ASTM D4837-02
(Specification)Standard Specification for Propylene Glycol Monomethyl Ether
Standard Specification for Propylene Glycol Monomethyl Ether
SCOPE
1.1 This specification covers propylene glycol monomethyl ether (PM).
Note 1—Propylene glycol monomethyl ether (PM) is a mixture of two isomers: 1-methoxy-2-propanol and 2-methoxy-1-propanol.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet for materials listed in this standard.
General Information
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Standards Content (Sample)
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 4837 – 02
Standard Specification for
1
Propylene Glycol Monomethyl Ether
This standard is issued under the fixed designation D 4837; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
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1. Scope * Determine Conformance with Specifications
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E 300 Practice for Sampling Industrial Chemicals
1.1 This specification covers propylene glycol monomethyl
2.2 U.S. Federal Specification:
ether (PM).
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
NOTE 1—Propylene glycol monomethyl ether (PM) is a mixture of two 6
of
isomers: 1-methoxy-2-propanol and 2-methoxy-1-propanol.
3. Properties
1.2 The following applies to all specified limits in this
standard; for purposes of determining conformance with this
3.1 Propylene glycol monomethyl ether (PM) shall conform
standard, an observed value or a calculated value shall be
to the following requirements:
rounded off “to the nearest unit” in the last right-hand digit
Purity, min, weight % 99.0
Apparent specific gravity:
used in expressing the specification limit, in accordance with
20/20°C 0.922 to 0.925 or
the rounding-off method of Practice E 29.
25/25°C 0.918 to 0.921
1.3 For specific hazard information and guidance, consult
Color, platinum cobalt scale, max 10
Water, max, weight % 0.25
the supplier’s Material Safety Data Sheet for materials listed in
Distillation Range:
this standard.
Initial boiling point, °C min 117
Dry point, °C max 125
A
2. Referenced Documents
Acidity (free acid acetic acid), max, weight % 0.01
A
2.1 ASTM Standards:
Equivalent to 0.1 mg of potassium hydroxide (KOH) per gram of specimen.
D 268 Guide for Sampling and Testing Volatile Solvents
4. Sampling
and Chemical Intermediates for Use in Paint and Related
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4.1 The material shall be sampled in accordance with
Coatings and Material
Practice E 300.
D 1078 Test Method for Distillation Range of Volatile
2
Organic Liquids
5. Test Methods
D 1209 Test Method for Color of Clear Liquids (Platinum-
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5.1 The properties enumerated in this specification shall be
Cobalt Scale)
determined in accordance with the following test methods:
D 1364 Test Method for Water in Volatile Solvents (Karl
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5.1.1 Apparent Specific Gravity—Determine the apparent
Fischer Reagent Titration Method)
specific gravity by any convenient method that is accurate to
D 1613 Test Method for Acidity in Volatile Solvents and
the third decimal place, the temperature of both specimen and
Chemical Intermediates Used in Paint, Varnish, Lacquer,
2
water being 20°C or 25°C. See Guide D 268 and Test Method
and Related Products
D 4052.
D 4052 Test Method for Density and Relative Density of
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5.1.2 Color—Test Method D 1209.
Liquids by Digital Density Meter
5.1.3 Gas Chromatographic Method—Test Method D 4773.
D 4773 Test Method for Purity of Propylene Glycol
5.1.4 Water—Test Method D 1364.
Monomethy
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