ASTM D7719-14c
(Specification)Standard Specification for High Aromatic Content Unleaded Hydrocarbon Aviation Gasoline
Standard Specification for High Aromatic Content Unleaded Hydrocarbon Aviation Gasoline
ABSTRACT
This specification covers formulating specifications for purchases of a high octane unleaded test fuel under contract and is intended solely for use by purchasing agencies for testing purposes. This specification also defines a specific type of high octane unleaded test fuel for use as an aviation spark-ignition fuel. A new high-octane unleaded test fuel has been developed, which maintains the key performance parameters of existing reciprocating aircraft engines.
SCOPE
1.1 This specification covers formulating specifications for purchases of a high aromatic content unleaded hydrocarbon aviation gasoline under contract and is intended solely for use by purchasing agencies.2
1.2 This specification defines a specific type of high aromatic content unleaded hydrocarbon aviation gasoline (hereafter also referred to as “D7719 fuel”) for use as an aviation spark-ignition fuel. It does not include all fuels satisfactory for reciprocating aviation engines. Certain equipment or conditions of use may permit a wider, or require a narrower, range of characteristics than is shown by this specification.
1.3 The D7719 fuel defined by this specification does not exhibit identical performance to those leaded fuels for which the existing aircraft and ground-based fuel handling equipment have been designed to operate on. Therefore, the suitability of this fuel for use on any specific aircraft, aircraft engine, or ground-based fuel handling equipment should be evaluated before use on that equipment.
1.4 Issuance of this specification does not constitute approval to operate certificated aircraft with this fuel. Fuels used in certified engines and aircraft are ultimately approved by the certifying authority subsequent to formal submission of evidence to the authority as part of the certification program for that aircraft and engine model.
1.5 This specification, unless otherwise provided, prescribes the required properties of unleaded fuel at the time and place of delivery.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
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Designation:D7719 −14c AnAmerican National Standard
Standard Specification for
High Aromatic Content Unleaded Hydrocarbon Aviation
Gasoline
This standard is issued under the fixed designation D7719; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 1.7 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
1.1 This specification covers formulating specifications for
responsibility of the user of this standard to establish appro-
purchases of a high aromatic content unleaded hydrocarbon
priate safety and health practices and determine the applica-
aviation gasoline under contract and is intended solely for use
2 bility of regulatory limitations prior to use.
by purchasing agencies.
1.2 This specification defines a specific type of high aro- 2. Referenced Documents
matic content unleaded hydrocarbon aviation gasoline (hereaf-
2.1 ASTM Standards:
ter also referred to as “D7719 fuel”) for use as an aviation
D86Test Method for Distillation of Petroleum Products at
spark-ignition fuel. It does not include all fuels satisfactory for
Atmospheric Pressure
reciprocating aviation engines. Certain equipment or condi-
D130Test Method for Corrosiveness to Copper from Petro-
tionsofusemaypermitawider,orrequireanarrower,rangeof
leum Products by Copper Strip Test
characteristics than is shown by this specification.
D323TestMethodforVaporPressureofPetroleumProducts
(Reid Method)
1.3 The D7719 fuel defined by this specification does not
D873Test Method for Oxidation Stability ofAviation Fuels
exhibit identical performance to those leaded fuels for which
(Potential Residue Method)
theexistingaircraftandground-basedfuelhandlingequipment
D909TestMethodforSuperchargeRatingofSpark-Ignition
have been designed to operate on. Therefore, the suitability of
Aviation Gasoline
this fuel for use on any specific aircraft, aircraft engine, or
D910Specification for Leaded Aviation Gasolines
ground-based fuel handling equipment should be evaluated
D1094Test Method for Water Reaction of Aviation Fuels
before use on that equipment.
D1266TestMethodforSulfurinPetroleumProducts(Lamp
1.4 Issuance of this specification does not constitute ap-
Method)
proval to operate certificated aircraft with this fuel. Fuels used
D1298Test Method for Density, Relative Density, or API
in certified engines and aircraft are ultimately approved by the
Gravity of Crude Petroleum and Liquid Petroleum Prod-
certifying authority subsequent to formal submission of evi-
ucts by Hydrometer Method
dence to the authority as part of the certification program for
D1319Test Method for HydrocarbonTypes in Liquid Petro-
that aircraft and engine model.
leum Products by Fluorescent Indicator Adsorption
1.5 Thisspecification,unlessotherwiseprovided,prescribes
D2386Test Method for Freezing Point of Aviation Fuels
therequiredpropertiesofunleadedfuelatthetimeandplaceof
D2622Test Method for Sulfur in Petroleum Products by
delivery.
Wavelength Dispersive X-ray Fluorescence Spectrometry
D2624Test Methods for Electrical Conductivity ofAviation
1.6 The values stated in SI units are to be regarded as
and Distillate Fuels
standard. No other units of measurement are included in this
D2700Test Method for Motor Octane Number of Spark-
standard.
Ignition Engine Fuel
D3237TestMethodforLeadinGasolinebyAtomicAbsorp-
tion Spectroscopy
This specification is under the jurisdiction of ASTM Committee D02 on
D4052Test Method for Density, Relative Density, and API
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
Gravity of Liquids by Digital Density Meter
Subcommittee D02.J0.02 on Spark and Compression Ignition Aviation Engine
Fuels.
Current edition approved Oct. 15, 2014. Published November 2014. Originally
approved in 2011. Last previous edition approved in 2014 as D7719–14b. DOI: For referenced ASTM standards, visit the ASTM website, www.astm.org, or
10.1520/D7719-14C. contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Supporting data have been filed atASTM International Headquarters and may Standards volume information, refer to the standard’s Document Summary page on
be obtained by requesting Research Report RR:D02-1721. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright ©ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA19428-2959. United States
D7719−14c
D4057Practice for Manual Sampling of Petroleum and 3.1.1 binary, adj—characterized by, or consisting of, two
Petroleum Products components.
D4171Specification for Fuel System Icing Inhibitors
3.1.2 biomass, n—biological material including any mate-
D4177Practice for Automatic Sampling of Petroleum and
rial other than fossil fuels which is or was a living organism or
Petroleum Products
component or product of a living organism.
D4306Practice for Aviation Fuel Sample Containers for
3.1.3 non-hydrocarbon, n—compound or compounds com-
Tests Affected by Trace Contamination
posedofcarbon,hydrogen,andotherelementssuchasoxygen,
D4809Test Method for Heat of Combustion of Liquid
nitrogen, sulfur, and phosphorus.
Hydrocarbon Fuels by Bomb Calorimeter (Precision
3.1.4 unleaded hydrocarbon aviation gasoline, n—gasoline
Method)
intended for use in aircraft powered by reciprocating spark-
D4814Specification for Automotive Spark-Ignition Engine
ignition engines, where lead is not intentionally added for the
Fuel
purpose of enhancing octane performance and which excludes
D4865Guide for Generation and Dissipation of Static Elec-
non-hydrocarbons, except for additives approved in this speci-
tricity in Petroleum Fuel Systems
fication.
D5006Test Method for Measurement of Fuel System Icing
Inhibitors (Ether Type) in Aviation Fuels
4. General
D5059Test Methods for Lead in Gasoline by X-Ray Spec-
4.1 Thisspecification,unlessotherwiseprovided,prescribes
troscopy
the required properties of a high aromatic content unleaded
D5191Test Method for Vapor Pressure of Petroleum Prod-
hydrocarbonaviationgasolineatthetimeandplaceofdelivery.
ucts (Mini Method)
D6469GuideforMicrobialContaminationinFuelsandFuel
5. Classification
Systems
D6733Test Method for Determination of Individual Com- 5.1 One grade of high aromatic content unleaded hydrocar-
ponents in Spark Ignition Engine Fuels by 50-Metre
bon aviation gasoline is provided, known as UL102.
Capillary High Resolution Gas Chromatography
6. Materials and Manufacture
D7826Guide for Evaluation of NewAviation Gasolines and
New Aviation Gasoline Additives
6.1 D7719 fuel, except as otherwise specified in this
E29Practice for Using Significant Digits in Test Data to
specification, shall consist of blends of refined reformate
Determine Conformance with Specifications
hydrocarbons. The sources for these hydrocarbons include
biomass, natural gas, or crude petroleum.
3. Terminology
6.1.1 See Appendix X1 for one particular composition that
3.1 Definitions: meets the parameters of Table 1.
TABLE 1 Detailed Requirements for High Aromatic Content Unleaded Hydrocarbon Aviation Gasoline
Octane Ratings Grade UL102 ASTM Test Method
Knock value, Motor Octane Number min 102.2 D2700
Density at 15 °C, kg/m min 790
D1298 or D4052
max 825
Distillation D86
Initial boiling point, °C Report D86
Fuel Evaporated D86
10 volume % at °C max 75 D86
40 volume % at °C min 75 D86
50 volume % at °C max 165 D86
90 volume % at °C max 165 D86
Final boiling point, °C max 180 D86
Sumof10%+50% evaporated min 135 D86
temperatures, °C
Recovery, volume % min 97 D86
Residue, volume % max 1.5 D86
Loss, volume % max 1.5 D86
Vapor pressure, 37.8 °C, kPa min 38.0
D323 orD5191
max 49.0
Freezing point, °C max -58 D2386
Sulfur, mass % max 0.05 D1266 or D2622
Net heat of combustion, MJ/kg min 41.5 D4809
Corrosion, copper strip, 2 h at 100 °C max No. 1 D130
Oxidation stability (5 h aging)
D873
Potential gum, mg/100 mL max 6
Water reaction
D1094
Volume change, mL max ±2
Electrical conductivity, pS/m max 450 D2624
Tetraethyl Lead, g Pb/L max 0.013 D3237 or D5059
TotalAromatics, vol% min 70 D1319 or D6733
D7719−14c
6.2 Additives—These can be added to each grade of D7719
DCI-4A MAC = 24.0 g/m
DCI-6A MAC = 15.0 g/m
fuel in the amount, and of the composition, specified in the
HITEC 580 MAC = 22.5 g/m
following list of approved materials:
NALCO 5403 MAC = 22.5 g/m
6.2.1 Dyes—Thetotalmaximumconcentrationofdyeinthe NALCO 5405 MAC = 11.0 g/m
UNICOR J MAC = 22.5 g/m
fuel is 6.0 mg/L.
SPEC-AID 8Q22 MAC = 24.0 g/m
6.2.1.1 The only blue dye present in the finished fuel shall
TOLAD 351 MAC = 24.0 g/m
TOLAD 4410 MAC = 22.5 g/m
be essentially 1,4-dialkylaminoanthraquinone.
6.2.1.2 The only yellow dyes in the finished fuel shall be
7. Detailed Requirements
essentially p-diethylaminoazobenzene (Color Index No.
7.1 The D7719 fuel shall conform to the requirements
11021) or 1,3-benzenediol 2,4-bis [(alkylphenyl)azo-].
prescribed in Table 1.
6.2.1.3 Theonlyreddyepresentinthefinishedfuelshallbe
7.2 Test results shall not exceed the maximum or be less
essentially alkyl derivatives of azobenzene-4-azo-2-naphthol.
than the minimum values specified in Table 1. No allowance
6.2.1.4 Theonlyorangedyepresentinthefinishedfuelshall
shall be made for the precision of the test methods. To
beessentiallybenzene-azo-2-napthol(ColorIndexNo.12055).
determine the conformance to the specification requirement, a
6.2.2 Other Additives—These may be added in the amount
test result may be rounded to the same number of significant
and of the composition specified in the following list of
figures as in Table 1 using Practice E29. Where multiple
approved materials. The quantities and types shall be declared
determinationsaremade,theaverageresult,roundedaccording
by the manufacturer. Additives added after the point of
to Practice E29, shall be used.
manufacture shall also be declared.
6.2.2.1 Antioxidants—The following oxidation inhibitors
8. Workmanship, Finish, and Appearance
may be added to the fuel separately, or in combination, in total
8.1 The D7719 fuel specified in this specification shall be
concentration not to exceed 12 mg of inhibitor (not including
free from undissolved water, sediment, and suspended matter.
weight of solvent) per litre of fuel.
No substances of known dangerous toxicity, under usual
(1)2,6-ditertiary butyl-4-methylphenol.
conditions of handling and use, shall be present except as
(2)2,4-dimethyl-6-tertiary butylphenol.
permitted in this specification.
(3)2,6-ditertiary butylphenol.
(4)75 % minimum 2,6-ditertiary butylphenol plus 25 %
9. Sampling
maximum mixed tertiary and tritertiary butylphenols.
9.1 Because of the importance of proper sampling proce-
(5)75 % minimum di- and tri-isopropyl phenols plus 25 %
dures in establishing fuel quality, use the appropriate proce-
maximum di- and tri-tertiary butylphenols.
dures in Practice D4057 or Practice D4177.
(6)72 % minimum 2,4-dimethyl-6-tertiary butylphenol
9.1.1 Although automatic sampling following Practice
plus 28 % maximum monomethyl and dimethyl tertiary butyl-
D4177maybeusefulincertainsituations,initialmanufacturer/
phenols.
supplierspecificationcompliancetestingshallbeperformedon
(7)N,N’-di-isopropyl-para-phenylenediamine.
a sample taken following procedures in Practice D4057.
(8)N,N’-di-secondary-butyl-para-phenylenediamine.
9.2 A number of D7719 fuel properties, including copper
6.2.2.2 Fuel System Icing Inhibitor (FSII)—One of the
corrosion, electrical conductivity, and others are very sensitive
following materials may be used:
to trace contamination which can originate from sample
(1)Isopropyl Alcohol (IPA, propan-2-ol), in accordance
containers. For recommended sample containers, refer to
with the requirements of Specification D4171 (Type II). May
Practice D4306.
be used in concentrations recommended by the aircraft manu-
facturer when required by the aircraft owner/operator.
10. Reports
(2)Di-Ethylene Glycol Monomethyl Ether (Di-EGME),
10.1 Thetypeandnumberofreportstoensureconformance
conforming to the requirements of Specification D4171 (Type
with the requirements of this specification shall be mutually
III). May be used in concentrations of 0.10 to 0.15 volume %
agreed to by the purchaser and the supplier of the D7719 fuel.
when required by the aircraft owner/operator.
(3)Test Method D5006 can be used to determine the
11. Test Methods
concentration of Di-EGME in aviation fuels.
11.1 Therequirementsenumeratedinthisspecificationshall
NOTE1—Additionofisopropylalcohol(IPA)mayreduceknockratings
be determined in accordance with the following ASTM test
below minimum specification values.
methods:
6.2.2.3 Electrical Conductivity Additive—Stadis450incon-
11.1.1 Knock Value (Motor Octane Number)—Test Method
centrations up to 3 mg/L is permitted. When loss of fuel
D2700.
conductivitynecessitatesretreatmentwithelectricalconductiv-
11.1.2 Tetraethyl Lead—Test Methods D3237 or D5059.
ity additive, further addition is permissible
11.1.3 Density—Test Methods D1298 or D4052.
6.2.2.4 Corrosion Inhibitor Additive—The following corro- 11.1.4 Distillation—Test Method D86.
sion inhibitors may be added to the fuel in concentrations not 11.1.5 Freezing Point—Test Method D2386.
to exceed the maximum allowable concentration (MAC) listed 11.1.6 Vapor Pressure—Test Methods D323 or D5191.
for each additive. 11.1.7 Net Heat of Combustion—Test Method D4809.
D7719−14c
11.1.8 Sulfur—Test Methods D1266 or D2622. 11.1.11 Water Reaction—Test Method D1094.
11.1.9 Corrosion (Copper Strip)—Test Method D130,2h
11.1.12 Electrical Conductivity—Test Method D2624.
test at 100°C in bomb.
11.1.13 Aromatic Content—Test Methods D1319 or D6733.
11.1.10 Potential Gum and Visible Lead Precipitate—Test
Method D873 except that wherever the letter X occurs (refer-
12. Keywords
ring to oxidation time) insert the number 5, designating the
12.1 aviation gasoline; binary; hydrocarbon; unleaded
number of hours prescribed in this specification.
APPENDIXES
(Nonmandatory Information)
X1. HIGH AROMATIC CONTENT BINARY UNLEADED HYDROCARBON AVIATION GASOLINE COMPOSITION
X1.1 Introduction hydrocarbon aviation gasoline developed for existing spark-
ignition aircraft engines.
X1.1.1 Anew high aromatic content unleaded hydrocarbon
aviation gasoline has been developed for reciprocating aircraft
X1.2 Composition
engines. The two essential performance parameters of MON
X1.2.1 The origin of the fuel lies in two essential engine
and VP are inversely related with respect
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7719 − 14b D7719 − 14c
Standard Specification for
High-Octane Unleaded FuelHigh Aromatic Content Unleaded
Hydrocarbon Aviation Gasoline
This standard is issued under the fixed designation D7719; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers formulating specifications for purchases of a high-octane (MON) unleaded fuel high aromatic
content unleaded hydrocarbon aviation gasoline under contract and is intended solely for use by purchasing agencies.
1.2 This specification defines a specific type of high-octane (MON) unleaded fuel high aromatic content unleaded hydrocarbon
aviation gasoline (hereafter also referred to as “D7719 fuel”) for use as an aviation spark-ignition fuel. It does not include all fuels
satisfactory for reciprocating aviation engines. Certain equipment or conditions of use may permit a wider, or require a narrower,
range of characteristics than is shown by this specification.
1.3 The D7719 fuel defined by this specification does not exhibit identical performance to those leaded fuels for which the
existing aircraft and ground-based fuel handling equipment have been designed to operate on. Therefore, the suitability of this fuel
for use on any specific aircraft, aircraft engine, or ground-based fuel handling equipment should be evaluated before use on that
equipment.
1.4 Issuance of this specification does not constitute approval to operate certificated aircraft with this fuel. Fuels used in certified
engines and aircraft are ultimately approved by the certifying authority subsequent to formal submission of evidence to the
authority as part of the certification program for that aircraft and engine model.
1.5 This specification, unless otherwise provided, prescribes the required properties of unleaded fuel at the time and place of
delivery.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
D86 Test Method for Distillation of Petroleum Products at Atmospheric Pressure
D130 Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test
D323 Test Method for Vapor Pressure of Petroleum Products (Reid Method)
D873 Test Method for Oxidation Stability of Aviation Fuels (Potential Residue Method)
D909 Test Method for Supercharge Rating of Spark-Ignition Aviation Gasoline
D910 Specification for Leaded Aviation Gasolines
D1094 Test Method for Water Reaction of Aviation Fuels
D1266 Test Method for Sulfur in Petroleum Products (Lamp Method)
D1298 Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by
Hydrometer Method
D1319 Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
This specification is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.J0.02 on Spark and Compression Ignition Aviation Engine Fuels.
Current edition approved Oct. 1, 2014Oct. 15, 2014. Published November 2014. Originally approved in 2011. Last previous edition approved in 2014 as
D7719 – 14a.D7719 – 14b. DOI: 10.1520/D7719-14B.10.1520/D7719-14C.
Supporting data have been filed at ASTM International Headquarters and may be obtained by requesting Research Report RR:D02-1721.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D7719 − 14c
D2386 Test Method for Freezing Point of Aviation Fuels
D2622 Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry
D2624 Test Methods for Electrical Conductivity of Aviation and Distillate Fuels
D2700 Test Method for Motor Octane Number of Spark-Ignition Engine Fuel
D3237 Test Method for Lead in Gasoline by Atomic Absorption Spectroscopy
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4171 Specification for Fuel System Icing Inhibitors
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D4306 Practice for Aviation Fuel Sample Containers for Tests Affected by Trace Contamination
D4809 Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (Precision Method)
D4814 Specification for Automotive Spark-Ignition Engine Fuel
D4865 Guide for Generation and Dissipation of Static Electricity in Petroleum Fuel Systems
D5006 Test Method for Measurement of Fuel System Icing Inhibitors (Ether Type) in Aviation Fuels
D5059 Test Methods for Lead in Gasoline by X-Ray Spectroscopy
D5191 Test Method for Vapor Pressure of Petroleum Products (Mini Method)
D6469 Guide for Microbial Contamination in Fuels and Fuel Systems
D6733 Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 50-Metre Capillary High
Resolution Gas Chromatography
D7826 Guide for Evaluation of New Aviation Gasolines and New Aviation Gasoline Additives
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
3. Terminology
3.1 Definitions:
3.1.1 aviation gasoline fuel, n—fuel possessing specific properties suitable for operating aircraft powered by reciprocating
spark-ignition engines.
3.1.1 binary, adj—characterized by, or consisting of, two components.
3.1.2 biomass, n—biological material including any material other than fossil fuels which is or was a living organism or
component or product of a living organism.
3.1.3 high-octane,non-hydrocarbon, adj—n—possessing a Motor octane number (MON) greater than 100.compound or
compounds composed of carbon, hydrogen, and other elements such as oxygen, nitrogen, sulfur, and phosphorus.
3.1.4 unleaded hydrocarbon aviation gasoline, n—gasoline intended for use in aircraft powered by reciprocating spark-ignition
engines, where lead is not intentionally added for the purpose of enhancing octane performance and which excludes
non-hydrocarbons, except for additives approved in this specification.
4. General
4.1 This specification, unless otherwise provided, prescribes the required properties of a binary aviation fuelhigh aromatic
content unleaded hydrocarbon aviation gasoline at the time and place of delivery.
5. Classification
5.1 One grade of high-octane unleaded fuel high aromatic content unleaded hydrocarbon aviation gasoline is provided, known
as UL102.
6. Materials and Manufacture
6.1 High-octaneD7719 unleaded fuel, except as otherwise specified in this specification, shall consist of blends of refined
reformate hydrocarbons. The sources for these hydrocarbons include biomass, natural gas, or crude petroleum.
6.1.1 See Appendix X1 for one particular composition that meets the parameters of Table 1.
6.2 Additives—These can be added to each grade of high-octaneD7719 unleaded aviation fuel in the amount, and of the
composition, specified in the following list of approved materials:
6.2.1 Dyes—The total maximum concentration of dye in the fuel is 6.0 mg/L.
6.2.1.1 The only blue dye present in the finished fuel shall be essentially 1,4-dialkylaminoanthraquinone.
6.2.1.2 The only yellow dyes in the finished fuel shall be essentially p-diethylaminoazobenzene (Color Index No. 11021) or
1,3-benzenediol 2,4-bis [(alkylphenyl)azo-].
6.2.1.3 The only red dye present in the finished fuel shall be essentially alkyl derivatives of azobenzene-4-azo-2-naphthol.
6.2.1.4 The only orange dye present in the finished fuel shall be essentially benzene-azo-2-napthol (Color Index No. 12055).
D7719 − 14c
TABLE 1 Detailed Requirements for High-Octane Unleaded FuelHigh Aromatic Content Unleaded Hydrocarbon Aviation Gasoline
Octane Ratings Grade UL102 ASTM Test Method
Knock value, Motor Octane Number min 102.2 D2700
Density at 15 °C, kg/m min 790
D1298 or D4052
max 825
Distillation D86
Initial boiling point, °C Report D86
Fuel Evaporated D86
10 volume % at °C max 75 D86
40 volume % at °C min 75 D86
50 volume % at °C max 165 D86
90 volume % at °C max 165 D86
Final boiling point, °C max 180 D86
Sum of 10 % + 50 % evaporated min 135 D86
temperatures, °C
Recovery, volume % min 97 D86
Residue, volume % max 1.5 D86
Loss, volume % max 1.5 D86
Vapor pressure, 37.8 °C, kPa min 38.0
D323 orD5191
max 49.0
Freezing point, °C max -58 D2386
Sulfur, mass % max 0.05 D1266 or D2622
Net heat of combustion, MJ/kg min 41.5 D4809
Corrosion, copper strip, 2 h at 100 °C max No. 1 D130
Oxidation stability (5 h aging)
D873
Potential gum, mg/100 mL max 6
Water reaction
D1094
Volume change, mL max ±2
Electrical conductivity, pS/m max 450 D2624
Tetraethyl Lead, g Pb/L max 0.013 D3237 or D5059
Total Aromatics, vol % min 70 D1319 or D6733
6.2.2 Other Additives—These may be added in the amount and of the composition specified in the following list of approved
materials. The quantities and types shall be declared by the manufacturer. Additives added after the point of manufacture shall also
be declared.
6.2.2.1 Antioxidants—The following oxidation inhibitors may be added to the fuel separately, or in combination, in total
concentration not to exceed 12 mg of inhibitor (not including weight of solvent) per litre of fuel.
(1) 2,6-ditertiary butyl-4-methylphenol.
(2) 2,4-dimethyl-6-tertiary butylphenol.
(3) 2,6-ditertiary butylphenol.
(4) 75 % minimum 2,6-ditertiary butylphenol plus 25 % maximum mixed tertiary and tritertiary butylphenols.
(5) 75 % minimum di- and tri-isopropyl phenols plus 25 % maximum di- and tri-tertiary butylphenols.
(6) 72 % minimum 2,4-dimethyl-6-tertiary butylphenol plus 28 % maximum monomethyl and dimethyl tertiary butylphenols.
(7) N,N’-di-isopropyl-para-phenylenediamine.
(8) N,N’-di-secondary-butyl-para-phenylenediamine.
6.2.2.2 Fuel System Icing Inhibitor (FSII)—One of the following materials may be used:
(1) Isopropyl Alcohol (IPA, propan-2-ol), in accordance with the requirements of Specification D4171 (Type II). May be used
in concentrations recommended by the aircraft manufacturer when required by the aircraft owner/operator.
(2) Di-Ethylene Glycol Monomethyl Ether (Di-EGME), conforming to the requirements of Specification D4171 (Type III).
May be used in concentrations of 0.10 to 0.15 volume % when required by the aircraft owner/operator.
(3) Test Method D5006 can be used to determine the concentration of Di-EGME in aviation fuels.
NOTE 1—Addition of isopropyl alcohol (IPA) may reduce knock ratings below minimum specification values.
6.2.2.3 Electrical Conductivity Additive—Stadis 450 in concentrations up to 3 mg/L is permitted. When loss of fuel conductivity
necessitates retreatment with electrical conductivity additive, further addition is permissible
6.2.2.4 Corrosion Inhibitor Additive—The following corrosion inhibitors may be added to the fuel in concentrations not to
exceed the maximum allowable concentration (MAC) listed for each additive.
DCI-4A MAC = 24.0 g/m
DCI-6A MAC = 15.0 g/m
HITEC 580 MAC = 22.5 g/m
NALCO 5403 MAC = 22.5 g/m
NALCO 5405 MAC = 11.0 g/m
UNICOR J MAC = 22.5 g/m
SPEC-AID 8Q22 MAC = 24.0 g/m
TOLAD 351 MAC = 24.0 g/m
TOLAD 4410 MAC = 22.5 g/m
D7719 − 14c
7. Detailed Requirements
7.1 The high-octaneD7719 unleaded fuel shall conform to the requirements prescribed in Table 1.
7.2 Test results shall not exceed the maximum or be less than the minimum values specified in Table 1. No allowance shall be
made for the precision of the test methods. To determine the conformance to the specification requirement, a test result may be
rounded to the same number of significant figures as in Table 1 using Practice E29. Where multiple determinations are made, the
average result, rounded according to Practice E29, shall be used.
8. Workmanship, Finish, and Appearance
8.1 The high-octaneD7719 unleaded fuel specified in this specification shall be free from undissolved water, sediment, and
suspended matter. No substances of known dangerous toxicity, under usual conditions of handling and use, shall be present except
as permitted in this specification.
9. Sampling
9.1 Because of the importance of proper sampling procedures in establishing fuel quality, use the appropriate procedures in
Practice D4057 or Practice D4177.
9.1.1 Although automatic sampling following Practice D4177 may be useful in certain situations, initial manufacturer/supplier
specification compliance testing shall be performed on a sample taken following procedures in Practice D4057.
9.2 A number of high-octaneD7719 unleaded fuel properties, including copper corrosion, electrical conductivity, and others are
very sensitive to trace contamination which can originate from sample containers. For recommended sample containers, refer to
Practice D4306.
10. Reports
10.1 The type and number of reports to ensure conformance with the requirements of this specification shall be mutually agreed
to by the purchaser and the supplier of the high-octaneD7719 unleaded fuel.
11. Test Methods
11.1 The requirements enumerated in this specification shall be determined in accordance with the following ASTM test
methods:
11.1.1 Knock Value (Lean Rating)—(Motor Octane Number)—Test Method D2700.
11.1.2 Tetraethyl Lead—Test Methods D3237 or D5059.
11.1.3 Density—Test Methods D1298 or D4052.
11.1.4 Distillation—Test Method D86.
11.1.5 Freezing Point—Test Method D2386.
11.1.6 Vapor Pressure—Test Methods D323 or D5191.
11.1.7 Net Heat of Combustion—Test Method D4809.
11.1.8 Sulfur—Test Methods D1266 or D2622.
11.1.9 Corrosion
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