ASTM D6271-10(2016)
(Test Method)Standard Test Method for Estimating Contribution of Environmental Tobacco Smoke to Respirable Suspended Particles Based on Solanesol (Withdrawn 2022)
Standard Test Method for Estimating Contribution of Environmental Tobacco Smoke to Respirable Suspended Particles Based on Solanesol (Withdrawn 2022)
SIGNIFICANCE AND USE
5.1 Environmental tobacco smoke consists of both vapor and particulate phase components. Due to the nature of vapor and particulate phases, they rarely correlate well, and an accurate assessment of ETS levels in indoor air requires determining good tracers of both phases. Among the attributes of an ideal ETS tracer, one critical characteristic is that the tracer should “remain in a fairly consistent ratio to the individual contaminant of interest or category of contaminants of interest (for example, suspended particulates) under a range of environmental conditions...” (5). Solanesol meets this requirement, staying in a constant ratio to the RSP contributed by tobacco smoke over a variety of ventilation conditions and sampling durations (6). UVPM and FPM, which are the tracers or markers employed by Test Methods D5955, also fulfill this requirement. Airborne solanesol, however, is unique in that it is specific to tobacco smoke and is found only in the particulate phase of ETS. Its high molecular weight and low volatility make it extremely unlikely that any solanesol will be lost from the membrane filter used for sample collection. Solanesol constitutes approximately 3 % by weight of the RSP of ETS (2,7,8), making it suitable for measurement at realistic smoking rates. Of the available ETS particulate phase markers (UVPM, FPM, and solanesol), all are currently used and relied upon, but solanesol is considered to be a better marker for the particulate phase of ETS and, as a result, provides the best way of quantifying the contribution of ETS particulate matter to RSP (3, 4, 9-13).
5.2 To be able to quantify the contribution of ETS to RSP with a tobacco-specific marker is important because RSP is not specific to tobacco smoke. RSP is a necessary indicator of overall air quality; the Occupational Safety and Health Administration (OSHA) has previously set a PEL (permissible exposure level) for respirable dust in the workplace of 5000 μg/m3. However, RSP emanates from n...
SCOPE
1.1 This test method covers the sampling/analysis of respirable suspended particles (RSP) and the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS). The test method is based on collection of total RSP on a membrane filter, extraction of the filter in methanol, and determination of solanesol, a C45 isoprenoid alcohol, by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection.
1.2 This test method is compatible with the determinations of gravimetric RSP, ultraviolet particulate matter (UVPM), and fluorescent particulate matter (FPM) (see Test Methods D5955), but does not require them. UVPM and FPM, which are based on the ultraviolet absorbance and fluorescence of the filter extract, are also used to estimate the contribution of ETS to RSP.
1.3 The sampling components consist of a 1.0-μm pore size polytetrafluoroethylene (PTFE) membrane filter in a filter cassette connected on the inlet end to a particle size separating device and, on the outlet end, to a sampling pump. This test method is applicable to personal and area sampling.
1.4 This test method is limited in sample duration only by the capacity of the membrane filter. The test method has been evaluated up to 24-h sample duration; a minimum sample duration of 1 h is recommended.
1.5 Limits of detection (LOD) for this test method at a sampling rate of 2 L/min are 0.042 μg/m3 for 1-h sample duration and 0.005 μg/m3 for 8-h sample duration.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary information is given in 13.6.
WI...
General Information
Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D6271 − 10 (Reapproved 2016)
Standard Test Method for
Estimating Contribution of Environmental Tobacco Smoke
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to Respirable Suspended Particles Based on Solanesol
This standard is issued under the fixed designation D6271; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope mine the applicability of regulatory limitations prior to use.
Specific precautionary information is given in 13.6.
1.1 This test method covers the sampling/analysis of respi-
1.8 This international standard was developed in accor-
rable suspended particles (RSP) and the estimation of the RSP
dance with internationally recognized principles on standard-
fraction attributable to environmental tobacco smoke (ETS).
ization established in the Decision on Principles for the
The test method is based on collection of total RSP on a
Development of International Standards, Guides and Recom-
membrane filter, extraction of the filter in methanol, and
mendations issued by the World Trade Organization Technical
determination of solanesol, a C isoprenoid alcohol, by high
45
Barriers to Trade (TBT) Committee.
performance liquid chromatography (HPLC) with ultraviolet
(UV) detection.
2. Referenced Documents
1.2 This test method is compatible with the determinations
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2.1 ASTM Standards:
of gravimetric RSP, ultraviolet particulate matter (UVPM), and
D1356 Terminology Relating to Sampling and Analysis of
fluorescent particulate matter (FPM) (see Test Methods
Atmospheres
D5955), but does not require them. UVPM and FPM, which
D1357 Practice for Planning the Sampling of the Ambient
are based on the ultraviolet absorbance and fluorescence of the
Atmosphere
filter extract, are also used to estimate the contribution of ETS
D3631 Test Methods for Measuring Surface Atmospheric
to RSP.
Pressure
1.3 The sampling components consist of a 1.0-µm pore size
D5337 Practice for Flow RateAdjustment of Personal Sam-
polytetrafluoroethylene (PTFE) membrane filter in a filter
pling Pumps
cassette connected on the inlet end to a particle size separating
D5955 Test Methods for Estimating Contribution of Envi-
device and, on the outlet end, to a sampling pump. This test
ronmental Tobacco Smoke to Respirable Suspended Par-
method is applicable to personal and area sampling.
ticles Based on UVPM and FPM
1.4 This test method is limited in sample duration only by
the capacity of the membrane filter. The test method has been
3. Terminology
evaluated up to 24-h sample duration; a minimum sample
3.1 Definitions—For definitions of terms used in this test
duration of1his recommended.
method, refer to Terminology D1356.
1.5 Limits of detection (LOD) for this test method at a
3.2 Definitions of Terms Specific to This Standard:
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sampling rate of 2 L/min are 0.042 µg/m for 1-h sample
3.2.1 environmental tobacco smoke (ETS)—an aged, dilute
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duration and 0.005 µg/m for 8-h sample duration.
composite of exhaled tobacco smoke (exhaled mainstream
1.6 The values stated in SI units are to be regarded as
smoke) and smoke from tobacco products (sidestream smoke).
standard. No other units of measurement are included in this
3.2.2 respirablesuspendedparticles(RSP)—particleswhich
standard.
canbedepositedinthegas-exchangeregionofthelungandare
1.7 This standard does not purport to address all of the
defined as particles that pass through a sampler having a
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safety concerns, if any, associated with its use. It is the
4.0-µm median cutpoint (1).
responsibility of the user of this standard to establish appro-
priate safety, health, and environmental practices and deter-
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
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This test method is under the jurisdiction of ASTM Committee D22 on Air contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Quality and is the direct responsibility of Subcommittee D22.05 on Indoor Air. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved March 1, 2016. Published March 2016. Originally the ASTM website.
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approved in 1998. Last previous edition approved in 2010 as D6271 – 10. DOI: The boldface numbers in parentheses refer to a list of references at the end of
10.1520/D6271-10R16. this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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D6271 − 10 (2016)
3.2.3 solanesol particulate matter (Sol-PM)—a tobacco- specific to tobacco smoke. RSP is a necessary indicator of
selective marker for the contribution of ETS particulate matter overal
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