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ASTM C759-10

(Test Method)

Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions

Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions

SIGNIFICANCE AND USE
These test methods are designed to show whether a given material meets the purchaser's specifications.
An assay is performed to determine whether the material has the specified plutonium content.
Determination of the isotopic content of the plutonium in the plutonium-nitrate solution is made to establish whether the effective fissile content is in compliance with the purchaser's specifications.
Impurity content is determined by a variety of methods to ensure that the maximum concentration limit of specified impurities is not exceeded. Determination of impurities is also required for calculation of the equivalent boron content (EBC).
SCOPE
1.1 These test methods cover procedures for the chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of nuclear-grade plutonium nitrate solutions to determine compliance with specifications.  
1.2 The analytical procedures appear in the following order:
  Sections   Plutonium by Controlled-Potential Coulometry  Plutonium by Amperometric Titration with Iron(II)  Plutonium by Diode Array Spectrophotometry Free Acid by Titration in an Oxalate Solution8 to 15 Free Acid by Iodate Precipitation-Potentiometric Titration
Test Method16 to 22 Uranium by Arsenazo I Spectrophotometric Test Method23 to 33 Thorium by Thorin Spectrophotometric Test Method34 to 42 Iron by 1,10-Phenanthroline Spectrophotometric Test Method43 to 50 Impurities by ICP-AES Chloride by Thiocyanate Spectrophotometric Test Method51 to 58 Fluoride by Distillation-Spectrophotometric Test Method59 to 66 Sulfate by Barium Sulfate Turbidimetric Test Method67 to 74 Isotopic Composition by Mass Spectrometry75 to 76 Plutonium 238 Isotopic Abundance by Alpha Spectrometry Americium-241 by Extraction and Gamma Counting77 to 85 Americium-241 by Gamma Counting86 to 94 Gamma-Emitting Fission Products, Uranium, and Thorium by Gamma-Ray Spectroscopy94 to 102 Rare Earths by Copper Spark Spectrochemical Test Method103 to 105 Tungsten, Niobium (Columbium), and Tantalum by Spectro
chemical Test Method106 to 114 Sample Preparation for Spectrographic Analysis for General
Impurities 115 to 118
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safeguard and safety hazard statements, see Section 6.  
8.1 This test method covers the determination of free acid in plutonium nitrate solutions (4, 5).  
16.1 This test method covers the determination of free acid in strong acid solutions of plutonium nitrate.  
23.1 This test method covers the determination of uranium in the range from 300 to 3000 μg/g of plutonium in plutonium nitrate solutions.  
34.1 This test method covers the determination of 10 to 150 μg of thorium per gram of plutonium in plutonium nitrate solutions.  
43.1 This test method covers the determination of microgram quantities of iron in plutonium nitrate solutions.  
51.1 This test method (9) is used to determine chloride in plutonium nitrate solution.  
59.1 This test method covers the determination of microquantities of fluoride in plutonium nitrate solutions.  
67.1 This test procedure covers the determination of the sulfate concentration in plutonium nitrate solutions in the range from 50 to 700 μg/g of plutonium.  
75.1 This test method covers the determination of the isotopic content of nuclear-grade plutonium nitrate solutions.  
77.1 This test method covers the determination of americium-241 in plutonium nitrate solutions.  
86.1 This test method covers the determination of americium-241 in plutonium nitrate solutions that do not contain significant amounts of other radioa...

General Information

Status
Historical
Publication Date
31-May-2010
ICS
27.120.30 - Fissile materials and nuclear fuel technology
Technical Committee
C26 - Nuclear Fuel Cycle
Drafting Committee
C26.05 - Methods of Test
Current Stage
Ref Project

Relations

Replaces
ASTM C759-04 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
Effective Date
01-Jun-2010
Replaced By
ASTM C759-18 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
Effective Date
01-Sep-2018
Referred By
ASTM C1432-15 - Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis
Effective Date
01-Jun-2010
Referred By
ASTM C758-18 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Metal
Effective Date
01-Jun-2010
Referred By
ASTM C1637-21 - Standard Test Method for Determination of Impurities in Plutonium Materials—Acid Digestion and Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) Analysis
Effective Date
01-Jun-2010
Referred By
ASTM C1307-21 - Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry
Effective Date
01-Jun-2010
Referred By
ASTM C1268-15 - Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry
Effective Date
01-Jun-2010

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ASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate SolutionsASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
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ASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
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REDLINE ASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate SolutionsREDLINE ASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
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REDLINE ASTM C759-10 - Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: C759 − 10
Standard Test Methods for
Chemical, Mass Spectrometric, Spectrochemical, Nuclear,
and Radiochemical Analysis of Nuclear-Grade Plutonium
1
Nitrate Solutions
This standard is issued under the fixed designation C759; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope bility of regulatory limitations prior to use. For specific
safeguard and safety hazard statements, see Section 6.
1.1 These test methods cover procedures for the chemical,
mass spectrometric, spectrochemical, nuclear, and radiochemi-
2. Referenced Documents
cal analysis of nuclear-grade plutonium nitrate solutions to
3
2.1 ASTM Standards:
determine compliance with specifications.
C697Test Methods for Chemical, Mass Spectrometric, and
1.2 Theanalyticalproceduresappearinthefollowingorder:
Spectrochemical Analysis of Nuclear-Grade Plutonium
Sections
Dioxide Powders and Pellets
2 C852Guide for Design Criteria for Plutonium Gloveboxes
Plutonium by Controlled-Potential Coulometry
2
Plutonium by Amperometric Titration with Iron(II) C1009Guide for Establishing and Maintaining a Quality
Plutonium by Diode Array Spectrophotometry
AssuranceProgramforAnalyticalLaboratoriesWithinthe
Free Acid by Titration in an Oxalate Solution 8 to 15
Nuclear Industry
Free Acid by Iodate Precipitation-Potentiometric Titration 16 to 22
Test Method C1068Guide for Qualification of Measurement Methods by
Uranium by Arsenazo I Spectrophotometric Test Method 23 to 33
a Laboratory Within the Nuclear Industry
Thorium by Thorin Spectrophotometric Test Method 34 to 42
C1108Test Method for Plutonium by Controlled-Potential
Iron by 1,10-Phenanthroline Spectrophotometric Test Method 43 to 50
Impurities by ICP-AES Coulometry
Chloride by Thiocyanate Spectrophotometric Test Method 51 to 58
C1128Guide for Preparation of Working Reference Materi-
Fluoride by Distillation-Spectrophotometric Test Method 59 to 66
als for Use in Analysis of Nuclear Fuel Cycle Materials
Sulfate by Barium Sulfate Turbidimetric Test Method 67 to 74
Isotopic Composition by Mass Spectrometry 75 to 76
C1156Guide for Establishing Calibration for a Measure-
Plutonium —238 Isotopic Abundance by Alpha Spectrometry
ment Method Used toAnalyze Nuclear Fuel Cycle Mate-
Americium-241 by Extraction and Gamma Counting 77 to 85
rials
Americium-241 by Gamma Counting 86 to 94
Gamma-Emitting Fission Products, Uranium, and Thorium by 94 to 102
C1165 Test Method for Determining Plutonium by
Gamma-Ray Spectroscopy
Controlled-Potential Coulometry in H SO at a Platinum
2 4
Rare Earths by Copper Spark Spectrochemical Test Method 103 to 105
Working Electrode
Tungsten, Niobium (Columbium), and Tantalum by Spectro 106 to 114
chemical Test Method
C1206Test Method for Plutonium by Iron (II)/Chromium
Sample Preparation for Spectrographic Analysis for General 115 to 118 4
(VI) Amperometric Titration (Withdrawn 2015)
Impurities
C1210Guide for Establishing a Measurement System Qual-
1.3 The values stated in SI units are to be regarded as
ity Control Program for Analytical Chemistry Laborato-
standard. The values given in parentheses are for information
ries Within the Nuclear Industry
only.
C1235 Test Method for Plutonium by Titanium(III)/
4
1.4 This standard does not purport to address all of the
Cerium(IV) Titration (Withdrawn 2005)
safety concerns, if any, associated with its use. It is the
C1268 Test Method for Quantitative Determination of
241
responsibility of the user of this standard to establish appro-
Am in Plutonium by Gamma-Ray Spectrometry
priate safety and health practices and determine the applica-
C1297Guide for Qualification of Laboratory Analysts for
the Analysis of Nuclear Fuel Cycle Materials
1
These test methods are under the jurisdiction of ASTM Committee C26 on
3
Nuclear Fuel Cycle and are the direct responsibility of Subcommittee C26.05 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Methods of Test. contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
CurrenteditionapprovedJune1,2010.PublishedJuly2010.Originallyapproved Standardsvolume information, refer to the standard’s Document Summary page on
in 1973. Last previous edition approved in 2004 as C759–04. DOI: 10.1520/ the ASTM website
4
C0759-10. The last approved version of this historical standard is referenced on
2
Discontinued as of November 15, 1992. www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
C759 − 10
C1307Test Method for PlutoniumAssay by Plut
...

This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:C759–04 Designation:C759–10
Standard Test Methods for
Chemical, Mass Spectrometric, Spectrochemical, Nuclear,
and Radiochemical Analysis of Nuclear-Grade Plutonium
1
Nitrate Solutions
This standard is issued under the fixed designation C759; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 These test methods cover procedures for the chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical
analysis of nuclear-grade plutonium nitrate solutions to determine compliance with specifications.
1.2 The analytical procedures appear in the following order:
Sections
2
Plutonium by Controlled-Potential Coulometry
2
Plutonium by Amperometric Titration with Iron(II)
Plutonium by Diode Array Spectrophotometry
Free Acid by Titration in an Oxalate Solution 8 to 15
Free Acid by Iodate Precipitation-Potentiometric Titration 16 to 22
Test Method
Uranium by Arsenazo I Spectrophotometric Test Method 23 to 33
Thorium by Thorin Spectrophotometric Test Method 34 to 42
Iron by 1,10-Phenanthroline Spectrophotometric Test Method 43 to 50
Impurities by ICP-AES
Chloride by Thiocyanate Spectrophotometric Test Method 51 to 58
Fluoride by Distillation-Spectrophotometric Test Method 59 to 66
Sulfate by Barium Sulfate Turbidimetric Test Method 67 to 74
Isotopic Composition by Mass Spectrometry 75 to 76
Plutonium —238 Isotopic Abundance by Alpha Spectrometry
Americium-241 by Extraction and Gamma Counting 77 to 85
Americium-241 by Gamma Counting 86 to 94
Gamma-Emitting Fission Products, Uranium, and Thorium by 94 to 102
Gamma-Ray Spectroscopy
Rare Earths by Copper Spark Spectrochemical Test Method 103 to 105
Tungsten, Niobium (Columbium), and Tantalum by Spectro 106 to 114
chemical Test Method
Sample Preparation for Spectrographic Analysis for General 115to118
Impurities123 to 126
Sample Preparation for Spectrographic Analysis for General 115to118
Impurities
1.3
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific safeguard and safety hazard statements, see Section 6.
2. Referenced Documents
3
2.1 ASTM Standards:
C697 Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Plutonium Dioxide
Powders and Pellets
C852 Guide for Design Criteria for Plutonium Gloveboxes
1
These test methods are under the jurisdiction of ASTM Committee C26 on Nuclear Fuel Cycle and are the direct responsibility of Subcommittee C26.05 on Methods
of Test.
Current edition approved Jan.June 1, 2004.2010. Published February 2004.July 2010. Originally approved in 1973. Last previous edition approved in 19982004 as
C759–98.C759–04. DOI: 10.1520/C0759-104.
2
Discontinued as of November 15, 1992.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standardsvolume information, refer to the standard’s Document Summary page on the ASTM website
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
C759–10
C1009 GuideforEstablishingaQualityAssuranceProgramforAnalyticalChemistryLaboratoriesWithintheNuclearIndustry
C1068 Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry
C1108 Test Method for Plutonium by Controlled-Potential Coulometry
C1128 Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials
C1156 Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials
C1165 TestMethodforDeterminingPlutoniumbyControlled-PotentialCoulometryinH SO ataPlatinumWorkingElectrode
2 4
C1206 Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration
C1210 Guide for Establishing a Measurement System Quality Control Program forAnalytical Chemistry Laboratories Within
the Nuclear Industry
C1235 Test Method for Plutonium by
...

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ASTM C1268-23(Test Method)
Standard Test Method for Quantitative Determination of 241Am in Plutonium by Gamma-Ray Spectrometry

SIGNIFICANCE AND USE
5.1 This test method allows the determination of 241Am in a plutonium solution without separation of the americium from the plutonium. It is generally applicable to any solution containing 241Am.  
5.2 The 241Am in solid plutonium materials may be determined when these materials are dissolved (see Practice C1168).  
5.3 When the plutonium solution contains unacceptable levels of fission products or other materials, this method may be used following a tri-n-octylphosphine oxide (TOPO) extraction, ion exchange or other similar separation techniques (see Test Methods C758 and C759).  
5.4 This test method is less subject to interferences from plutonium than alpha counting since the energy of the gamma ray used for the analysis is better resolved from other gamma rays than the alpha particle energies used for alpha counting.  
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5.6 This test method is applicable only to homogeneous solutions. This test method is not suitable for solutions containing solids.  
5.7 Solutions containing 241Am at concentrations as little as 1 × 10−5 g/L may be analyzed using this method. The lower limit depends on the detector used and the counting geometry. Solutions containing high concentrations may be analyzed following an appropriate dilution.
SCOPE
1.1 This test method covers the quantitative determination of 241Am by gamma-ray spectrometry in plutonium nitrate solution samples that do not contain significant amounts of radioactive fission products or other high specific activity gamma-ray emitters.  
1.2 This test method can be used to determine the 241Am in samples of plutonium metal, oxide and other solid forms, when the solid is appropriately sampled and dissolved.  
1.3 The values stated in SI units are to be regarded as standard. Additionally, the non-SI units of electron volts, kiloelectron volts, and liters are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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ASTM C1168-23(Practice)
Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis

SIGNIFICANCE AND USE
5.1 Plutonium and uranium mixtures are used as nuclear reactor fuels. For use as a nuclear reactor fuel, the material must meet certain criteria for combined uranium and plutonium content, effective fissile content, and impurity content as described in Specifications C757 and C833. After dissolution using one of the procedures described in this practice, the material is assayed for plutonium and uranium to determine if the content is correct as specified by the purchaser.  
5.2 Unique plutonium materials, such as alloys, compounds, and scrap metals, are typically dissolved with various acid mixtures or by fusion with various fluxes. Many plutonium salts are soluble in hydrochloric acid. One or more of the procedures included in this practice may be effective for some of these materials; however their applicability to a particular plutonium material shall be verified by the user.
SCOPE
1.1 This practice is a compilation of dissolution techniques for plutonium materials that are applicable to the test methods used for characterizing these materials. Dissolution treatments for the major plutonium materials assayed for plutonium or analyzed for other components are listed. Aliquots of the dissolved materials are dispensed on a mass basis when one of the analyses must be of high precision, such as plutonium assay; otherwise they are dispensed on a volume basis.  
1.2 Procedures in this practice are intended for the dissolution of plutonium metal, plutonium oxide, and uranium-plutonium mixed oxides. Aliquots of dissolved materials are analyzed using test methods, such as those developed by Subcommittee C26.05 on Methods of Test, to demonstrate compliance with applicable requirements. These may include product specifications such as Specifications C757 and C833.  
1.3 One or more of the procedures in this practice may be applicable to unique plutonium materials, such as alloys, compounds, and scrap materials. The user must determine the applicability of this practice to such materials.  
1.4 The treatments, in order of presentation, are as follows:    
Procedure Number  
Procedure Title  
Section  
1  
Dissolution of Plutonium Metal with Hydrochloric Acid at Room Temperature  
9  
2  
Dissolution of Plutonium Metal with Hydrochloric Acid and Heating  
10  
3  
Dissolution of Plutonium Metal with Sulfuric Acid  
11  
4  
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12  
5  
Dissolution of Plutonium Oxide and Uranium-Plutonium Mixed Oxides by Sodium Bisulfate Fusion  
13  
6  
Dissolution of Uranium-Plutonium Mixed Oxides and Low-Fired Plutonium Oxide in Beakers  
14  
7  
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8  
Open-Vessel (with Reflux Condenser) Dissolution of Mixed Oxide Powder  
16  
9  
Closed-Vessel Hot Block Dissolution of Plutonium Oxide Powder  
17  
10  
Open-Vessel (with Reflux Condenser) Dissolution of Mixed Oxide Pellets  
18  
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SCOPE
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ASTM C833-23(Specification)
Standard Specification for Sintered (Uranium-Plutonium) Dioxide Pellets for Light Water Reactors

ABSTRACT
This specification covers finished sintered and ground (uranium-plutonium) dioxide pellets for use in thermal reactors. It applies to uranium-plutonium dioxide pellets containing plutonium additions up to 15 % weight. The diversity of manufacturing methods shall be recognized by which uranium-plutonium dioxide pellets are produced and the many special requirements for chemical and physical characterization that may be imposed by the operating conditions to which the pellets will be subjected in specific reactor systems. The following are different chemical requirements that shall be determined: uranium content, plutonium content, impurity content, stoichiometry, moisture content, gas content, and americium-241 content. Nuclear requirements such as isotopic content, plutonium equivalent at a given date, equivalent boron content, and reactivity shall also be determined. Physical properties of the pellets like dimensions, density, grain size, pore morphology, plutonium-oxide homogeneity, plutonium-oxide particle size, plutonium-oxide particle distribution, integrity, and surface cracks shall be determined as well. The surfaces of finished pellets shall be visually free of loose chips, oil, macroscopic inclusions, and foreign materials. An estimate of the fuel pellet irradiation stability shall be obtained unless adequate allowance for such effects are factored into the fuel rod design. The estimate of the stability shall consist of either conformance to the thermal stability test as specified in the or by adequate correlation of manufacturing process or microstructure to in-reactor behavior, or both.
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Standard Guide for Design, Fabrication, and Installation of Nuclear Fuel Dissolution Facilities

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4.1 The purpose of this guide is to provide information that will help to ensure that nuclear fuel dissolution facilities are conceived, designed, fabricated, constructed, and installed in an economic and efficient manner. This guide will help facilities meet the intended performance functions, eliminate or minimize the possibility of nuclear criticality and provide for the protection of both the operator personnel and the public at large under normal and abnormal (emergency) operating conditions as well as under credible failure or accident conditions.
SCOPE
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1.2 Applicability and Exclusions:  
1.2.1 Operations—This guide does not cover the operation of nuclear fuel dissolution facilities. Some operating considerations are noted to the extent that these impact upon or influence design.
1.2.1.1 Dissolution Procedures—Fuel compositions, fuel element geometry, and fuel manufacturing methods are subject to continuous change in response to the demands of new reactor designs and requirements. These changes preclude the inclusion of design considerations for dissolvers suitable for the processing of all possible fuel types. This guide will only address equipment associated with dissolution cycles for those fuels that have been used most extensively in reactors as of the time of issue (or revision) of this guide. (See Appendix X1.)  
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1.2.2.1 This guide does not address special dissolution processes that may require substantially different equipment or pose different hazards than those associated with the fuel types noted above. Examples of precluded cases are electrolytic dissolution and sodium-bonded fuels processing. The guide does not address the design and fabrication of continuous dissolvers.  
1.2.3 Ancillary or auxiliary facilities (for example, steam, cooling water, electrical services) are not covered. Cold chemical feed considerations are addressed briefly.  
1.2.4 Dissolution Pretreatment—Fuel pretreatment steps incidental to the preparation of spent fuel assemblies for dissolution reprocessing are not covered by this guide. This exclusion applies to thermal treatment steps such as “Voloxidation” to drive off gases prior to dissolution, to mechanical decladding operations or process steps associated with fuel elements disassembly and removal of end fittings, to chopping and shearing operations, and to any other pretreatment operations judged essential to an efficient nuclear fuels dissolution step.  
1.2.5 Fundamentals—This guide does not address specific chemical, physical or mechanical technology, fluid mechanics, stress analysis or other engineering fundamentals that are also applied in the creation of a safe design for nuclear fuel dissolution facilities.  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI unit...

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ASTM
ASTM C859-23(Terminology)
Standard Terminology Relating to Nuclear Materials

SCOPE
1.1 This terminology standard contains terms, definitions, descriptions of terms, nomenclature, and explanations of acronyms and symbols specifically associated with standards under the jurisdiction of Committee C26 on Nuclear Fuel Cycle. The content of this terminology standard may also be applicable to documents not under the jurisdiction of Committee C26, in which case this terminology standard may be referenced in those documents.  
1.2 While subcommittees within Committee C26 are free to only provide terms and definitions within individual standards, each subcommittee may request the addition of utilized terms and definitions to this terminology standard if it believes that such serves the broader interest of Committee C26 and the nuclear fuel cycle profession. Therefore, terms and definitions proposed for inclusion in Terminology C859 need not be used in more than one committee standard before being considered.  
1.3 In general, technical terms that are defined in common dictionaries would not also be defined in this terminology standard unless there is a need to emphasize a specific definition in making appropriate use of a Committee C26 standard.  
1.4 Subcommittee C26.10 (Nondestructive Assay) also has a terminology standard applicable to its standards: Terminology C1673.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM C1554-18(2023)(Guide)
Standard Guide for Materials Handling Equipment for Hot Cells

SIGNIFICANCE AND USE
4.1 Materials handling equipment operability and long-term integrity are concerns that originate during the design and fabrication sequences. Such concerns are most efficiently addressed during one or the other of these stages. Equipment operability and integrity can be compromised during handling and installation sequences. For this reason, the subject equipment should be handled and installed under closely controlled and supervised conditions.  
4.2 This guide is intended as a supplement to other standards (Section 2, Referenced Documents), and to federal and state regulations, codes, and criteria applicable to the design of equipment intended for this use.  
4.3 This guide is intended to be generic and to apply to a wide range of types and configurations of materials handling equipment.  
4.4 The term materials handling equipment is used herein in a generic sense. It includes manipulators, cranes, carts or bogies, and special equipment for handling tools and material in hot cells.  
4.5 This service imposes stringent requirements on the quality and the integrity of the equipment, as follows:  
4.5.1 Boots and similar protective covers should not restrict movement of the equipment, should be properly sealed to the equipment and should withstand the radiation, cell atmosphere, dust, cell temperatures, chemical exposures, and cleaning and decontamination reagents, and also resist snags and tearing.  
4.5.2 Materials handling equipment should be capable of withstanding rigorous chemical cleaning and decontamination procedures.  
4.5.3 Materials handling equipment should be designed and fabricated to remain dimensionally stable throughout its life cycle.  
4.5.4 Attention to fabrication tolerances is necessary to allow the proper fit-up between components for the proper installation and mounting of materials handling equipment in hot cells, for example, when parts or components are being replaced. Fabrication tolerances should be controlled to provide sufficie...
SCOPE
1.1 Intent:  
1.1.1 This guide covers materials handling equipment used in hot cells (shielded cells) for the processing and handling of nuclear and radioactive materials. The intent of this guide is to aid in the selection and design of materials handling equipment for hot cells in order to minimize equipment failures and maximize the equipment utility.  
1.1.2 It is intended that this guide record the principles and caveats that experience has shown to be essential to the design, fabrication, installation, maintenance, repair, replacement, and decontamination and decommissioning of materials handling equipment capable of meeting the stringent demands of operating, dependably and safely, in a hot cell environment where operator visibility is limited due to the radiation exposure hazards.  
1.1.3 This guide may apply to materials handling equipment in other radioactive remotely operated facilities such as suited entry repair areas and canyons, but does not apply to materials handling equipment used in commercial power reactors.  
1.1.4 This guide covers mechanical master-slave manipulators and electro-mechanical manipulators, but does not cover electro-hydraulic manipulators.  
1.2 Applicability:  
1.2.1 This guide is intended to be applicable to equipment used under one or more of the following conditions:
1.2.1.1 The materials handled or processed constitute a significant radiation hazard to man or to the environment.
1.2.1.2 The equipment will generally be used over a long-term life cycle (for example, in excess of two years), but equipment intended for use over a shorter life cycle is not excluded.
1.2.1.3 The equipment can neither be accessed directly for purposes of operation or maintenance, nor can the equipment be viewed directly, for example, without shielded viewing windows, periscopes, or a video monitoring system.  
1.3 User Caveats:  
1.3.1 This standard is not a substitute for applied engin...

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ASTM
ASTM C1703-18(2023)(Practice)
Standard Practice for Sampling of Gaseous Uranium Hexafluoride for Enrichment

SIGNIFICANCE AND USE
5.1 Uranium hexafluoride is normally produced and handled in large (typically 1 to 14-ton) quantities and must, therefore, be characterized by reference to representative samples (see ISO 7195). The samples are used to determine compliance with the applicable commercial specification C787. The quantities involved, physical properties, chemical reactivity, and hazardous nature of UF6 are such that for representative sampling, specially designed equipment must be used and operated in accordance with the most carefully controlled and stringent procedures. This practice can be used by UF6 converters to review the effectiveness of existing procedures or as a guide to the design of equipment and procedures for future use.  
5.2 The intention of this practice is to avoid liquid UF6 sampling once the cylinder has been filled. For safety reasons, manipulation of large quantities of liquid UF6 should be avoided when possible.  
5.3 It is emphasized that this practice is not meant to address conventional or nuclear criticality safety issues.
SCOPE
1.1 This practice covers methods for withdrawing representative sample(s) of uranium hexafluoride (UF6) during a transfer occurring in the gas phase. Such transfer in the gas phase can take place during the filling of a cylinder during a continuous production process, for example the distillation column in a conversion facility. Such sample(s) may be used for determining compliance with the applicable commercial specification, for example Specification C787.  
1.2 Since UF6 sampling is taken during the filling process, this practice does not address any special additional arrangements that may be agreed upon between the buyer and the seller when the sampled bulk material is being added to residues already present in a container (“heels recycle”). Such arrangements will be based on QA procedures such as traceability of cylinder origin (to prevent for example contamination with irradiated material).  
1.3 If the receiving cylinder is purged after filling and sampling, special verifications must be performed by the user to verify the representativity of the sample(s). It is then expected that the results found on volatile impurities with gas phase sampling may be conservative.  
1.4 This practice is only applicable when the transfer occurs in the gas phase. When the transfer is performed in the liquid phase, Practice C1052 should apply. This practice does not apply to gas sampling after the cylinder has been filled since the sample taken will not be representative of the cylinder.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM C1347-08(2023)(Practice)
Standard Practice for Preparation and Dissolution of Uranium Materials for Analysis

SIGNIFICANCE AND USE
4.1 The materials covered that must meet ASTM specifications are uranium metal and uranium oxide.  
4.2 Uranium materials are used as nuclear reactor fuel. For this use, these materials must meet certain criteria for uranium content, uranium-235 enrichment, and impurity content, as described in Specifications C753 and C776. The material is assayed for uranium to determine whether the content is as specified.  
4.3 Uranium alloys, refractory uranium materials, and uranium containing scrap and ash are unique uranium materials for which the user must determine the applicability of this practice. In general, these unique uranium materials are dissolved with various acid mixtures or by fusion with various fluxes.
SCOPE
1.1 This practice covers dissolution treatments for uranium materials that are applicable to the test methods used for characterizing these materials for uranium elemental, isotopic, and impurities determinations. Dissolution treatments for the major uranium materials assayed for uranium or analyzed for other components are listed.  
1.2 The treatments, in order of presentation, are as follows:    
Procedure Title  
Section  
Dissolution of Uranium Metal and Oxide with Nitric Acid  
8.1  
Dissolution of Uranium Oxides with Nitric Acid and Residue
Treatment  
8.2  
Dissolution of Uranium-Aluminum Alloys in Hydrochloric Acid
with Residue Treatment  
8.3  
Dissolution of Uranium Scrap and Ash by Leaching with Nitric
Acid and Treatment of Residue by Carbonate Fusion  
8.4  
Dissolution of Refractory Uranium-Containing Material by
Carbonate Fusion  
8.5  
Dissolution of Uranium—Aluminum Alloys
Uranium Scrap and Ash, and Refractory
Uranium-Containing Materials by
Microwave Treatment  
8.6  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM C1165-23(Test Method)
Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H2SO4 at a Platinum Working Electrode

SIGNIFICANCE AND USE
5.1 This test method is used to ascertain whether or not materials meet specifications for plutonium concentration or plutonium mass fraction.  
5.1.1 The materials (nuclear grade plutonium nitrate solutions, plutonium metal, plutonium oxide powder, and mixed oxide and carbide powders and pellets) to which this test method applies are subject to nuclear safeguards regulations governing their possession and use. However, adherence to this test method does not automatically guarantee regulatory acceptance of the resulting safeguards measurements. It remains the sole responsibility of the user of this test method to ensure that its application to safeguards has the approval of the proper regulatory authorities.  
5.1.2 When used in conjunction with appropriate certified reference materials (CRMs), this test method can demonstrate traceability to the international measurements system (SI).  
5.2 Fitness for Purpose of Safeguards and Nuclear Safety Application—Methods intended for use in safeguards and nuclear safety applications shall meet the requirements specified by Guide C1068 for use in such applications.  
5.3 A chemical calibration of the coulometer is necessary for accurate results.
FIG. 1 Example of a Cell Design Used at Los Alamos National Laboratory (LANL)
SCOPE
1.1 This test method covers the determination of milligram quantities of plutonium in unirradiated uranium-plutonium mixed oxide having a U/Pu ratio range of 0.1 to 10. This test method is also applicable to plutonium metal, plutonium oxide, uranium-plutonium mixed carbide, various plutonium compounds including fluoride and chloride salts, and plutonium solutions.  
1.2 The recommended amount of plutonium for each aliquant in the coulometric analysis is 5 mg to 10 mg. Precision worsens for lower amounts of plutonium, and elapsed time of electrolysis becomes impractical for higher amounts of plutonium.  
1.3 The quantity values stated in SI units are to be regarded as standard. The quantity values with non-SI units are given in parentheses for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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