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ASTM D2627-08

(Specification)

Standard Specification for Diacetone Alcohol

Standard Specification for Diacetone Alcohol

ABSTRACT
This specification establishes the properties and requirements for diacetone alcohol. Specimens shall be suitably sampled and tested, and shall conform accordingly to specified values of the following properties: apparent specific gravity; color (Pt-Co units); distillation range (initial boiling point and dry point); nonvolatile matter content; odor; water content; acidity (free acid as acetic acid); and water solubility.
SCOPE
1.1 This specification covers diacetone alcohol.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
31-Oct-2008
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

Relations

Replaces
ASTM D2627-07 - Standard Specification for Diacetone Alcohol
Effective Date
01-Nov-2008

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D2627 −08
StandardSpecification for
1
Diacetone Alcohol
This standard is issued under the fixed designation D2627; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D1353 Test Method for Nonvolatile Matter in Volatile Sol-
2
vents for Use in Paint, Varnish, Lacquer, and Related
1.1 This specification covers diacetone alcohol.
Products
1.2 The following applies to all specified limits in this
D1364 Test Method for Water in Volatile Solvents (Karl
standard; for purposes of determining conformance with this
Fischer Reagent Titration Method)
standard, an observed value or a calculated value shall be
D1476 Test Method for Heptane Miscibility of Lacquer
rounded off “to the nearest unit” in the last right-hand digit
Solvents
used in expressing the specification limit, in accordance with
D1613 Test Method for Acidity in Volatile Solvents and
the rounding-off method of Practice E29.
Chemical Intermediates Used in Paint, Varnish, Lacquer,
and Related Products
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this D1722 Test Method for Water Miscibility of Water-Soluble
Solvents
standard.
D4052 Test Method for Density, Relative Density, and API
1.4 For specific hazard information and guidance, consult
Gravity of Liquids by Digital Density Meter
the supplier’s Material Safety Data Sheet.
D5386 Test Method for Color of Liquids Using Tristimulus
1.5 This standard does not purport to address all of the
Colorimetry
safety concerns, if any, associated with its use. It is the
E29 Practice for Using Significant Digits in Test Data to
responsibility of the user of this standard to establish appro-
Determine Conformance with Specifications
priate safety and health practices and determine the applica-
E300 Practice for Sampling Industrial Chemicals
bility of regulatory limitations prior to use.
2.2 U.S. Federal Specification:
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
2. Referenced Documents
4
of
3
2.1 ASTM Standards:
D56 Test Method for Flash Point by Tag Closed Cup Tester
3. Properties
D268 Guide for Sampling and Testing Volatile Solvents and
3.1 Diacetone alcohol shall conform to the following re-
Chemical Intermediates for Use in Paint and Related
quirements:
Coatings and Material
Apparent specific gravity
D1078 Test Method for Distillation Range of Volatile Or-
20/20°C 0.938–0.941 or
ganic Liquids
25/25°C 0.935–0.938
Color, Pt-Co units, max (Note 3) 25
D1209 Test Method for Color of Clear Liquids (Platinum-
Distillation, 760 mm Hg
Cobalt Scale)
Initial boiling point, °C, min 135
D1296 Test Method for Odor of Volatile Solvents and
Dry point, °C, max 172
Nonvolatile matter, g/100 mL, max 0.01
Diluents
Odor (see Note 1) nonresidual
Water, wt %, max (see Note 2) 0.1
Acidity (free acid as acetic acid), wt %, max 0.01
1
This specification is under the jurisdiction of the ASTM Committee D01 on Water solubility miscible with distilled water
in all proportions
Paint and Related Coatings, Materials, and Applications and is the direct responsi-
Flash point, °C, min 62.0
bility of Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermedi-
_____________
ates.
Current edition approved Nov. 1, 2008. Published November 2008. Originally
NOTE 1—Optional: Test for odor only when agreed upon as necessary
approved in 1967. Last previous edition approved in 2007 as D2627 – 07. DOI:
between the purchaser and the supplier.
10.1520/D2627-08.
2
This compound is also known as 4-hydroxy-4-methyl-pentanone-2.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
4
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,
Standards volume information, refer to the standard’s Document Summary page on Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http://
the ASTM website. www.dodssp.daps.mil.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D2627 − 08
NOTE 2—In some cases, Test Method D1476 may serve as a useful
5.1.3 Distillation Range—Test Method D1078, using a tem-
alternative method to determine the presence of water. Because it is a
perature measuring device having a range of 123 to 177°C and
qualitative test, its use would require agreement between user and
a resolution of 0.1°C.
supplier.
NOTE 3—Instrumental Pt-Co color determined by Tes
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D2627–07 Designation: D 2627 – 08
Standard Specification for
1
Diacetone Alcohol
This standard is issued under the fixed designation D 2627; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
2
1.1 This specification covers diacetone alcohol.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, consult the supplier’s Material Safety Data Sheet.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
3
2.1 ASTM Standards:
D 56 Test Method for Flash Point by Tag Closed Cup Tester
D 268 Guide for Sampling andTestingVolatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and
Material
D 1078 Test Method for Distillation Range of Volatile Organic Liquids
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 1296 Test Method for Odor of Volatile Solvents and Diluents
D 1353 Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products
D 1364 Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
D 1476 Test Method for Heptane Miscibility of Lacquer Solvents
D 1613 Test Method forAcidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related
Products
D 1722 Test Method for Water Miscibility of Water-Soluble Solvents
D 4052 Test Method for Density and Relative Density of Liquids by Digital Density Meter
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
E 29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E 300 Practice for Sampling Industrial Chemicals
2.2 U.S. Federal Specification:
4
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging of
3. Properties
3.1 Diacetone alcohol shall conform to the following requirements:
Apparent specific gravity
20/20°C 0.938–0.941 or
25/25°C 0.935–0.938
Color, Pt-Co units, max (Note 3) 25
1
This specification is under the jurisdiction of the ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved JuneNov. 1, 2007.2008. Published July 2007.November 2008. Originally approved in 1967. Last previous edition approved in 20022007 as
D 2627 – 027.
2
This compound is also known as 4-hydroxy-4-methyl-pentanone-2.
3
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
4
Available from Standardization Documents Order Desk, DODSSP, Bldg. 4, Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http://www.dodssp.daps.mil.
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D2627–08
Distillation, 760 mm Hg
Initial boiling point, °C, min 135
Dry point, °C, max 172
Nonvolatile matter, g/100 mL, max 0.01
Odor (see Note 1) nonresidual
Odor (see Note 1) nonresidual
Water, wt %, max (see Note 2) 0.1
Acidity (free acid as acetic acid), wt %, max 0.01
Water solubility miscible with distilled water
in all proportions
Flash point, °C, min 62.0
_____________
NOTE 1—Optional: Test for odor only when agreed upon as necessary between the purchaser and the supplier.
NOTE 2—In some cases, Test Method D 1476may serve as a useful alternative method to de
...

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5.1 In order to calculate the volatile organic content (VOC) of paints containing EPA exempt solvents, it is necessary to know the acetone, methyl acetate, or parachlorobenzotrifluoride content. This gas chromatographic test method provides a simple and direct way for measuring these solvents. Each analyte is measured with respect to a unique internal standard. For acetone, the internal standard used is acetone-d6, for methyl acetate it is methyl acetate-d3, and for PCBTF it is metachlorobenzotrifluoride (MCBTF). These unique analyte/internal standard pairs behave very nearly as single solvents with respect to evaporation rate and adsorption rate onto a coated silica fiber (SPME) but are separable on a gas chromatograph (GC) capillary column. The only critical analytical technique required for successfully performing this test method is the ability of an analyst to weigh a paint sample and internal standard, corresponding to the analyte of interest, into a septum capped vial. After weighing, solvent evaporation has no effect on the final value of the determination. Since whole paint is not injected into the gas chromatograph, the analytical system is never compromised.
SCOPE
1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
Note 1: Water-borne paints are internally standardized and diluted with water followed by addition of solid sodium chloride.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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