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ASTM D2917-07(2013)

(Specification)

Standard Specification for Methyl Isoamyl Ketone

Standard Specification for Methyl Isoamyl Ketone

ABSTRACT
This specification covers the properties and requirements for 98 % grade methyl isoamyl ketone for use in paint, varnish, lacquer, and related products. The material shall be sampled and tested appropriately, and shall conform to properties as to apparent specific gravity, color (Pt-Co scale), distillation (initial boiling and dry points), water content, acidity as acetic acid, and purity.
SCOPE
1.1 This specification covers methyl isoamyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet.

General Information

Status
Historical
Publication Date
31-May-2013
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

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ASTM D2917-07(2013) - Standard Specification for Methyl Isoamyl KetoneASTM D2917-07(2013) - Standard Specification for Methyl Isoamyl Ketone
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ASTM D2917-07(2013) - Standard Specification for Methyl Isoamyl Ketone
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D2917 −07 (Reapproved 2013)
Standard Specification for
1
Methyl Isoamyl Ketone
This standard is issued under the fixed designation D2917; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D4052 Test Method for Density, Relative Density, and API
Gravity of Liquids by Digital Density Meter
1.1 This specification covers methyl isoamyl ketone (98 %
D5386 Test Method for Color of Liquids Using Tristimulus
grade) for use in paint, varnish, lacquer, and related products.
Colorimetry
1.2 The following applies to all specified limits in this
E29 Practice for Using Significant Digits in Test Data to
standard: for purposes of determining conformance with this
Determine Conformance with Specifications
standard, an observed value or a calculated value shall be
E300 Practice for Sampling Industrial Chemicals
rounded off “to the nearest unit” in the last right-hand digit
2.2 U.S. Federal Specification:
used in expressing the specification limit, in accordance with
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
the rounding-off method of Practice E29.
3
of
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this 3. Properties
standard.
3.1 Methyl isoamyl ketone shall conform to the following
1.4 For specific hazard information and guidance, see the requirements:
supplier’s Material Safety Data Sheet.
Apparent specific gravity:
20/20°C 0.812 to 0.815
or
2. Referenced Documents
25/25°C 0.809 to 0.812
2
2.1 ASTM Standards:
Color, Pt-Co scale, max (Note 1) 15
Distillation, °C
D268 Guide for Sampling and Testing Volatile Solvents and
Initial boiling point, min 140
Chemical Intermediates for Use in Paint and Related
Dry point, max 148
Coatings and Material Water, wt %, max 0.1
Acidity as acetic acid, wt %, max 0.02
D1078 Test Method for Distillation Range of Volatile Or-
Purity, wt %, min 98
ganic Liquids
__________________
D1209 Test Method for Color of Clear Liquids (Platinum-
NOTE 1—Instrumental Pt-Co color determined by Test Method D5386
Cobalt Scale)
has been shown to have no statistically significant difference from Pt-Co
D1364 Test Method for Water in Volatile Solvents (Karl
color determined by Test Method D1209. However, it is not known
Fischer Reagent Titration Method) whether methyl isoamyl ketone was part of the sample set included in the
interlaboratory study.
D1476 Test Method for Heptane Miscibility of Lacquer
Solvents
4. Sampling
D1613 Test Method for Acidity in Volatile Solvents and
Chemical Intermediates Used in Paint, Varnish, Lacquer, 4.1 The material shall be sampled in accordance with
and Related Products Practice E300.
D3893 Test Method for Purity of Methyl Amyl Ketone and
5. Test Methods
Methyl Isoamyl Ketone by Gas Chromatography
5.1 The properties enumerated in this specification shall be
determined in accordance with the following ASTM test
1
This specification is under the jurisdiction of ASTM Committee D01 on Paint
methods:
and Related Coatings
...

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1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
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