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ASTM D5436-13

(Specification)

Standard Specification for Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and Shapes

Standard Specification for Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and Shapes

ABSTRACT
This specification covers poly(methyl mathacrylate) plastic rods, tubes, and other shapes produced by casting or machining cast blanks. It does not however apply to heat-formed and molded or extruded parts and shapes, or sections that are made by assembling or joining two or more pieces. The plastics may be of two types according to the material's ultraviolet light absorbing properties while the castings may be specified according to the surface finishing which may be a smooth surface finish obtained either in the casting process or by surface polishing or a rough, unfinished surface which may be frosted, abraded, sanded, machined, or as-cast. Tests shall be conducted in the standard laboratory atmosphere to determine the physical and optical properties of the materials. The specimens shall conform to the index of refraction, specific gravity, water absorption, deflection temperature under flexural load, tensile strength, elongation at break, spectral transmittance, luminous transmittance, and haze requirements.
SCOPE
1.1 This specification covers poly(methyl methacrylate) rods, tubes, and other shapes produced by casting or machining cast blanks. This specification does not apply to heat-formed and molded or extruded parts and shapes, or sections that are made by assembling or joining two or more pieces. Note 1—The properties included in this specification are those required to identify the types and grades of materials covered. There may be other requirements necessary to identify particular characteristics.  
1.2 The values stated in SI units are to be regarded as standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Note 2—There is no known ISO equivalent to this standard.

General Information

Status
Historical
Publication Date
30-Sep-2013
ICS
83.140.99 - Other rubber and plastics products
Technical Committee
D20 - Plastics
Drafting Committee
D20.15 - Thermoplastic Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D5436-03(2008) - Standard Specification for Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and Shapes
Effective Date
01-Oct-2013
Referred By
ASTM E1067/E1067M-18 - Standard Practice for Acoustic Emission Examination of Fiberglass Reinforced Plastic Resin (FRP) Tanks/Vessels
Effective Date
01-Oct-2013

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ASTM D5436-13 - Standard Specification for Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and ShapesASTM D5436-13 - Standard Specification for Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and Shapes
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D5436 −13
StandardSpecification for
Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and
1
Shapes
This standard is issued under the fixed designation D5436; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* D1003 Test Method for Haze and Luminous Transmittance
of Transparent Plastics
1.1 This specification covers poly(methyl methacrylate)
D1600 Terminology forAbbreviatedTerms Relating to Plas-
rods,tubes,andothershapesproducedbycastingormachining
tics
cast blanks. This specification does not apply to heat-formed
D3892 Practice for Packaging/Packing of Plastics
and molded or extruded parts and shapes, or sections that are
E29 Practice for Using Significant Digits in Test Data to
made by assembling or joining two or more pieces.
Determine Conformance with Specifications
NOTE1—Thepropertiesincludedinthisspecificationarethoserequired
to identify the types and grades of materials covered. There may be other
3. Terminology
requirements necessary to identify particular characteristics.
3.1 The terminology used in this specification is in accor-
1.2 The values stated in SI units are to be regarded as
dance with Terminology D883 and Terminology D1600.
standard.
4. Classification
1.3 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
4.1 Types—This specification covers two types of cast
responsibility of the user of this standard to establish appro-
methacrylate plastics:
priate safety and health practices and determine the applica-
4.1.1 Type UVA—Material having ultraviolet-lightabsorbing
bility of regulatory limitations prior to use.
properties as shown in Table 1.
4.1.2 Type UVT—Material not subject to the light-absorbing
NOTE 2—There is no known ISO equivalent to this standard.
properties shown in Table 1.
2. Referenced Documents
4.2 Finish—Castings may be specified with the following
2
finishes:
2.1 ASTM Standards:
4.2.1 Finish 1—Rods, tubes, and shapes having a smooth
D542 Test Method for Index of Refraction of Transparent
surface finish obtained either in the casting process or by
Organic Plastics
highly polishing the surface.
D570 Test Method for Water Absorption of Plastics
4.2.2 Finish 2—Rods, tubes, and shapes having a rough,
D618 Practice for Conditioning Plastics for Testing
unfinished surface which may be frosted, abraded, sanded,
D638 Test Method for Tensile Properties of Plastics
machined, or as-cast.
D648 Test Method for Deflection Temperature of Plastics
Under Flexural Load in the Edgewise Position
NOTE 3—The sawed ends of Finish 1 and Finish 2 rods, tubes, and
D792 Test Methods for Density and Specific Gravity (Rela-
shapes are not polished.
tive Density) of Plastics by Displacement
5. General Requirements
D883 Terminology Relating to Plastics
5.1 Finish 1 and Finish 2 cast tubes are subject to the
following permissible variations from the specified dimen-
1
This specification is under the jurisdiction of ASTM Committee D20 on
sions:
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
5.1.1 Cast tubes shall be specified with either Type A or
Materials.
Type B wall thickness tolerances as listed in Table 2. Type A
Current edition approved Oct. 1, 2013. Published October 2013. Originally
tolerancesarespecifiedforapplicationswherewallthicknessis
approved in 1993. Last previous edition approved in 2008 as D5436 – 03(2008).
DOI: 10.1520/D5436-13.
critical to performance, otherwise Type B is generally speci-
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
fied.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
5.1.2 Cast tubes are subject to the outside-diameter toler-
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. ances listed in Table 3.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5436−13
TABLE 1 Detail Requirements for Cast Methacrylate Rods, Tubes, TABLE 4 Sizes and Permissible Length Tolerances for Cut-to-
and Shapes Length Cast Rod and Tube
Type UVA Type UVT Nominal Outside Permissible Length
Diameter, Tolerances,
Index of refraction, n , 23°C
D
mm (in.) ±, mm (in.)
min: 1.48 1.48
max: 1.50 1.50 up to 76 (3.0) 2 (0.079)
up to 280 (11.0) 3 (0.118)
Specific gravity, 23/23°C (73.4/73.4°F)
min: 1.18 1.18 greater than 280 (11.0
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5436 − 03 (Reapproved 2008) D5436 − 13
Standard Specification for
Cast Poly(Methyl Methacrylate) Plastic Rods, Tubes, and
1
Shapes
This standard is issued under the fixed designation D5436; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specification covers poly(methyl methacrylate) rods, tubes, and other shapes produced by casting or machining cast
blanks. This specification does not apply to heat-formed and molded or extruded parts and shapes, or sections that are made by
assembling or joining two or more pieces.
NOTE 1—The properties included in this specification are those required to identify the types and grades of materials covered. There may be other
requirements necessary to identify particular characteristics.
1.2 The values stated in SI units are to be regarded as standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
NOTE 2—There is no known ISO equivalent to this standard.
2. Referenced Documents
2
2.1 ASTM Standards:
D542 Test Method for Index of Refraction of Transparent Organic Plastics
D570 Test Method for Water Absorption of Plastics
D618 Practice for Conditioning Plastics for Testing
D638 Test Method for Tensile Properties of Plastics
D648 Test Method for Deflection Temperature of Plastics Under Flexural Load in the Edgewise Position
D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement
D883 Terminology Relating to Plastics
D1003 Test Method for Haze and Luminous Transmittance of Transparent Plastics
D1600 Terminology for Abbreviated Terms Relating to Plastics
D3892 Practice for Packaging/Packing of Plastics
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
3. Terminology
3.1 The terminology used in this specification is in accordance with Terminology D883 and Terminology D1600.
4. Classification
4.1 Types—This specification covers two types of cast methacrylate plastics:
4.1.1 Type UVA—Material having ultraviolet-lightabsorbing properties as shown in Table 1.
4.1.2 Type UVT—Material not subject to the light-absorbing properties shown in Table 1.
4.2 Finish—Castings may be specified with the following finishes:
1
This specification is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic Materials.
Current edition approved Nov. 1, 2008Oct. 1, 2013. Published December 2008October 2013. Originally approved in 1993. Last previous edition approved in 20032008
as D5436 – 03.D5436 – 03(2008). DOI: 10.1520/D5436-03R08.10.1520/D5436-13.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5436 − 13
TABLE 1 Detail Requirements for Cast Methacrylate Rods, Tubes,
and Shapes
Type UVA Type UVT
Index of refraction, n , 23°C
D
min: 1.48 1.48
max: 1.50 1.50
Specific gravity, 23/23°C (73.4/73.4°F)
min: 1.18 1.18
max: 1.20 1.20
Spectral transmittance, %, max
270 nm: 5 .
280 nm: 5 .
290 nm: 5 .
310 nm: 5 .
340 nm: 5 .
Luminous transmittance, %, min
up to 4.7 mm (0.187 in.) thickness: 91 91
25.4 mm (1.00 in.) thickness: 89 89
greater than 25.4 mm (1.00 in.) thickness: 87 87
Haze, %, max 3.0 3.0
Deflection temperature under load at 1820
kPa (264 psi), °C (°F) min.
<12.0 mm (0.472 in.) 87 (188.6) 87 (188.6)
>12.0 mm (0.472 in.)–24.0 mm (0.944 in.) 88 (190.4) 88 (190.4)
>24.0 mm (0.944 in.)–100 mm (3.937 in.) 93 (199.4) 93 (199.4)
Water absorption at 23°C
Gain in weight, 3.2 mm (0.125 in.) thick, %, 0.8 0.8
max
Tensile strength at 23°C (73.4°F), min, MPa 55 (8000) 55 (8000)
(psi)
Elongation
...

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SIGNIFICANCE AND USE
5.1 Molding and extruding plastic pellets require dust free, dry pellets to prevent processing problems. Plastic producers try to remove the dust and streamers with dust removal systems prior to packaging and loading. How to accurately measure dust and streamer content in plastic pellets is an important quality control issue.  
5.2 Particle size analysis is used to determine a percentage of particle size distribution from a representative sample of the whole. In terms of size analysis concerning plastic pellets, sieving is used to determine the dust content in the range of 500 to 2000 micron. Test Method D1921, Test Method B, is used to determine this type of particle sizing.  
5.3 After dry sieve analysis, particles smaller than 500 microns need to be analyzed by wet method. A fresh sample shall be used for wet analysis. This test method allows washing down the fines attached to the pellets by electrostatic forces.  
5.4 The wet analysis provides accurate quantification of small to large amounts of fines, negating static effects, and eliminating detrimental effects of mechanical agitation. A wet analysis must be employed to accurately quantify lower PPM dust levels in plastic pellets.
SCOPE
1.1 This test method measures the amount of fine particles adhered on plastic pellets or granules in which they are commonly produced and supplied. The lower limit of this test method is restricted only by the porosity of the filter disc used to capture the particle size being quantified.  
1.2 The wet analysis technique allows for separation and collection of statically charged particles by liquid wash and filtration methods. This must be performed under standard laboratory conditions.  
1.3 The values stated in SI units are to be regarded as standard.  
1.4 This test method describes an essential practice to check the quality of plastics once the production cycle is terminated and to evaluate the performance of pellet cleaning systems or of the special pneumatic conveying systems for the distinct size fractions below 500 micron only.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this standard.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D1562-22(Specification)
Standard Classification System and Basis for Specification for Cellulose Acetate Propionate Molding and Extrusion Compounds (CAP)

SCOPE
1.1 This classification system covers requirements for plasticized cellulose acetate propionate thermoplastic compounds suitable for injection molding and extrusion. These compounds have a propionyl content less than 48 % and an acetyl content less than 3 % and can contain dyes and pigments. Cellulosic plastic materials, being thermoplastic, are reprocessable and recyclable. This classification system allows for the use of those cellulosic materials, provided that all specific requirements of this classification system are met.  
1.2 The properties included in this classification system are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are specified by using the suffixes as given in Section 5.  
1.3 This classification system and subsequent line call out specification are intended to provide a means of calling out plastic materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be made by those having expertise in the plastic field only after careful consideration of the design and performance required of the part, environment to which it will be exposed, fabrication process to be employed, costs involved, and inherent properties of the material other than those covered by this classification system.  
1.4 The values stated in SI units are to be regarded as standard.  
1.5 The following safety hazards caveat pertains only to the test method portion, Section 11, of this classification system. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this standard.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D5336-22(Specification)
Standard Classification System and Basis for Specification for Polyphthalamide (PPA) Injection Molding Materials

ABSTRACT
This specification covers the classification, testing, and requirements of polyphthalamide (PPA) materials, both virgin and recycled, suitable for injection molding. This specification is intended to be a means of calling out plastics materials used in the fabrication of end items or parts, and not for the selection of materials. The materials are classified into groups according to crystallinity, and are further subdivided into classes and grades as specified. Materials shall be sampled, prepared, and conditioned appropriately for testing, for which specimens shall conform to specified values of the following requirements: inherent viscosity; melting temperature; glass transition; tensile strength; flexural strength and modulus; Izod impact strength; deflection temperature; and moisture.
SCOPE
1.1 This classification system covers polyphthalamide (PPA) materials suitable for injection molding.  
1.2 The properties included in this classification system are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are to be specified by using suffixes as given in Section 5.  
1.3 This classification system allows for the use of recycled materials provided that all specification requirements are met.  
1.4 This classification system is intended to be a means of calling out plastics materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be made by those having expertise in the plastics field only after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this classification system.  
1.5 The values stated in SI units are to be regarded as the standard (see IEEE/ASTM SI-10). The values given in parentheses are for information only.  
1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of this classification system: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 11.7.1.
Note 1: There is no known ISO equivalent to this standard. ISO 16396-1/-2 for polyamides may also be used to describe and classify these PPA materials, but the technical content is significantly different.
Note 2: ASTM Standard D6779 on polyamide materials also includes PPA materials in its coverage of various polyamide chemistries. This standard gives additional information for classification and specification for PPA compositions classified as Group 10 (PA6T/66), Group 12 (PA6T/6I/66) and Group 13 (PA6T/6I) in ASTM Standard D6779 and includes provisions for other PPA compositions to utilize the classification presented.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D3294-22(Specification)
Standard Specification for Polytetrafluoroethylene (PTFE) Resin Molded Sheet and Molded Basic Shapes

ABSTRACT
This specification establishes the requirements and test methods for the material, dimensions, and workmanship, and the physical and electrical properties of molded sheet manufactured from polytetrafluoroethylene (PTFE) resin molding materials and molded basic shapes made from resin molding and extrusion materials. The sheet or molded basic shape shall be made from unpigmented PTFE and shall be free from foreign matters. Each of the samples shall undergo visual and dimensional inspection to verify their compliance with the standard requirements. The specimens shall conform to the following physical and electrical property requirements: tensile strength; elongation; dielectric strength; specific gravity; porosity; and melting point. Examination for internal defects shall also be conducted to ensure that the specimens are free from microscopic cracks, voids, inclusions, and other surface defects that might affect the serviceability of the materials.
SCOPE
1.1 This specification establishes requirements and methods of test for the material, dimensions, and workmanship, and the physical and electrical properties of molded sheet in minimum thicknesses of 0.794 mm (1/32 in.) manufactured from PTFE resin molding materials defined in Specification D4894.  
1.2 This specification also establishes requirements for molded basic shapes made from molding materials. This specification is for products 300 mm (12 in.) or less in a dimension parallel to and 12.7 mm (0.5 in.) or greater in the dimension perpendicular to the direction of the applied molding pressure.  
1.3 The values stated in SI units are to be regarded as the standard.  
1.4 The following precautionary caveat pertains only to the test method portion, Section 7, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Special attention is called to 13.2, 13.3, 13.6, 13.8, and A1.  
Note 1: There is no known ISO equivalent to this standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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