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ASTM D2627-97

(Specification)

Standard Specification for Diacetone Alcohol

Standard Specification for Diacetone Alcohol

SCOPE
1.1 This specification covers diacetone alcohol.  
1.2 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.

General Information

Status
Historical
Publication Date
09-Dec-1997
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

Relations

Replaced By
ASTM D2627-02 - Standard Specification for Diacetone Alcohol
Effective Date
10-Aug-2002

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ASTM D2627-97 - Standard Specification for Diacetone Alcohol
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Standards Content (Sample)

Designation: D 2627 – 97
AMERICAN SOCIETY FOR TESTING AND MATERIALS
100 Barr Harbor Dr., West Conshohocken, PA 19428
Reprinted from the Annual Book of ASTM Standards. Copyright ASTM
Standard Specification for
1
Diacetone Alcohol
This standard is issued under the fixed designation D 2627; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
7
2
of
1.1 This specification covers diacetone alcohol.
1.2 For specific hazard information and guidance, consult
3. Properties
the supplier’s Material Safety Data Sheet.
3.1 Diacetone alcohol shall conform to the following re-
2. Referenced Documents quirements:
Apparent specific gravity
2.1 ASTM Standards:
20/20°C 0.938–0.941
D 268 Guide for Sampling and Testing Volatile Solvents
25/25°C 0.935–0.938
and Chemical Intermediates for Use in Paint and Related
Color, Pt-Co units, max 25
3
Distillation, 760 mm Hg
Coatings and Materials
Initial boiling point, °C, min 135
D 1078 Test Method for Distillation Range of Volatile
Dry point, °C, max 172
3
Organic Liquids Nonvolatile matter, g/100 mL, max 0.01
Odor (see Note 1) nonresidual
D 1209 Test Method for Color of Clear Liquids (Platinum-
Water, wt %, max (see Note 2) 0.1
3
Cobalt Scale)
Acidity (free acid as acetic acid), wt %, max 0.01
D 1296 Test Method for Odor of Volatile Solvents and
Water solubility miscible with distilled water
3
in all proportions
Diluents
_____________
D 1353 Test Method for Nonvolatile Matter in Volatile
NOTE 1—Optional: Test for odor only when agreed upon as necessary
Solvents for Use in Paint, Varnish, Lacquer, and Related
between the purchaser and the supplier.
3
Products
NOTE 2—This quantitative water limit ensures that the material is
D 1364 Test Method for Water in Volatile Solvents (Karl
miscible without turbidity with 19 volumes of 99 % heptane at 20°C.
3
Fischer Reagent Titration Method)
D 1613 Test Method for Acidity in Volatile Solvents and 4. Sampling
Chemical Intermediates Used in Paint, Varnish, Lacquer,
4.1 The material shall be sampled in accordance with
3
and Related Products
Practice E 300.
D 1722 Test Method for Water Miscibility of Water-Soluble
3
Solvents 5. Test Methods
D 4052 Test Method for Density and Relative Density of
5.1 The properties enumerated in this specification shall be
4
Liquids by Digital Density Meter
determined in accordance with the following ASTM test
5
E 1 Specification for ASTM Thermometers
methods:
6
E 300 Practice for Sampling Industrial Chemicals
5.1.1 Apparent Specific Gravity—Determine the apparent
2.2 U.S. Federal Specification:
specific gravity by any convenient method that is accurate to
the third decimal place, the temperature of both specimen and
water being 20°C or 25°C. (See Guide D 268 and Test Method
D 4052.)
5.1.2 Color—Test Method D 1209.
NOTE 3—Diacetone a
...

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1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
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