D01.21 - Chemical Analysis of Paints and Paint Materials

SIGNIFICANCE AND USE
4.1 This test method is the procedure of choice for determining volatiles in coatings for the purpose of calculating the volatile organic content in coatings under specified test conditions. The weight percent solids content (nonvolatile matter) may be determined by difference. This information is useful to the paint producer and user and to environmental interests for determining the volatiles emitted by coatings.
SCOPE
1.1 This test method describes a procedure for the determination of the weight percent volatile content of solventborne and waterborne coatings. Test specimens are heated at 110 °C ± 5 °C for 60 min.  
Note 1: The coatings used in these round-robin studies represented air-dried, air-dried oxidizing, heat-cured baking systems, and also included multicomponent paint systems.  
1.2 Sixty minutes at 110 °C ± 5 °C is a general purpose test method based on the precision obtained with both solventborne and waterborne coatings (see Section 9).  
1.3 This test method is viable for coatings wherein one or more parts may, at ambient conditions, contain liquid coreactants that are volatile until a chemical reaction has occurred with another component of the multi-package system.  
Note 2: Committee D01 has run round-robin studies on volatiles of multicomponent paint systems. The only change in procedure is to premix the weighed components in the correct proportions and allow the specimens to stand at room temperature for 1 h prior to placing them into the oven.  
1.4 Test Method D5095 for Determination of the Nonvolatile Content in Silanes, Siloxanes and Silane-Siloxane Blends Used in Masonry Water Repellent Treatments is the standard method for nonvolatile content of these types of materials.  
1.5 Test Methods D5403 for Volatile Content of Radiation Curable Materials is the standard method for determining nonvolatile content of radiation curable coatings, inks and adhesives.  
1.6 Test Method D6419 for Volatile Content of Sheet-Fed and Coldset Web Offset Printing Inks is the method of choice for these types of printing inks.  
1.7 This test method may not be applicable to all types of coatings. Other procedures may be substituted with mutual agreement between the producer and the user.  
Note 3: If unusual decomposition or degradation of the specimen occurs during heating, the actual time and temperature used to cure the coating in practice may be substituted for the time and temperature specified in this test method, subject to mutual agreement between the producer and the user. The U.S. EPA Reference Method 24 specifies 110 °C ± 5 °C for 1 h for coatings.
Note 4: Practice D3960 for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings describes procedures and calculations and provides guidance on selecting test methods to determine VOC content of solventborne and waterborne coatings.  
1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
2.1 These test methods are applicable to varnish and are useful to producers and users in determining nonvolatile content and are sometimes an appropriate measure of the film-forming matter in varnish.
SCOPE
1.1 These test methods determine the fraction of a varnish that is nonvolatile at the temperature of the test while volatile solvents are driven off. It is sometimes an approximate measure of the film-forming matter in a varnish.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific statement, see Section 3.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method measures the amount of formaldehyde that is evolved from a coating containing melamine-formaldehyde resin(s) during cure at elevated temperature. Cure formaldehyde results from a side-reaction during cross-linking of functionalized polymers with melamine-formaldehyde resins. Cure formaldehyde is evolved in the final bake or cure oven, when the coating temperature is high enough to initiate cross-linking. Formaldehyde can be released from a coating during application, solvent flash-off and cure. Free formaldehyde is primarily evolved during coating application and solvent flash-off. Test Method D1979 measures “free formaldehyde” in amino resins and Test Method D6191 measures formaldehyde evolved from coatings at ambient temperature. This method measures only the formaldehyde released during heat cure, which is primarily “cure formaldehyde.”  
5.2 This test method is not intended to duplicate the evolved formaldehyde from an industrial process, but serves as a reproducible comparative laboratory evaluation.  
5.3 This test method has not been evaluated with catalyzed coating systems that cure at or below 40 °C, such as those used by the wood-finishing industry, and would likely require special adaptation for this application.
SCOPE
1.1 This test method is for the determination of formaldehyde evolved from melamine-formaldehyde-based coatings during the cure step. The results may be used to determine the “cure formaldehyde” evolved from a sample under controlled laboratory conditions.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This test method is capable of measuring from 500 μg/g to 22 000 μg formaldehyde/g dry coating under the test conditions specified (3 000 ml/min total flow, 50 ml/min DNPH tube flow). The ratio of total flow to DNPH tube flow could be adjusted to extend the range of the method.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Driers accelerate the drying of oil, paint, printing ink, and varnish.  
3.2 These test methods are applicable to liquid driers manufactured for use in paints and related coatings.  
3.3 The tests for metallic content using ethylenediaminetetraacetic acid dihydrate (EDTA) are intended for concentrated solutions of single metals; two or more metals may cause interference.
SCOPE
1.1 These test methods cover the test procedures to be applied to liquid paint driers used in paints and related coatings. Typical paint driers, listed in Specification D600, are carboxylates of lead, cobalt, manganese, zinc, iron, calcium, and zirconium.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is useful for determining the amount of metallic zinc in zinc dust pigment, and also in dried films of both inorganic and organic zinc-rich coatings. Test Methods D521 is an appropriate method for analyzing zinc dust, but has shortcomings when applied to samples of cured coatings.
SCOPE
1.1 This test method covers the determination by differential scanning calorimetry of the metallic zinc content of both zinc-dust pigment, and of dried films of zinc-rich coatings. This test method is applicable to both inorganic and organic zinc-rich coatings.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method may be used to confirm the stated content of a pure liquid vanadium drier manufactured for use by the coatings industry.
SCOPE
1.1 This test method covers the titrimetric determination of vanadium in liquid vanadium driers and utilizes the disodium salt of ethylenediaminetetraacetic acid dihydrate (EDTA).  
1.2 This test method is limited to the determination of the vanadium content of a liquid vanadium drier that does not contain other drier elements. This test method is not applicable to drier blends.  
1.3 All cations that can be titrated with EDTA in alkaline media interfere and must not be present in the sample.  
1.4 This test method has been tested for concentrations of 3 % and 4 % vanadium, but there is no reason to believe that it is not suitable for higher or lower vanadium concentrations provided specimen size is adjusted proportionately.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The acid and base concentrations are a measurement of the titratable acidic and alkaline components in the electrocoat baths. These measurements are used for research, production or electrocoat bath process control.
SCOPE
1.1 These test methods cover the determination of acid and base milliequivalent contents of anodic and cathodic electrocoat baths and their ultrafiltrates.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method may be used to confirm in the presence of rare earths the stated cerium content of liquid pure cerium or rare earth driers manufactured for use in the coatings industry.
SCOPE
1.1 This test method covers the titrimetric determination of cerium in liquid cerium and rare earth paint driers and utilizes ferrous ammonium sulfate.  
1.2 This test method is not applicable to dryer blends.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method may be used to confirm the stated calcium or zinc content of pure liquid calcium or zinc driers soluble in toluene-alcohol and manufactured for use by the coatings industry.
SCOPE
1.1 This test method covers a titrimetric determination of calcium in liquid calcium driers and zinc in liquid zinc driers that can be dissolved in a toluene-alcohol mixture and utilizes the disodium salt of ethylenediaminetetraacetic acid dihydrate (EDTA).  
1.2 This test method is not applicable to drier blends.  
1.3 All cations that can be titrated with EDTA in alkaline media interfere and must not be present in the sample.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The conductivity of electrocoat baths results from the presence of ionic species in the bath, which come from the vehicle and from the presence of impurities present as ionizable acids, bases, salts, or combinations of these. The presence of excessive amounts of ionic impurities is detrimental to the application and performance properties of electrocoating paints. The test is suitable for use in research, production, quality control and electrocoat bath process control.  
4.2 Other related methods for determining the electrical conductivity of water are described in Test Methods D1125.
SCOPE
1.1 This test method covers the determination of the electrical conductivity of electrocoat baths or ultrafiltrate samples using commercially available equipment.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides basic engineering data that may be used to determine the amount of VOC delivered to the inlet of a VOC control device. The procedure is useful for establishing the quantity of VOC that is evolved from the coating in the flash zone or bake oven and available to be incinerated, although the same procedure can be followed when other forms of VOC abatement are used.  
4.2 The total amount of VOC removed from the process by the VOC control device is a function of the amount available as given by this test method combined with the VOC removal efficiency of the control device.
SCOPE
1.1 This test method describes the determination of the amount of volatile organic compound (VOC) released from applied waterborne automotive coatings that is available for delivery to a VOC control device. The determination is accomplished by measuring the weight loss of a freshly coated test panel subject to evaporation or drying and by analysis of the VOC or water content in the coating.  
1.2 This test method is applicable to the VOC released from application and baking operations after the paint has been applied in a simulation of a production process, or in an actual production facility.  
1.3 Symbols and calculations from several other methods that determine VOC: Practice D3960, EPA 450/3-88-018 and EPA 450/3-84-019 have been incorporated into this test method. The majority of symbols and calculations used in this test method are unique because this test method deals uniquely with differences in weight of applied paint samples that have been subject to drying, curing or solvent addition.
Note 1: Training and knowledge of the product being evaluated are essential for obtaining meaningful data from this test method. It is recommended that several practice runs be performed, and the laboratories repeatability evaluated before performing this test on the test samples.  
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Titanium dioxide pigments are components with high refractive index that significantly influence the opacity, color, durability, and other properties of coatings. This test method for determining titanium dioxide content is quicker and easier to use than Test Methods D1394, a wet chemical analysis method for pigments. It is conveniently applicable to single samples and to large numbers of samples. Only a single relatively stable reagent used to prepare standards and paints under test need be stored. Drawdown specimens used as standards, once prepared, can be stored indefinitely and used repeatedly.
SCOPE
1.1 This test method covers the determination of titanium dioxide content in liquid paint. This test method is applicable to both water-reducible and solvent-reducible paints.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Separation of the vehicle from the pigment in solvent-reducible paints is required in order to characterize paint vehicles by chemical, spectroscopic, or chromatographic techniques. Characterization of vehicles is important since they play a major role in the performance of coatings.
SCOPE
1.1 This practice covers the procedure for the separation of the vehicle from the pigment in solvent-reducible paint.  
1.2 In the development of the practice the following materials were tested: white soya and white fish oil isophthalic alkyd semi-gloss enamels, white linseed oil paint, white soya and white linseed o-phthalic alkyd enamels. It is considered to be applicable to similar materials.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This guide includes chromates that are not readily soluble in water and that have water solubilities (Chromate ION) within the range of the more soluble calcium chromate and the much less soluble lead chromate. The major occupations involving potential exposure to insoluble chromates are in roasting of chromite ore, the manufacture of chromate pigments, the manufacture of coatings containing chromate pigments, and spray painting with these coatings. There is insufficient evidence to conclude that trivalent chromium compounds are carcinogenic.
SCOPE
1.1 This guide covers control procedures for the safe production, storage, transportation, and handling of only the hexavalent chromium compounds found in Table 1 and their various hydrates, and mixtures of coprecipitates of the same regardless of crystalline form.  
1.2 This guide is not intended to cover (a) such “soluble” chromates as chromates of sodium, potassium, magnesium, or ammonium; (b) soluble bichromates; (c) chromic acid; (d) volatile chromyl compounds; (e) any trivalent chromium compound; or (f) elemental chromium. Omission of said compounds or classes of compounds should not be construed to mean that they may be handled without due regard to their particular physical, chemical, and toxicological hazards (9, 10, 11).  
1.3 The chromate ion, CrO4−2, depending upon the acidity, complexes to form di-, tri-, and higher polychromates; hence, the chromates listed in Table 1 may contain mixtures of polychromates, depending on the method of isolation and end use.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. (For more specific precautionary information see Section 5.)  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The United Nations Committee of Experts on the Transport of Dangerous Goods in their recommended regulations place materials having a flash point below 23 °C (73.5 °F) in Packing Group II. However, if viscous substances such as paint and related coatings, adhesives, polishes, etc., meet certain requirements, they can be placed in Group III along with materials having a flash point between 23 °C and 60.5 °C (73.5 °F and 140 °F). One of the requirements is that less than 3 % of clear liquid separates from the bulk of the material when subjected to this test method.  
4.2 At the present time most international regulatory bodies such as the International Civil Aviation Organization (ICAO) and the International Maritime Organization (IMO) use the U.N. Recommendations. It is anticipated that most national transportation regulatory bodies will adopt the U.N. Recommendations as their regulations for control of transportation of hazardous materials. At present the United States permits the transshipment of hazardous materials through the United States to other countries under regulations of the IMO and ICAO.
SCOPE
1.1 This test method covers the determination of the amount of liquid separated as an upper layer in a 24-h period from viscous solutions or dispersions that contain dispersed solids such as paints, enamels, pigmented lacquers, adhesives, polishes, and other similar materials.  
Note 1: The amount of clear liquid that separates during this test is one of the criteria in the United Nations Recommendations on the Transportation of Dangerous Goods2 for the placement of flammable viscous liquids into packing groups related to flash points (See 4.1).  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method describes a rapid method for separating pigment from solvent-reducible paints.  
3.2 This test method is used by paint producers and consumers for product acceptance and process control.
SCOPE
1.1 This test method covers the separation of pigment from solvent-reducible paints and the calculation of the percent pigment from the results of nonvolatile determinations on the total paint and the separated vehicle.  
Note 1: This test method has been proven to be applicable to most solvent-reducible paints, the exception being those paints containing severely bleeding pigments or pigments such as carbon black that are very difficult or impossible to centrifuge.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Identification of specific acrylic polymers in emulsion paints is often difficult or impossible by infrared alone. This is particularly true when the acrylic is present in a small amount as a comonomer with vinyl acetate, or when blended with alkyds or other ester systems. If identification of an acrylic component is required in such a system, it may often be accomplished by gas-liquid chromatographic analysis of the pyrolyzed paint film. The presence of a number of other polymers may often also be confirmed by pyrolysis since they produce characteristic and reproducible pyrograms.  
5.2 The pyrograms obtained from unknown samples vary in complexity according to the sample composition. It is necessary to establish the presence or absence of as many components as possible from a study of the infrared spectra obtained in the first part of this practice. The gas-liquid chromatography results may then be used to help identify any unknown components present and to confirm identifications made by infrared.
SCOPE
1.1 This practice describes a procedure for the qualitative identification in emulsion paints of most types of polymers present as major components of the paint vehicle. Limitations are discussed in Sections 5 and 10.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is intended for use as a rapid quality control, acceptance, and assessment test. Results are obtained in five to fifteen minutes on most materials. Since the instrument parameters are adjusted to produce the same results as Test Method D2369, which takes over one hour to run, the time and effort expended on determining the optimal conditions for testing a coating with this instrumental method is valuable when numerous measurements are going to be made on different lots or batches of the same material. Also, the automation of the measurement and the calculations should lead to fewer mistakes being made by less-trained operators.
SCOPE
1.1 This test method is used to obtain rapid determination of the weight percent nonvolatile (solids) content via instrumental loss in weight technology. It is not meant as a replacement for Test Method D2369.  
1.2 This test method is principally intended for quality control labs and manufacturing environments where previously characterized materials will be tested repeatedly for different batches or lots.  
1.3 This test method can be used for waterborne and solventborne resins, intermediates and finished paint products. This test method may not be applicable to all types of coatings.  
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no similar or equivalent ISO standard.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Control of water content is often important in controlling the performance of paint and paint ingredients, and it is critical in controlling volatile organic compound (VOC) content.  
4.2 Paint materials are often insoluble in common Karl Fischer solvents such as methanol. Pyridine has been found to be a nearly universal solvent for these materials; however, the Karl Fischer reaction is too slow in that solvent at room temperature. To speed it up, 1-ethylpiperidine is added at 5 % as a buffer, or “catalyst.”  
4.3 For nonpyridine-based reagents, a number of different solvent systems are available to increase solubility and to minimize interferences from ketones and aldehydes.
SCOPE
1.1 This test method is applicable to all paints and paint materials, including resins, monomers, and solvents, with the exception of aldehydes and certain active metals, metal oxides, and metal hydroxides. While the evaluation was limited to pigmented products containing amounts of water in the 30 % to 70 % range, there is reason to believe that higher and lower concentrations can be determined by this test method.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Excessive amounts of unreacted monomer may cause concerns relating to toxicity and odor. This test method is designed to measure the unreacted monomer content of latexes. The results may be used to monitor the extent of polymerization during manufacture, as well as to establish maximum unreacted monomer content for regulatory purposes.
SCOPE
1.1 This test method is for the determination of the unreacted monomer content of acrylic latexes. Monomers that have been successfully determined by this procedure include n-butyl methacrylate, n-butyl acrylate, styrene, and methyl methacrylate. The determination of other monomers has not been evaluated, but this test method is believed to be applicable. The established working range of this test method is from 100 μg/g to 000 μg/g, but there is no reason to believe it will not work outside of this range, provided that appropriate dilutions and adjustments in specimen size are made.  
1.2 The unreacted monomer in acrylic latexes is expected to change with time and environmental factors. This time dependence of the determination may be seen as an artificially large deviation of results, making the test method mostly applicable for in-house quality control, where sampling and analysis conditions can be better controlled.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method may be used in quality control laboratories when the repeated analysis of titanium dioxide in similar paints may be required. Reagents and time are kept to a minimum when this test method is used in place of wet chemical analysis such as in Test Methods D1394. However, reproducibility and repeatability are not as good as in Test Methods D1394.
SCOPE
1.1 This test method covers the atomic absorption (AA) analysis of titanium dioxide content in pigments recovered from whole paint. It is applicable to quality control situations where the same type of product is repeatedly analyzed.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 In order to calculate volatile organic content (VOC) in waterborne paints, it is necessary to know the water content. This gas chromatographic test method provides a relatively simple and direct way to determine water content.
SCOPE
1.1 This test method is for the determination of the total water content of waterborne paints. It has been evaluated for latex systems (styrene-butadiene, poly(vinylacetate)-acrylic, acrylic), epoxy acrylic resin systems and acrylic systems. The established working range of this test method is from 15 % to 90 %. There is no reason to believe that it will not work outside of this range.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Samples are taken from batches, lots, and shipments of paint in order to determine their uniformity and compliance with specification requirements. It is very important that these samples be of convenient and economical size and that they be representative of the batch of paint at the time it was filled into shipping or storage containers.  
4.2 The time and effort necessary to ensure that the sample is representative of the original material will be repaid in reduction of laboratory work and elimination of possible rejections of acceptable material.
SCOPE
1.1 This practice describes methods of taking representative samples of fluid paint or pigmented coating products from containers of any type.  
1.2 Two ISO standards, ISO 1513 and ISO 15528, cover the details and equipment for sampling of liquid paints and associated materials in much greater detail than this standard. The reader is referred to those standards for more information.  
1.3 The sampling of dry powder paints, clear coatings, mixed solvents, and nonpigmented materials of any type is not covered in this procedure.  
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method measures the volume of dry coating obtainable from a given volume of liquid coating. This value is useful for calculating the volatile organic content (VOC) of a coating and could be used to estimate the coverage (square feet of surface covered at a specified dry film thickness per unit volume) obtainable with different coating products.
Note 1: In Practice D3960 paragraph 10.3.1, the equation for calculating the VOC content using the percent volume nonvolatile is given. Prior to this method a satisfactory procedure for measuring percent volume nonvolatile did not exist (see Note 11 in Practice D3960).
Note 2: Since the actual coverage of a coating includes the void volume and the porosity of the film, the coverage value calculated from this method will be inaccurate by that amount, that is, the actual coverage will be greater. The higher the pigment to binder ratio (P/B) of a coating or the higher content of void containing material (latices, hollow beads, etc.) or both, the greater will be the deviation of the coverage calculation (This is also true to a lesser degree with Test Method D2697).  
4.2 For various reasons the volume nonvolatile value obtained for a coating is often not equal to that predicted from simple linear addition of the weights and volumes of the raw materials in a formulation. One reason is that the volume occupied by a solution of resin in solvent may be the same, greater, or less than the total volume of the separate ingredients. Such contraction or expansion of resin solutions is governed by a number of factors, one of which is the extent and direction of spread between solubility parameters of the resin and solvent.  
4.3 The spatial configuration of the pigment particles and the degree to which the pigment particles are filled with the binder also affect the volume of a dry coating film. Above the critical pigment volume concentration, the apparent volume of the dry film is significantly greater than theoretical...
SCOPE
1.1 This test method covers the determination of the percent volume nonvolatile matter of a variety of clear and pigmented coatings. The approach used should provide faster and more accurate results than the use of the liquid displacement technique in Test Method D2697, particularly for coatings that are difficult to wet or that contain voids, cracks or other defects. The improvement in accuracy stems from the superior ability of helium gas under pressure to penetrate very small pores and surface irregularities in dried films. This provides a more accurate determination of void volumes than can be obtained via liquid displacement.  
1.2 The technique will provide results under the following constraints:  
1.2.1 The stability of the helium gas pycnometer is greater than ±0.005 cm3.  
1.2.2 Test specimen weights are greater than 1 g.  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is intended to provide a measure of the volume of dry coating obtainable from a given volume of liquid coating. This value is useful for comparing the coverage (square feet of surface covered at a specified dry film thickness per unit volume) obtainable with different coating products.  
4.2 For various reasons the value obtained may not be equal to that predicted from simple additivity of the weights and volumes of the raw materials in a formulation. One reason is that the volume occupied by a solution of resin in solvent may be the same, greater, or less than the total volume of the separate ingredients: such contraction or expansion in resin solutions is governed by a number of factors, one of which is the extent and direction of spread between solubility parameters of the resin and solvent.  
4.3 The spatial configuration of the pigment particles and the degree to which the spaces between the pigment particles are filled with the binder also affect the volume of a dry coating formulation. Above the critical pigment volume concentration, the apparent volume of the dry film is significantly greater than theoretical due to the increase in unfilled voids between pigment particles. The use of volume nonvolatile matter values in such instances should be carefully considered as the increased volume is largely due to air trapped in these voids.
SCOPE
1.1 This test method is believed to be applicable to the determination of the volume of nonvolatile matter of a variety of coatings. An interlaboratory study to establish the precision of this test method included a water-reducible exterior latex paint and three automotive coatings that included a solvent-reducible primer surfacer, water reducible primer surfacer, water reducible enamel topcoat, and acrylic dispersion lacquer topcoat. Earlier collaborative studies included a gloss enamel, a flat wall paint, a gloss house enamel, an industrial baking enamel, an interior latex paint, and an exterior latex paint. This method does not apply to radiation curable materials or pigmented coatings.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method is used by paint producers and consumers for product process control and for product acceptance.
SCOPE
1.1 This test method covers a procedure for the pigment content determination of water-based paints. It is applicable only to pigments that do not decompose or lose weight at temperatures below 500 °C. Such pigments include most metal oxides, silicates, and a majority of anhydrous inorganic salts.  
1.2 Many water-based paints contain pigments and organic colorants that lose water of hydration or decompose at this temperature. The residual ash should be carefully inspected for changes in color or texture that could indicate a pigment alteration and hence lead to erroneous results. Caution should therefore be exercised when applying this test method to samples containing unknown pigment compositions.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The permissible level of heavy metals in certain coatings is specified by governmental regulatory agencies. This test method provides a fully documented procedure for determining low concentrations of chromium present in both water- and solvent-reducible coatings to determine compliance.
SCOPE
1.1 This test method covers the determination of the content of chromium (including chromium oxide) in the range between 0.005 and 1.0 % present in the solids of liquid coatings or in dried films obtained from previously coated substrates. There is no reason to believe that higher levels could not be determined by this test method, provided that appropriate dilutions and adjustments in specimen size and reagent quantities are made.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 In order to calculate the volatile organic content (VOC) of paints containing EPA exempt solvents, it is necessary to know the acetone, methyl acetate, or parachlorobenzotrifluoride content. This gas chromatographic test method provides a simple and direct way for measuring these solvents. Each analyte is measured with respect to a unique internal standard. For acetone, the internal standard used is acetone-d6, for methyl acetate it is methyl acetate-d3, and for PCBTF it is metachlorobenzotrifluoride (MCBTF). These unique analyte/internal standard pairs behave very nearly as single solvents with respect to evaporation rate and adsorption rate onto a coated silica fiber (SPME) but are separable on a gas chromatograph (GC) capillary column. The only critical analytical technique required for successfully performing this test method is the ability of an analyst to weigh a paint sample and internal standard, corresponding to the analyte of interest, into a septum capped vial. After weighing, solvent evaporation has no effect on the final value of the determination. Since whole paint is not injected into the gas chromatograph, the analytical system is never compromised.
SCOPE
1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
Note 1: Water-borne paints are internally standardized and diluted with water followed by addition of solid sodium chloride.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The permissible level of heavy metals in certain coatings is specified by governmental regulatory agencies. This test method provides a fully documented procedure for determining low concentrations of mercury present in both water and solvent-reducible coatings to determine compliance.
SCOPE
1.1 This test method covers the determination of the content of mercury in the range between 10 and 1000 ppm (mg/kg) present in liquid coatings, coatings vehicles, or in dried films obtained from previously coated substrates. There is no reason to believe that higher levels could not be determined by this test method, provided that appropriate dilutions and adjustments in specimen size and reagent quantities are made.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7 and 9.1.1.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The permissible level of heavy metals in certain coatings is specified by governmental regulatory agencies. This test method provides a fully documented procedure for determining low concentrations of antimony present in both water- and solvent-reducible coatings to determine compliance.
SCOPE
1.1 This test method covers the determination of the content of antimony in the range between 50 and 200 ppm (mg/kg) present in the solids of liquid coatings or in dried films obtained from previously coated substrates. There is no reason to believe that higher levels could not be determined by this test method, provided that appropriate dilutions and adjustments in specimen size and reagent quantities are made.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This test method covers the pigment content of paints and several traffic marking materials (thermoplastic and preformed tape) by low-temperature furnace ashing. Some organic pigments may be lost by this method and some water or moisture contained in pigments will be lost.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The pH is the measure of the free hydrogen ion concentration of a sample, and it indicates whether an electrocoat bath is acidic, neutral, or basic. Since pH measurements of good precision are made in aqueous solutions, it is suggested that the pH measurements of electrocoat baths are only semi-quantitative, and therefore such measurements should be referred to as apparent pH measurements.  
4.2 The pH of electrocoat paints is used for research, production, and quality control or electrocoat bath process control.  
4.3 Other related methods for determining the pH of water or aqueous systems are described in Test Methods D1293 and E70.
SCOPE
1.1 This test method covers the measurement of the free hydrogen ion concentration of electrocoat baths and their ultrafiltrates.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Flash point measures the response of the test specimen to heat and ignition source under controlled laboratory conditions. It is only one of a number of properties that must be considered in assessing the overall flammability hazard of a material.  
5.2 Flash point is used in shipping and safety regulations by governmental regulatory agencies to define flammable and combustible materials and to classify them. Consult the particular regulation involved for precise definitions of these classes.  
5.3 Flash point can indicate the possible presence of highly volatile and flammable impurities or contaminants in a given liquid, such as the presence of residual solvents in solvent-refined drying oils.  
5.4 These equilibrium flash point test methods use a smaller specimen (2 mL) and a shorter test time (1 min) than traditional non-equilibrium test methods such as Test Method D56 and Test Methods D93.  
5.5 Test Methods D3828, Test Method D8174, and ISO 3679 are similar test methods and use the same apparatus.
SCOPE
1.1 These test methods cover procedures for determining whether a material does or does not flash at a specified temperature (flash/no flash Method A) or for determining the lowest finite temperature at which a material does flash (Method B), when using a small scale closed-cup apparatus. The test methods are applicable to paints, enamels, lacquers, varnishes, solvents, and related products having a flash point between 0 °C and 110 °C (32 °F and 230 °F) and viscosity lower than 15 000 mm2/s (cSt) at 25 °C (77 °F).
Note 1: Tests at higher or lower temperatures are possible however the precision has not been determined.
Note 2: More viscous materials can be tested in accordance with Annex A4.
Note 3: Organic peroxides can be tested in accordance with Annex A5, which describes the applicable safety precautions.
Note 4: The U.S. Department of Labor (OSHA, Hazard Communications), the U.S. Department of Transportation (RSPA), and the U.S. Environmental Protection Agency (EPA) have specified Test Methods D3278 as one of several acceptable methods for the determination of flash point of liquids in their regulations.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method may be used to confirm the stated content of a liquid iron drier soluble in isopropyl alcohol and manufactured for use in the coatings industry. The content determines activity level.
SCOPE
1.1 This test method covers the titrimetric determination of iron in liquid iron driers soluble in isopropyl alcohol and utilizes the disodium salt of ethylenediaminetetraacetic acid dihydrate (EDTA).  
1.2 This test method is limited to the determination of the iron content of a liquid drier that does not contain other drier elements. This method is not applicable to drier blends.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Calculation of the weight percent volatile organic content of water-borne paints, requires that the water content be known. This test method provides a direct way to determine the weight percent volatile organic matter of water-borne aerosol paints minus the matter content. This test method is modeled after Method 36.4
SCOPE
1.1 This test method is for the determination of the weight percent volatile content of water-borne paints in aerosols.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Current U.S. regulations restrict the amount of lead that may be present in consumer paint products to less than 0.06 % based on the total solids. This test method provides a rapid means for screening paints to determine compliance with those regulations. The test method may be adjusted to meet regulations with a different limit on lead content.
SCOPE
1.1 This test method is intended as a screening test to determine if the solids in a paint contain more than 0.06 % lead. The test described can differentiate between 0.05 and 0.06 %. Paints giving a result greater than 0.05 % should be analyzed quantitatively for lead using Test Method D3335. This test method provides a more definitive and reliable screening test than Test Method D3618.  
1.2 There is no reason to believe that higher levels of lead could not be determined by this test method provided that appropriate dilutions and adjustments in specimen size and reagent quantities are made.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 In the determination of VOC, cure water is treated as a VOC in other test methods, as these methods are unable to account for cure water. This test method allows taking credit for cure water as total water is measured, a value which includes cure water.  
5.2 Total water content and volatile content results obtained with this method may be used in Practice D3960 to calculate VOC of the coating.
SCOPE
1.1 This test method is designed to measure total water which includes cure water resulting from the heat induced condensation reaction of coatings. Cure water cannot be measured directly by Test Method D4017. This task is accomplished by measuring water content in the vapors evolved during heating. This test method will yield total water content. This test method also permits for the simultaneous determination of total volatile content. The results of this test method may be used to calculate VOC content. Although this test method was designed for phenolic coatings, it can be used with other types of coatings.  
1.2 Materials used for method development and evaluation had total water values from 20 to 37 %. Use of this test method on coatings outside these values will need to be validated by the user.  
1.3 Sample heating is accomplished with a Brinkmann Instruments Model 832 drying oven,2 or other mutually agreed upon alternative, passing all of the evolved vapors into a Karl Fischer titration vessel.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 It is important to monitor the anion concentrations and anion contaminants in electrocoat baths. Wet chemical methods are long, tedious, and of questionable accuracy in the ppm range. Ion chromatography offers a fast, convenient and accurate alternative. Since IC analysis of electrocoat bath samples is difficult, the permeates are often analyzed for contaminants. This guide addresses some important considerations for such analyses.
SCOPE
1.1 This guide is used for the determination of nitrate anion in electrocoat bath permeate by use of chemically suppressed and non-suppressed ion chromatography (IC).  
1.2 Other anions, with the exception of phosphate, may be determined in electrocoat bath permeates by use of this guide.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 With the need to calculate volatile organic content (VOC) of paints, and with acetone, p-chlorobenzotrifluoride, methyl acetate and t-butyl acetate4 considered as exempt volatile compounds, it is necessary to know the content of these analytes. This gas chromatographic test method provides a relatively simple and direct way to determine their content. However, because the detectors used in this test method are not selective, and because some coatings are very complex mixtures, compounds may be present in the sample that coelute with the analyte, giving a result that is erroneously high. Or a component may elute with the internal standard, giving a result that is erroneously low. It is therefore important to know the composition of the sample to ensure that there are no interferences, under the analysis conditions used. Test Method D6438 employs mass-spectral detection of analytes and may be used as an alternative method.
SCOPE
1.1 This test method is for the determination of the total-concentration of acetone, p-chlorobenzotrifluoride, methyl acetate, or t-butyl acetate, or combination of any of the four, in solvent-reducible and water-reducible paints, coatings, resins, and raw materials. Because unknown compounds that co-elute with the analyte being measured or with the internal standard, will lead to erroneous results, this test method should only be used for materials of known composition so that the possibility of interferences can be eliminated. The established working range of this test method is from 1 % to 100 % for each analyte by weight.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The choice of pigments and extenders influences the appearance, durability, cost, and other properties of paint. This test method is a convenient way, and probably the most reliable, to identify pigments in paint.
SCOPE
1.1 This test method covers the identification of crystalline pigments and extenders in liquid paint and dry paint film. It is applicable to both water-reducible and solvent-reducible paint. It also may be used to identify pigment and extender in grind paste or alone as dry powder. It is not applicable to amorphous components such as carbon black, amorphous silica, or highly processed clay.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 6.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Flash point and fire point of a liquid are physical properties that may be used to define their flammability hazards. The flash point may be used to classify materials in government regulations.
SCOPE
1.1 This test method covers the determination by Tag Open-Cup Apparatus of the flash point and fire point of liquids having flash points between −18 and 165°C (0 and 325°F) and fire points up to 325°F.  
1.2 This test method, when applied to paints and resin solutions that tend to skin over or that are very viscous, gives less reproducible results than when applied to solvents.  
Note 1: In order to conserve time and sample, the fire point of a material may be determined by the Tag Open-Cup Method by continuing the heating of the specimen to its fire point. Fire points may also be determined by Test Method D92, which should be used for fire points beyond the scope of this test method.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard should be used to measure and describe the properties of materials, products, or assemblies in response to heat and flame under controlled laboratory conditions and should not be used to describe or appraise the fire hazard or fire risk of materials, products, or assemblies under actual fire conditions. However, results of this test may be used as elements of a fire risk assessment which takes into account all of the factors pertinent to an assessment of the fire hazard of a particular end use.  
1.5 Warning—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Safety Data Sheet (SDS) for details and EPA’s website, http://www.epa.gov/mercury/faq.htm, for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method measures the amount of formaldehyde that is released from a coating under laboratory conditions. The amount of formaldehyde available for release from a coating may vary depending on composition, and may decrease as the sample ages.  
4.2 This test method may be used for typical air dried paints where water is the major volatile material. The useful range is estimated to be from 10 ppm to 1000 ppm formaldehyde in the sample.  
4.3 Significant amounts of other volatile aldehydes, such as acetaldehyde, are reported to cause an interference with the determination of formaldehyde. This limitation is not expected to cause a problem for most common water reducible coatings.  
4.4 Samples containing organic solvents as the major volatile component have not been evaluated and are not expected to be compatible with this test method.
SCOPE
1.1 This test method may be used to measure the amount of formaldehyde evolved from air-dry water reducible coatings utilizing latices, resin emulsions, or water reducible alkyds. The results may be used to define the “free” formaldehyde evolved from a sample under controlled laboratory conditions.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The nonvolatile content and pigment content are measures of total solids and inorganic pigment solids, respectively, in electrocoat paints. In addition to production quality control, these properties are important in maintaining electrocoat baths in the optimum range.  
4.2 Other test methods for determining nonvolatile content of paint and paint related materials are described in Guide D2832.
SCOPE
1.1 These test methods cover the characterization of electrocoat baths through the determination of nonvolatile content of inorganic pigment content.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The identification of pigments in a sample of liquid paint or paint film is often important for regulatory purposes. Many inorganic pigments or extenders utilized in past paint formulation are now regulated by federal, state, or municipal health authorities. XRF is one of the more common and convenient methods employed to characterize the pigment composition of a paint formulation.  
5.2 XRF techniques, in general, do not provide the ability to identify the chemical nature of organic pigments. There are instances where XRF techniques, used in tandem with other analytical methods, such as solid state Carbon 13 Nuclear Magnetic Resonance (C-13 NMR), can identify the organic pigments utilized in coatings. However, XRF provides only an elemental sketch of the inorganic pigmentation. The chemical composition of the pigments is inferred by the analyst from the samples, color, elemental information, and common sense. Small impurities are often found in pigments, so the relative XRF intensities also serve to guide the analyst in proposing the probable pigment present.
SCOPE
1.1 This guide covers the general considerations for proper use of X-ray fluorescence (XRF) spectroscopy. Because many differences exist between XRF instruments, no detailed operating instructions are provided. The analyst should follow the instructions provided by the manufacturer for his instrument.  
1.2 The analyst is encouraged to consult the chemical literature, various trade journals, pigment supplier publications, etc., as well as the instrument manuals from the manufacturer.  
1.3 XRF is commonly employed to determine the elements present in inorganic pigments and extenders, often in concert with other analysis techniques. Organic pigments cannot normally be identified solely by XRF. On occasion, organic pigments contain heavier elements that can distinguish between major classes of these pigments or may serve to distinguish one of the two distinct pigments. However, the analyst should be wary of a qualitative pigment identification solely by XRF technique.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard information see Section 3 on Radiation Concerns.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is the procedure of choice for determining the volatile content in aerosol coatings under specified test conditions modeled after Method 35.4 The inverse value, nonvolatile, is used to determine the weight percent solids content. This information is useful to the paint producer, user, and to environmental interests for determining the grams of volatile organic compounds per gram of solids emitted from aerosol cans.
SCOPE
1.1 This test method is for the determination of the weight percent volatile organic compounds of solvent-borne paints in aerosol cans. It offers a unique way to obtain paint specimens from aerosol cans.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. A specific hazard statement is given in 6.7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides basic engineering data that may be used to determine the amount of VOC available for delivery at the inlet of a VOC control device (particularly for the automobile industry).6 Typically, the procedure is useful for establishing the quantity of VOC that is evolved from the coating in the baking oven and available to be incinerated, although the same procedure can be followed for other forms of VOC abatement (that is, carbon, adsorption, etc.).  
4.2 This test method may be adaptable for use directly in a production environment if all the critical factors (for example, temperature, cleanliness, vibration, accessibility, etc.) can be adequately controlled.  
4.3 The total amount of VOC removed from the process by the VOC control device is a function of the amount available as given by this test method combined with the VOC removal efficiency of the control device.
SCOPE
1.1 This test method covers the determination of the amount of volatile organic compound (VOC) released from applied solventborne automotive coatings that is available for delivery to a VOC control device. This is accomplished by measuring the weight loss of a freshly coated test panel subjected to solvent evaporation or baking in a laboratory simulation of the production process.  
1.2 This test method is applicable to the VOC released from flashoff and baking operations after the paint has been applied.  
1.3 This test method is applicable to solventborne automotive coating materials and is intended to represent or simulate the production process. The same general principles apply to waterborne coatings that contain volatile organic compounds (VOC), although specific procedural details are not presented herein to differentiate between VOC and water.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method ensures that before the flash test is run the air/vapor space above the specimen has attained a saturation concentration of vapor by using standard closed cups under equilibrium conditions. The saturation concentration of the vapors will be attained at some temperature between that of the liquid and the cooler apparatus lid. However, this temperature will be close to the temperature of the specimen after it has been maintained at the specified temperature for at least a 10-min period. This test method does not provide for the determination of the actual flash point but only whether a specimen does or does not flash at a specified temperature.
SCOPE
1.1 This test method covers the determination of whether a liquid complies with the closed-cup flash point requirements in government regulations, or in specifications, or as agreed between the purchaser and the seller.  
1.2 This test method is limited to a temperature range between 0 and 110°C (32 and 230°F).  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.  
1.5 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method, using a slow rate of heating, provides a uniform temperature throughout the specimen. The slow rate of heating is necessary because of the low thermal conductivity of some liquids such as paints, resins, and related products, and also because of the poor heat transfer by convection in high-viscosity products. Since the specimen is being heated at a reduced rate, the longer time interval between each determination is necessary to reestablish after each flash test the saturation concentration of vapor in the air space above the specimen.
Note 1: ISO 1523 is used in United Nations Recommendations for Transportation of Dangerous Goods and in the International Civil Aviation Organization (ICAO) regulations and for similar regulations in the International Maritime Dangerous Goods (IMDG) code. Test Method D3941, which is similar to ISO 1523, is used in the United States Department of Transportation (USDOT) regulations. The ICAO and IMDG codes are used for transshipment of hazardous materials through the United States to other countries.
SCOPE
1.1 This test method covers the determination of the flash point of liquids in which the specimen and the air/vapor mixture above it are approximately in temperature equilibrium.  
1.2 This test method is limited to a temperature range from 0 to 110°C (32 to 230°F).  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.  
1.5 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method provides a procedure for determining qualitatively the composition of solvent in paints containing only hydrocarbon solvents.
SCOPE
1.1 This test method covers the determination of the nature of solvent in solvent-reducible house paints containing only hydrocarbon solvents.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The permissible level of heavy metals in certain coatings is specified by governmental regulatory agencies. This test method provides a fully documented procedure for determining low concentrations of lead, cadmium, and cobalt present in both water and solvent-reducible coatings to determine compliance.
SCOPE
1.1 This test method covers the determination of lead2 contents between 0.01 and 5 %, cadmium contents between 50 and 150 ppm (mg/kg), and cobalt contents between 50 and 2000 ppm (mg/kg) present in the nonvolatile portion of liquid coatings or contained in dried films. There is no reason to believe that higher levels of all three elements could not be determined by this test method, provided that appropriate dilutions and adjustments in specimen size and reagent quantities are made.  
1.2 Only pigmented coatings were used for evaluating this test method, but there is no reason to believe that varnishes and lacquers could not be analyzed successfully, provided that appropriate precautions are taken.  
1.3 This test method is not applicable to the determination of lead in samples containing antimony pigments (low recoveries are obtained).  
1.4 If lead is present in the sample to be analyzed in the form of an organic lead compound at a concentration greater than 0.1 %, small losses of lead may occur, resulting in slightly poorer precision than shown in Section 12.  
1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.