ASTM D2375-05(2011)

Standard Test Method for Manganese in Paint Driers by EDTA Method (Withdrawn 2016)

SIGNIFICANCE AND USE
The amount of manganese drier used in oxidizing-type coatings significantly affects their drying properties. This test method may be used to confirm the stated manganese content of pure liquid manganese drier soluble in toluene-alcohol and manufactured for use by the coatings industry.
SCOPE
1.1 This test method covers a titrimetric determination of manganese in liquid paint driers that can be dissolved in a toluene-alcohol mixture and utilizes the disodium salt of ethylenediaminetetraacetic acid dihydrate (EDTA).
1.2 This test method is not applicable to drier blends.
1.3 All cations that can be titrated with EDTA in alkaline media interfere and must not be present in the sample.
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
WITHDRAWN RATIONALE
This test method covers a titrimetric determination of manganese in liquid paint driers that can be dissolved in a toluene-alcohol mixture and utilizes the disodium salt of ethylenediaminetetraacetic acid dihydrate (EDTA).
Formerly under the jurisdiction of Committee D01 on Paint and Related Coatings, Materials, and Applications, this test method was withdrawn in April 2016. This standard is being withdrawn without replacement due to its limited use by industry.

General Information

• Status: Withdrawn
• Publication Date: 31-May-2011
• Withdrawal Date: 05-Apr-2016
• ICS: 87.060.99 - Other paint ingredients
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.21 - Chemical Analysis of Paints and Paint Materials

Relations

• Replaces: ASTM D2375-05 - Standard Test Method for Manganese in Paint Driers by EDTA Method
• Effective Date: 01-Jun-2011
• Referred By: ASTM D564-87(2023) - Standard Test Methods for Liquid Paint Driers
• Effective Date: 01-Jun-2011

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D2375 − 05(Reapproved 2011)
Standard Test Method for
Manganese in Paint Driers by EDTA Method
This standard is issued under the fixed designation D2375; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 4. Significance and Use
1.1 This test method covers a titrimetric determination of 4.1 The amount of manganese drier used in oxidizing-type
manganese in liquid paint driers that can be dissolved in a coatings significantly affects their drying properties. This test
toluene-alcohol mixture and utilizes the disodium salt of
method may be used to confirm the stated manganese content
ethylenediaminetetraacetic acid dihydrate (EDTA). of pure liquid manganese drier soluble in toluene-alcohol and
manufactured for use by the coatings industry.
1.2 This test method is not applicable to drier blends.
1.3 All cations that can be titrated with EDTA in alkaline
5. Apparatus
media interfere and must not be present in the sample.
5.1 Centrifuge, capable of developing 1000 to 2000 g.
1.4 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
6. Reagents
standard.
6.1 Purity of Reagents—Reagent grade chemicals shall be
1.5 This standard does not purport to address all of the
used in all tests. Unless otherwise indicated, it is intended that
safety concerns, if any, associated with its use. It is the
all reagents shall conform to the specifications of the Commit-
responsibility of the user of this standard to establish appro-
tee onAnalytical Reagents of theAmerican Chemical Society,
priate safety and health practices and determine the applica-
where such specifications are available. Other grades may be
bility of regulatory limitations prior to use.
used, provided it is first ascertained that the reagent is of
sufficiently high purity to permit its use without lessening the
2. Referenced Documents
accuracy of the determination.
2.1 ASTM Standards:
6.2 Purity of Water—Unless otherwise indicated, references
D600Specification for Liquid Paint Driers
towatershallbeunderstoodtomeanreagentwaterconforming
D1193Specification for Reagent Water
to Type II of Specification D1193.
E180Practice for Determining the Precision of ASTM
Methods for Analysis and Testing of Industrial and Spe-
6.3 Ammonium Chloride (NH Cl).
cialty Chemicals (Withdrawn 2009)
6.4 Ammonium Hydroxide (sp gr 0.90)—Concentrated am-
E300Practice for Sampling Industrial Chemicals
monium hydroxide (NH OH).
3. Summary of Test Method
6.5 l-Ascorbic Acid.
3.1 Theliquiddrierisdissolvedintolueneandethylalcohol
6.6 Buffer Solution—Add 350 mLof concentrated NH -OH
and treated with an excess of standard EDTA solution. The
(sp gr 0.90) to 54 g of NH Cl and dilute to 1 L with water.
excess is titrated with standard zinc chloride solution using
6.7 Eriochrome Black-T Indicator—Triturate 0.2 g of Eri-
Eriochrome Black-T as the indicator.
ochrome Black-T and 100 g of NaCl, and store the mixture in
a tightly stoppered bottle. This mixture remains stable for
several years.
This test method is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, andApplications and is the direct responsibility of
6.8 Ethyl Alcohol (95%), pure or denatured.
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.
Current edition approved June 1, 2011. Published June 2011. Originally
approved in 1965. Last previous edition approved in 2005 as D2375–05. DOI:
10.1520/D2375-05R11.
2 4
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Reagent Chemicals, American Chemical Society Specifications, American
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Chemical Society, Washington, DC. For suggestions on the testing of reagents not
Standards volume information, refer to the standard’s Document Summary page on listed by the American Chemical Society, see Analar Standards for Laboratory
the ASTM website. Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
The last approved version of this historical standard is referenced on and National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,
www.astm.org. MD.
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D2375 − 05 (2011)
6.9 EDTA, Standard Solution (0.05 M)—Dissolve 18.62 g 9. Procedure
of EDTAin water and dilute to 1 L. Store in a polyethylene or
9.1 Check the clarity of the drier. If not clear, centrifuge a
borosilicate glass bottle.
portion of the sample until it is clear. Keep the centrifuge tube
stoppered so that solvent will not evaporate.
6.10 Hydrochloric Acid (sp gr 1.19)—Concentrated (hydro-
chloric acid (HCl).
9.2 From a buret place a few grams of the drier in a 50-mL
Erlenmeyer flask th
...