Standard Specification for High Octane Unleaded Test Fuel

ABSTRACT
This specification covers formulating specifications for purchases of a high octane unleaded test fuel under contract and is intended solely for use by purchasing agencies for testing purposes. This specification also defines a specific type of high octane unleaded test fuel for use as an aviation spark-ignition fuel. A new high-octane unleaded test fuel has been developed, which maintains the key performance parameters of existing reciprocating aircraft engines.
SCOPE
1.1 This specification covers formulating specifications for purchases of a high octane unleaded test fuel under contract and is intended solely for use by purchasing agencies for testing purposes.  
1.2 This specification defines a specific type of high octane unleaded test fuel for use as an aviation spark-ignition fuel.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

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Publication Date
30-Apr-2011
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ASTM D7719-11 - Standard Specification for High Octane Unleaded Test Fuel
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D7719 – 11
Standard Specification for
High Octane Unleaded Test Fuel
This standard is issued under the fixed designation D7719; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
This new test fuel specification is for a high-octane unleaded fuel to be used for gathering data
toward a commercial research report and specification on an unleaded high-octane aviation gasoline.
A new high-octane unleaded test fuel has been developed which maintains the key performance
parameters of existing reciprocating aircraft engines. The two essential performance parameters of
MON and VP are inversely related with respect to composition and thus can uniquely define a
composition range of the two components. The values for VPand MON in Table 1 reflect the limiting
values of the two components. The binary fuel exhibits a higher volumetric energy density (net heat
of combustion times density) which is of great performance interest, although not explicitly stated in
Table 1. The distillation parameters reflect the binary compositional effects. This is an unleaded fuel,
so the limit of TEL in Table 1 is the same as is used in Specification D4814 for mogas and is meant
to mitigate unintentional contamination by TEL. Lastly, references to dyes remain in the specification
so that test groups may use them as necessary.
1. Scope D873 Test Method for Oxidation Stability ofAviation Fuels
(Potential Residue Method)
1.1 This specification covers formulating specifications for
D1094 Test Method for Water Reaction of Aviation Fuels
purchases of a high octane unleaded test fuel under contract
D1266 Test Method for Sulfur in Petroleum Products
and is intended solely for use by purchasing agencies for
2 (Lamp Method)
testing purposes.
D1298 Test Method for Density, Relative Density (Specific
1.2 This specification defines a specific type of high octane
Gravity), or API Gravity of Crude Petroleum and Liquid
unleaded test fuel for use as an aviation spark-ignition fuel.
Petroleum Products by Hydrometer Method
1.3 The values stated in SI units are to be regarded as
D2386 Test Method for Freezing Point of Aviation Fuels
standard. No other units of measurement are included in this
D2622 Test Method for Sulfur in Petroleum Products by
standard.
Wavelength Dispersive X-ray Fluorescence Spectrometry
2. Referenced Documents
D2624 TestMethodsforElectricalConductivityofAviation
and Distillate Fuels
2.1 ASTM Standards:
D2700 Test Method for Motor Octane Number of Spark-
D86 Test Method for Distillation of Petroleum Products at
Ignition Engine Fuel
Atmospheric Pressure
D3237 Test Method for Lead in Gasoline by Atomic Ab-
D130 Test Method for Corrosiveness to Copper from Pe-
sorption Spectroscopy
troleum Products by Copper Strip Test
D4052 Test Method for Density, Relative Density, and API
D323 Test Method for Vapor Pressure of Petroleum Prod-
Gravity of Liquids by Digital Density Meter
ucts (Reid Method)
D4057 Practice for Manual Sampling of Petroleum and
Petroleum Products
This specification is under the jurisdiction of ASTM Committee D02 on
D4171 Specification for Fuel System Icing Inhibitors
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
D4177 Practice for Automatic Sampling of Petroleum and
D02.J0 on Aviation Fuels.
Petroleum Products
Current edition approved May 1, 2011. Published May 2011. DOI: 10.1520/
D7719–11.
D4306 Practice for Aviation Fuel Sample Containers for
Supporting data have been filed at ASTM International Headquarters and may
Tests Affected by Trace Contamination
be obtained by requesting Research Report RR:D02-1721.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D7719 – 11
D4809 Test Method for Heat of Combustion of Liquid 5. Classification
Hydrocarbon Fuels by Bomb Calorimeter (Precision
5.1 One grade of high octane unleaded test fuel is provided,
Method)
known as UL102.
D4814 Specification for Automotive Spark-Ignition Engine
Fuel 6. Materials and Manufacture
D5006 Test Method for Measurement of Fuel System Icing
6.1 High octane unleaded test fuel, except as otherwise
Inhibitors (Ether Type) in Aviation Fuels
specified in this specification, shall consist of blends of refined
D5059 Test Methods for Lead in Gasoline by X-Ray Spec-
reformate hydrocarbons. The sources for these hydrocarbons
troscopy
include biomass, natural gas, or crude petroleum.
D5190 Test Method for Vapor Pressure of Petroleum Prod-
6.1.1 SeeAppendixX1foroneparticularcompositionbeing
ucts (Automatic Method)
test that meets the parameters of Table 1.
D5191 Test Method for Vapor Pressure of Petroleum Prod-
6.2 Additives—These can be added to each grade of high-
ucts (Mini Method) octane unleaded aviation fuel in the amount, and of the
E29 Practice for Using Significant Digits in Test Data to composition, specified in the following list of approved mate-
Determine Conformance with Specifications rials:
6.2.1 Dyes—Thetotalmaximumconcentrationofdyeinthe
fuel is 6.0 mg/L.
3. Terminology
6.2.1.1 The only blue dye present in the finished fuel shall
3.1 Definitions:
be essentially 1,4-dialkylaminoanthraquinone.
3.1.1 aviation gasoline fuel, n—fuel possessing specific
6.2.1.2 The only yellow dyes in the finished fuel shall be
properties suitable for operating aircraft powered by recipro-
essentially p-diethylaminoazobenzene (Color Index No.
cating spark-ignition engines.
11021) or 1,3-benzenediol 2,4-bis [(alkylphenyl)azo-].
3.1.2 binary, adj—characterized by, or consisting of, two
6.2.1.3 The only red dye present in the finished fuel shall be
components.
essentially alkyl derivatives of azobenzene-4-azo-2-naphthol.
3.1.3 biomass, n—plant material, vegetation, or agricultural
6.2.1.4 Theonlyorangedyepresentinthefinishedfuelshall
waste used as a fuel or energy source.
be essentially benzene-azo-2-napthol (Color Index No. 12055).
3.1.4 high-octane, adj—possessing a motor octane number
6.2.2 Other Additives—These may be added in the amount
(MON) greater than 100.
and of the composition specified in the following list of
approved materials. The quantities and types shall be declared
4. General
by the manufacturer. Additives added after the point of
4.1 Thisspecification,unlessotherwiseprovided,prescribes manufacture shall also be declared.
the required properties of a binary aviation fuel at the time and 6.2.2.1 Antioxidants—The following oxidation inhibitors
place of delivery. may be added to the fuel separately, or in combination, in total
TABLE 1 Detailed Requirements for High Octane Unleaded Test Fuel
Octane Ratings Grade UL102 ASTM Test Method
Knock value, Motor Octane Number min 102.2 D2700
Density at 15°C, kg/m3 min 790
D1298 or D4052
max 825
Distillation D86
Initial boiling point, °C Report D86
Fuel Evaporated D86
10 volume % at °C max 75 D86
40 volume % at °C min 75 D86
50 volume % at °C max 165 D86
90 volume % at °C max 165 D86
Final boiling point, °C max 180 D86
Sumof10%+50% evaporated temperatures, °C min 135 D86
Recovery, volume % min 97 D86
Residue, volume % max 1.5 D86
Loss, vol
...

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