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ASTM D3257-06(2012)

(Test Method)

Standard Test Methods for Aromatics in Mineral Spirits by Gas Chromatography (Withdrawn 2021)

Standard Test Methods for Aromatics in Mineral Spirits by Gas Chromatography (Withdrawn 2021)

SIGNIFICANCE AND USE
4.1 These test methods were developed to measure the types and amounts of aromatics in mineral spirits to determine compliance with air pollution regulations that restrict the aromatic content of solvents. They have been demonstrated to be workable and to produce accurate results. However, due to the sensitivity of the tests to operating variables, some laboratories having limited experience with gas chromatographic analyses of hydrocarbons may experience difficulty in performing the tests.
SCOPE
1.1 These test methods cover the determination of ethylbenzene and total eight-carbon (C8) and heavier aromatics in the concentration range from 0.1 to 30 % in mineral spirits having a distillation range from 149 to 210°C (300 to 410°F) as determined by Test Method D86. The procedures permit the identification and calculation of concentrations of aromatic components to 0.1 volume %.  
1.2 It is recognized by analytical chemists that a single column gas chromatography analysis of an unknown sample is risky. In such cases, multiple and different analytical techniques must be used for absolutely positive identification, for example, several different gas chromatography columns, gas chromatography/mass spectrometer, or gas chromatography/infrared, etc. In these test methods the material is known and is clearly defined.  
1.3 Oxygenated compounds, if present, may interfere and cause erroneous results. Such oxygenated compounds are not normally present in mineral spirits.  
1.4 Three test methods are covered as follows:  
1.4.1 Test Method A, measurement of ethylbenzene content, C8 plus higher aromatics (except ethylbenzene), and total aromatics by means of a single packed column gas chromatographic analysis.  
1.4.2 Test Method B, measurement of ethylbenzene content by means of a rapid packed column gas chromatographic analysis.  
1.4.3 Test Method C, measurement of ethylbenzene content, C8 plus higher aromatics (except ethylbenzene) and total aromatics by means of a capillary column gas chromatographic analysis.  
1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.6 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.7 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-May-2012
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

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ASTM D3257-06(2012) - Standard Test Methods for Aromatics in Mineral Spirits by Gas Chromatography (Withdrawn 2021)ASTM D3257-06(2012) - Standard Test Methods for Aromatics in Mineral Spirits by Gas Chromatography (Withdrawn 2021)
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ASTM D3257-06(2012) - Standard Test Methods for Aromatics in Mineral Spirits by Gas Chromatography (Withdrawn 2021)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D3257 − 06 (Reapproved 2012)
Standard Test Methods for
1
Aromatics in Mineral Spirits by Gas Chromatography
This standard is issued under the fixed designation D3257; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* 1.6 For purposes of determining conformance of an ob-
served or a calculated value using this test method to relevant
1.1 Thesetestmethodscoverthedeterminationofethylben-
specifications, test result(s) shall be rounded off “to the nearest
zene and total eight-carbon (C ) and heavier aromatics in the
8
unit” in the last right-hand digit used in expressing the
concentration range from 0.1 to 30% in mineral spirits having
specificationlimit,inaccordancewiththerounding-offmethod
a distillation range from 149 to 210°C (300 to 410°F) as
of Practice E29.
determined by Test Method D86. The procedures permit the
identification and calculation of concentrations of aromatic 1.7 For hazard information and guidance, see the supplier’s
components to 0.1 volume%. Material Safety Data Sheet.
1.8 This standard does not purport to address all of the
1.2 It is recognized by analytical chemists that a single
safety concerns, if any, associated with its use. It is the
column gas chromatography analysis of an unknown sample is
responsibility of the user of this standard to establish appro-
risky. In such cases, multiple and different analytical tech-
priate safety and health practices and determine the applica-
niques must be used for absolutely positive identification, for
bility of regulatory limitations prior to use.
example, several different gas chromatography columns, gas
chromatography/mass spectrometer, or gas chromatography/
2. Referenced Documents
infrared,etc.Inthesetestmethodsthematerialisknownandis
2
clearly defined.
2.1 ASTM Standards:
D86Test Method for Distillation of Petroleum Products at
1.3 Oxygenated compounds, if present, may interfere and
Atmospheric Pressure
cause erroneous results. Such oxygenated compounds are not
E29Practice for Using Significant Digits in Test Data to
normally present in mineral spirits.
Determine Conformance with Specifications
1.4 Three test methods are covered as follows:
E180Practice for Determining the Precision of ASTM
1.4.1 Test Method A, measurement of ethylbenzene content,
Methods for Analysis and Testing of Industrial and Spe-
C plus higher aromatics (except ethylbenzene), and total 3
8
cialty Chemicals (Withdrawn 2009)
aromatics by means of a single packed column gas chromato-
E260Practice for Packed Column Gas Chromatography
graphic analysis.
2.2 ASTM Adjuncts:
1.4.2 Test Method B, measurement of ethylbenzene content
4
D2PP Determination of Precision and Bias Data
by means of a rapid packed column gas chromatographic
analysis.
3. Summary of Test Methods
1.4.3 Test Method C, measurement of ethylbenzene content,
3.1 The material, with an internal standard, is introduced
C plus higher aromatics (except ethylbenzene) and total
8
into a gas chromatographic column containing a strongly polar
aromaticsbymeansofacapillarycolumngaschromatographic
liquid phase. The polar phase has very little affinity for
analysis.
saturated and olefinic hydrocarbons while exhibiting a pro-
1.5 The values stated in SI units are to be regarded as the
nounced retention of aromatics. This selectivity, which is
standard. The values given in parentheses are for information
illustrated in Fig. 1 results in the elution of all saturated and
only.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
1
These test methods are under the jurisdiction of ASTM Committee D01 on contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Paint and Related Coatings, Materials, and Applications and are the direct Standards volume information, refer to the standard’s Document Summary page on
responsibility of Subcommittee D01.35 on Solvents, Plasticizers, and Chemical the ASTM website.
3
Intermediates. The last approved version of this historical standard is referenced on
Current edition approved June 1, 2012. Published August 2012. Originally www.astm.org.
4
approved in 1973. Last previous edition approved in 2006 as D3257–06. DOI: Available from ASTM International Headquarters. Order Adjunct No.
10.1520/D3257-06R12. ADJD6300.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
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