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ASTM D2693-07(2012)

(Specification)

Standard Specification for Ethylene Glycol (Withdrawn 2021)

Standard Specification for Ethylene Glycol (Withdrawn 2021)

ABSTRACT
This specification establishes the properties and requirements for ethylene glycol for use in the preparation of surface coatings. The material shall be appropriately sampled and tested, and shall conform to the following specified requirements: apparent specific gravity; color (Pt-Co units); distillation range (initial boiling point and dry point); water content; acidity as acetic acid; diethylene glycol content; and iron content.
SCOPE
1.1 This specification covers ethylene glycol for use in the preparation of surface coatings.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.

General Information

Status
Historical
Publication Date
30-Jun-2012
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

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ASTM D2693-07(2012) - Standard Specification for Ethylene Glycol (Withdrawn 2021)ASTM D2693-07(2012) - Standard Specification for Ethylene Glycol (Withdrawn 2021)
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ASTM D2693-07(2012) - Standard Specification for Ethylene Glycol (Withdrawn 2021)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D2693 −07 (Reapproved 2012)
Standard Specification for
1
Ethylene Glycol
This standard is issued under the fixed designation D2693; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 3. Properties
1.1 This specification covers ethylene glycol for use in the
3.1 Ethylene glycol shall conform to the following require-
preparation of surface coatings.
ments:
1.2 The values stated in SI units are to be regarded as
Apparent specific gravity
20/20°C 1.1151 to 1.1156
standard. No other units of measurement are included in this
or
standard.
25/25°C 1.1129 to 1.1134
Color, Pt-Co units, max (Note 1) 15
1.3 The following applies to all specified limits in this
Distillation range, 760 mm Hg
standard; for purposes of determining conformance with this
Initial boiling point, °C, min 193
Dry point, °C, max 204
standard, an observed value or a calculated value shall be
Water, wt %, max 0.2
rounded off “to the nearest unit” in the last right-hand digit
Acidity as acetic acid, wt %, max 0.005
used in expressing the specification limit, in accordance with
Diethylene glycol, wt %, max 1.0
Iron, ppm, max 1.0
the rounding-off method of Practice E29.
1.4 For specific hazard information and guidance, consult
NOTE 1—Instrumental Pt-Co color determined by Test Method D5386
has been shown to have no statistically significant difference from Pt-Co
the supplier’s Material Safety Data Sheet.
color determined by Test Method D1209. However, it is not known
2. Referenced Documents whether ethylene glycol was part of the sample set included in the
interlaboratory study.
2
2.1 ASTM Standards:
D1209 Test Method for Color of Clear Liquids (Platinum-
4. Sampling
Cobalt Scale)
D4052 Test Method for Density, Relative Density, and API
4.1 The material shall be sampled in accordance with
Gravity of Liquids by Digital Density Meter
Practice E300.
D5386 Test Method for Color of Liquids Using Tristimulus
Colorimetry
5. Test Methods
E29 Practice for Using Significant Digits in Test Data to
5.1 The properties enumerated in this specification shall be
Determine Conformance with Specifications
determined in accordance with Test Methods E202.
E202 Test Methods for Analysis of Ethylene Glycols and
Propylene Glycols
5.2 The specific gravity can also be determined in accor-
E300 Practice for Sampling Industrial Chemicals
dance with Test Method D4052.
2.2 U.S. Federal Specification:
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
6. Packaging and Package Marking
3
of
6.1 Package size shall be agreed upon by the purchaser and
1 the supplier.
This specification is under the jurisdiction of ASTM Commi
...

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5.1 In order to calculate the volatile organic content (VOC) of paints containing EPA exempt solvents, it is necessary to know the acetone, methyl acetate, or parachlorobenzotrifluoride content. This gas chromatographic test method provides a simple and direct way for measuring these solvents. Each analyte is measured with respect to a unique internal standard. For acetone, the internal standard used is acetone-d6, for methyl acetate it is methyl acetate-d3, and for PCBTF it is metachlorobenzotrifluoride (MCBTF). These unique analyte/internal standard pairs behave very nearly as single solvents with respect to evaporation rate and adsorption rate onto a coated silica fiber (SPME) but are separable on a gas chromatograph (GC) capillary column. The only critical analytical technique required for successfully performing this test method is the ability of an analyst to weigh a paint sample and internal standard, corresponding to the analyte of interest, into a septum capped vial. After weighing, solvent evaporation has no effect on the final value of the determination. Since whole paint is not injected into the gas chromatograph, the analytical system is never compromised.
SCOPE
1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
Note 1: Water-borne paints are internally standardized and diluted with water followed by addition of solid sodium chloride.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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