ASTM D7825-12

Standard Guide for Generating a Process Stream Property Value through the Application of a Process Stream Analyzer

SIGNIFICANCE AND USE
4.1 The standards employed in the Process Stream Analyzer PSPV Generation Flow Diagram each have a specific deliverable that when combined into a single system produces a PSPV enabling the representation of product by process stream analyzer.  
4.2 The description of each standard in the process provides the user with an overview of the application of the standard in the process for developing a PSPV.
SCOPE
1.1 This guide covers and provides a workflow overview of the necessary steps related to generating a Process Stream Property Value obtained from the application of a process stream analyzer.  
1.2 Generating a Process Stream Property Value from the application of a process stream analyzer requires the use of several ASTM standards. These standards describe procedures to collect a representative sample, establish and validate the relationship to the primary test method, and calculate a property value with an expected uncertainty. Each standard builds or prepares data, or both, to be used in another standard. The workflow process culminates to produce a process stream analyzer result that represents a user defined batch of product. The sequence in which the standards are to be utilized is defined in this guide.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 31-Oct-2012
• ICS: 25.040.40 - Industrial process measurement and control
• Technical Committee: D02 - Petroleum Products, Liquid Fuels, and Lubricants
• Drafting Committee: D02.25 - Performance Assessment and Validation of Process Stream Analyzer Systems

Relations

• Replaced By: ASTM D7825-18 - Standard Practice for Generating a Process Stream Property Value through Application of a Process Stream Analyzer
• Effective Date: 01-Oct-2018
• Referred By: ASTM D8340-22 - Standard Practice for Performance-Based Qualification of Spectroscopic Analyzer Systems
• Effective Date: 01-Nov-2012

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D7825 − 12
Standard Guide for
Generating a Process Stream Property Value through the
1
Application of a Process Stream Analyzer
This standard is issued under the fixed designation D7825; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope and Control Charting Techniques to Evaluate Analytical
Measurement System Performance
1.1 This guide covers and provides a workflow overview of
D6624 Practice for Determining a Flow-Proportioned Aver-
the necessary steps related to generating a Process Stream
age Property Value (FPAPV) for a Collected Batch of
Property Value obtained from the application of a process
Process Stream Material Using Stream Analyzer Data
stream analyzer.
D6708 Practice for Statistical Assessment and Improvement
1.2 Generating a Process Stream Property Value from the
of Expected Agreement Between Two Test Methods that
application of a process stream analyzer requires the use of
Purport to Measure the Same Property of a Material
several ASTM standards. These standards describe procedures
D7235 GuideforEstablishingaLinearCorrelationRelation-
to collect a representative sample, establish and validate the
ship Between Analyzer and Primary Test Method Results
relationship to the primary test method, and calculate a
Using Relevant ASTM Standard Practices
property value with an expected uncertainty. Each standard
D7278 GuideforPredictionofAnalyzerSampleSystemLag
builds or prepares data, or both, to be used in another standard.
Times
The workflow process culminates to produce a process stream
D7453 Practice for Sampling of Petroleum Products for
analyzer result that represents a user defined batch of product.
Analysis by Process Stream Analyzers and for Process
The sequence in which the standards are to be utilized is
Stream Analyzer System Validation
defined in this guide.
D7808 Practice For Determining the Site Precision of a
1.3 This standard does not purport to address all of the Process Stream Analyzer on Process Stream Material
safety concerns, if any, associated with its use. It is the
E1655 Practices for Infrared Multivariate Quantitative
responsibility of the user of this standard to establish appro- Analysis
priate safety and health practices and determine the applica-
E2617 Practice for Validation of Empirically Derived Mul-
bility of regulatory limitations prior to use.
tivariate Calibrations
2. Referenced Documents
3. Terminology
2
2.1 ASTM Standards:
3.1 Definitions—Please refer to the individually cited
D3764 Practice forValidation of the Performance of Process
ASTM standards for definitions.
Stream Analyzer Systems
3.2 Acronyms:
D4177 Practice for Automatic Sampling of Petroleum and
3.2.1 FPAPV(s)—Flow Proportional Average Property Val-
Petroleum Products
D6122 Practice for Validation of the Performance of Multi- ue(s)
variate Online, At-Line, and Laboratory Infrared Spectro-
3.2.2 MLR—Multilinear Regression
photometer Based Analyzer Systems
3.2.3 PCR—Principal Components Regression
D6299 Practice for Applying Statistical Quality Assurance
3.2.4 PLS—Partial Least Squares
1
3.2.5 PSPV(s)—Process Stream Property Value(s)
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
3.2.6 PTM—Primary Test Method
Subcommittee D02.25 on Performance Assessment and Validation of Process
Stream Analyzer Systems.
3.2.7 PTMR(s)—Primary Test Method Result(s)
Current edition approved Nov. 1, 2012. Published February 2013. DOI: 10.1520/
D7825-12.
3.2.8 PPTMR(s)—Predicted Primary Test Method Result(s)
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
3.2.9 QC—Quality Control
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. 3.2.10 UAR(s)—Uncorrected Analyzer Result(s)
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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D7825 − 12
4. Significance and Use 5. Flow Diagram and Work Process
4.1 The standards employed in the Process StreamAnalyzer
5.1 Aflow chart showing the process for generating a PSPV
PSPV Generation Flow Diagram each have a specific deliver-
is shown in Fig. 1.
ablethatwhencombinedintoasinglesystemproducesaPSPV
5.2 The various standards shown in the flow chart are
enabling the representation of product by process stream
applied in sequence, building on the results of the previous
analyzer.
standards. The end result
...