ASTM C757-06(2011)e1
(Specification)Standard Specification for Nuclear-Grade Plutonium Dioxide Powder, Sinterable
Standard Specification for Nuclear-Grade Plutonium Dioxide Powder, Sinterable
ABSTRACT
This specification covers sinterable nuclear-grade plutonium dioxide powders obtained by the oxalate precipitation route, calcination, or any other equivalent process acceptable to the buyer. Included is plutonium dioxide of various isotopic compositions as normally prepared by in-reactor neutron irradiation of natural or slightly enriched uranium, or recycled plutonium mixed with uranium. The material shall conform to required chemical compositions of plutonium, uranium, americium, impurities (boron, cadmium, carbon, chlorine, chromium, fluorine, iron, gadolinium, nickel, nitride nitrogen, and thorium), equivalent boron, and gamma activity. Materials shall also adhere to physical property requirements as to cleanliness and workmanship, particle size, and surface area.
SCOPE
1.1 This specification covers nuclear grade plutonium dioxide, sinterable powder obtained by the oxalate precipitation route, calcined above 500°C, or any other equivalent process acceptable to the buyer. Included is plutonium dioxide of various isotopic compositions as normally prepared by in-reactor neutron irradiation of natural or slightly enriched uranium or by in-reactor neutron irradiation of recycled plutonium mixed with uranium.
1.2 There is no discussion of or provision for preventing criticality incidents, nor are health and safety requirements, the avoidance of hazards, or shipping precautions and controls discussed. Observance of this specification does not relieve the user of the obligation to be aware of and conform to all national and local regulations on processing, shipping, or using source or special nuclear materials. For examples in the U.S. Government, relevant documents are Code of Federal Regulations, Title 10 Nuclear Safety Guide, U.S. Atomic Energy Commission Report TID-7016 , and “Handbook of Nuclear Safety”, H. K. Clark, U.S. Atomic Energy Commission Report, DP-532 .
1.3 The PuO2 shall be produced by a qualified process and in accordance with a quality assurance program approved by the user.
1.4 The values stated in SI units are to be regarded as the standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
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Designation:C757 −06(Reapproved 2011)
Standard Specification for
Nuclear-Grade Plutonium Dioxide Powder, Sinterable
This standard is issued under the fixed designation C757; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
´ NOTE—Section 4.6 was changed editorially in June 2011.
INTRODUCTION
This specification is intended to provide the nuclear industry with a general standard for sinterable
plutonium dioxide powder. It recognizes the diversity of manufacturing methods by which plutonium
dioxide powders are produced, and the many special requirements for chemical and physical
characterization that may be imposed by the end use of the powder in a specific reactor system. It is,
therefore, anticipated that the buyer may supplement this specification with more stringent or
additional requirements for specific applications.
1. Scope 1.4 The values stated in SI units are to be regarded as the
standard.
1.1 This specification covers nuclear grade plutonium
1.5 This standard does not purport to address all of the
dioxide, sinterable powder obtained by the oxalate precipita-
safety concerns, if any, associated with its use. It is the
tion route, calcined above 500°C, or any other equivalent
responsibility of the user of this standard to establish appro-
process acceptable to the buyer. Included is plutonium dioxide
priate safety and health practices and determine the applica-
of various isotopic compositions as normally prepared by
bility of regulatory limitations prior to use.
in-reactor neutron irradiation of natural or slightly enriched
uranium or by in-reactor neutron irradiation of recycled pluto-
2. Referenced Documents
nium mixed with uranium.
2.1 ASTM Standards:
1.2 There is no discussion of or provision for preventing
C697 Test Methods for Chemical, Mass Spectrometric, and
criticality incidents, nor are health and safety requirements, the
Spectrochemical Analysis of Nuclear-Grade Plutonium
avoidance of hazards, or shipping precautions and controls
Dioxide Powders and Pellets
discussed. Observance of this specification does not relieve the
C1233 Practice for Determining Equivalent Boron Contents
useroftheobligationtobeawareofandconformtoallnational
of Nuclear Materials
and local regulations on processing, shipping, or using source
C1295 Test Method for Gamma Energy Emission from
or special nuclear materials. For examples in the U.S.
Fission Products in Uranium Hexafluoride and Uranyl
Government, relevant documents are Code of Federal
Nitrate Solution
Regulations, Title 10 Nuclear Safety Guide, U.S. Atomic
2.2 ANSI Standard:
Energy Commission Report TID-7016 , and “Handbook of
ANSI/ASME NQA-1 Quality Assurance Requirements for
Nuclear Safety”, H. K. Clark, U.S. Atomic Energy Commis-
Nuclear Facility Applications
sion Report, DP-532 .
2.3 U.S. Government Documents:
1.3 The PuO shall be produced by a qualified process and
Code of Federal Regulations, Title 10, Nuclear Safety
in accordance with a quality assurance program approved by
Guide, U.S. Atomic Energy Commission Report TID-
the user.
“Handbook of Nuclear Safety,” Clark, H. K., U.S. Atomic
Energy Commission Report, DP-532
This specification is under the jurisdiction of ASTM Committee C26 on
Nuclear Fuel Cycle and is the direct responsibility of Subcommittee C26.02 on Fuel
and Fertile Material Specifications. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
CurrenteditionapprovedJune1,2011.PublishedJuly2011.Originallyapproved contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
in 1974. Last previous edition approved in 2006 as C757 – 06. DOI: 10.1520/ Standards volume information, refer to the standard’s Document Summary page on
C0757-06R11E01. the ASTM website.
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Available from Superintendent of Documents, U.S. Government Printing Available from American National Standards Institute, 11 W. 42nd St., 13th
Office, Washington, DC 20402. Floor, New York, NY 10036.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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C757−06 (2011)
2.4 ISO Standard: lives of 30 days or greater shall be measured. The gamma
ISO 8300 Determination of Pu Content in Plutonium Diox- radiation from fission products shall be less than 10
ide (PuO ) of Nuclear Grade Quality, Gravimetric MeV·Bq/g Pu.
Method 4.7.1 The list of nuclides and mean energies per disintegra-
tion found in Test Method C1295 are to be used in the
3. Isotopic Content
calculations.
3.1 Concentrations and homogeneity ranges of the pluto-
5. Physical Properties
nium isotopes shall be as specified by the buyer.
5.1 Cleanliness and Workmanship—The PuO powder shall
3.2 The isotopic composition of the final product shall be
be free of visible fragments of foreign matter.
determined by mass spectrometry and shall be reported on a
weight basis.
5.2 Particle Size—All the PuO powder shall be capable of
passinga100µmsieveand95 %ofthepowderbyweightshall
4. Chemical Composition
be capable of passing a 44 µm sieve.
4.1 Plutonium Content—The minimum Pu content shall be
5.3 SurfaceArea—Thespecificsurfaceareashallnotbeless
86.0 weight % as sampled on the date of sampling and 87.5
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than 5 m /g and not greater than 30 m /g based on a Brunauer,
weight % after heating4hto 950°C.
Emmett, Teller (BET) adsorption method. See Notes 1 and 2.
4.2 Uranium Content—The uranium content of the pluto-
NOTE 1—A specific surface area as low as 2 m /g has been demon-
nium dioxide shall be measured and reported on a plutonium strated to be acceptable when subsequently blended with other powder(s)
of greater specific surface area. Therefore, powder with a specific surface
basis.
area as low as 2 m /g may be acceptable if agreed upon between the
4.3 Americium Content—The ame
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