oSIST prEN 197-1:2018
(Main)Cement - Part 1: Composition, specifications and conformity criteria for common cements
Cement - Part 1: Composition, specifications and conformity criteria for common cements
This document defines and gives the specifications of 39 distinct common cements, 7 sulfate resisting common cements as well as 3 distinct low early strength blast furnace cements and 2 sulfate resisting low early strength blast furnace cements and their constituents. The definition of each cement includes the proportions in which the constituents are to be combined to produce these distinct products in a range of nine strength classes. The definition also includes requirements which the constituents have to meet. It also includes mechanical, physical, and chemical requirements. Furthermore, this standard states the conformity criteria and the related rules. Necessary durability requirements are also given.
In addition to those sulfate resisting cements defined in the present document, other cements conforming either to this standard or to other standards, European or national, have been nationally demonstrated to have sulfate resisting properties. These cements which are listed in Annex A, are considered by different CEN Member countries as sulfate resisting within the limits of their territory.
NOTE 1 In addition to the specified requirements, an exchange of additional information between the cement manufacturer and user can be helpful. The procedures for such an exchange are not within the scope of this standard but should be dealt with in accordance with national standards or regulations or can be agreed between the parties concerned.
NOTE 2 The word "cement" in EN 197-1 is used to refer only to common cements unless otherwise specified.
This document does not cover:
- very low heat special cement covered by EN 14216;
- supersulfated cement covered by EN 15743;
- calcium aluminate cement covered by EN 14647;
- masonry cement covered by EN 413-1.
Zement - Teil 1: Zusammensetzung, Anforderungen und Konformitätskriterien von Normalzement
Dieses Dokument legt die Eigenschaften und Anforderungen von 39 unterschiedlichen Normalzementen, sieben Normalzementen mit hohem Sulfatwiderstand, drei unterschiedlichen Hochofenzementen mit niedriger Anfangsfestigkeit und zwei Hochofenzementen mit niedriger Anfangsfestigkeit und hohem Sulfat-widerstand sowie ihren Bestandteilen fest. Die Definition jeder Zementart enthält die Anteile der Bestandteile, die erforderlich sind, um diese verschiedenen Produkte in neun Festigkeitsklassen herzustellen. Die Definition enthält auch die Anforderungen, die die Bestandteile erfüllen müssen, sowie die Anforderungen an die mechanischen, physikalischen und chemischen Eigenschaften. Darüber hinaus enthält diese Norm die Konformitätskriterien und die damit verbundenen Regeln sowie die erforderlichen Anforderungen an die Dauerhaftigkeit.
Neben den in diesem Dokument definierten Zementen mit hohem Sulfatwiderstand gibt es weitere Zemente, die entweder dieser Norm oder anderen Normen, ob europäisch oder national, entsprechen und deren Sulfatwiderstandsfähigkeit unter nationalen Bedingungen nachgewiesen wurde. Diese Zemente, die in Anhang A aufgeführt sind, gelten in den jeweiligen CEN-Mitgliedsländern innerhalb ihrer Länder als sulfatwiderstandsfähig.
ANMERKUNG 1 Neben den festgelegten Anforderungen kann ein Austausch von zusätzlichen Informationen zwischen Zementhersteller und -anwender sinnvoll sein. Die Vorgehensweisen für einen solchen Austausch sind nicht Gegenstand dieser Norm, sondern sie sollten in Übereinstimmung mit den nationalen Normen oder Vorschriften festgelegt werden oder können zwischen den Beteiligten vereinbart werden.
ANMERKUNG 2 Wenn nicht anders angegeben, bezieht sich das Wort "Zement" in EN 197-1 nur auf Normalzemente.
Dieses Dokument gilt nicht für:
- Sonderzement mit sehr niedriger Hydratationswärme nach EN 14216;
- Sulfathüttenzement nach EN 15743;
- Tonerdezement nach EN 14647;
- Putz- und Mauerbinder nach EN 413-1.
Ciment - Partie 1 : Composition, spécifications et critères de conformité des ciments courants
Cement - 1. del: Sestava, zahteve in merila skladnosti za običajne cemente
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-december-2018
&HPHQWGHO 6HVWDYD]DKWHYHLQPHULODVNODGQRVWL]DRELþDMQHFHPHQWH
Cement - Part 1: Composition, specifications and conformity criteria for common
cements
Zement - Teil 1: Zusammensetzung, Anforderungen und Konformitätskriterien von
Normalzement
Ciment - Partie 1 : Composition, spécifications et critères de conformité des ciments
courants
Ta slovenski standard je istoveten z: prEN 197-1
ICS:
91.100.10 Cement. Mavec. Apno. Malta Cement. Gypsum. Lime.
Mortar
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
DRAFT
EUROPEAN STANDARD
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2018
ICS 91.100.10 Will supersede EN 197-1:2011
English Version
Cement - Part 1: Composition, specifications and
conformity criteria for common cements
Ciment - Partie 1 : Composition, spécifications et Zement - Teil 1: Zusammensetzung, Anforderungen
critères de conformité des ciments courants und Konformitätskriterien von Normalzement
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 51.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 197-1:2018 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 6
1 Scope . 7
2 Normative references . 7
3 Terms and definitions . 8
4 Cement . 10
5 Constituents . 11
5.1 General . 11
5.2 Main constituents . 11
5.2.1 Portland cement clinker (K) . 11
5.2.2 Granulated blast furnace slag (S) . 12
5.2.3 Pozzolanic materials (P, Q) . 12
5.2.4 Fly ashes (V, W) . 12
5.2.5 Burnt shale (T) . 13
5.2.6 Limestone (L, LL) . 14
5.2.7 Silica fume (D) . 14
5.3 Minor additional constituents . 14
5.4 Calcium sulfate . 15
5.5 Additives . 15
6 Composition and notation. 15
6.1 Composition and notation of common cements. 15
6.2 Composition and notation of sulfate resisting common cements (SR-Cements) . 20
6.3 Composition and notation of low early strength common cements . 22
7 Requirements . 22
7.1 Mechanical requirements . 22
7.1.1 Standard strength . 22
7.1.2 Early strength . 22
7.2 Physical requirements . 23
7.2.1 Initial setting time . 23
7.2.2 Soundness . 23
7.2.3 Heat of hydration . 23
7.3 Chemical requirements . 23
7.4 Durability requirements . 24
7.4.1 General . 24
7.4.2 Sulfate resistance . 24
7.4.3 Total alkali content. 25
8 Standard designation . 25
9 Conformity criteria . 27
9.1 General requirements . 27
9.2 Conformity criteria for mechanical, physical and chemical properties and evaluation
procedure . 28
9.2.1 General . 28
9.2.2 Statistical conformity criteria. 29
9.2.3 Single result conformity criteria . 31
9.3 Conformity criteria for cement composition . 32
9.4 Conformity criteria for properties of the cement constituents . 32
Annex A (informative) List of common cements considered as sulfate resisting by National
Standards in different CEN member countries but not included in Table 2 or not
fulfilling the requirements given in Table 5 . 33
Annex ZA (informative) Relationship of this European Standard with Regulation (EU)
No 305/2011 . 35
ZA.1 Scope and relevant characteristics . 35
ZA.2 System of Assessment and Verification of Constancy of Performance (AVCP) . 36
ZA.3 Assignment of AVCP tasks . 36
Bibliography . 38
European foreword
This document (prEN 197-1:2018) has been prepared by Technical Committee CEN/TC 51 “Cement and
building lime”, the secretariat of which is held by NBN.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 197-1:2011.
This document has been prepared under a standardization request given to CEN by the European
Commission and the European Free Trade Association, and supports basic requirements of Regulation
(EU) No 305/2011 amended by the Commission Delegated Regulations (EU) No 157/2014 of
30 October 2013, No 568/2014 of 18 February 2014 and No 574/2014 of 21 February 2014.
For relationship with Regulation (EU) No 305/2011, see informative Annex ZA, which is an integral part
of this document.
Annexes A and ZA are informative.
Compared to the version EN 197-1:2011 the following major changes have been included in this
document:
— CEM II/C and CEM VI have been defined as new cement types;
— CEM V has been renamed as Slag-pozzolanic cement;
— the total alkali content was included as part of the essentials characteristics and corresponding
rules were laid down;
— Annex ZA has been revised.
EN 197, Cement, is currently composed with the following parts:
— Part 1: Composition, specifications and conformity criteria for common cements
— Part 2: Conformity evaluation
The preparation of a standard for cement was initiated by the European Economic Community (EEC) in
1969 and, at the request of a member state later in 1973, the work was given to the European
Committee for Standardization (CEN). The Technical Committee CEN/TC 51 was entrusted with the
task of preparing a cement standard for the countries of Western Europe, comprising the EEC and EFTA
members.
In the early eighties, CEN/TC 51 decided to include in the standard for cement only those cements
which are intended for use in any plain and reinforced concrete and which are familiar in most
countries in Western Europe because they have been produced and used in these countries for many
years. The EU Construction Products Directive (89/106/EEC) required the incorporation of all
traditional and well-tried cements in order to remove technical barriers to trade in the construction
field. There are currently no criteria for the descriptions “traditional” and “well tried” and it was
maintained the need to separate the “common cements” from “special cements”, i.e. those with
additional or special properties.
The requirements in this standard are based on the results of tests on cement in accordance with
EN 196-1, EN 196-2, EN 196-3, EN 196-5, EN 196-6, EN 196-7, EN 196-8, and EN 196-9. The scheme for
the assessment and verification of constancy of performance (AVCP) of common cements including
common cements with low heat of hydration and common cements generally accepted as being sulfate
resisting and of special cements are specified in EN 197-2.
In 2006, CEN/TC 51 began to investigate the possible standardization of some new cements produced
using traditional constituents and manufacturing methods but where compositions were outside the
limits of EN 197-1. Based on the results of a pre-normative study presented in 2011, new cements
containing Portland cement clinker and, as other main constituents, limestone, granulated blast furnace
slag or siliceous fly ash or natural pozzolana, have been standardized in this document as CEM II/C and
CEM VI.
The strength attained at twenty-8 days is the important criterion in classifying cement for most uses. In
order to achieve a specific strength class at twenty-8 days the early strength, at two days or at seven
days, can vary and some types of cement may not attain the minimum early strengths specified in
EN 197-1 for common cements.
The heat of hydration is linked to the early reactivity and lower early strengths indicate lower heat
evolution and lower temperatures in concrete. For these cements additional precautions in use can be
necessary to ensure adequate curing and safety in construction.
The purpose of this standard is to specify the composition requirements and conformity requirements
for common cements, including common cements with low heat of hydration and common cements
with adequate sulfate resistance as well as low early strength blast furnace cements and low early
strength blast furnace cements with low heat of hydration.
Cement types and strength classes defined in this document allow the specifier and/or the user to fulfil
objectives of sustainability for cement based constructions. Cement types produced by using
constituents listed and defined in Clause 5 allow the manufacturer to minimize the use of natural
resources in accordance with local conditions of production.
Introduction
It is recognized that different cements have different properties and performance. Those performance
tests now available (i.e. setting time, strength, soundness and heat of hydration), have been included in
this standard. In addition, work is being carried out by CEN/TC 51 to identify any additional tests which
are needed to specify further performance characteristics of cement. Until further performance tests
are available it is necessary that the choice of cement, especially the type and/or strength class in
relation to the requirements for durability depending on exposure class and type of construction in
which it is incorporated, follows the appropriate standards and/or regulations for concrete, mortar,
grout etc. valid in the place of use.
1 Scope
This document defines and gives the specifications of 39 distinct common cements, 7 sulfate resisting
common cements as well as 3 distinct low early strength blast furnace cements and 2 sulfate resisting
low early strength blast furnace cements and their constituents. The definition of each cement includes
the proportions in which the constituents are to be combined to produce these distinct products in a
range of nine strength classes. The definition also includes requirements which the constituents have to
meet. It also includes mechanical, physical, and chemical requirements. Furthermore, this standard
states the conformity criteria and the related rules. Necessary durability requirements are also given.
In addition to those sulfate resisting cements defined in the present document, other cements
conforming either to this standard or to other standards, European or national, have been nationally
demonstrated to have sulfate resisting properties. These cements which are listed in Annex A, are
considered by different CEN Member countries as sulfate resisting within the limits of their territory.
NOTE 1 In addition to the specified requirements, an exchange of additional information between the cement
manufacturer and user can be helpful. The procedures for such an exchange are not within the scope of this
standard but should be dealt with in accordance with national standards or regulations or can be agreed between
the parties concerned.
NOTE 2 The word “cement” in EN 197-1 is used to refer only to common cements unless otherwise specified.
This document does not cover:
— very low heat special cement covered by EN 14216;
— supersulfated cement covered by EN 15743;
— calcium aluminate cement covered by EN 14647;
— masonry cement covered by EN 413-1.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 196-1, Methods of testing cement — Part 1: Determination of strength
EN 196-2, Methods of testing cement — Part 2: Chemical analysis of cement
EN 196-3, Methods of testing cement — Part 3: Determination of setting times and soundness
EN 196-5, Methods of testing cement — Part 5: Pozzolanicity test for pozzolanic cement
EN 196-6, Methods of testing cement — Part 6: Determination of fineness
EN 196-7, Methods of testing cement — Part 7: Methods of taking and preparing samples of cement
EN 196-8, Methods of testing cement — Part 8: Heat of hydration — Solution method
EN 196-9, Methods of testing cement — Part 9: Heat of hydration — Semi-adiabatic method
EN 197-2, Cement — Part 2: Conformity evaluation
EN 451-1, Method of testing fly ash — Part 1: Determination of free calcium oxide content
EN 933-9, Tests for geometrical properties of aggregates — Part 9: Assessment of fines — Methylene blue
test
EN 13639, Determination of total organic carbon in limestone
ISO 9277, Determination of the specific surface area of solids by gas adsorption — BET method
ISO 9286, Abrasive grains and crude — Chemical analysis of silicon carbide
ISO 10694, Soil quality — Determination of organic and total carbon after dry combustion (elementary
analysis)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
reactive calcium oxide (CaO)
fraction of the calcium oxide which, under normal hardening conditions, can form calcium silicate
hydrates or calcium aluminate hydrates
Note 1 to entry: To evaluate this fraction, the total calcium oxide content (see EN 196-2) is reduced by the
fraction corresponding to calcium carbonate (CaCO ), based on the measured carbon dioxide (CO ) content (see
3 2
EN 196-2), and the fraction corresponding to calcium sulfate (CaSO ), based on the measured sulfate (SO )
4 3
content (see EN 196-2) after subtraction of the SO taken up by alkalis.
3.2
reactive silicon dioxide (SiO )
fraction of the silicon dioxide which is soluble after treatment with hydrochloric acid (HCl) and with
boiling potassium hydroxide (KOH) solution
Note 1 to entry: The quantity of reactive silicon dioxide is determined by subtracting from the total silicon
dioxide content (see EN 196-2) the fraction contained in the residue insoluble in hydrochloric acid and potassium
hydroxide (see EN 196-2), both on a dry basis.
3.3
main constituent
specially selected inorganic material in a proportion exceeding 5 % by mass related to the sum of all
main and minor additional constituents
3.4
minor additional constituent
specially selected inorganic material used in a proportion not exceeding a total of 5 % by mass related
to the sum of all main and minor additional constituents
3.5
type of common cement
one of the 39 products in the family of common cements
Note 1 to entry: Table 1 lists the 39 products in the family of common cements.
3.6
strength class of cement
class of compressive strength
3.7
autocontrol testing
continual testing by the manufacturer of cement spot samples taken at the point(s) of release from the
factory/depot
3.8
control period
period of production and dispatch identified for the evaluation of the autocontrol test results
3.9
characteristic value
value of a required property outside of which lies a specified percentage, the percentile P , of all the
k
values of the population
3.10
specified characteristic value
characteristic value of a mechanical, physical or chemical property which in the case of an upper limit is
not to be exceeded or in the case of a lower limit is, as a minimum, to be reached
3.11
single result limit value
value of a mechanical, physical or chemical property which – for any single test result – in the case of an
upper limit is not to be exceeded or in the case of a lower limit is, as a minimum, to be reached
3.12
allowable probability of acceptance CR
for a given sampling plan, allowed probability of acceptance of cement with a characteristic value
outside the specified characteristic value
3.13
sampling plan
specific plan which states the (statistical) sample size(s) to be used, the percentile P and the allowable
k
probability of acceptance CR
3.14
spot sample
sample which is taken at the same time and from one and the same place, relating to the intended tests,
and which can be obtained by combining one or more immediately consecutive increments
Note 1 to entry: See EN 196-7.
3.15
heat of hydration
quantity of heat developed by the hydration of a cement within a given period of time
3.16
low heat common cement
common cement with a limited heat of hydration
3.17
sulfate resisting common cement
common cement which fulfils the requirements for sulfate resisting properties
3.18
low heat low early strength blast furnace cement
low early strength blast furnace cement with a limited heat of hydration
3.19
sulfate resisting low early strength blast furnace cement
low early strength blast furnace cement which fulfils the requirements for sulfate resisting properties
3.20
total alkali content
alkali content of a cement determined according to EN 196-2 and expressed as the sodium oxide
equivalent
Note 1 to entry: The “available” or “effective” alkali content or any calculated alkali content of cement (e.g.
weighted value) is not dealt with in this document.
4 Cement
Cement is a hydraulic binder, i.e. a finely ground inorganic material which, when mixed with water,
forms a paste which sets and hardens by means of hydration reactions and processes and which, after
hardening, retains its strength and stability even under water.
Cement conforming to this standard, termed CEM cement, shall, when appropriately batched and mixed
with aggregate and water, be capable of producing concrete or mortar which retains its workability for
a sufficient time and shall after defined periods attain specified strength levels and also possess long-
term volume stability.
Hydraulic hardening of CEM cement is primarily due to the hydration of calcium silicates but other
chemical compounds can also participate in the hardening process, e.g. aluminates. The sum of the
proportions of reactive calcium oxide (CaO) and reactive silicon dioxide (SiO ) in CEM cement shall be
at least 50 % by mass when the proportions are determined in accordance with EN 196-2.
CEM cements consist of different materials and are statistically homogeneous in composition resulting
from quality ensured production and material handling processes. The link between these production
and material handling processes and the conformity of cement to this standard is elaborated in
EN 197-2.
NOTE There are also cements whose hardening is mainly due to other compounds, e.g. calcium aluminate in
calcium aluminate cement.
5 Constituents
5.1 General
The requirements for the constituents specified in 5.2 to 5.5 shall be determined in principle in
accordance with the test methods described in EN 196 unless otherwise specified.
5.2 Main constituents
5.2.1 Portland cement clinker (K)
Portland cement clinker is made by sintering a precisely specified mixture of raw materials (raw meal,
paste or slurry) containing elements, usually expressed as oxides, CaO, SiO , Al O , Fe O and small
2 2 3 2 3
quantities of other materials. The raw meal, paste or slurry is finely divided, intimately mixed and
therefore homogeneous.
Portland cement clinker is a hydraulic material which shall consist of at least two-thirds by mass of
calcium silicates (3CaO · SiO and 2CaO · SiO ), the remainder consisting of aluminium and iron
2 2
containing clinker phases and other compounds. The ratio by mass (CaO)/(SiO ) shall be not less than
2,0. The content of magnesium oxide (MgO) shall not exceed 5,0 % by mass.
Portland cement clinker incorporated in sulfate resisting Portland cement (CEM I, see 6.2) and sulfate
resisting pozzolanic cements (CEM IV, see 6.2) shall fulfil additional requirements for tricalcium
aluminate content (C A). The tricalcium aluminate content of the clinker shall be calculated by
Formula (1) as follows:
C A = 2,65 A – 1,69 F (1)
where
A is the percentage of aluminium oxide (Al O ) by mass of the clinker as determined in
2 3
accordance with EN 196-2;
F is the percentage of iron (III) oxide (Fe O ) by mass of the clinker as determined in
2 3
accordance with EN 196-2.
It can happen that a negative C A value is obtained from the calculation. In this case, the value 0 % by
mass should be recorded. A test method to determine the C A content of clinker from the analysis of a
spot sample of cement is currently under development by CEN/TC 51. Until this method is available, the
C A content should be directly measured on the clinker. In the specific case of CEM I, it is permissible to
calculate the C A content of clinker from the chemical analysis of the cement. The minimum frequency
of testing and the use of alternative methods for the direct or indirect evaluation of C A should be
included in the factory production control (see EN 197-2). A typical frequency of testing is two per
month in routine situations.
Sulfate resisting Portland cements and sulfate resisting pozzolanic cements are made with Portland
cement clinker in which the C A content does not exceed:
— for CEM I: 0 % by mass, 3 % by mass or 5 % by mass as appropriate (see 6.2);
— for CEM IV/A and CEM IV/B: 9 % by mass.
5.2.2 Granulated blast furnace slag (S)
Granulated blast furnace slag is made by rapid cooling of a slag melt of suitable composition, as
obtained by smelting iron ore in a blast furnace and contains at least two-thirds by mass of glassy slag
and possesses hydraulic properties when suitably activated.
Granulated blast furnace slag shall consist of at least two-thirds by mass of the sum of calcium oxide
(CaO), magnesium oxide (MgO) and silicon dioxide (SiO ). The remainder contains aluminium oxide
(Al O ) together with small amounts of other compounds. The ratio by mass (CaO + MgO)/(SiO ) shall
2 3 2
exceed 1,0.
5.2.3 Pozzolanic materials (P, Q)
5.2.3.1 General
Pozzolanic materials are natural substances of siliceous or silico-aluminous composition or a
combination thereof. Although fly ash and silica fume have pozzolanic properties, they are specified in
separate subclauses (see 5.2.4 and 5.2.7).
Pozzolanic materials do not harden in themselves when mixed with water but, when finely ground and
in the presence of water, they react at normal ambient temperature with dissolved calcium hydroxide
(Ca(OH) ) to form strength-developing calcium silicate and calcium aluminate compounds. These
compounds are similar to those which are formed in the hardening of hydraulic materials. Pozzolanas
consist essentially of reactive silicon dioxide (SiO ) and aluminium oxide (Al O ). The remainder
2 2 3
contains iron oxide (Fe O ) and other oxides. The proportion of reactive calcium oxide for hardening is
2 3
negligible. The reactive silicon dioxide content shall be not less than 25,0 % by mass.
Pozzolanic materials shall be correctly prepared, i.e. selected, homogenized, dried, or heat-treated and
comminuted, depending on their state of production or delivery.
5.2.3.2 Natural pozzolana (P)
Natural pozzolanas are usually materials of volcanic origin or sedimentary rocks with suitable chemical
and mineralogical composition and shall conform to 5.2.3.1.
5.2.3.3 Natural calcined pozzolana (Q)
Natural calcined pozzolanas are materials of volcanic origin, clays, shales or sedimentary rocks,
activated by thermal treatment and shall conform to 5.2.3.1.
5.2.4 Fly ashes (V, W)
5.2.4.1 General
Fly ash is obtained by electrostatic or mechanical precipitation of dust-like particles from the flue gases
from furnaces fired with pulverized coal.
NOTE For definition of fly ash see EN 450-1.
Ash obtained by other methods shall not be used in cement that conforms to this standard.
Fly ash can be siliceous or calcareous in nature. The former has pozzolanic properties; the latter can
have, in addition, hydraulic properties. The loss on ignition of fly ash determined in accordance with
EN 196-2, but using an ignition time of 1 h, shall be within one of the following limits:
a) 0 % to 5,0 % by mass;
b) 0 % to 7,0 % by mass;
c) 0 % to 9,0 % by mass.
The upper limit of loss on ignition of the fly ash used as a main constituent for the production of a
cement shall be stated on its packaging and/or delivery note.
The purpose of the requirement for the loss on ignition is to limit the residue of unburnt carbon in the
fly ash. It is therefore sufficient to show, through direct measurement of unburnt carbon residue, that
the content of unburnt carbon falls within the limits of the categories specified above. The content of
unburnt carbon is determined in accordance with ISO 10694.
5.2.4.2 Siliceous fly ash (V)
Siliceous fly ash is a fine powder of mostly spherical particles having pozzolanic properties. It consists
essentially of reactive silicon dioxide (SiO ) and aluminium oxide (Al O ). The remainder contains iron
2 2 3
oxide (Fe O ) and other compounds.
2 3
The proportion of reactive calcium oxide (CaO) shall be less than 10,0 % by mass, the content of free
calcium oxide, as determined by the method described in EN 451-1 shall not exceed 1,0 % by mass. Fly
ash having a free calcium oxide content higher than 1,0 % by mass but less than 2,5 % by mass is also
acceptable, provided that the requirement on expansion (soundness) does not exceed 10 mm when
tested in accordance with EN 196-3 using a mixture of 30 % by mass of siliceous fly ash and 70 % by
mass of a CEM I cement conforming to this document.
The reactive silicon dioxide content shall not be less than 25,0 % by mass.
5.2.4.3 Calcareous fly ash (W)
Calcareous fly ash is a fine powder, having hydraulic and/or pozzolanic properties. It consists
essentially of reactive calcium oxide (CaO), reactive silicon dioxide (SiO ) and aluminium oxide
(Al O ). The remainder contains iron oxide (Fe O ) and other compounds. The proportion of reactive
2 3 2 3
calcium oxide shall not be less than 10,0 % by mass. Calcareous fly ash containing between 10,0 % and
15,0 % by mass of reactive calcium oxide shall contain not less than 25,0 % by mass of reactive silicon
dioxide.
Adequately ground calcareous fly ash containing more than 15,0 % by mass of reactive calcium oxide
shall have a compressive strength of at least 10,0 MPa at 28 days when tested in accordance with
EN 196-1. Before testing, the fly ash shall be ground and the fineness, expressed as the proportion by
mass of the ash retained when wet sieved on a 40 µm mesh sieve, shall be between 10 % and 30 % by
mass. The test mortar shall be prepared with ground calcareous fly ash only instead of cement. The
mortar specimens shall be demoulded 48 h after preparation and then cured in a moist atmosphere of
relative humidity of at least 90 % until tested.
The expansion (soundness) of calcareous fly ash shall not exceed 10 mm when tested in accordance
with EN 196-3 using a mixture of 30 % by mass of calcareous fly ash ground as described above and
70 % by mass of a CEM I cement conforming to this document.
If the sulfate (SO ) content of the fly ash exceeds the permissible upper limit for the sulfate content of
the cement then this has to be taken into account for the manufacture of the cement by appropriately
reducing the other calcium sulfate-containing constituents.
5.2.5 Burnt shale (T)
Burnt shale, specifically burnt oil shale, is produced in a special kiln at temperatures of approximately
800 °C. Owing to the composition of the natural material and the production process, burnt shale
contains clinker phases, mainly dicalcium silicate and monocalcium aluminate. It also contains, besides
small amounts of free calcium oxide and calcium sulfate, larger proportions of pozzolanically reacting
oxides, especially silicon dioxide. Consequently, in a finely ground state burnt shale shows pronounced
hydraulic properties like Portland cement and in addition pozzolanic properties.
Adequately ground burnt shale shall have a compressive strength of at least 25,0 MPa at 28 days when
tested in accordance with EN 196-1. The test mortar shall be prepared with finely ground burnt shale
only instead of cement. The mortar specimens shall be demoulded 48 h after preparation and cured in a
moist atmosphere of relative humidity of at least 90 % until tested.
The expansion (soundness) of burnt shale shall not exceed 10 mm when tested in accordance with
EN 196-3 using a mixture of 30 % by mass of ground burnt shale and 70 % by mass of a CEM I cement
conforming to this document.
If the sulfate (SO ) content of the burnt shale exceeds the permissible upper limit for the sulfate content
of the cement then this has to be taken into account for the manufacture of the cement by appropriately
reducing the other calcium sulfate-containing constituents.
5.2.6 Limestone (L, LL)
Limestone shall meet the following requirements:
a) The calcium carbonate (CaCO ) content calculated from the calcium oxide content shall be at least
75 % by mass.
b) The clay content, determined by the methylene blue test in accordance with EN 933-9, shall not
exceed 1,20 g/100 g. For this test the limestone shall be ground to a fineness of approximately
5 000 cm /g determined as specific surface in accordance with EN 196-6.
c) The total organic carbon (TOC) content, when tested in accordance with EN 13639, shall conform to
one of the following criteria:
1) LL: shall not exceed 0,20 % by mass;
2) L: shall not exceed 0,50 % by mass.
5.2.7 Silica fume (D)
Silica fume originates from the reduction of high purity quartz with coal in electric arc furnaces in the
production of silicon and ferrosilicon alloys and consists of very fine spherical particles containing at
least 85 % by mass of amorphous silicon dioxide. The content of elemental silicon (Si) determined
according to ISO 9286, shall not be greater than 0,4 % by mass.
Silica fume shall meet the following requirements:
a) the loss on ignition shall not exceed 4,0 % by mass determined in accordance with EN 196-2 but
using an ignition time of 1 h;
b) the specific surface (BET) of the untreated silica fume shall be at least 15,0 m /g when tested in
accordance with ISO 9277.
For intergrinding with clinker and calcium sulfate the silica fume may be in its original state or
compacted or pelletized (with water) or equivalently processed.
5.3 Minor additional constituents
Minor additional constituents are specially selected, inorganic natural mineral materials, inorganic
mineral materials derived from the clinker production process or constituents as specified in 5.2 unless
they are included as main constituents in the cement.
Minor additional constituents, after appropriate preparation and on account of their particle size
distribution, improve the physical properties of the cement (such as workability or water retention).
They can be inert or have slightly hydraulic, latent hydraulic or pozzolanic properties. However, no
requirements are set for them in this respect.
Minor additional constituents shall be correctly prepared, i.e. selected, homogenized, dried and
comminuted depending on their state of production or delivery. They shall not increase the water
demand of the cement appreciably, impair the resistance of the concrete or mortar to deterioration in
any way or reduce the corrosion protection of the reinforcement.
Information on the minor additional constituents in the cement should be available from the
manufacturer on request.
5.4 Calcium sulfate
Calcium sulfate is added to the other constituents of cement during its manufacture to control setting.
Calcium sulfate can be gypsum (calcium sulfate dihydrate, CaSO · 2H O), hemihydrate
4 2
(CaSO · 1/2H O), or anhydrite (anhydrous calcium sulfate, CaSO ) or any mixture of them. Gypsum
4 2 4
and anhydrite are found naturally. Calcium sulfate is also available as a by-product of certain industrial
processes.
5.5 Additives
Additives for the purpose of this document are constituents not covered in 5.2 to 5.4 which are added to
improve the manufacture or the properties of the cement.
The total quantity of additives shall not exceed 1,0 % by mass of the cement (except for pigments). The
quantity of organic additives on a dry basis shall not exceed 0,2 % by mass of the cement. A higher
quantity may be incorporated in cements provided that the maximum quantity, in % by mass, is
declared on the packaging and/or the delivery note.
These additives shall not promote corrosion of the reinforcement or impair the properties of the
cement or of the concrete or mortar made from the cement.
When admixtures for concrete, mortar or grouts conforming to the EN 934 series are used in cement
the designation of the admixture shall be declared on bags or delivery documents.
6 Composition and notation
6.1 Composition and notation of common cements
The products in the family of common cements, covered by this document, and their notation are given
in Table 1. They are grouped into six main cement types as follows:
— CEM I Portland cement,
— CEM II Portland composite cement,
— CEM III Blast furnace cement,
— CEM IV Pozzolanic cement,
— CEM V Slag-pozzolanic cement,
— CEM VI Composite cement.
The composition of each of the products in the family of common cements shall be in accordance with
Table 1.
NOTE For clarity in definition, the requirements for the composition refer to the sum of all main and minor
additional constituents. The final cement is to be understood as the main and minor additional constituents plus
the necessary calcium sulfate (see 5.4) and any additives (see 5.5).
Table 1 — The 39 products in the family of common cements
a
Composition (percentage by mass )
Main constituents
Notation of the 39 products
Pozzolana Fly ash
Minor
Main
(types of common cement)
Blast-
Silica Burnt additional
types
Clinker furnace Limestone
natural calca-
fume shale constituen
natural siliceous
slag
calcined reous
ts
b
Type name Type notation K S P Q V W T L LL
D
CEM I Portland cement CEM I 95–100 – – – – – – – – – 0–5
CEM II/A-S 80–94 6–20 – – – – – – – – 0–5
Portland-slag
cement
CEM II/B-S 65–79 21–35 – – – – – – – – 0–5
Portland-silica
CEM II/A-D 90–94 – 6–10 – – – – – – – 0–5
fume cement
CEM II/A-P 80–94 – – 6–20 – – – – – – 0–5
Portland-
CEM II/B-P 65–79 – – 21–35 – – – – – – 0–5
pozzolana
CEM II/A-Q 80–94 – – – 6–20 – – – – – 0–5
cement
CEM II/B-Q 65–79 – – – 21–35 – – – – – 0–5
CEM II/A-V 80–94 – – – – 6–20 – – – – 0–5
CEM II
CEM II/B-V 65–79 – – – – 21–35 – – – – 0–5
Portland-fly ash
cement
CEM II/A-W 80–94 – – – – – 6–20 – – – 0–5
CEM II/B-W 65–79 – – – – – 21–35 – – – 0–5
Portland-burnt CEM II/A-T 80–94 – – – – – – 6–20 – – 0–5
shale cement CEM II/B-T 65–79 – – – – – – 21–35 – – 0–5
CEM II/A-L 80–94 – – – – – – – 6–20 – 0–5
Portland-
CEM II/B-L 65–79 – – – – – – – 21–35 – 0–5
limestone
CEM II/A-LL 80–94 – – – – – – – – 6–20 0–5
cement
CEM II/B-LL 65–79 – – – – – – – – 21–35 0–5
a
Composition (percentage by mass )
Main constituents
Notation of the 39 products
Pozzolana Fly ash
Minor
Main
(types of common cement) Blast-
Silica Burnt additional
types
Clinker furnace Limestone
natural calca-
fume shale constituen
natural siliceous
slag
calcined reous
ts
b
Type name Type notation K S P Q V W T L LL
D
CEM II/A-M 80–88 < –––––––––––––––––––––––––– 12–20 –––––––––––––––––––––––––- > 0–5
CEM II/B-M 65–79 < ––––––––––––––––––––
...
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