Méthode de calcul de l'intensité de l'émission de dioxyde de carbone de la production de la fonte et de l'acier

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DRAFT INTERNATIONAL STANDARD
ISO/DIS 14404-4
ISO/TC 17 Secretariat: JISC
Voting begins on: Voting terminates on:
2019-12-04 2020-02-26
Calculation method of carbon dioxide emission intensity
from iron and steel production —
Part 4:
Guidance for using ISO 14404 family
ICS: 13.020.40; 77.080.01
THIS DOCUMENT IS A DRAFT CIRCULATED
FOR COMMENT AND APPROVAL. IT IS
THEREFORE SUBJECT TO CHANGE AND MAY
NOT BE REFERRED TO AS AN INTERNATIONAL
STANDARD UNTIL PUBLISHED AS SUCH.
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ISO/DIS 14404-4:2019(E)
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PROVIDE SUPPORTING DOCUMENTATION. ISO 2019
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ISO/DIS 14404-4:2019(E)
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ISO/DIS 14404-4:2019(E)
Contents Page

Foreword ..........................................................................................................................................................................................................................................v

Introduction ................................................................................................................................................................................................................................vi

1 Scope ................................................................................................................................................................................................................................. 1

2 Normative references ...................................................................................................................................................................................... 1

3 Terms and definitions ..................................................................................................................................................................................... 1

3.1 Emissions ..................................................................................................................................................................................................... 2

3.2 Gas fuel ........................................................................................................................................................................................................... 2

3.3 Liquid fuel ................................................................................................................................................................................................... 3

3.4 Solid fuel ....................................................................................................................................................................................................... 3

3.5 Auxiliary material ................................................................................................................................................................................. 4

3.6 Energy carriers ....................................................................................................................................................................................... 5

3.7 Ferrous containing materials ..................................................................................................................................................... 5

3.8 Alloys ............................................................................................................................................................................................................... 5

3.9 Product and by-product .................................................................................................................................................................. 5

3.10 Others .............................................................................................................................................................................................................. 6

4 Symbols .......................................................................................................................................................................................................................... 7

5 Principles ..................................................................................................................................................................................................................... 7

5.1 General ........................................................................................................................................................................................................... 7

5.2 Relevance ..................................................................................................................................................................................................... 8

5.3 Completeness ........................................................................................................................................................................................... 8

5.4 Consistency ................................................................................................................................................................................................ 8

5.5 Accuracy ........................................................................................................................................................................................................ 8

5.6 Transparency ............................................................................................................................................................................................ 8

6 Characteristic features of ISO 14404 Family ........................................................................................................................... 8

7 Guidance for applying ISO 14404 family to all types of steel plants ...............................................................9

7.1 General ........................................................................................................................................................................................................... 9

7.2 Application of ISO 14404 family for steel plants not covered in Parts 1, 2 and 3 ......................11

7.2.1 Steel Plants with iron making processes other than BF and DRI .................. ......................11

7.2.2 Steel Plants with multiple process routes ...............................................................................................11

7.2.3 Steel plants which purchase pig iron from outside .........................................................................11

7.2.4 Steel plants which purchase all or part of semi-finished steel product

from outside ......................................................................................................................................................................11

7.3 Guideline for making comparisons using ISO 14404 family ........................................................................15

8 Calculation using the Universal Calculation Sheet .........................................................................................................15

8.1 General ........................................................................................................................................................................................................15

8.2 Calculation procedure ....................................................................................................................................................................17

8.2.1 Data collection of crude steel production (or final steel production) ............................17

8.2.2 Data collection of direct and/or upstream CO emission sources .....................................17

8.2.3 Data collection of credit CO emissions sources ...............................................................................19

8.2.4 Calculation ..........................................................................................................................................................................20

9 Additional guidance to the entire ISO 14404 family ....................................................................................................23

9.1 Evaluation of Slag ...............................................................................................................................................................................23

9.2 Explanation of emission factors for by-product gases (informative Annex in part 1) ...........23

9.2.1 General...................................................................................................................................................................................23

9.2.2 Explanation of emission factors based on world average electricity equivalent ..24

9.2.3 Explanation of emission factors based on natural gas equivalent .....................................25

9.2.4 Evaluation of stock ......................................................................................................................................................26

9.3 Selection of calorific values and emission factors for electricity and fuel ........................................26

Annex A (informative) Calculation of energy consumption and intensity .................................................................27

Annex B (informative) Application of ISO 14404 family ...............................................................................................................30

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ISO/DIS 14404-4:2019(E)

Annex C (informative) Universal Calculation Sheet ...........................................................................................................................31

Annex D (informative) An example of template for using different emission factors or

emission sources from Table 7 ...........................................................................................................................................................35

Bibliography .............................................................................................................................................................................................................................37

iv © ISO 2019 – All rights reserved
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ISO/DIS 14404-4:2019(E)
Foreword

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Attention is drawn to the possibility that some of the elements of this document may be the subject of

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© ISO 2019 – All rights reserved v
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ISO/DIS 14404-4:2019(E)
Introduction

The steel industry recognizes the urgent need to take actions concerning climate change. Slowing

and halting global warming requires reductions in GHG emissions on a global scale. To play a part in

achieving these reductions, it is necessary for steel plants to identify the amount of CO emitted during

the production of steel products, in order to identify next opportunities for reduction of CO .

As the calculation methods for CO emission and intensity in iron and steel industry, ISO 14404-1 (for

steel plants with blast furnace) and ISO 14404-2 (steel plants with electric arc furnace) were published

in 2013, and ISO 14404-3 (for steel plants with electric arc furnace and coal-based or gas-based direct

reduction iron facility) was published in 2017.

ISO 14404 family specifies calculation methods for the carbon dioxide (CO ) intensity of a steel plant

from the amounts of the major inputs (purchased items) and outputs (sold items), such as natural

resources, intermediate products, and energy. The concept is shown in Figure 1 —.

Figure 1 — Conceptual diagram of calculation method in ISO 14404 family

This calculation method only uses basic imports and exports that are commonly measured and recorded

by the plants; thus, the method requires neither the measurement of the specific efficiency of individual

equipment or processes nor dedicated measurements of the complex flow and recycling of materials

and waste heat. In this way, the calculation method ensures its simplicity and universal applicability

without requiring steel plants to install additional dedicated measuring devices or to collect additional

dedicated data other than commonly used data in the management of plants.

In addition, ISO 14404 family provides the guidance to consider the activities in the boundary that

are located outside of the site boundary by considering the upstream emissions of the intermediate

products produced in such “outsourced steel production activities”. The conceptual diagram of

boundary and site boundary is shown in Figure 2 —.
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ISO/DIS 14404-4:2019(E)
Figure 2 — Conceptual diagram of boundary and site boundary

Intermediate products with possibilities of considering upstream emissions include the following:

— Electricity / steam

— Substances produced in the basic activities existing in the target process route (eg purchased coke

used in the BF - BOF route)

— Substances that substitute the iron source of the process route even if they do not exist in the target

process route (eg purchased DRI used in the BF - BOF route)

ISO 14404 family is based on “CO Emissions Data Collection User Guide” established by the World

Steel Association (worldsteel), which consists more than 161 major steel companies in 60 countries

and regions of the world. Actual data collection among worldsteel members has been conducted yearly

based upon this guide since 2007. While ISO 14404 family and worldsteel "CO Emissions Data Collection

User Guide" share the same concept, they have different characteristics where the worldsteel’s User

Guide provides the method suitable for collecting data from steel plants across the world in a uniform

way, and ISO 14404 family provide methods suitable for the evaluation of CO intensity of steel plant for

each process route (i.e. combination of iron source and steelmaking process).

Therefore, while worldsteel method applies common boundary and CO emission factors to all

steelworks regardless of their process routes, ISO 14404 family defines the boundary, CO emission

factors and intermediate products for which upstream emissions are considered for each of the process

routes, such as BF-BOF (part 1), Scrap-EAF (part 2) and DRI-EAF (part 3).

ISO 14404 part 4 provides the guidance for calculating the CO intensity at all types of steel plants,

including steel plants with process routes not covered in ISO 14404-1, 2, 3 (steel plants with process

routes other than BF - BOF, Scrap - EAF, DRI - EAF) as well as steel plants with multiple process routes,

by defining the boundary, CO emission factors and the intermediate products for which upstream

emissions are considered for each of all types of steel plants. ISO 14404 part 4 also includes Universal

Calculation Sheet, which covers all relevant emission sources from ISO 14404-1, 2, 3, to assist the

calculation of CO emissions.

Moreover, ISO 14404 part 4 provides additional guidance to the entire ISO 14404 family for the

following topics, which have not been covered by ISO 14404-1, 2, 3.
a) Evaluation of exported slags
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ISO/DIS 14404-4:2019(E)
b) Evaluation of by-product gas
c) Evaluation of stock
d) Selection of calorific values and emission factors for electricity and fuel
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DRAFT INTERNATIONAL STANDARD ISO/DIS 14404-4:2019(E)
Calculation method of carbon dioxide emission intensity
from iron and steel production —
Part 4:
Guidance for using ISO 14404 family
1 Scope

ISO 14404 part 4 provides the guidance for calculating the CO intensity at steel plants with all types

of process routes, by defining the boundary, CO emission factors and the intermediate products for

which upstream emissions are considered for all types of process routes. In particular, ISO 14404 part

4 provides the guidance to apply ISO 14404 family to following types of steel plants. ISO 14404 part 4

also includes Universal Calculation Sheet, which covers all relevant emission sources from ISO 14404-1,

2, 3, to assist the calculation of CO emissions.
i. Steel plants with different process routes from ISO 14404-1, 2, 3 (7.2.1)
ii. Steel plants with more than one process route (7.2.2)
iii. Steel plants purchasing pig iron from the outside (7.2.3)

iv. Steel plants and rerollers purchasing part or all of crude steel from outside (7.2.4)

Moreover, ISO 14404 part 4 provides additional guidance to the entire ISO 14404 family for the

following topics.
a) Evaluation of exported slags
b) Evaluation of by-product gas
c) Evaluation of stock
d) Selection of calorific values and emission factors for electricity and fuel

Conversion to energy consumption and to consumption efficiency can be obtained using Annex A.

While the use of the calculation result is outside Scope of this standard, appropriate applications and

inappropriate application are recommended in Annex B.
2 Normative references
There are no normative references in this document.
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

— ISO Online browsing platform: available at http:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
© ISO 2019 – All rights reserved 1
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ISO/DIS 14404-4:2019(E)
3.1 Emissions
3.1.1
emission source
process emitting CO during the production of steel products

Note 1 to entry: There are three categories of CO emission sources: direct, upstream and credit. Examples of

emission sources that are subject to this document are given in 3.1.2, 3.1.3 and 3.1.4.

3.1.2
direct CO emission
CO emissions from steel production activity inside the boundary

Note 1 to entry: Direct CO emission is categorized as “direct GHG emissions” in ISO 14064-1.

3.1.3
upstream CO emission

CO emissions from imported material related to outsourced steel production activities outside the site

boundary and from imported electricity and steam into the site boundary

Note 1 to entry: CO emissions from imported material in this term are categorized as “other indirect GHG

emissions” in ISO 14064-1.

Note 2 to entry: CO emissions from imported electricity and steam in this term are categorized as “energy

indirect GHG emissions” in ISO 14064-1.
3.1.4
credit CO emission
CO emission that corresponds to exported material and electricity or steam

Note 1 to entry: Credit CO emission is categorized as “direct GHG emissions” in ISO 14064-1.

3.2 Gas fuel
3.2.1
natural gas

mixture of gaseous hydrocarbons, primarily methane, naturally occurring in the earth and used

principally as a fuel
3.2.2
coke oven gas
COG
gas recovered from coke oven
3.2.3
blast furnace gas
BFG
gas recovered from blast furnace
3.2.4
BOF gas
LDG
gas recovered from basic oxygen furnace (Linze Donawitz converter)
Note 1 to entry: BOF: basic oxygen furnace
3.2.5
town gas
fuel gas manufactured for domestic and industrial use
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ISO/DIS 14404-4:2019(E)
3.2.6
COREX gas
gas recovered from COREX
3.2.7
Other gas

gas other than natural gas, coke oven gas, blast furnace gas, BOF gas and town gas

3.3 Liquid fuel
3.3.1
heavy oil
No. 4 to No.6 fuel oil defined by ASTM
Note 1 to entry: ASTM: American Society for Testing and Materials.
3.3.2
light oil
No. 2 to No.3 fuel oil defined by ASTM
3.3.3
kerosene
paraffin (oil)
3.3.4
LPG
liquefied petroleum gas
3.4 Solid fuel
3.4.1
coking coal
coal for making coke, including anthracite
3.4.2
BF injection coal
pulverized coal injection (PCI) coal, including anthracite
Note 1 to entry: BF: blast furnace
3.4.3
sinter coal
BOF coal
coal for sinter/BOF, including anthracite
3.4.4
EAF coal
coal used for an electric arc furnace (EAF), including anthracite
3.4.5
steam coal
boiler coal for producing electricity and steam, including anthracite
3.4.6
coke
solid carbonaceous material
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ISO/DIS 14404-4:2019(E)
3.4.7
charcoal
devolatilized or coked carbon neutral materials
EXAMPLE Trees, plants.
3.4.8
SR/DRI coal

coal used for smelting reduction (SR, including COREX)/ direct reduction iron (DRI), including

anthracite
3.4.9
Other coal

coal other than steam coal, coking coal, BF injection coal, sinter coal, EAF coal, coke, charcoal and SR/

DRI coal
3.5 Auxiliary material
3.5.1
limestone
calcium carbonate
CaCO
3.5.2
burnt lime
CaO
3.5.3
crude dolomite
calcium magnesium carbonate
CaMg(CO )
3 2
3.5.4
burnt dolomite
CaMgO
3.5.5
electric arc furnace graphite electrodes
EAF graphite electrodes
net use of EAF graphite electrodes or attrition loss
3.5.6
nitrogen

inert gas separated from air at an oxygen plant, imported from outside the boundary or exported to

outside the boundary
3.5.7
argon

inert gas separated from air at an oxygen plant, imported from outside the boundary or exported to

outside the boundary
3.5.8
oxygen

gas separated from air at an oxygen plant, imported from outside the boundary or exported to outside

the boundary
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ISO/DIS 14404-4:2019(E)
3.6 Energy carriers
3.6.1
electricity

electricity imported from outside the boundary or exported to outside the boundary

3.6.2
steam
pressurized water vapour imported from/exported to outside the boundary
3.7 Ferrous containing materials
3.7.1
pellets
agglomerated spherical iron ore calcinated by rotary kiln
3.7.2
sinter

bulk iron ore sintered by baking mixture of fine iron ore, coke breeze and pulverized lime

3.7.3
hot metal

intermediate liquid iron products containing 3 % to 5 % by mass carbon produced by smelting iron ore

with equipment such as blast furnace
3.7.4
cold iron
solidified hot metal as an intermediate solid iron product
3.7.5
scrap
used steel available for reprocessing
3.7.6
gas-based DRI
direct reduced iron (DRI) reduced by a reducing gas such as reformed natural gas
3.7.7
coal-based DRI
direct reduced iron (DRI) reduced by coal
3.8 Alloys
3.8.1
ferro-nickel
alloy of iron and nickel
3.8.2
ferro-chromium
alloy of iron and chromium
3.8.3
ferro-molybdenum
alloy of iron and molybdenum
3.9 Product and by-product
3.9.1
CO for external use
CO exported to outside the boundary
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ISO/DIS 14404-4:2019(E)
3.9.2
coal tar

by-products of the carbonization of coal to coke, containing complex and variable mixtures of phenols

and polycyclic aromatic hydrocarbons
3.9.3
coal light oil
benzole

light oil recovered by COG gas purification, consisting mainly of benzene, toluene and xylene (BTX)

3.9.4
BF slag to cement
blast furnace slag supplied to cement industry
3.9.5
BOF slag to cement
BOF slag supplied to cement industry
3.10 Others
3.10.1
other emission source

other related emission sources such as plastics, scraps, desulfurization additives, alloys, fluxes for

secondary metallurgy, dust, sludge, etc.
3.10.2
boundary

limit of activity used to calculate CO emissions intensity for steel production activities

Note 1 to entry: boundary may be different from the site boundary
3.10.3
site boundary

boundary defined by the target steel production site for the calculation of CO emission and intensity

3.10.4
process route

route of steel production defined by the combination of iron source and steel making process

3.10.5
EAF
electric arc furnace
furnace that melts and refines iron-bearing material into steel
3.10.6
casting

pouring steel directly from a ladle through a tundish into a mould shaped to form billets, blooms or

slabs, or pouring steel from a ladle into a mould shaped to form ingots
3.10.7
lime kiln

kiln used to produce burnt lime (3.5.2) by the calcination of limestone (calcium carbonate)

3.10.8
oxygen plant
cryogenic air separator to produce high-purity oxygen
3.10.9
steam boiler
boiler for production of steam
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ISO/DIS 14404-4:2019(E)
3.10.10
power plant
plant that generates electricity
3.10.11
RHF
reheating furnace

heating furnace used in hot rolling mills to heat the steel stock (billets, blooms or slabs)

3.10.12
hot rolling
rolling at elevated temperature
3.10.13
cold rolling
rolling at room temperature
3.10.14
coating

covering steel with another material (tin, chrome, zinc, etc.), primarily for corrosion resistance

Note 1 to entry: Coating materials may include tin, chrome, zinc, etc.
4 Symbols
The symbols used in this part of ISO 14404 are given in Table 1 —.
Table 1 — Symbols
Symbols Unit Description
Ed,CO tons (or tonnes) of CO Direct CO emissions
2 2 2
Eu,CO tons (or tonnes) of CO Upstream CO emissions
2 2 2
Ec,CO tons (or tonnes) of CO Credit CO emissions
2 2 2
ECO ,annual tons (or tonnes) of CO Annual CO emissions
2 2 2
ICO tons (or tonnes) of CO per ton CO intensity factor
2 2 2

Kt,d,CO tons (or tonnes) of CO per unit Emission factor for calculation of direct CO emissions

2 2 2

Kt,u,CO tons (or tonnes) of CO per unit Emission factor for calculation of upstream CO emissions

2 2 2

Kt,c,CO tons (or tonnes) of CO per unit Emission factor for calculation of credit CO emissions

2 2 2
P — Annual crude steel production
Qt,d,CO — Quantities of direct CO emission sources
2 2
Qt,u,CO — Quantities of upstream CO emission sources
2 2
Qt,c,CO — Quantities of credit CO emission sources
2 2
5 Principles
5.1 General

The application of principles is a base to ensure that calculated CO intensity is effectively usable for

steel producers to assess their production site efficiency universally without specificity of product

configurations, location of site, and individual facility used in the site.
...

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