iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM D126-87(2002)

(Test Method)

Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green

Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green

SCOPE
1.1 These test methods cover procedures for the chemical analysis of yellow, orange, and green pigments containing lead chromate and chromium oxide green.
1.2 The analytical procedures appear in the following order:SectionsChrome Yellow, Chrome Orange, and Molybdate O rangeOrganic Colors and Lakes7Moisture and Other Volatile Matter8Matter Soluble in Water9Lead Chromate10 and 11Total Lead12Sulfate13 and 14Carbon Dioxide15Molybdenum16 and 17Extenders18-22Calculation of Substances Other than Insoluble Lead Compounds23 and 24Pure Chrome Green and Reduced Chrome G reenOrganic Colors and Lakes25Moisture and Other Volatile Matter26Matter Soluble in Water27Iron Blue28Lead Chromate29 and 30Barium Sulfate and Insoluble Siliceous Material31Total Lead32Sulfate33Calcium Oxide Soluble in Acid34 and 35Extenders36Calculation of Insoluble Lead Com-pounds37 Chromium Oxide GreenOrganic Colors and Lakes38Moisture and Other Volatile Matter39Matter Soluble in Water40Total Chromium as Chromium Oxide41
1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Note 3.

General Information

Status
Historical
Publication Date
28-May-1987
ICS
87.060.10 - Pigments and extenders
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.31 - Pigment Specifications
Current Stage
Ref Project

Relations

Replaced By
ASTM D126-87(2006) - Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green
Effective Date
01-Nov-2006
Referred By
ASTM D2218-67(2019) - Standard Specification for Molybdate Orange Pigments
Effective Date
29-May-1987
Referred By
ASTM D211-67(2023) - Standard Specification for Chrome Yellow and Chrome Orange Pigments
Effective Date
29-May-1987
Referred By
ASTM D4797-17(2022) - Standard Test Methods for Gravimetric Analysis of White and Yellow Thermoplastic Pavement Marking
Effective Date
29-May-1987
Referred By
ASTM D263-05(2023) - Standard Specification for Chrome Oxide Green Pigment
Effective Date
29-May-1987

Buy Standard

ASTM D126-87(2002) - Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide GreenASTM D126-87(2002) - Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green
PreviousNext
Standard
ASTM D126-87(2002) - Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green
English language
7 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D126–87(Reapproved2002)
Standard Test Methods for
Analysis of Yellow, Orange, and Green Pigments Containing
1
Lead Chromate and Chromium Oxide Green
This standard is issued under the fixed designation D126; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope 2. Referenced Documents
1.1 These test methods cover procedures for the chemical 2.1 ASTM Standards:
analysisofyellow,orange,andgreenpigmentscontaininglead D280 Test Methods for Hygroscopic Moisture (and Other
2
chromate and chromium oxide green. Matter Volatile Under the Test Conditions) in Pigments
1.2 Theanalyticalproceduresappearinthefollowingorder: D521 Test Methods for Chemical Analysis of Zinc Dust
2
(Metallic Zinc Powder)
Sections
CHROME YELLOW,CHROME ORANGE, AND MOLYBDATE ORANGE
D1013 Test Method for Determining Total Nitrogen in
Organic Colors and Lakes 7
2
Resins and Plastics
Moisture and Other Volatile Matter 8
3
D1193 Specification for Reagent Water
Matter Soluble in Water 9
Lead Chromate 10 and 11
E11 Specification for Wire Cloth Sieves for Testing Pur-
Total Lead 12
4
poses
Sulfate 13 and 14
Carbon Dioxide 15
3. Summary of Test Methods
Molybdenum 16 and 17
Extenders 18-22
3.1 Chrome Yellow, Chrome Orange, and Molybdate Or-
Calculation of Substances Other than Insoluble Lead
ange:
Compounds 23 and 24
PURE CHROME GREEN AND REDUCED CHROME GREEN
3.1.1 Organic colors and lakes are determined qualitatively
Organic Colors and Lakes 25
by boiling the sample in water, then ethyl alcohol, and finally
Moisture and Other Volatile Matter 26
Matter Soluble in Water 27 chloroform.
Iron Blue 28
3.1.2 Moisture and other volatile matter are determined in
Lead Chromate 29 and 30
accordance with Test Method A of Test Methods D280.
Barium Sulfate and Insoluble Siliceous Material 31
Total Lead 32 3.1.3 Matter soluble in water is determined by boiling in
Sulfate 33
water and filtering.
Calcium Oxide Soluble in Acid 34 and 35
3.1.4 Leadchromateisdeterminedbydissolvingthesample
Extenders 36
in dilute HCl, filtering and titrating potentiometrically with
Calculation of Insoluble Lead Com-
pounds 37
FeSO solution after addition of HClO .
4 4
CHROMIUM OXIDE GREEN
3.1.5 Total lead is determined by precipitation as lead
Organic Colors and Lakes 38
Moisture and Other Volatile Matter 39 sulfide solution with H SO and final precipitation as lead
2 4
Matter Soluble in Water 40
sulfate.
Total Chromium as Chromium Oxide 41
3.1.6 Sulfate is determined by dissolving the sample in
1.3 This standard does not purport to address all of the
acetic acid, neutralizing with sodium carbonate, plus addition
safety problems, if any, associated with its use. It is the
of HCl to an aliquot followed by addition of BaCl to
2
responsibility of the user of this standard to establish appro-
precipitate as barium sulfate.
priate safety and health practices and determine the applica-
3.1.7 Carbon dioxide is determined by evolution.
bility of regulatory limitations prior to use. Specific hazard
3.1.8 Molybdenum is determined by precipitation as the
statements are given in Note 3.
sulfide, solution in HNO and H SO , addition of NH OH and
3 2 4 4
H SO . The solution is reduced in a Jones reductor, collected
2 4
under Fe (SO ) solution and titrated with KMnO solution.
2 4 3 4
1
These test methods are under the jurisdiction of ASTM Committee D01 on
Paint and Related Coatings, Materials, and Applications and are the direct
2
responsibility of Subcommittee D01.31 on Pigment Specifications. Annual Book of ASTM Standards, Vol 06.03.
3
Current edition approved May 29, 1987. Published July 1987. Originally Annual Book of ASTM Standards, Vol 11.01.
e1 4
published as D126–22. Last previous edition D126–65(1981) . Annual Book of ASTM Standards, Vol 14.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D126
5
3.1.9 Extenders are either: Society, where such specifications are available. Other grades
3.1.9.1 Calciumcarbonate,calciumsulfate,magnesiumcar- may be used, provided it is first ascertained that the reagent is
bonate or; of sufficiently high purity to permit its use without lessening
(a) (a) The compounds in 3.1.9.1 are determined qualita- the accuracy of the determination.
tively by precipitation with ammonium solution. 5.2 Water—Unless otherwise indicated, references to water
(b) (b) If chromium is present, it is reduced and the lead for use in the preparation of reagents and in analy
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D6131-17(2023)(Test Method)
Standard Test Method for Evaluating the Relative Tint Undertone of Titanium Dioxide Pigments

SIGNIFICANCE AND USE
5.1 This test method allows the user to make a determination of the blueness or yellowness of the tint undertone of titanium dioxide pigments, versus a reference pigment agreed upon by the parties to the test. This is an important measure of tone, since it gives both a measure of effective particle size, and quick approximation of the blue/yellow undertone that can be expected when a coating containing the titanium dioxide is tinted.  
5.2 Such matters as the vehicle for preparing the dispersions and the mechanical method of preparing the dispersion are left to the user. However, variation in these practices will lead to increased variance in the results, so users ought to fix these parameters, in-so-far as is possible, within any one laboratory. This will lead to reduced uncertainty of the results within that laboratory, and it is seldom that interlaboratory comparisons of this test result is needed.  
5.3 Each user must decide whether the loss of accuracy in his measurements due to variation of these parameters is negligibly small for the purpose for which the data are obtained.
SCOPE
1.1 This test method is intended to be used to determine the tint undertone (blue or yellow) of titanium dioxide pigments. This relates to the effective particle size of the pigment  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D2745-00(2023)(Test Method)
Standard Test Method for Relative Tinting Strength of White Pigments by Reflectance Measurements

SIGNIFICANCE AND USE
4.1 Tinting strength is one of the most important properties of a white pigment. This test method provides a means of testing this property for quality control.  
4.2 This test method is a referee method, and the vehicle for preparing the dispersion and the black for tinting are suggested, but others may be used provided both the purchaser and the seller agree to the changes.  
4.3 The results obtained with a muller do not necessarily agree with industrial situations where different dispersing conditions exist. However, dispersing with a muller is a fast, relatively inexpensive way of testing tinting strength for routine quality control.
SCOPE
1.1 This test method describes the procedure for determining the relative tinting strength of white pigments by reflectance measurements of black tints.  
1.2 This test method is applicable only for comparing the test pigment with a reference standard of the same type and grade.  
Note 1: Test Method D332 describes a procedure for visual assessment of blue-tinted samples.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D6580-17(2023)(Test Method)
Standard Test Method for The Determination of Metallic Zinc Content in Both Zinc Dust Pigment and in Cured Films of Zinc-Rich Coatings

SIGNIFICANCE AND USE
4.1 This test method is useful for determining the amount of metallic zinc in zinc dust pigment, and also in dried films of both inorganic and organic zinc-rich coatings. Test Methods D521 is an appropriate method for analyzing zinc dust, but has shortcomings when applied to samples of cured coatings.
SCOPE
1.1 This test method covers the determination by differential scanning calorimetry of the metallic zinc content of both zinc-dust pigment, and of dried films of zinc-rich coatings. This test method is applicable to both inorganic and organic zinc-rich coatings.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D210-05(2023)(Specification)
Standard Specification for Bone Black Pigment

ABSTRACT
This specification covers bone black, ivory black, or drop black pigment. The pigment may be in dry form or in aqueous dispersion. Dry pigment shall be made by the calcinations of bones, unmixed with any other substance. Dry pigment shall compose of ash, ash insoluble in acids, and coarse particles. Pigment in aqueous dispersion shall be made by grinding the pigment with water, dispersing agent, biocide, fungicide, pH stabilizer, and defoamer. ASTM test methods shall be conducted for coarse particles, pigment and linseed oil in paste in oil, and mass color and tinting strength.
SCOPE
1.1 This specification covers the pigment commercially known as bone black, ivory black, or drop black. The pigment may be purchased in the dry form or as an aqueous dispersion.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D6619-00(2023)(Practice)
Standard Practice for Incorporating Pigments by High Speed Dispersion

SIGNIFICANCE AND USE
3.1 High speed dispersion is a commonly used dispersion method in the coatings industry. For the purpose of this practice, “high speed” would normally be understood to be a range of RPM between 3 000 and 10 000. This practice provides a reference for its use, so that a producer and user can standardize on an incorporation technique. This will minimize differences in the millbase, and allow the interested parties to concentrate on the physical, chemical, or optical methods to be run.
SCOPE
1.1 This practice covers the dispersion of pigments using a laboratory size high-speed impeller mill. It is similar in technical content to ISO 8780-3.
Note 1: This practice is restricted to mill bases of moderately high viscosity due to either high vehicle concentration or high pigment concentration, or both, which can produce high shear force. It is not intended to provide a means of formulating either pilot plant or full-scale mill base compositions (scaling up the process from laboratory equipment to factory mills is not simple).  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D126-87(2023)(Test Method)
Standard Test Methods for Analysis of Yellow, Orange, and Green Pigments Containing Lead Chromate and Chromium Oxide Green

SIGNIFICANCE AND USE
4.1 These test methods are for analysis designed as an aid in quality of yellow, orange, and green pigments containing lead chromate and chromium oxide green. Some sections may be applicable to analysis of these pigments when extracted from whole paints.
SCOPE
1.1 These test methods cover procedures for the chemical analysis of yellow, orange, and green pigments containing lead chromate and chromium oxide green.  
1.2 The analytical procedures appear in the following order:    
Sections  
Chrome  Yellow, Chrome Orange, and Molybdate Orange  
Organic Colors and Lakes  
7  
Moisture and Other Volatile Matter  
8  
Matter Soluble in Water  
9  
Lead Chromate  
10 and 11  
Total Lead  
12  
Sulfate  
13 and 14  
Carbon Dioxide  
15  
Molybdenum  
16 and 17  
Extenders  
18 – 22  
Calculation of Substances Other than Insoluble Lead
Compounds  
23 and 24  
Pure  Chrome Green and Reduced Chrome Green  
Organic Colors and Lakes  
25  
Moisture and Other Volatile Matter  
26  
Matter Soluble in Water  
27  
Iron Blue  
28  
Lead Chromate  
29 and 30  
Barium Sulfate and Insoluble Siliceous Material  
31  
Total Lead  
32  
Sulfate  
33  
Calcium Oxide Soluble in Acid  
34 and 35  
Extenders  
36  
Calculation of Insoluble Lead Compounds  
37  
Chromium Oxide Green  
Organic Colors and Lakes  
38  
Moisture and Other Volatile Matter  
39  
Matter Soluble in Water  
40  
Total Chromium as Chromium Oxide  
41  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Note 3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    8 pages
    English language
    sale 15% off
ASTM
ASTM D263-05(2023)(Specification)
Standard Specification for Chrome Oxide Green Pigment

ABSTRACT
This specification establishes the properties and requirements for the dry pigment commercially known as chrome oxide green. The pigment shall consist of practically pure chromium sesqui-oxide without any admixture. Specimens shall be sampled and tested adequately, and shall conform to the following composition requirements: total chromium; total water-soluble matter; moisture and other volatile matter; coarse particles (total residue retained on a No. 325 sieve); and organic colors or lakes. The pigments shall adhere to mass color, tint character, and tinting strength requirements as well.
SCOPE
1.1 This specification covers the dry pigment commercially known as chrome oxide green.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off
ASTM
ASTM D279-02(2023)(Test Method)
Standard Test Methods for Bleeding of Pigments

SIGNIFICANCE AND USE
4.1 Test Method A determines the amount of color produced when the pigment is in direct contact with a selected solvent such as toluene. It is useful as a rapid, easily conducted test of the general bleeding characteristics of pigments.  
4.2 Test Method B determines the amount of color migration into a white film applied over a base coat containing the pigment. It may give a more practical evaluation of whether a pigment will meet specific requirements for bleed resistance.  
4.3 Both Test Method A and Test Method B measure the extent of bleed.
SCOPE
1.1 These test methods cover procedures for determining the bleeding characteristics of dry pigments by direct solvent extraction of the pigment and by overstriping a film with a white coating and observing for the color migration from the base coat containing the pigment.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D185-07(2023)(Test Method)
Standard Test Methods for Coarse Particles in Pigments

SIGNIFICANCE AND USE
3.1 In production of paints, smoothness of the paint film is of paramount importance. Agglomerates or coarse particles larger than 45 μm are difficult to disperse and may prevent obtaining a smooth film. These test methods are a valuable quality control test for grading raw materials.
SCOPE
1.1 These test methods cover the determination of the amount of coarse particles in dry pigments.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D50-90(2023)(Test Method)
Standard Test Methods for Chemical Analysis of Yellow, Orange, Red, and Brown Pigments Containing Iron and Manganese

SIGNIFICANCE AND USE
3.1 These test methods compile in one place, recommended procedures for analyzing inorganic colored pigments. These pigments are used extensively in paints, and for this reason their compositions are important to the formulators and user.
SCOPE
1.1 These test methods cover procedures for the chemical analysis of yellow, orange, red, and brown pigments containing iron and manganese. The test methods apply specifically to the following pigments: synthetic hydrated yellow iron oxide, yellow ocher, red and brown iron oxides, raw and burnt umber, raw and burnt sienna, and venetian red.  
1.2 The analytical procedures appear in the following order:    
ASTM  
Method  
Refer-  
Dry Pigments
Sections  
ences  
Moisture and Other Volatile Matter  
6  
D280  
Loss on Ignition  
7  
Coarse Particles  
8  
D185  
Matter Soluble in Water  
9  
D1208  
Organic Coloring Matter  
10  
Iron Oxide  
11 and 12  
Calcium Compounds (Reported as CaO)  
13 and 14  
Sulfates Soluble in Hydrochloric Acid  
15 and 16  
Lead Chromate (in Ochers)  
17  
Calcium Carbonate (in Venetian Red)  
18  
C25  
Manganese (in Siennas and Umbers)  
19 and 20  
Pigment Pastes in Oil  
Pigment Content  
21  
D1208  
Moisture and Other Volatile Matter  
22  
D1208  
Nonvolatile Matter in Vehicle  
23  
Moisture by Distillation  
24  
D1208  
Coarse Particles and Skins  
25  
D185  
Consistency (Stormer)  
26  
D562  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to us.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off