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ASTM B532-85(2021)

(Specification)

Standard Specification for Appearance of Electroplated Plastic Surfaces

Standard Specification for Appearance of Electroplated Plastic Surfaces

ABSTRACT
This specification limits the amounts and types of visual defects that can be tolerated on decoratively electroplated surfaces of plastic products. The appearance of surfaces will be separately evaluated depending on the prominence of the surface under conditions of ordinary use. The classifications are: surface A; surface B; and surface C. The part under test shall be evaluated in the same relative position as it will normally be viewed under usual conditions of use.
SIGNIFICANCE AND USE
5.1 Where electroplated plastics are used for decorative purposes, the appearance after plating is important. This standard provides a means of evaluating the appearance of the substrate and the coating.
SCOPE
1.1 This specification limits the amounts and types of visual defects that can be tolerated on decoratively electroplated surfaces of plastic products. The quantity of defects permitted shall be specified by the purchaser.  
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Mar-2021
ICS
25.220.40 - Metallic coatings
Technical Committee
B08 - Metallic and Inorganic Coatings
Drafting Committee
B08.05 - Decorative Coatings
Current Stage
Ref Project

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ASTM B532-85(2021) - Standard Specification for Appearance of Electroplated Plastic SurfacesASTM B532-85(2021) - Standard Specification for Appearance of Electroplated Plastic Surfaces
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ASTM B532-85(2021) - Standard Specification for Appearance of Electroplated Plastic Surfaces
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: B532 −85 (Reapproved 2021) Endorsed by American
Electroplaters Society
Endorsed by National
Association of Metal Finishers
Standard Specification for
1
Appearance of Electroplated Plastic Surfaces
This standard is issued under the fixed designation B532; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 4.1.3 Surface C—The surface not readily seen by the
observer except at an angle, or by special observation.
1.1 This specification limits the amounts and types of visual
4.1.4 Surface D—The surface not visible to the observer
defects that can be tolerated on decoratively electroplated
under conditions of normal use.
surfaces of plastic products. The quantity of defects permitted
shall be specified by the purchaser.
5. Significance and Use
1.2 This international standard was developed in accor-
5.1 Where electroplated plastics are used for decorative
dance with internationally recognized principles on standard-
purposes, the appearance after plating is important. This
ization established in the Decision on Principles for the
standard provides a means of evaluating the appearance of the
Development of International Standards, Guides and Recom-
substrate and the coating.
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
6. Method of Evaluation
2. Referenced Documents
6.1 The part under test shall be evaluated in the same
2
2.1 ASTM Standards:
relative position as it will normally be viewed under usual
B374 Terminology Relating to Electroplating
conditions of use.
D883 Terminology Relating to Plastics
6.2 After proper positioning, the part under test shall be
3. Terminology
evaluated at a distance of not less than 600 mm nor more than
900 mm from the observer, using diffused daylight-type
3.1 Definitions—See Terminology B374 for terms relating
2
fluorescent lighting or 1500 to 1600 lm/m at the surface of the
to electroplating. For terms not relating to electroplating, see
part being inspected.
Terminology D883.
6.3 Theobservershallhave20/20visionatadistanceof600
4. Classification of Surfaces
to 900 mm, corrected with eyeglasses if necessary.
4.1 The appearance of surfaces will be separately evaluated
depending on the prominence of the surface under conditions
7. Appearance Guide
of ordinary use.
7.1 Table 1 limits the extent to which various defects are
4.1.1 Surface A—The surface that appears most prominent
acceptable on each of the four surface classifications described
to the observer, or most likely to be noticed at first glance.
in Section 4.
4.1.2 Surface B—The surface (usually adjacent to Surface
A) which is somewhat less prominent to the observer. 7.2 In Table 1 the term “some” assumes that the defects
cited are not outstanding, too numerous, or located too closely
together. The specific number of defects permitted, and their
1
This specification is under the jurisdiction of ASTM Committee B08 on
spacing, shall be specified by the purchaser. The term “no”
Metallic and Inorganic Coatings and is the direct responsibility of Subcommittee
B08.05 on Decorative
...

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ASTM B489-85(2023)(Practice)
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4.1 The routine measurement of the ductility of electrodeposited and autocatalytically deposited metal coatings can be useful in process control, especially when the electroplating process is used for decorative and engineering purposes.
SCOPE
1.1 This practice covers a test procedure for determining the ductility of electrodeposited and autocatalytically deposited coatings on sheet or strip basis metals. The purpose of the test is to determine the resistance of metal coatings to cracking during distortion.2  
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ABSTRACT
This specification covers the requirements for a coating that is a mixture of cadmium and tin mechanically deposited on metal products. The coating shall be 45 to 75 mass % cadmium, the remainder tin. All steel parts that have ultimate tensile strength of 1000 MPa and above and that contain tensile stresses caused by machining, grinding, straightening, or cold forming operation shall be given a stress relief heat treatment prior to cleaning and metal deposition. High-strength steels that have heavy oxide or scale shall be cleaned before application of the coating in accordance with guide B 242. Chromate treatment for Type II shall be done in a solution containing hexavalent chromium. The cadmium-tin coating shall be sufficiently adherent to the basis metal to pass the prescribed testing. Steel springs and other high-strength steel parts shall be free from hydrogen embrittlement. The coating shall be uniform in appearance and substantially free of blisters, pits, nodules, flaking and other defects that can adversely affect the function of the coating. Chemical composition of the cadmium-tin coating shall be determined when required on the purchase order by procedures given in methods E 87 or test methods E 396. The thickness of the coating shall be determined by the microscopical method, the magnetic method, or the beta backscatter method as applicable. Chromate conversion coatings of cadmium-tin both have an essentially silvery-white appearance. Adhesion of the cadmium-tin deposit to the basis metal shall be tested in a manner that is consistent with the service requirements of the coated article. Coated parts to be tested for the absence of embrittlement from cleaning shall be tested for brittle failure in accordance with a suitable method.
SCOPE
1.1 This specification covers the requirements for a coating that is a mixture of cadmium and tin mechanically deposited on metal products. The coating is provided in various thicknesses up to and including 12 μm.  
1.2 Mechanical deposition greatly reduces the risk of hydrogen embrittlement and is suitable for coating bores and recesses in many parts that cannot be conveniently plated electrolytically. (See Appendix X1.)  
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1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazards statements, see Section 7.  
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ASTM B696-00(2023)(Specification)
Standard Specification for Coatings of Cadmium Mechanically Deposited

ABSTRACT
This specification covers the requirements for coating of cadmium mechanically deposited on metal products. Cadmium coatings shall classified on the basis of thickness, as follows: Class 12; Class 8; and Class 5. Cadmium coatings shall be identified as Type I and Type II on the basis of supplementary treatment required. The coating shall be uniform in appearance and free of blisters, pits, nodules, flaking, and other defects that can adversely affect the function of the coating. All steel parts that have ultimate tensile strength and that contains tensile stresses caused by machining, grinding, straightening, or cold-forming operation shall be given a stress relief heat treatment prior to cleaning and metal deposition. The minimum hours to failure (appearance of white corrosion products and red rust for mechanically deposited cadmium coatings on iron and steel) of Type I and Type II coatings shall be indicated to guarantee satisfactory performance. The test specimen shall undergo adhesion, corrosion resistance, and appearance tests. The thickness of the coating shall be determined by the microscopical method, or the magnetic method, or the beta backscatter method, as applicable.
SCOPE
1.1 This specification covers the requirements for a coating of cadmium mechanically deposited on metal products. The coating is provided in various thicknesses up to and including 12 μm.  
1.2 Mechanical deposition greatly reduces the risk of hydrogen embrittlement and is suitable for coating bores and recesses in many parts that cannot be conveniently electroplated (see Appendix X3).  
1.3 Cadmium coatings are usually applied to provide engineering properties and corrosion resistance. The performance of a cadmium coating depends largely on its thickness and the kind of environment to which it is exposed. Without proof of satisfactory correlation, accelerated tests such as the salt spray (fog) test cannot be relied upon to predict performance in other environments, nor will these serve as comparative measures of the corrosion resistance afforded by coatings of different metals. Thus, although there is a marked superiority of cadmium coatings over zinc coatings of equal thickness in the salt spray test, this is often not the case under conditions of use, so that further testing in the service environment should be conducted.  
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1.5 Warning—Cadmium is toxic and must not be used in a coating for articles that can come into contact with food or beverages, or for dental or other equipment that can be inserted into the mouth. Consult appropriate agencies for regulations in this connection.  
1.6 Warning—Because of the toxicity of cadmium vapors and cadmium oxide fumes, cadmium-coated articles must not be used at temperatures of 320 °C and above. They must not be welded, spot-welded, soldered, or otherwise strongly heated without adequate ventilation that will efficiently remove all toxic fumes.  
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Standard Test Method for Corrosion Testing of Decorative Electrodeposited Coatings by the Corrodkote Procedure

SIGNIFICANCE AND USE
4.1 Nickel/chromium and copper/nickel/chromium electrodeposited coatings are widely used for decorative and protective applications. The Corrodkote test provides a method of controlling the quality of electroplated articles and is suitable for manufacturing control, as well as research and development.
SCOPE
1.1 This test method covers the Corrodkote2 method of evaluating the corrosion performance of copper/nickel/chromium and nickel/chromium coatings electrodeposited on steel, zinc alloys, aluminum alloys, plastics and other substrates.  
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ABSTRACT
This specification covers the requirements for electrodeposited cadmium coatings on products of iron, steel, and other metals. Cadmium coatings are used for corrosion resistance and for corrosion prevention of the basis metal part. The as deposited coating (Type I) is useful for the lowest cost protection in a mild or noncorrosive environment where early formation of white corrosion products is not detrimental or harmful to the function of a component. The prime purpose of the supplementary chromate finishes (Types II and III) on the electroplated cadmium is to increase corrosion resistance.Electrodeposited cadmium coatings shall be classified on the basis of thickness as Class 25, 12, 8, and 5. The coating shall be essentially pure cadmium produced by electrodeposition usually from an alkaline cyanide solution. The basis metal shall be subjected to such cleaning procedures as necessary to ensure a surface satisfactory for subsequent electroplating. Cadmium shall be deposited directly on the basis metal part without an undercoat of another metal except when the part is either stainless steel or aluminum and its alloys. The plating shall be applied after all basis metal heat treatments and mechanical operations. The thickness of the coating everywhere on the significant surface shall conform to the requirements of the specified class. The cadmium coating shall be sufficiently adherent to the basis metal to pass the tests. The supplementary Type II chromate film shall be adherent, nonpowdery, and abrasion resistant. The thickness of electrodeposited cadmium coatings shall be determined by the applicable test methods.
SCOPE
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ASTM B650-95(2023)(Specification)
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ABSTRACT
This specification covers the requirements for electrodeposited chromium coatings (sometimes referred to as functional or hard chromium) applied to ferrous alloy substrates for engineering applications, particularly for increasing wear, abrasion, fretting, and corrosion resistance; for reducing galling or seizing, and static and kinetic friction; and for building up undersize or worn parts. Coatings shall be classified according to their thickness. Coatings shall be sampled, tested, and shall conform accordingly to specified requirements as to appearance, stress relief and hydrogen embrittlement treatment, thickness (to measured either by microscopical, magnetic, coulometric, or X-ray spectrometry method), adhesion (to be assessed either by bend, file, heat and quench, or push test), porosity (to be examined either by ferroxyl, neutral salt spray, or copper sulfate test), workmanship, and packaging.
SCOPE
1.1 This specification covers the requirements for electrodeposited chromium coatings applied to ferrous alloys for engineering applications.  
1.2 Electrodeposited engineering chromium, which is sometimes called “functional” or “hard” chromium, is usually applied directly to the basis metal and is much thicker than decorative chromium. Engineering chromium is used for the following:  
1.2.1 To increase wear and abrasion resistance,  
1.2.2 To increase fretting resistance,  
1.2.3 To reduce static and kinetic friction,  
1.2.4 To reduce galling or seizing, or both, for various metal combinations,  
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1.2.6 To build up undersize or worn parts.  
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SCOPE
1.1 This specification covers the requirements for electrodeposited zinc iron alloy coatings on metals.  
1.2 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following precautionary caveat pertains to the test method portion only, Section 8, of this specification:  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM B689-97(2023)(Specification)
Standard Specification for Electroplated Engineering Nickel Coatings

ABSTRACT
This specification covers the requirements for electroplated nickel coatings applied to metal products for engineering applications (for example, for use as a buildup for mismachined or worn parts), for electronics applications (including as underplates in contacts or interconnections), and in certain joining applications. Coatings shall be available in any one of the following types: Type 1, coatings electroplated from solutions not containing hardeners, brighteners, or stress control additives; Type 2, electrodeposits used at moderate temperatures, and contain sulfur or other codeposited elements or compounds that are present to increase the hardness, refine grain structure, or control internal stress; and Type 3, electroplates containing dispersed submicron particles such as silicon carbide, tungsten carbide, and aluminum oxide that are present to increase hardness and wear resistance at specified temperatures. Metal parts shall undergo pre- and post-coating treatments to reduce the risk of hydrogen embrittlement, and peening. Coatings shall be sampled, tested, and conform accordingly to specified requirements as to appearance, thickness (measured either destructively by microscopical or coulometric method, or nondestructively by magnetic or X-ray method), adhesion (examined either by bend, file, heat and quench, or push test), porosity (assessed either by hot water, ferroxyl, or flowers of sulfur test), workmanship, and hydrogen embrittlement relief.
SCOPE
1.1 This specification covers the requirements for electroplated nickel coatings applied to metal products for engineering applications, for example, for use as a buildup for mismachined or worn parts, for electronic applications, including as underplates in contacts or interconnections, and in certain joining applications.  
1.2 Electroplating of nickel for engineering applications (Note 1) requires technical considerations significantly different from decorative applications because the following functional properties are important:  
1.2.1 Hardness, strength, and ductility,  
1.2.2 Wear resistance,  
1.2.3 Load bearing characteristics,  
1.2.4 Corrosion resistance,  
1.2.5 Heat scaling resistance,  
1.2.6 Fretting resistance, and  
1.2.7 Fatigue resistance.  
Note 1: Functional electroplated nickel coatings usually contain about 99 % nickel, and are most frequently electrodeposited from a Watts nickel bath or a nickel sulfamate bath. Typical mechanical properties of nickel electroplated from these baths, and the combined effect of bath operation and solution composition variables on the mechanical properties of the electrodeposit are given in Guide B832. When electroplated nickel is required to have higher hardnesses, greater wear resistance, certain residual stress values and certain leveling characteristics, sulfur and other substances are incorporated in the nickel deposit through the use of certain addition agents in the electroplating solution. For the effect of such additives, see Section 4 and Annex A3. Cobalt salts are sometimes added to the plating solution to produce harder nickel alloy deposits.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM B633-23(Specification)
Standard Specification for Electrodeposited Coatings of Zinc on Iron and Steel

ABSTRACT
This specification establishes the requirements for electrodeposited zinc coatings applied to iron or steel articles for corrosion protection purposes. Electrodeposited zinc-coated steel wires or sheets are not covered here. The coatings shall be provided in four standard thickness classes in the as-plated condition or with one of three types of supplementary finishes. The surfaces of the articles shall under go pre-plating basis metal cleaning, pre- and post-coating treatment for reducing the risk of hydrogen embrittlement, and reactivation and supplementary treatments. Coatings should be sampled, prepared, tested and conform accordingly to specified requirements as to appearance (luster and workmanship), thickness, adhesion, corrosion resistance, and hydrogen embrittlement.
SCOPE
1.1 This specification covers material and process requirements for electrodeposited zinc coatings applied to iron or steel articles to protect them from corrosion.  
1.2 This specification is not intended to provide the design activity with all the background needed to properly specify their zinc coating requirements. The users of Specification B633 are encouraged to review this specification in its entirety including the appendices, and access the supplementary papers, other standards, and published literature referenced herein and within other related references.  
1.3 The coatings are provided in four standard thickness classes (4.1), in the as-plated condition or with one of five types of supplementary finishes (4.2).  
1.4 High strength metals, including high strength steels having a tensile strength greater than 1700 MPa (247 ksi, 46 HRC) should not be zinc electroplated in accordance with this specification.  
1.5 It does not cover continuous processes for electrodeposited zinc coated steel wire or sheets (see Specification A591/A591M for sheets).  
1.6 For zinc electroplating of mechanical fasteners, the purchaser is encouraged to consider Specification F1941/F1941M.  
1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This standard has been revised to address RoHS requirements that seek to limit the exposure of workers and the public from exposure to toxic metals. Additional types V and VI have been added to permit non-chromate passivate treatments to be used in replacement of hexavalent chromium.  
1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM B840-22(Specification)
Standard Specification for Electrodeposited Coatings of Zinc Cobalt Alloy Deposits

ABSTRACT
This specification covers the requirements for electrodeposited zinc cobalt alloy coatings on metals. The coating class is Class 1 and five coating types are Type a, Type b, Type c, Type d, and Type e. The metal to be plated shall be subjected to such cleaning, pickling, and electroplating procedures. Coating requirements include: substrate, nature of coating, appearance, thickness, adhesion, corrosion resistance, and pre- and post-coating treatments of iron and steel for reducing the risk of hydrogen embrittlement. Adhesion, porosity, corrosion resistance, or appearance tests shall be made.
SCOPE
1.1 This specification covers the requirements for electrodeposited zinc cobalt alloy coatings on metals.  
1.2 The following precautionary caveat pertains to the test method portion only, Section 8, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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