination of certain substances in electrotechnical products
- Part 8: Phthalates in polymers by gas chromatography-mass
spectrometry (GC-MS), gas chromatography-mass spectrometry
using a pyrolyzer/thermal desorption accessory (Py/TD-GC-MS)
(IEC 62321-8:2017)
Détermination de certaines substances dans les produits Verfahren zur Bestimmung von bestimmten Substanzen in
électrotechniques - Partie 8: Analyse des phtalates dans les Produkten der Elektrotechnik - Teil 8: Phthalate in
polymères par chromatographie en phase gazeuse- Polymeren mit Pyrolyse-Gaschromatographie-
spectrométrie de masse (GC-MS), chromatographie en Massenspektrometrie (Py-GC-MS), Ionen-Anlagerungs-
phase gazeuse-spectrométrie de masse par Massenspektrometrie (IAMS), Gaschromatographie-
pyrolyse/thermodésorption (Py/TD-GC-MS) Massenspektrometrie (GC-MS) und
(IEC 62321-8:2017) Flüssigchromatographie-Massenspektrometrie (LC-MS)
(IEC 62321-8:2017)
This European Standard was approved by CENELEC on 2017-05-02. CENELEC members are bound to comply with the CEN/CENELEC
Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC
Management Centre or to any CENELEC member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the
same status as the official versions.
CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic,
Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,
Switzerland, Turkey and the United Kingdom.
European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members.
Ref. No. EN 62321-8:2017 E
European foreword
The text of document 111/416/CDV, future edition 1 of IEC 62321-8, prepared by
IEC/TC 111 "Environmental standardization for electrical and electronic products and systems" was
submitted to the IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-8:2017.
The following dates are fixed:
(dop) 2018-02-02
• latest date by which the document has to be
implemented at national level by
publication of an identical national
standard or by endorsement
• latest date by which the national (dow) 2020-05-02
standards conflicting with the
document have to be withdrawn
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CENELEC shall not be held responsible for identifying any or all such patent rights.
Endorsement notice
The text of the International Standard IEC 62321-8.2017 was approved by CENELEC as a European
Standard without any modification.
In the official version, for Bibliography, the following notes have to be added for the standards
indicated:
ISO 3696 NOTE Harmonized as EN ISO 3696.
ISO/IEC 17025 NOTE Harmonized as EN ISO/IEC 17025.
IEC 62321-2:2013 NOTE Harmonized as EN 62321-2:2014.
IEC 62321-6:2015 NOTE Harmonized as EN62321-6:2016
Annex ZA
(normative)
Normative references to international publications
with their corresponding European publications
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.
NOTE 1 When an International Publication has been modified by common modifications, indicated by (mod), the relevant
EN/HD applies.
NOTE 2 Up-to-date information on the latest versions of the European Standards listed in this annex is available here:
www.cenelec.eu.
Publication Year Title EN/HD Year
IEC 62321-1 2013 Determination of certain substances in EN 62321-1 2013
electrotechnical products -- Part 1:
Introduction and overview
IEC 62321-8 ®
Edition 1.0 2017-03
INTERNATIONAL
STANDARD
NORME
INTERNATIONALE
Determination of certain substances in electrotechnical products –
Part 8: Phthalates in polymers by gas chromatography-mass spectrometry
(GC-MS), gas chromatography-mass spectrometry using a pyrolyzer/thermal
desorption accessory (Py/TD-GC-MS)
Détermination de certaines substances dans les produits électrotechniques –
Partie 8: Analyse des phtalates dans les polymères par chromatographie en
phase gazeuse-spectrométrie de masse (GC-MS), chromatographie en phase
gazeuse-spectrométrie de masse par pyrolyse/thermodésorption (Py/TD-GC-MS)
INTERNATIONAL
ELECTROTECHNICAL
COMMISSION
COMMISSION
ELECTROTECHNIQUE
INTERNATIONALE
ICS 31.020; 71.040.50 ISBN 978-2-8322-4144-8
– 2 – IEC 62321-8:2017 © IEC 2017
CONTENTS
FOREWORD . 6
INTRODUCTION . 8
1 Scope . 9
2 Normative references . 9
3 Terms, definitions and abbreviated terms . 10
3.1 Terms and definitions . 10
3.2 Abbreviated terms . 10
4 Principle . 11
5 Reagents and materials . 11
5.1 GC-MS method . 11
5.2 Py/TD-GC-MS method . 12
6 Apparatus . 12
6.1 GC-MS method . 12
6.2 Py/TD-GC-MS method . 13
7 Sampling . 14
7.1 General . 14
7.2 GC-MS method . 14
7.3 Py/TD-GC-MS method . 14
8 Procedure . 14
8.1 General instructions for the analysis . 14
8.1.1 Overview . 14
8.1.2 GC-MS method . 14
8.1.3 Py/TD-GC-MS method . 14
8.2 Sample preparation . 15
8.2.1 GC-MS method . 15
8.2.2 Py/TD-GC-MS method . 16
8.3 Instrumental parameters . 16
8.3.1 GC-MS method . 16
8.3.2 Py/TD-GC-MS method . 18
8.4 Calibrants . 18
8.5 Calibration . 19
8.5.1 GC-MS method . 19
8.5.2 Py/TD-GC-MS method . 20
9 Calculation of phthalate concentration . 21
9.1 GC-MS method . 21
9.2 Py/TD-GC-MS method . 22
10 Precision . 23
10.1 GC-MS method . 23
10.1.1 Threshold judgement . 23
10.1.2 Repeatability and reproducibility . 24
10.2 Py/TD-GC-MS method . 25
10.2.1 Screening judgement . 25
10.2.2 Repeatability and reproducibility . 26
11 Quality assurance and control . 27
11.1 General . 27
IEC 62321-8:2017 © IEC 2017 – 3 –
11.2 GC-MS method . 27
11.2.1 Performance . 27
11.2.2 Limit of detection (LOD) or method detection limit (MDL) and limit of
quantification (LOQ) . 28
11.3 Py/TD-GC-MS method . 29
11.3.1 Sensitivity . 29
11.3.2 Blank test . 29
11.3.3 Limit of detection (LOD) or method detection limit (MDL) and limit of
quantification (LOQ) . 29
12 Test report . 30
Annex A (informative) Determination of phthalates in polymers by ion attachment
mass spectrometry (IAMS) . 31
A.1 Principle . 31
A.2 Reagents and materials . 31
A.3 Apparatus .
...
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